• 지질공학
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• 제24권4호
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• pp.575-581
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• 2014

The reliable measurement of geotechnical properties in cold regions should account for their fluctuations with temperature. The objective of this paper is to introduce a chemical model based on the Arrhenius equation that can predict the properties of materials as their temperature changes. The model can monitor phases and reaction rates as they change with temperature. It has been already applied in the fields of geology, construction, chemistry, materials engineering, and food science. The application of the Arrhenius equation requires a reliable estimate of the activation energy. Therefore, this study also demonstrates several methods for evaluating activation energy in different contexts through summaries and reviews of previous research related to the Arrhenius equation. This paper may be of wide use in obtaining temperature-dependent parameters in geotechnical engineering.

• 한국신뢰성학회지:신뢰성응용연구
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• 제13권2호
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• pp.117-127
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• 2013

In this paper, we studied the correlation between the activation energy($E_a$) of the raw materials and the structural characteristics of the White LED PKGs. The samples used in the study were composed of low power LED 3type and high power LED 5type. To calculate the activation energy($E_a$) of the White LED PKGs conducted three conditions of high temperature operation test based on the Arrhenius model. The number of samples used in the experiment is 10, respectively. The $T_j$ of Conditions and target specifics expressed $T_{j1}$, $T_{j2}$, $T_{j3}$. The activation energy ($E_a$) of the samples was calculated based on the value of the actually measured lifetime. We investigated the correlation between the activation energy ($E_a$) of the raw materials and the structural characteristics of the White LED PKGs. As a result, White LED PKGs activation energy($E_a$) value was confirmed that the material properties affected more than the structural characteristics of the LED PKGs and we found that activation energy of each LED Model has difference. Normally, The activation energy of phosphor of YAG type was indicated from 0.21 to 0.25[eV] and Silicate type was indicated from 0.12 to 0.16[eV]. According to the results, we confirmed that the activation energy of phosphor of YAG type is higher more than The activation energy of phosphor of Silicate type.

• 한국전기전자재료학회논문지
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• 제29권1호
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• pp.17-22
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• 2016

The activation energy of a material is an important factor that significantly affects the lifetime and can be used to develop a degradation model. In this study, a thermal analysis was carried out to evaluate and collect quantitative data on the degradation of insulation materials like EPR and CSP used for nuclear power plant cables. The activation energy was determined from the relationship between log ${\beta}$ and 1/T based on the Flynn.Wall.Ozawa method, by a TGA test. The activation energy was also derived from the relationship between ln(t) and 1/T based on isothermal analysis, by an OIT test. The activation energy of EPR derived from thermal analysis was used to calculate the accelerated aging time corresponding to the number of years of use, employing the Arrhenius equation, and determine the elongation corresponding to the accelerated aging time.

• Advances in nano research
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• 제10권5호
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• pp.437-448
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• 2021

In this article, an analytically and numerically 3D nanoliquid flow by a porous rotatable disk is presented in the presence of gyrotactic microorganisms. The mathematical model in the form of partial differential system is transmuted into dimensionless form by utilizing the appropriate transformation. The homotopy analysis approach is applied to attain the analytic solution of the problem. The effect of promising parameters on velocity distribution, temperature profile, nanoparticles volume fraction and motile microorganism distribution field are evaluated through graphs and in tabular form. The existence of Brownian motion and thermophoresis impacts are more proficient for heat transfer enhancement. Further the unique features like heat absorption/generation and energy activation are also examined for the present flow problem. The obtained results are compared with the earliear investigation to check the accuracy of present model.

• Elastomers and Composites
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• 제46권2호
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• pp.144-151
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• 2011

Intermittent CSR 측정법을 이용하여 hydrogenated NBR(이하 HNBR) 오링의 노화 거동과 수명 예측에 관하여 연구하였다. HNBR 오링의 가교 구조는 황 가교와 퍼옥사이드 가교를 이용하여 각각 제조하였다. Intermittent CSR jig는 오링의 실제 사용환경을 고려하여 설계 제작하였다. 각 측정 조건에 따른 마찰 영향, 열 손실 영향 및 Mullins effect에 의한 intermittent CSR의 응력 거동 변화를 관찰하였다. 오링의 노화 거동은 $100{\sim}120^{\circ}C$에서의 가속 노화 연구를 통하여 관찰하였다. 고장조건 50%와 40%에 대하여 HNBR 오링은 선형 노화 거동을 나타내었으며, Arrhenius relationship을 만족시켰다. HNBR-S 오링의 활성화 에너지는 70.6 kJ/mol로 나타났으며, Arrhenius plot으로부터 오링의 예측 수명은 고장 조건 50%와 40%에 대하여 각각 31.1년과 33.7년으로 나타났다. HNBR-P 오링의 활성화 에너지는 72.1 kJ/mol로 나타났으며, Arrhenius plot으로부터 오링의 예측 수명은 고장 조건 50%와 40%에 대하여 각각 34.0년과 36.5년으로 나타났다. 황 가교에 비하여 퍼옥사이드 가교에서 고무의 노화 속도가 느리게 나타났으며, 활성화 에너지는 높게 나타났다.

