• 한국해양공학회지
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• 제6권1호
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• pp.105-112
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• 1992

The main purpose of this study is to derive a law of fatigue crack growth rate in the region of elastic or elasto-plastic fracture mechanics at elevated temperatures through the application of dimensional analysis. An equation of elasto-plastic fatigue crack growth rate at elevated temperatures appeared a new Arrhenius type equation containing J-integral range and absolute temperature. The elastic or elasto-plastic crack growth rate equation shows a fairly good agreement with the experimental results for Cr-Mo-V rotor steel and Hastelloy-X alloy in the comparatively wide temperature ranges.

• 한국수산과학회지
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• 제15권3호
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• pp.207-210
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• 1982

갑오징어 우리나라에서 비교적 맏이 어획되어 대부분 천연건조에 의해 가공되고 있다. 갑오징어의 고정층 건조를 실시하여 건조 속도 및 Shirai식에 의한 건조 속도 상수 (k) 를 구하고, Arrhenius' plot에 의해 온도 의존성을 관찰하여 다음과 같은 결론을 얻었다. 1. 갑오징어의 수분 함량을 $40\%$이하로 낮추는데 본 실험의 경구 4시간이내가 소요되어 고정층 건조방법이 배등의 열풍건조법보다 효과적인 방법으로 판단된다. 2. 시료의 세분화, 껍질 제거, 열풍의 온도 상승 및 방향 조정 등으로 건조시간을 2시간으로 단축할 수 있었다. 3. 본 실험의 결과는 Shirai식과 Arrhenius' law에 잘 적용되었다.

• 한국분말재료학회지
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• 제20권1호
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• pp.48-52
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• 2013

A study of oxidation kinetic of Fe-36Ni alloy has been investigated using thermogravimetric apparatus (TGA) in an attempt to define the basic mechanism over a range of temperature of 400 to $1000^{\circ}C$ and finally to fabricate its powder. The oxidation rate was increased with increasing temperature and oxidation behavior of the alloy followed a parabolic rate law at elevated temperature. Temperature dependence of the reaction rate was determined with Arrhenius-type equation and activation energy was calculated to be 106.49 kJ/mol. Based on the kinetic data and micro-structure examination, oxidation mechanism was revealed that iron ions and electrons might migrate outward along grain boundaries and oxygen anion diffused inward through a spinel structure, $(Ni,Fe)_3O_4$.

• 대한기계학회논문집
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• 제14권6호
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• pp.1552-1560
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• 1990

본 연구에서는 로터강(Cr-Mo-V 강)과 저탄소합금강(A517-F강)의 CT시험편을 대상으로 한 고온피로 시험결과를 토대로 차원해석법을 도입시켜 고온하의 균열성장률 을 유도한 다음 온도(T)와 응력확대계수범위(.DELTA.K,T)인 아레니우스 형태의 식을 유도하 였다.그리고 유도된 균열 성장 법칙을 파리스식과 비교 검토하여 본 연구에서 유도 된 이 균열성장법칙의 타당성을 검토하고자 한다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.1997-2002
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• 2007

The reformer is one of the most important chemical processes for the production of high purity hydrogen from fossil fuel. This study compares zero-dimensional model with CFD models for reaction analysis of methane-steam reformer. The zero-dimensional model is an empirical equation, however CFD model uses reactions of Arrhenius type. Because the reaction coefficients of the steam-methane catalytic reforming have not been reported before in the form of Arrhenius type, the present study aims to find the appropriate reaction coefficients. The used CFD code is Fluent 6.2 version. Several models are compared for the case of various operating temperature, mass of catalyst and steam to methane ratio.

