• KSBB Journal
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• v.24 no.1
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• pp.53-58
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• 2009

This study was focused on the investigation of the characteristics of TPH and BTEX removal in oil-contaminated sandy soil and fine soil with injection of microorganisms, nutrients, and surfactants. As the result of the experiments maintained moisture contents by 10${\sim}$20%, the TPH removal efficiency in oil-contaminated sandy soil was the highest in C-1 (microorganisms+nutrients), and the efficiency in C-2 (microorganisms+nutrients+surfactants) was higher than the efficiency in C-0(microorganisms). In 81 days, TPH removal efficiency in case of C-0, C-1 and C-2 showed 51%, 83%, 63% respectively. The results of D group with fine soil showed similar trends as C group, but the TPH removal efficiency of D group was lower than that of C group. Those of both C and D group were the highest in 1 group (microganisms+nutrients). The pH of fine soil was some lower than that of sandy soil or was similar to sandy soil. In 14 days, BTEX removal efficiency in case of C-0, C-1, C-2, D-0, D-1 and D-2 showed 99.8%, 99.4%, 96.0%, 99.5%, 99.2%, 96.3% respectively. Those of both C and D group were the highest in 0 group (microganisms).

• Membrane and Water Treatment
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• v.9 no.3
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• pp.137-146
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• 2018

Soil washing is one of the most frequently used remediation technologies for heavy metal-contaminated soils. Inorganic and organic acids and chelating agents that can enhance the removal of heavy metals from contaminated soils have been employed as soil washing agents. However, the toxicity, low removal efficiency and high cost of these chemicals limit their use. Given that humic substance (HS) can effectively chelate heavy metals, the development of an eco-friendly, performance-efficient and cost-effective soil washing agent using a nano-scale chelator composed of HS was examined in this study. Copper (Cu) and lead (Pb) were selected as target heavy metals. In soil washing experiments, HS concentration, pH, soil:washing solution ratio and extraction time were evaluated with regard to washing efficiency and the chelation effect. The highest removal rates by soil washing (69% for Cu and 56% for Pb) were achieved at an HS concentration of 1,000 mg/L and soil:washing solution ratio of 1:25. Washing with HS was found to be effective when the pH value was higher than 8, which can be attributed to the increased chelation effect between HS and heavy metals at the high pH range. In contrast, the washing efficiency decreased markedly in the low pH range due to HS precipitation. The chelation capacities for Cu and Pb in the aqueous phase were determined to be 0.547mmol-Cu/g-HS and 0.192mmol-Pb/g-HS, respectively.

• Journal of Soil and Groundwater Environment
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• v.14 no.5
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• pp.62-70
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• 2009

A field soil highly contaminated with petroleum hydrocarbons (JP-8 and diesel fuels) was employed for its remediation by a lab-scale thermal desorption process. The soil was collected in the vicinity of an underground storage tank in a closed military base and its contamination level was as high as 4,476 ppm as total petroleum hydrocarbon (TPH). A lab scale directly-heated low temperature thermal desorption (LTTD) system of 10-L capacity was developed and operated for the thermal treatment of TPH contaminated soils in this study. The desired operation temperature was found to be approximately $200-300^{\circ}C$ from the thermal gravimetric analysis of the contaminated field soils. The removal efficiencies higher than 90% were achieved by the LTTD treatment at $200^{\circ}C$ for 10 min as well as at $300^{\circ}C$ for 5 min. As the water content in the soils increased and therefore they were likely to be present as lumps, the removal efficiency noticeably decreased, indicating that a pre-treatment such as field drying should be required. The analysis of physical and chemical properties of soils before and after the LTTD treatment demonstrated that no significant changes occurred during the thermal treatment, supporting no needs for additional post-treatments for the soils treated by LTTD. The results presented in this study are expected to provide useful information for the field application and verification of LTTD for the highly contaminated geo-environment.

