• Title/Summary/Keyword: Aromatic species

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Phenanthrene-induced Oxidative DNA Damage of Lymphocytes and the Suppression by Ginseng Extract (페난트렌에 의한 임파구 DNA의 산화적 손상과 인삼추출물에 의한 억제)

  • Yoo, Ah-Reum;Lee, Mi-Young
    • Journal of Ginseng Research
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    • v.33 no.4
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    • pp.355-360
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    • 2009
  • Phenanthrene ($C_{14}H_{10}$) is a polycyclic aromatic hydrocarbon with three aromatic rings, and it can be produced by incomplete combustion of fossil fuels. Comet assay was used to examine the oxidative DNA damage of lymphocytes by phenanthrene and to measure the suppressive effects of ginseng extract on the DNA damage in this investigation. The in vitro oxidative DNA damage by phenanthrene increased in a dose-dependent manner in the lymphocyte. However, the DNA damage was significantly inhibited by ascorbate. Moreover, pretreatment, cotreatment and posttreatment with ginseng extract enhanced lymphocyte resistance to the phenanthrene-induced DNA damage. Phenanthrene enhanced the generation of intracellular reactive oxygen species, and the elevated reactive oxygen species level was reduced by treatment with ginseng extract.

Growth and Aromatic Constituents of Wild and Domesticated Codonopsis lanceolata Grown at Two Different Regions (야생 및 재배더덕의 재배장소에 따른 생육 및 향기성분)

  • 이승필;김상국;최부술;이상철;김길웅
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.5
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    • pp.587-593
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    • 1995
  • Growth characteristics and aromatic constituents of wild and domesticated Codonopsis lanceolata grown in different regions were investigated to find the best cultural condition for quality improvement. The results were as followings: Air temperature of wild region was lower to 4~8 and soil temperature was also lower to 3 compared with domesticated region. Soil of wild region had about three times richer organic matter with lower pH. Chromosome number of wild and domestcated species was 2n=16, ovary number was 3, but seed number of wild species was 132 vs domesticated showing 62. Recovery yield of wild species grown wild region had 0.55%, besides that, the wild species grown in domesticated region had 0.34. But the domesticated species in wild and domesticated regions was the same as 0.28. Inorganic element contents of domesticated region showed much higher than that of wild region. Major aromatic constituents were specified in wild Codonopsis lanceolata as dimethyl benzene, 3-ethyl-5-2-(ethylbutyl)-octadecane, benzaldehyde, 14, 14-dimethyl-hexadecanoate, methylhexadecenoate of which was not detected in domesticated species.

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The Temporal and Spatial Distribution of Volatile Organic Compounds(VOCs) in the Urban Residential Atmosphere of Seoul, Korea

  • Anthwal, Ashish;Park, Chan-Goo;Jung, Kweon;Kim, Min-Young;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • v.4 no.1
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    • pp.42-54
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    • 2010
  • Automobile emissions have caused a major hydrocarbon pollution problem in the ambient air of many cities around the world. This study was conducted to measure the pollution status of volatile organic compounds (VOCs) in some urban residential areas in Seoul, Korea. A total of 20 VOCs (11 aromatic and 9 chlorinated species) were identified at 4 urban residential sites in Seoul, Korea from February 2009 to July 2009. Comparison of total VOC (TVOC) concentration data indicated the dominance of the aromatic species with the maximum (72.2 ppbC) at Jong Ro (JR) and the minimum at Yang Jae (33.4 ppbC). The peak concentration of TVOC occurred during spring at all sites with an exception at Gang Seo (GS), where it was recorded during winter. The distribution of individual VOCs at the study sites was characterized by high toluene concentration. A strong correlation of benzene was also observed with other VOCs and criteria pollutants at all sites (except YJ). The overall results of this study suggest that vehicular emissions have greatly contributed to the increase in VOC pollution at all the study sites.

Simultaneous Degradation of Polycyclic Aromatic Hydrocarbons by Attractive Ligninolytic Enzymes from Phlebia brevispora KUC9045

  • Lee, Aslan Hwanhwi;Lee, Hanbyul;Kim, Jae-Jin
    • Korean Journal of Environmental Biology
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    • v.34 no.3
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    • pp.201-207
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    • 2016
  • The hazards associated with the polycyclic aromatic hydrocarbons (PAHs) are known to be recalcitrant by their structure, but white rot fungi are capable of degrading recalcitrant organic compounds. Phlebia brevispora KUC9045 isolated from Korea was investigated its efficiency of degradation of four PAHs, such as phenanthrene, anthracne, fluoranthene, and pyrene. And the species secreted extracellular laccase and MnP (Manganese dependent peroxidase) during degradation. P. brevispora KUC9045 demonstrated effective degradation rates of phenanthrene (66.3%), anthracene (67.4%), fluoranthene (61.6%), and pyrene (63.3%), respectively. For enhancement of degradation rates of PAHs by the species, Remazol Brilliant Blue R (RBBR) was preferentially supplemented to induce ligninolytic enzymes. The biodegradation rates of the three PAHs including phenanthrene, fluoranthene, and pyrene were improved as higher concentration of Remazol Brilliant Blue R was supplemented. However, anthracene was degraded with the highest rate among four PAHs after two weeks of the incubation without RBBR addition. According to the previous study, RBBR can be clearly decolorized by P. brevispora KUC9045. Hence, the present study demonstrates simultaneous degradation of dye and PAHs by the white rot fungus. And it is considered that the ligninolytic enzymes are closely related with the degradation. In addition, it indicated that dye waste water might be used to induce ligninolytic enzymes for effective degradation of PAHs.

