• Title/Summary/Keyword: Arsenic (As)

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The Effects of Organic, Inorganic, and Microbiological Stabilizers on the Transfer of Arsenic and Heavy Metals to Rice Plant (유기, 무기 및 미생물학적 안정화제가 비소 및 중금속의 벼 전이에 미치는 영향)

  • Hui-Yeon Kim;Ga-Hyun Park;Yejin Choi;Eui-Jeong Hwang;Daeung Yoon;Jong-Un Lee
    • Economic and Environmental Geology
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    • v.57 no.4
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    • pp.417-429
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    • 2024
  • To assess the effectiveness of stabilization techniques on the transfer of As and heavy metals in soil to rice plant, pot experiments were conducted using organic (biochar), inorganic (limestone-steel slag mixture), and microbiological (sulfate-reducing bacteria, SRB) stabilizers. The results showed that microbiological treatments, particularly when SRB and SO42- were co-injected, achieved higher stabilization efficiencies for Pb, Cu, and Cd in soil solution by the end of the experiments (153 days). The transfer of Pb, Zn, Cu, and Cd to the rice stems, leaves, and husks was reduced across all stabilization treatments. Notably, in husks, the stabilization efficiencies of Pb, Zn, Cu, and Cd ranged from 30% to 65% for organic stabilizers and 23% to 69% for inorganic stabilizers, surpassing those achieved with microbiological stabilizers. This study highlighted the potential of SRB as an effective alternative or supplementary stabilizer to conventional options such as limestone, steel slag, and biochar in reducing the transfer of heavy metals to crops in paddy soils.

The Significance of the Distribution Patterns of Certain Elements in the Stream Sediments' of the St. Austell Granite Mass, Cornwall (영국(英國)콘웰주(州)의 성(聖)오우스텔 화강암괴(花崗岩塊)에 대(對)한 지구화학적(地球化學的) 연구(硏究))

  • Lee, Jae Yeong;Olinze, Simon Kaine
    • Economic and Environmental Geology
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    • v.2 no.4
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    • pp.23-71
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    • 1969
  • Sediment samples were taken at about half-mile intervals from all the inajor rivers draining the St. Austell granite mass. The minus 80 mesh(B.S.S.) fraction of each sample was analysed, using semiquantitative methods, for sodium, potassium, lithium, phosphorus, nickel, chromium, tin, tungsten, arsenic copper, zinc and lead. The work was carried out with the view to gaining further information as to the geographical distribution of such different granite facies as might axist, and to investigate the geochemical dispersion of these elements with relation to mineralisation in this area. The sesults confirm Exley's suggestion that the mass consists of two major granite intrusions, the earlier undifferentiated one is joined on the west by a later differentiated intrutive. During the work grid deviation maps proved particularly useful in obtaining data concerning the nature of the granite but frequency diagrams were not particularly helpful. All the known lode areas were associated with stream sediments containing anomalously high concentrations of lode metals and it is concluded that these high concentrations are due premarily to lode material transferred to the streams in the form of tailings lost during milling operations.

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Study on the Possibility of Occurrence of Apple Replant Disease in Kyungpook Region (경북지역(慶北地域)사과원(園)의 개식장해(改植障害) 발생가능성(發生可能性)에 관(關)한 연구(硏究))

  • Kim, Kyu Rae
    • Current Research on Agriculture and Life Sciences
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    • v.11
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    • pp.91-99
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    • 1993
  • In order to clarify the possibility of occurrence of apple replant disease and the severity of it in Kyungbuk area, 23 apple orchard soils older than 20 years were collected and growth response of apple seedlings in the soil was tested by soil fumigation. Some factors concerned with apple replant disease in some cases were also checked. The results were as follows. 1. Plant height of apple seedlings was significantly increased in 6 apple orchards and up to 38% in a most conspicuous case by soil fumigation. 2. Fresh weight of aboveground part(except leaves), underground part and whole plant(except leaves) of apple seedlings was significantly increased in 10,4 and 9 apple orchards, respectively by soil fumigation. The response of soil fumigation was pronounced in fresh weight of aboveground part of apple seedlings, more than 50% increase in 5 apple orchards. 3. The effects of available copper and arsenic content in soil and soil nematodes population on the plant height and fresh weight of apple seedlings were not recognized as important factors causing apple replant disease. 4. Effect of soil PH on the occurrence of apple replant disease was not recognized.