• Journal of Soil and Groundwater Environment
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• v.15 no.6
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• pp.53-63
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• 2010

Pneumatic fracturing is an emerging tool to enhance the remediation efficiency of contaminated unsaturated zones by injecting high pressure air and inducing artificial fracture networks. Pneumatic fracturing is reported to be well suited for the cases where the contaminated unsaturated zone thickness is less than 5 m as many contaminated domestic sites in Korea. Nevertheless, there have been almost no studies carried out on the site-specific efficiency and the optimized design of pneumatic fracturing considering the unsaturated zone characteristics of Korea. In this study, we employ numerical simulations to compare the efficiency of pneumatic fracturing on the aspect of the site remediation and the porosity improvement at several hypothetic unsaturated zones composed of four typical soil types. According to the simulation results, it is found that the zone with fine grains soil such as clay and silt shows better efficiency than the zone composed of coarse grains in terms of air flow and porosity enhancements. The results imply that pneumatic fracturing may improve the efficiency of site reclamation by jointly or independently applied to the many contaminated sites in Korea.

• Journal of the Korean GEO-environmental Society
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• v.11 no.11
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• pp.63-75
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• 2010

There are several remediation technologies for heavy metal contaminated soils but increasing cost limits the application of the technology if the contaminated area is large. Therefore, stabilization, which blocks the release of heavy metals or makes slow the release, is one of the applicable technology for the heavy metal contaminated soil. Current study is an applicability test for a smelter area with various stabilizer such as magnetite, hematite, zeolite-A, zeolite-X, zeolite-Y, zinc oxide, calcium oxide, carbon trioxide, manganese oxide, manganese dioxide, fish bone, sodium phosphate. The soil contaminated with arsenic, lead, copper, nickel, and zinc could not be stabilized only one stabilizer which is known to have stability for certain metal. Many of the stabilizer works for a few metal but not all of the heavy metal. In several cases, stabilizers increase the release of the other metals while they stabilize some metals. In general, the stabilizing efficiency was increased with time. For Ni, Pb, calcium oxide, carbon trioxide, manganese oxide had good stabilizing effect in water extractable portion. For Cu, manganese oxide, zeolite showed good results especially in the exchangeable portion of the sequential extraction. For As, magnetite had good ability but most of the metal oxide which showed good result for other heavy metals increased with the release of As. Current study suggest that multiple stabilizers are needed for the contaminated soil and dose of the stabilizer and stabilizing time should be carefully considered for the soil contaminated with various metals.

• Journal of the Korean Society of Groundwater Environment
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• v.3 no.2
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• pp.60-69
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• 1996

Along with rapid industrial development, toxic chemicals have been discharged extensively into the environment. Many of them have flowed into the soil which is final acceptor of environmental pollutants. As a result, they have deteriorated soil and groundwater environment. Once the soil and groundwater were contaminated by pollutants, these media can not be easily restored without artificial remediation. Foreign countries which accomplished earlier industrialization compared to our country have invested enormous capital for the remediation of contaminated sites and the development of relevant technology. In our country the reserch on the development of remediation technology has been conducted for several years, but it is still in its initial stage. This report represents remediation technologies, their adaptability and clean up procedure etc. which are being used for the managenent of contaminated site in advanced countries.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.10a
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• pp.1-11
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• 2003

The objectives of this paper are to overview present status of soil pollution in Korea, to review the current policies and management strategies for soil pollution prevention and remediation of contaminated sites, and to suggest some recommendations to be considered toward more efficient policies. Soils in Korea are contaminated mainly by industrial facilities, landfills, underground storage tanks, abandoned/inactive mines, military camps, and other sources. Concentrations of most of soil pollutants were similar to the background levels, except for a few heavily contaminated sites such as industrial sites or abandoned/inactive mines. The Soil Environment Conservation Act (SECA), which was effective from 1995, provides a comprehensive legal framework for both preventing soil pollution and remedying contaminated sites in Korea. The Act includes various management policies such as the designation of standards and soil pollution policy area, soil monitoring networks, management of suspected contamination sources, and extended 'polluter-pays' principle. To make current policies more efficient and reasonable, some policies or strategies such as the establishment of national priority list, more detailed standards, risk-based cleanup goal, fund raise, soil erosion problem, and finally, integrity between soil and groundwater management frameworks may need to be pursued in the long term.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.6
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• pp.631-638
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• 2010