• 한국추진공학회지
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• 제20권4호
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• pp.34-39
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• 2016

열분석기인 시차 주사 열량계를 이용하여 $BKNO_3$ 화약의 아레니우스(Arrhenius) 동역학 상수인 활성화 에너지와 Pre-Exponential Factor를 구하였다. 기존의 방법과 달리 고온 가속 노화와 DSC를 병행하여 보다 정밀한 활성화 에너지를 구하였고 열 유속의 적분값을 비교하여 저장 온도에 따른 분율을 구하였다. 이를 통하여 수명 예측을 위한 $BKNO_3$ 화약의 가속노화 시험 조건을 제시하고 열 가속노화에 관한 의미를 재고하였다.

• 공업화학
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• 제7권2호
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• pp.356-361
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• 1996

반응성 첨가제로 HQ와 PGE를 합성시킨 HQ-PGE를 사용하여, DGEBA/MDA계의 경화반응이 일어날 때의 속도론을 DSC와 FT-IR을 이용하여 조사하였다. 그리고, Kissinger equation과 Arrhenius equation을 이용하여 활성화 에너지와 pre-exponential factor 값을 구하였다. 계의 활성화 에너지는 HQ-PGE가 첨가되었을 때 감소하였다. 합성 HQ-PGE가 5 phr 첨가되었을 때, DGEBA/MDA계의 활성화 에너지는 FT-IR로 측정하였을 때 7.8 kcal/mol, DSC로 측정하였을 때에 11.3 kcal/mol을 나타내었다. 이 값은 HQ-PGE가 첨가되지 않은 경우보다 각각 30%, 9% 감소된 값이었다. 이 결과들을 통해서 반응성 첨가제로 사용된 HQ-PGE는 본 계에서 촉매의 역할을 함을 알 수 있었다.

• 한국전기전자재료학회논문지
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• 제28권8호
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• pp.501-507
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• 2015

In this paper, EPR (ethylene propylene rubber) insulation material was accelerated degradation test at $121^{\circ}C$, $136^{\circ}C$, $151^{\circ}C$, and experiment the typical EAB (elongation at break) at mechanical characteristics analysis. It is shown that the failure-time at the point of 50% of the initial value of Elongation rate to obtain the activation energy. The failure-time was shown each 5,219 hr, 3,165 hr, and 668 hr at three temperatures. In order to derive the activation energy, Arrhenius methodology was applied. Also, we got the Arrhenius plot from three accelerated temperatures. The activation energy values got 0.98 eV from EAB test. The experimental data were evaluated for estimating the probability density, and the suitable distribution by using statistical program MINITAB. It is shown that EAB data by the acceleration thermal degradation is most suitable for the Weibull distribution.

• 동력기계공학회지
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• 제20권4호
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• pp.38-43
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• 2016

Safety-related equipments of Nuclear Power Plants(NPP) have to perform environmental qualification test in accordance with IEEE-323 standards. However, non-metallic materials replace new one regularly instead of the test because they are considered as consumable parts. In this study, the seven kinds of non-metallic materials are selected and their activation energy was experimentally evaluated with uncertainty analysis by using thermogravimetric analyzer(TGA). In order to obtain activation energy of non-metallic materials, mass difference, temperature raising rate and conversion rate on the specimen are analyzed. It is postulated that the three experiment conditions are important to get a reliable activation energy. This postulate was experimentally confirmed using Arrhenius equation and Flynn-Wall-Ozawa analysis.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 추계학술대회 논문집
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• pp.163-166
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• 1995

It was investigated the properties of TSC (Thermally Stimulated Current) to understand carriers behavior from long ago. Activation Energy of their properties is very important to verify electrical characteristics. So, for many years, many researchers were worked to get the activation energy, more compeletely. But, if boundary conditions were not satisfied, the values of activation energy contained several errors. In this work, to obtain the activation energy related to charged particles, the peak temperature Tp and the slope of tangential line on any coordinates of Arrhenius plot are applied. The calculation process can be denied with by computer, and the result of observation shows that the cures of calculation data and simulation data coincide very compeletely.