• Bulletin of the Korean Chemical Society
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• 제32권1호
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• pp.291-295
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• 2011

The catalytic enantioselective conjugate addition reaction of $\alpha$-nitroacetate to $\alpha,\beta$-unsaturated enones promoted by chiral bifunctional organocatalysts is described. The treatment of $\alpha$-nitroacetate to $\alpha,\beta$-unsaturated enones afforded the corresponding Michael adducts with high enantioselectivity. The conjugate addition adducts are easily converted to chiral $\gamma$-nitro ketones and $\delta$-keto esters.

• 자원ㆍ환경경제연구
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• 제25권4호
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• pp.495-516
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• 2016

본 연구는 국제 원유가격의 변동에 따른 수송용 유류제품 가격의 비대칭성(rockets and feather)을 오차수정모형을 사용하여 분석한다. 회귀분석결과에 따르면, 모든 수송용 유류제품에서 비대칭성 현상이 일관성 있게 나타났으며, 특히 고급휘발유에서는 타 유종에 비해서 비용 상승기와 비용 하강기에 모두에서 비용의 변화의 충격에 민감하게 반응하는 것으로 추정되었다. 이는 비용상승기의 경우, 마진이 높은 고급휘발유의 특성상, 이를 빠르게 반영하는 것은 이윤극대화를 추구하는 기업의 합리적인 반응일 것으로 추정된다. 그러나 비용이 하락할 경우에 고급휘발유가 타 유종에 비해서 빠르게 하락하는 현상은, 고급휘발유 가격이 상승할 때, 일반휘발유로 이동했던 소비자들과 고급휘발유에 대한 잠재적 수요를 가진 일반 휘발유 소비자들을 고급휘발유 소비로 끌어들일 수 있는 유인이 존재하기 때문으로 판단된다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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• pp.199-199
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• 2011

The addition of a carbanion to ${\yen}{\acute{a}}{\yen}{\hat{a}}$-unsaturated carbonyl compounds is of importance in the C-C bond formation reactions for modern pharmaceuticals and organic synthesis. Recently, heterogeneous asymmetric catalysis became more attractive area of research because of the easy recovery and separation of the catalyst from the reaction system. Most of synthetic methods for heterogeneous catalysts were grafting or immobilization of homogeneous catalyst onto the solid supports. Trans-1,2-Diaminocyclohexane(DACH) and L-proline ligands have been enormously used as chiral ligands in several catalytic transformation under homogenous conditions. Our group prepared l-proline functionalized mesoporous silica was synthesized under acidic condition using a poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer template (EO20PO70EO20, Pluronic P-123, BASF). Furthermore, we successfully directly synthesized trans-1,2 diaminocyclohexane functionalized mesoporous silica by using microwave method. The direct functionalization of chiral ligand into the framework of mesoporous materials is expected to be useful for the heterogeneous asymmetric catalysis. So, we adopt the direct synthesis of chiral ligand functionalized mesoporous silica by using thermal and microwave irradiation. Then, chiral ligand functionalized mesoporous silicas were applied to enantioselective asymmetric catalytic reactions.

• Journal of Biosystems Engineering
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• 제42권3호
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• pp.127-135
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• 2017

Purpose: Purpose: The usability of a mathematical model modified for analysis of the static stability of an asymmetric tractor-harvester system was investigated. Method: The modified asynchronous mathematical model was validated through empirical experiments, and the effects of movements of the center of gravity (CG) coordinates on the stability against lateral overturning were analyzed through simulations. Results: Changes in the lateral overturning angle of the system were investigated when the coordinates of the CG of the system were moved within the variable range. The errors between simulation results and empirical experiments were compared, and the results were -4.7% at the left side overturning and -0.1% at the right side overturning. The asymmetric system was characterized in such a way that the right side overturning had an increase in overturning angle in the (+) variable range, while it had a decrease in overturning angle in the (-) variable range. In addition, the left side overturning showed an opposite result to that of the right side. At the declination angle (296<${\gamma}$<76), the right side overturning had an increase in the maximum overturning angle of 3.6%, in the minimum overturning angle of 20.3%, and in the mean overturning angle of 15.9%. Furthermore, at the declination angle (284<${\gamma}$<64), the left side overturning had a decrease in the maximum overturning angle of 29.2%, in the minimum overturning angle of 44%, and in a mean overturning angle of 39.7%. Conclusion: The modified mathematical model was useful for predicting the overturning angle of the asymmetric tractor-harvester system, and verified that a movement of the CG coordinates had a critical effect on its stability. In particular, the left side overturning was the most vulnerable to stability, regardless of the direction of declination angle.

• 한국광학회지
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• 제31권4호
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• pp.183-190
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• 2020

본 논문에서는 넓은 조사 면적에 단거리 조사시에도 균일한 조명도 분포를 가지도록 하는 비대칭 배광의 조명 광학계에 대한 연구를 진행하였다. 단거리에 설치되는 조명의 경우 조사 거리가 짧기 때문에 충분한 배광 분포 형성이 되지 못해 조명의 균일도를 만족하기 어렵다. 또한 시인성을 위해 조명기기가 기울어져 설치되기 때문에 비대칭 배광의 조명 설계가 요구된다. 이러한 문제점을 해결하기 위해 비대칭 배광을 가지는 조명 광학계 설계를 통해 근거리 조사 시에도 대상 표면에 균일한 조명도를 얻을 수 있었으며, 이를 근거리 조명 중 하나인 라이선스 램프에 적용하여 법규 기준을 만족하는 것을 확인하였다.