The objective of this study was to evaluate the efficiency of zerovalent iron and basic oxygen furnace slag on arsenic stabilization in soils. For this, arsenic (V) contaminated soil and roxarsone contaminated soil were incubated after incorporation with zerovalent iron (ZVI) or basic oxygen furnace slage (BOFS) at four different levels (0%, 1%, 3%, and 5%) for 30 days and then the residual concentrations of arsenic were analysed following extraction with aqua reqia, 1N HCl and 0.01 M $CaCl_2$. The total concentration of arsenic was 2,285 mg/kg in the As(V) contaminated soil and 6.5 mg/kg in the roxarsone contaminated soil. 1 N HCl extractable arsenic concentration in the As(V) contaminated soil was initially 1,351 mg/kg and this was significantly declined by 713~1,034 mg/kg following incubation with ZVI while BOFS treatment showed no effect on the stabilization of inorganic arsenate except 5% treatment which showed around 100 mg/kg reduction in 1N HCl extractable arsenic. Similarly, in the roxarsone contaminated soil 1N HCl extractable concentration of arsenic was reduced from 3.13 mg/kg to 0.69 mg/kg with ZVI treatment increased from 1% to 5% while BOFS treatment did not lead to any statistically significant reduction. Available (0.01M $CaCl_2$ extractable) arsenic was initially 0.85 mg/kg in the As(V) contaminated soil and this declined by 0.79 mg/kg following incorporation with 5% ZVI, which accounted for more than 90% of the available As in the control. When As(V)-contaminated soil was treated with BOFS, the available arsenic was increased due to competing effect of the phosphate originated from BOFS with arsenate for the adsorption sites. For the roxarsone contaminated soil, the greater the treatment of ZVI or BOFS, the lower the available arsenic concentration although it was still higher than that of the control.

• Journal of Soil and Groundwater Environment
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• v.7 no.2
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• pp.13-22
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• 2002

Soil washing by surfactants is a technology to enhance mobilization and subsequent degradation of oil pollutants by reducing the surface tension of pollutants which is combined with soil. In this study, biosurfactant, rhamnolipid was produced from Pseudomonas aemginosa ATCC 9027 which had an excellent biodegradable activity in soil without causing secondary pollution. Effects of chemical surfactants on the removal of diesel from diesel-contaminated soil were compared to those of biosurfactants including rhamnolipid. Diesel removal efficiency by rhamnolipid extracted from P. aeruginosa culture broth was over 95% in both batch and column washing test in 5,000ppm diesel-contaminated soil with 1% surfactants after washing for 24 hours. On the contrary, the results of chemical surfactants were below 50∼80%, The chemical surfactants with HLB value(8∼15) showed more then 75% efficiency of diesel removal. But, when the HLB values were below 8 or over 15. their efficiency were observed as less then 60% of diesel removal. Rhamnolipid, biologically produced surfactants, may also be promising agent for enhancing diesel removal from contaminated soil.

• Journal of Korea Soil Environment Society
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• v.4 no.2
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• pp.193-201
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• 1999

This study was conducted to check the applicability of pilot-scale co-composting for the remediation of diesel contaminated soil during the winter. Nutrients and microbes were added to enhance the efficiency of bioremediation and fermenting composts were also added to stimulate the microbial activities. As a result. the soil pile was kept at adequate temperature for the bioremediation during the test period of 30∼40 days and initial concentration(2,340mg TPH/kg dry soil) was reduced to 216mg TPH/kg dry soil (approximately 91% removal). During the initial 10∼30 days, it was found that the TPH concentration and the microbial population were rapidly reduced and increased. respectively. The co-composting technology studied can be effectively applied to remediate the diesel contaminated soil during the winter.