• The Transactions of the Korea Information Processing Society
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• v.3 no.1
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• pp.118-126
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• 1996

Memory hierarchy is a useful mechanism for improving the memory access speed and making the program space larger by layering the memories and separating program spaces from memory spaces. However, it needs at least two memory accesses for each data reference : a TLB(Translation Lookaside Buffer) access for the address translation and a data cache access for the desired data. If the cache size increases to the multiplication of page size and the cache associativity, it is difficult to access the TLB with the cache in parallel, thereby making longer the critical timing path in the processor. To achieve such parallel accesses, we present the hybrid mapped TLB which combines a direct mapped TLB with a very small fully-associative mapped TLB. The former can reduce the TLB access time. while the latter removes the conflict misses from the former. The trace-driven simulation shows that under given workloads the proposed TLB is effective even when a fully-associative mapped TLB with only four entries is added because the effects of its increased misses are offset by its speed benefits.

• Korean Journal of Biological Psychiatry
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• v.18 no.2
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• pp.80-89
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• 2011

Pavlovian fear conditioning has been extensively studied for the understanding of neurobiological basis of memory and emotion. Pavlovian fear conditioning is an associative memory which forms when conditioned stimulus (CS) is paired with unconditioned stimulus (US) once or repeatedly. This behavioral model is also important for the understanding of anxiety disorders such as posttraumatic stress disorder. Here we describe the neural circuitry involved in fear conditioning and the molecular mechanisms underlying fear memory formation. During consolidation some memories fade out but other memories become stable and concrete. Emotion plays an important role in determining which memories will survive. Memory becomes unstable and editable again immediately after retrieval. It opens the possibility for us of modulating the established fear memory. It provides us with very efficient tools to improve the efficacy of cognitive-behavior therapy and other exposure-based therapy treating anxiety disorders.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.80-83
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• 2007

In order to characterize the catalytically active sites on carbon black, acetylene chemisorption had been examined recently at 773 and 873 K by using a pulse technique. As the inject ion was repeated at 773 K, the adsorbed amount gradually decreased and eventually the adsorption did not occur any more. At 873 K a constant amount of $C_2H_2$ was consumed repeatedly after several injections. Good linear relationships were obtained between the methane decomposition rate at 1123 or 1173 K and the cumulative acetylene adsorption at 773 K or the constant acetylene consumption at 873 K. Reasonable models for the associative acetylene chemisorption at 773 K and the constant acetylene consumption at 873 K on the armchair face at the edges of graphene layers were proposed. The constant consumpt ion may be explained by the "$C_2H_2$-addition-hydrogen- abstract ion (CAHA)" mechanism.

• The Korean Journal of Food And Nutrition
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• v.5 no.1
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• pp.23-32
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• 1992

Kinetic studies of nucleophilic substitution reactions of dansyl, bansyl, dabsyl chlorides with pyridines have been investigated at $0^{\circ}C$ in a range of methanol-acetonitrile binary solvent mixtures. The order of magnitude for reactivity of substrates with pyridines in the same reaction condition is dabsyl chloride>dansyl chloride> bansyl chloride. The value of $\rho$n(-2.29~ -4.66) and $\beta$(0.537~0.901) associated with a change substituent in the nucleophile are large and indicate a relatively advanced bond formation in the transition state. Solvatochromic correlations were predicted the increase of bond formation transition state according to the increasing MeCN contents, showing the greater contribution of polarity polarizability ($\pi$*) than hydro-gen bond donar acidity($\alpha$). We conclude that the reactions of dansyl, bansyl, dabsyl chlorides with pyridines proceed via associative Sn2 type reaction mechanism.

• Proceedings of the Korean Information Science Society Conference
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• 2003.10a
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• pp.223-225
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• 2003

본 논문은 서로 다른 두 구조의 캐쉬와 새로운 뱅크선별기를 이용하여, 보다 효율적인 뱅크관리 메커니즘을 응용한 새로운 개념의 캐쉬 구조에 대한 설명을 한다. 크기가 작음에도 불구하고, 낮은 접근 실패율(Miss ratio)와 높은 저전력 효과는 기존의 일반적인 직접사상 캐쉬와 비교했을 때, 성능면에서 월등한 차이를 나타내고 있다. 이러한 결과의 원인은 직접사상 캐쉬와 완전연관 버퍼의 최적화된 구성과. 효과적인 뱅크선별기를 사용하여 적은 전력에도 높은 성능을 발휘하는 새로운 메커니즘을 사용하였기 때문이다. 제안한 구조의 성능은 다양한 크기의 직접사상 캐쉬와 비교하였으며, 접근 실패율, 평균 메모리 접근 시간, 전력소비, Energy * Delay Product 등 모두 4가지의 지표를 사용하였다.

• Bulletin of the Korean Chemical Society
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• v.20 no.5
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• pp.573-576
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• 1999

The rate constants and kinetic solvent isotope effects (KSIE, KMeOH/kMeOD) for solvolyses of para-substituted phenylchloroformates in CH3OH, CH3OD, H2O, D2O, 50% D2O-CH3OD were determined at 15.0 and 25.0℃ using conductometric method. Kinetic solvent isotope effects for the solvolyses of para-substituted phenyl chloroformates were 2.39-2.51, 2.21-2.28, and 1.67-1.69 for methanol, 50% aqueous methanol, and water, respectively. The slopes of Hammett plot for solvolysis of para-substituted phenyl chloroformates in methanol, 50% aqueous methanol, and water were 1.49, 1.17 and 0.89, respectively. The Hammett type plot of KSIE, log (KSIE) versus p, can be a useful mechanistic tool for solvolytic reactions. The slopes of such straight lines for para-substituted phenyl chloroformates are almost zero in methanol, 50% aqueous methanol, and water. It was shown that the reaction proceeds via an associative SN2 and/or general base catalysis addition-elimination (SAN) mechanism based on activation parameters, Hammett p values, and slopes of Hammett type plot of KS-IE.