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Chemical Remediation and Recirculation Technologies of Wastewater from Metal-Contaminated Soil Washing (금속오염(金屬汚染) 토양세척(土壤洗滌) 폐수(廢水)의 화학적(化學的) 처리(處理)와 재순환(再循環) 기술(技術))

  • Lim, Mi-Hee;Abn, Ji-Whan
    • Resources Recycling
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    • v.20 no.3
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    • pp.28-39
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    • 2011
  • This review investigated theoretical principals and practical application examples on recirculation system of soil washing-wastewater treatment-treated water recycling. As for technologies which have attempted to remediating metals-contaminated soil in and around country, there are reactive barriers, encapsulation, solidification/stabilization, soil washing, and phytoremediation. Among those, in particular, this review covers soil washing technology which physicochemically removes contaminants from soils. The major drawbacks of this technology are to generate a large amount of wastewater which contains contaminants complexed with ligands of washing solution and needs additional treatment process. To solve these problems, many chemical treatment methods have been developed as follows: precipitation/coprecipitation, membrane filtration, adsorption treatment, ion exchange, and electrokinetic treatment. In the last part of the review, recent research and field application cases on soil washing wastewater treatment and recycling were introduced. Based on these integrated technologies, it could be achieved to solve the problem of soil washing wastewater and to enhance cost effective process by reducing total water resources use in soil washing process.

Feasibility of Present Soil Remediation Technologies in KOREA for the Control of Contaminated Marine Sediment: Heavy Metals (우리나라 현존 토양정화 기술의 해양오염퇴적물 정화사업 적용 가능성 검토: 중금속)

  • Kim, Kyoung-Rean;Choi, Ki-Young;Kim, Suk-Hyun;Hong, Gi-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.12
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    • pp.1076-1086
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    • 2010
  • Soil remediation technologies were experimented to evaluate whether the technologies could be used to apply remediation of contaminated marine sediment. In this research, marine sediments were sampled at "Ulsan" and "Jinhae" where remediation projects are considered, and then the possibility of heavy metal removal was evaluated throughout the technologies. Heavy metal concentration of silt and clay fraction was higher than that of sand fraction at "Ulsan". Heavy metal removal of the silt and clay fraction was arsenic (As) 81.5%, mercury (Hg) 93.8% by particle separation, cadmium (Cd) 72.2%, mercury (Hg) 93.8% by soil washing technology, cadmium (Cd) 70.8%, lead (Pb) 65.6% by another soil washing technology. Based on experimental results, tested particle separation and soil washing technologies could be used to remove heavy metals of sand fraction and silt and clay fraction. Heavy metal removal by soil washing technology which was composed of separation, washing and physical or chemical reaction by additives such as acid, organic solvents was more effective comparing to that of particle separation. Since heavy metal concentration of all treated samples was suitable for national soil standards, all the tested technologies were could be used not only to remove heavy metals of marine contaminated sediment but also to reuse treated samples in land.

Prognostic Significance of CD44v6/v7 in Acute Promyelocytic Leukemia

  • Chen, Ping;Huang, Hui-Fang;Lu, Rong;Wu, Yong;Chen, Yuan-Zhong
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.8
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    • pp.3791-3794
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    • 2012
  • CD44v, especially splice variants containing exon v6, has been shown to be related closely to development of different tumors. High levels of CD44v6/v7 have been reported to be associated with invasiveness and metastasis of many malignancies. The objective of this study was to detect expression of CD44v6-containing variants in patients with acute promyelocytic leukemia (APL) and evaluate the potential of CD44v6/v7 for risk stratification. Reverse transcription polymerase chain reaction (RT-PCR) followed by PCR product purification, ligation into T vectors and positive clone sequencing were used to detect CD44 v6-containing variant isoforms in 23 APL patients. Real-time quantitative PCR of the CD44v6/v7 gene was performed in patients with APL and in NB4 cells that were treated with all-trans retinoic acid (ATRA) or arsenic trioxide ($As_2O_3$). Sequencing results identified four isoforms (CD44v6/v7, CD44v6/v8/v10, CD44v6/v8/v9/v10, and CD44v6/v7/v8/v9/v10) in bone marrow mononuclear cells of 23 patients with APL. The level of CD44v6/v7 in high-risk cases was significantly higher than those with low-risk. Higher levels of CD44v6/v7 were found in three patients with central nervous system relapse than in other patients inthe same risk group. Furthermore, in contrast to ATRA, only $As_2O_3$ could significantly down-regulate CD44v6/v7 expression in NB4 cells. Our data suggest that CD44v6/v7 expression may be a prognostic indicator for APL.

Monitoring of Heavy Metals in Agricultural Soils from Consecutive Applications of Commercial Liquid Pig Manure (돈분액비 연용 농경지 중 중금속 함량 모니터링)