• 디지털콘텐츠학회 논문지
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• 제12권2호
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• pp.141-150
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• 2011

최근 다양한 기기에서 플래시 메모리 저장장치인 SSD가 활용되고 있다. SSD 기반 시스템에서 기존 하드 디스크 기반 버퍼 교체 알고리즘은 플래시 메모리의 특성을 고려하지 않고 이는 시스템의 성능 저하의 원인이 된다. 본 논문에서는 SSD의 특성을 고려하여 읽기 버퍼와 쓰기 버퍼를 분리하고 각각의 버퍼에 서로 다른 크기의 교체 단위와 서로 교체 알고리즘을 적용하는 ABM (Asymmetric Buffer Management) 정책을 제안한다. 추가적으로 제안한 정책을 보완하기 위해 쓰기 교체 지연 정책, 동적 크기 적응화 알고리즘을 적용하였다. 제안한 ABM 정책은 효과적으로 성능을 향상시키는 것으로 나타났으며, 특히 여러 알고리즘 중 가장 성능이 좋은 ABM-LRU-CLC의 경우 기존의 LRU에 비해 최대 32% 성능이 향상되는 것으로 나타났다.

• 대한통합의학회지
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• 제6권3호
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• pp.25-32
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• 2018

Purpose : This study investigated the effects of different types of plank exercise on abdominal muscle thickness in subjects with asymmetric pelvic anterior tilt. Methods : Participants with a diagnosis of pelvic anterior tilt were divided into an experimental group (n=12) and a control group (n=13). The thicknesses of the transverse abdominis (TrA), internal oblique (IO), and external oblique (EO) muscles were measured using an ultrasound diagnostic apparatus. The data were analyzed using an SPSS (Ver. 21) program. Results : In the experimental group, there was a significant difference in the thicknesses of the left and right muscles in the standing and elbow plank exercises (p<.05). All the muscle thicknesses increased significantly during the plank exercises(elbow plank, right-side plank, and left-side plank) as compared with those in the standing position (p<.05). In addition, the side-plank exercise resulted in significantly higher muscle thickness of the supported side (p<.01, p<.001). Conclusion : These findings suggest that asymmetric exercise should be applied to the change of the left and right muscles of the abdominal when applying plank exercise according to pelvic anterior tilt.

• 한국생산제조학회지
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• 제22권1호
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• pp.8-14
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• 2013

This paper intends to provide the whirling characteristics of an asymmetric rotor-shaft system with a non-ideal DC motor. The equations of motion have been derived in terms of system parameters such as the internal/external damping, the asymmetry and the motor voltage. By imposing the conditions that the motor input power should be balanced by the dissipated power, steadystate whirling characteristics are obtained such as the whirling amplitude, the whirling frequency and the stability diagrams. Results show that the whirling stability is affected by the internal/external damping and the asymmetry as well as the motor voltage. Also, the whirling amplitude at the steadystate is increased and the motor speed is lowered as the internal damping becomes higher or the external damping is reduced. In addition, the asymmetry causes the variation of the whirling orbit, which becomes splitted into two distinct trajectories. Finally, non-ideal characteristics of the DC motor is found to reduce the whirling motion in case of steadystate whirling with high asymmetry and high internal damping.

• Journal of Mechanical Science and Technology
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• 제14권12호
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• pp.1386-1395
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• 2000

The mear field structure of round turbulent jets with initially asymmetric velocity distributions is investigated experimentally. Experiments are carried out using a constant temperature hot-wire anemometry system to measure streamwise velocity in the jets. The measurements are undertaken across the jet at various streamwise stations in a range starting from the jet exit plane and up to a downstream location of twelve diameters. The experimental results include the distributions of mean and instantaneous velocities, vorticity field, turbulence intensity, and the Reynolds shear stresses. The asymmetry of the jet exit plane was obtained by using circular cross-section pipes with a bend upstream of the exit. There pipes used here include a straight pipe, and 90 and 160 degree-bend pipes. Therefore, at the upstream of the upstream of the pipe exit, secondary flow through the bend mean streamwise velocity distribution could be controlled by changing the curvature of pipes. The jets into the atmosphere have two levels of initial velocity skewness in addition to an axisymmetric jet from a straight pipe. In case of the curved pipe, a six diameter-long straight pipe section follows the bend upstream of the exit. The Reynolds number based on the exit bulk velocity is 13,400. The results indicate that the near field structure is considerably modified by the skewness of an initial mean velocity distribution. As the skewness increases, the decay rate of mean velocity at the centerline also increases.

• 정보처리학회논문지B
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• 제10B권6호
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• pp.619-628
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• 2003

본 논문에서는 웨이블릿 변환 영역에서 계수간의 특성을 이용한 효과적인 워터마크 검출 방법을 제안한다. 제안한 방법은 영상을 2단계 웨이블릿 변환 후 비가시성과 강인성을 고려하여 기저대역과 고주파 대역을 제외한 중간 대역에 이진 워터마크를 삽입하였다. 각종 공격으로 변형된 영상에서 워터마크론 효과적으로 김출하기 위해 계수 선택 임계치를 삽입시보다 검출시에 보다 높게 설정하는 비대칭 임계치 워터마킹 방법을 사용하였다. 또한 워터마크 검출시 선택된 웨이블릿 변환 계수 쌍의 차이가 일정 이하일 경우에 검출값을 그대로 유지하는 방법으로 검출 강도를 높였다. 실험 결과 제안한 방법은 비교적 우수한 화질에서 손실 JPEG 압축, 잡음 첨가, 클로핑, 블러링 등의 공격에 강임함을 알 수 있었다.