• 한국식품과학회지
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• 제25권5호
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• pp.558-564
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• 1993

쌀보리를 시료로 하여 건조조건을 다르게 하여 유동층 건조특성에 영향을 미치는 외부요인에 대해서 조사한 결과를 요약하면 다음과 같다. 쌀보리의 유동층건조는 항률건조기가 없이 감률건조 1단계, 감률건조 2단계의 두 단계로 일어남을 알 수 있었다. 또한 건조속도상수는 충전량이 적을수록, 공기속도가 클수록, 공기온도가 높을수록, 상대습도가 낮을수록 켰으며, 감율건조단계에서의 건조속도상수는 Arrhenius형의 plot에서 좋은 직선관계를 나타내어 이 단계가 활성화 과정임을 알 수 있으며, 감률건조 제 1단계의 활성화 에너지는 1900ca1/gmol, 감률건조 제 2단계의 활성화 에너지는 2500ca1/gmol을 각각 나타내었다.

• 한국식품저장유통학회지
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• 제24권4호
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• pp.505-509
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• 2017

Water vapor adsorption kinetics of vacuum-dried jujube powder were investigated in temperature and relative humidity ranges of 10 to $40^{\circ}C$ and 32 to 75%, respectively. Water vapor was initially adsorbed rapidly and then reached equilibrium condition slowly. Reaction rate constant for water vapor adsorption of vacuum-dried jujube powder increased with an increase in temperature. The temperature dependency of water activity followed the Clausius-Clapeyron equation. The net isosteric heat of sorption increased with an increase in water activity. Good straight lines were obtained with plotting of $1/(m-m_0)$ vs. 1/t. It was found that water vapor adsorption kinetics of vacuum-dried jujube powder was accurately described by a simple empirical model, and temperature dependency of the reaction rate constant followed the Arrhenius-type equation. The activation energy ranged from 50.90 to 56.00 kJ/mol depending on relative humidity. Arrhenius kinetic parameters ($E_a$ and $k_0$) for water vapor adsorption by vacuum-dried jujube powder showed an effect between the parameters with the isokinetic temperature of 302.51 K. The information on water vapor adsorption kinetics of vacuum-dried jujube powder can be used to establish the optimum condition for storage and processing of jujube.

• 한국표면공학회지
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• 제44권4호
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• pp.131-136
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• 2011

A kinetic study has been made for the growth of nanocrystalline diamond (NCD) particles to a continuous thin film on silicon substrate in a microwave plasma chemical vapor deposition reactor. Parameters of deposition have been microwave power of 1.2 kW, the chamber pressure of 110 Torr, and the Ar/$CH_4$ ratio of 200/2 sccm. The deposition has been carried out at temperatures in the range of $400\sim700^{\circ}C$ for the times of 0.5~16 h. It has been revealed that a continuous diamond film evolves from the growth and coalescence of diamond crystallites (or particles), which have been heterogeneously nucleated at the previously scratched sites. The diamond particles grow following an $h^2$ = k't relationship, where h is the height of particles, k' is the particle growth rate constant, and t is the deposition time. The k' values at the different deposition temperatures satisfy an Arrhenius equation with the apparent activation energy of 4.37 kcal/mol or 0.19 eV/ atom. The rate limiting step should be the diffusion of carbon species over the Si substrate surface. The growth of diamond film thickness (H) shows an H = kt relationship with deposition time, t. The film growth rate constant, k, values at the different deposition temperatures show another Arrhenius-type expression with the apparent activation energy of 3.89 kcal/mol or 0.17 eV/atom. In this case, the rate limiting step might be the incorporation reaction of carbon species from the plasma on the film surface.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.286-288
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• 2014

• 한국식품과학회지
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• 제20권5호
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• pp.711-717
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• 1988

배추의 염절임중 배추 조직으로의 소금흡수 속도를 측정하고 확산에 관한 수학적인 모델과 computer simulation을 통해서 확산계수를 구하였다. 배추 줄기로의 소금의 침투 및 탈염 될 때의 확산계수는 각각 $1.7{\times}10^{-11}m^2/s$와 $11.6{\times}10^{-11}m^2/s$이었다. Apparent diffusivity는 소금의 농도와 배추의 종류에 커다란 영향을 받지 않으며, 온도의존성은 Arrhenius식으로 나타낼 수 있고 이때의 활성화 에너지는 66 KJ/mol 이었다.