  • Go, Woo-Ri;Kim, Ji-Young;Yoo, Ji-Hyock;Lee, Ji-Ho;Kunhikrishnan, Anitha;Lee, Jeong-Mi;Kim, Kye-Hoon;Kim, Doo-Ho;Kim, Won-Il
    • Korean Journal of Environmental Agriculture
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    • v.31 no.3
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    • pp.217-223
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    • 2012
  • BACKGROUND: Increase of heavy metals in agricultural ecosystem has become a social issue nationwide as it is related to public health. This study was performed to find out the status and long-term trends with consecutive application with the commercial liquid pig manure in the agricultural fields. METHODS AND RESULTS: Heavy metals including arsenic, cadmium, copper, lead, nickel, and zinc were analyzed in the 41 samples of paddy fields and 54 samples of upland fields consecutively applied with commercial liquid pig manure for 0 to 16 years. Heavy metal accumulation were not increased statistically at the both paddy and upland fields as the consecutive application year of commercial liquid pig manure were increased. However, some of surveyed upland soils exceeded the criteria of cadmium, copper, and zinc designated by the Soil Environmental Conservation Act in Korea. CONCLUSION: Therefore, analysis of heavy metals, specially copper and zinc, in agricultural fields is absolutely necessary before liquid pig manure application to the fields. In addition, heavy metal accumulation in agricultural fields following to the long-term application of liquid pig manure will be monitored periodically considering with bioavailability of copper and zinc to the crops as an essential nutrients.

Study on the Chemical Compositions of Sun-dried, Refined, and Processed Salt Produced in Chonbuk Area (전라북도내 천일염, 재제 및 가공염의 성분 조사에 관한 연구)

  • 조은자;신동화
    • Journal of Food Hygiene and Safety
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    • v.13 no.4
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    • pp.360-364
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    • 1998
  • The sun-dried, refined, and processed salt (roasted and bamboo salt) manufactured in Chonbuk province were analyzed their chemical compositions and minerals including heavy metals for safety evaluation. Average content of each eomponent as the lowest and the highest were as follows-pH; 6.80 (refined) to 10.35 (bamboo), water content; 0.13% (bamboo) to 10.7% (sun-dried), sodium chloride; 96.6% (roasted) to 84.3% (sun-dried), 804; 0.59% (bamboo) to 3.0% (sun-dried), water insoluble matters; 0.001% (refined) to 1.98% (bamboo), acid inoluble matters; <0.001% (refined) to 0.21% (bamboo), calcium; 0.038% (refined) to 0.213% (sun-dried), magnesium; 0.111% (refmed) to 1.078% (sun-dried), lead; 0.45 ppm (refmed) to 1.15 ppm (bamboo). Cadminium, arsenic and mercury were not detected in all salt. As the analytical results, all salts were differtent in their chemical compositions and safe in view of heavy metals.

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Investigation of Unintentionally Hazardous Substance in Teas (식수대용차 재료의 비의도적 유해물질 오염도 조사연구)

  • Park, Hye min;Kim, Ae Gyeong;Yang, Yong shik;Choi, Su Yeon;Seo, Doo Ri;Cho, Bae Sik;Seo, Kye Won;Kim, Jinhee
    • Journal of Food Hygiene and Safety
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    • v.35 no.2
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    • pp.162-169
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    • 2020
  • This study was conducted to survey levels of heavy metals, benzopyrene and mycotoxins in teas purchased from online markets, supermarkets, and traditional markets in Gwangju, Korea. We examined the arsenic, cadmium and lead content in heavy metals. We also tested for benzo(a)pyrene, which is classified as a carcinogen. In addition, we tested for the mycotoxins aflatoxin (AFB1, AFB2, AFG1, AFG2), ochratoxin A (OTA), fumonisin (FUB1, FUB2), and zearalenone (ZON). According to our results, heavy metals were detected within the allowable range (below 5.0 mg/kg for lead) and all samples met with the standards for tea as presented in the Korean Food Code. The Benzo(a)pyrene showed a detection rate of 12.8% in 16 of 125 samples and mycotoxins showed 23.2% in 29 of 125 samples. However, safe levels regarding benzo(a)pyrene and mycotoxin in tea were not ascertainable since the standards are not set in the Korean Food Code.

Evaluation of Heavy Metal Contents in Mudflat Solar Salt, Salt Water, and Sea Water in the Nationwide Salt Pan (전국 염전에서 생산된 갯벌천일염, 함수 및 해수의 중금속 함량 평가)

  • Kim, Hag-Lyeol;Yoo, Young-Joo;Lee, In-Sun;Ko, Gang-Hee;Kim, In-Cheol
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.7
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    • pp.1014-1019
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    • 2012
  • This study was conducted to evaluate the heavy metal contents of mudflat solar salt, salt water, and sea water produced in the nationwide salt pan. In mudflat solar salt, moisture contents were significantly different (p<0.001) between regions, ranging from 7.357% to 14.862%. Arsenic (As) content ranged from 0.007 ppm to 0.497 ppm, cadmium (Cd) from 0.000 ppm to 0.101 ppm, plumbum (Pb) from 0.000 ppm to 0.191 ppm, hydrargyrum (Hg) from 0.006 ppb to 0.180 ppb, and copper (Cu) from 0.039 ppm to 4.794 ppm between regions, which were significantly different (p<0.001). Further, As, Cd, Pb, and Hg contents of sea and salt water were not in excess of their criterion points. Our results suggest that heavy metal contents of mudflat solar salt, salt water, and sea water produced in the nationwide salt pan were at safe levels. However, continuous management of heavy metal contamination, such as PVC met, is still necessary.