• Bulletin of the Korean Chemical Society
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• v.12 no.3
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• pp.282-286
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• 1991

Kinetic studies of the reactions of benzyl benzenesulfonates with benzylamines in methanol and acetonitrile have been carried out. The reaction was found to proceed by a dissociative $S_N2$ in MeCN but by an associative $S_N2$ mechanism in MeOH. The transition state was rather loose in MeCN whereas it was tight in MeOH, in contrast to a tighter TS in MeCN for the corresponding reactions with aniline. The reaction of benzylamine in MeOH was characteristic of the highly solvated nucleophile, benzylamine, compared to the normal reaction in MeCN.

• The KIPS Transactions:PartA
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• v.16A no.2
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• pp.69-78
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• 2009

One of the most effective way to improve cache performance is to exploit both temporal and spatial locality given by any program executive characteristics. In this paper we present a high performance and low power cache structure with a bank selection mechanism that enhances exploitation of spatial and temporal locality. The proposed cache system consists of two parts, i.e., a main direct-mapped cache with a small block size and a fully associative buffer with a large block size as a multiple of the small block size. Especially, the main direct-mapped cache is constructed as two banks for low power consumption and stores a small block which is selected from fully associative buffer by the proposed bank selection algorithm. By using the bank selection algorithm and three state bits, We selectively extend the lifetime of those small blocks with high temporal locality by storing them in the main direct-mapped caches. This approach effectively reduces conflict misses and cache pollution at the same time. According to the simulation results, the average miss ratio, compared with the Victim and STAS caches with the same size, is improved by about 23% and 32% for Mibench applications respectively. The average memory access time is reduced by about 14% and 18% compared with the he victim and STAS caches respectively. It is also shown that energy consumption of the proposed cache is around 10% lower than other cache systems that we examine.

• Journal of the Korean Chemical Society
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• v.33 no.2
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• pp.164-167
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• 1989

The rate for the aquation of $trans-[Cr(tmd)_2FX]^+(X=F^-,\;Cl^-)$ ion in aqueous acidic solution has been measured by spectrophotometric method at various temperatures and pressures. The rate constants are increased with increasing temperatures and pressures. The values of activation entropy are 5.2 eu for $trans-[Cr(tmd)_2F_2]^+$ and -16.62 eu for $trans-[Cr(tmd)_2FCl]^+$ ions. Activation volumes have all negative values and lie in the limited range $-3∼-2\;cm^3mol^{-1}$ for $trans-[Cr(tmd)_2F_2]^+$ and $-8∼-7\;cm^3mol^{-1} for $trans-[Cr(tmd)_2FCl]^+$ ion. From the above results, we may deduce that the mechanism for the aquation of $trans-[Cr(tmd)_2F_2]^+$ and $trans-[Cr(tmd)_2FCl]^+$ ions is interchange-associative mechanism and dissociative mechanism respectively.

• Journal of KIISE:Computer Systems and Theory
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• v.27 no.11
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• pp.908-918
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• 2000

캐쉬의 성능을 향상시키는 가장 효과적인 방법은 프로그램 수행 특성에 내재되어 있는 시간적 (temporal locality) -공간적 지역성 (spatial locality)을 활용하는 것이다. 본 논문에서는 추가적인 장치나 컴파일러의 도움 없이 단지 캐쉬의 구조적인 특징과 간단한 메커니즘만을 이용하여 두 가지 타입의 지역성을 효과적으로 반영할 수 있는 새로운 캐쉬 시스템이 제안된다. 제안하는 새로운 캐쉬 시스템은 다른 블록 크기와 다른 연관도를 가지는 두 개의 캐쉬로써 구성되어 진다. 즉 작은 블록 크기를 지원하는 직접사상 캐쉬 (direct-mapped cache)와 큰 블록을 지원하는 완전 연관 버퍼 (fully-associative buffer)로 구성되어 진다. 큰 블록은 여러 개의 작은 블록으로 구성되어지며 두 캐쉬에서 접근 실패가 발생할 경우 직접사상 캐쉬의 접근 실패가 발생한 작은 블록과 그 이웃 작은 블록을 완전 연관 버퍼에 저장시킴으로써 한번 참조가 일어난 블록의 이웃 블록이 참조될 확률이 높다는 공간적 지역성의 특성을 효과적으로 반영할 수 있다. 또한 참조가 일어난 블록은 제어 비트를 사용하여 선택적으로 작은 블록을 직접사상 캐쉬에 저장함으로써 시간적 지역성을 보다 효과적으로 사용할 수 있다 시뮬레이션 결과에 따르면 기존의 직접사상 캐쉬의 4배 크기보다도 좋은 성능 향상을 보이고 있으며, 동일한 크기의 victim 캐쉬보다 우수한 성능을 보이고 소비 전력 면에서는 5% 정도의 전력 감소를 보이고 있다.