Diacetylene Polymerize in Amorphous State? Free Radical Initiated Polymerization of Aromatic Diacetylenes.

  • Beristain Miriam F.;Ogawa Takeshi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.321-321
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    • 2006
  • Aromatic diacetylenes form stable oligomeric diradicals when irradiated with UV light or heated at temperatures above their melting points. In this paper, the formation of stable diradicals is discussed, and the mechanism of polymerization in the presence of peroxide in solution, is discussed. The diphenyldiacetylene undergoes polymerization through coupling of diradicals, and not by the successive addition of radical species.

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A Short Kinetic Mechanism for Premixed Flames of Aromatic Compound : Benzene (방향족 화합물 화염의 축소 반응 메카니즘 개발 : 벤젠)

  • Lee, Ki Yong
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.161-164
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    • 2015
  • A short kinetic mechanism for premixed benzene/air flames was developed with a reduction method of Simulation Error Minimization Connectivity Method(SEM-CM). It consisted of 38 species and 336 elementary reactions. Flame speeds were calculated and compared with those from full mechanisms and experiments of other researcher. Those comparisons are in good agreement between the full mechanism and the short mechanism at high pressure condition. In numerical work the running time with the short mechanism was over 10 times faster than one with the full mechanism.

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The Effect of the Oxygen-Enrichment on the PAH Production in Fuel-Rich $CH_4/CH_3Cl$ Premixed Flames (과농조건인 $CH_4/CH_3Cl$ 예혼합화염에서 산소부화가 PAH 생성에 미치는 효과)

  • Lee, Ki-Yong
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.9-14
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    • 2010
  • Numerical simulations of freely propagating fuel-rich $CH_4/CH_3Cl$ premixed flames were performed at atmospheric pressure in order to understand the effect of the oxygen enrichment on the production of PAH. A chemical kinetic mechanism was used, which involved 157 gas-phase species and 1693 forward reactions. The calculated flame speeds were compared with the experiments for the flames established on the equivalence ratios of 1~1.6, the results of which were in good agreement. As the level of oxygen enrichment was increased, the concentrations of one or four ring aromatic hydrocarbons were decreased. This might cause the fact that the contribution of PAH species to soot was weakened.

A Short Kinetic Mechanism for Premixed Flames of Aromatic Compound : Benzene (방향족 화합물 화염의 축소 반응 메카니즘 개발 : 벤젠)

  • Lee, Ki Yong
    • Journal of the Korean Society of Combustion
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    • v.20 no.4
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    • pp.49-55
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    • 2015
  • A short kinetic mechanism for premixed benzene/air flames was developed with a reduction method of Simulation Error Minimization Connectivity Method(SEM-CM). It consisted of 38 species and 336 elementary reactions. Flame speeds were calculated and compared with those from full mechanisms and experiments of other researchers. Flame temperature, the heat release rate, the concentration profiles of major species and radicals were also calculated with both mechanism. Those comparisons are in good agreement between the full mechanism and the short mechanism at high pressure condition. In numerical work the running time with the short mechanism was over 12 times faster than one with the full mechanism.

Measurements of 50 Non-polar Organic Compounds Including Polycyclic Aromatic Hydrocarbons, n-Alkanes and Phthalate Esters in Fine Particulate Matter (PM2.5) in an Industrial Area of Chiba Prefecture, Japan

  • Ichikawa, Yujiro;Watanabe, Takehisa;Horimoto, Yasuhide;Ishii, Katsumi;Naito, Suekazu
    • Asian Journal of Atmospheric Environment
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    • v.12 no.3
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    • pp.274-288
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    • 2018
  • Quantitative data of 50 non-polar organic compounds constituting $PM_{2.5}$ were continuously collected and analyzed from June 2016 to October 2017 (approximately 17 months) at Ichihara, one of the largest industrial areas in Japan. Target non-polar organic compounds including 21 species of polycyclic aromatic hydrocarbons (PAHs), 24 species of n-alkanes and 5 species of phthalate esters(PAEs) were simultaneously measured by gas chromatography/mass spectrometry. Basically, the average concentrations of the total PAHs, n-alkanes and PAEs in each season remained nearly level, and seasonal variations were little throughout the study period. These results suggest that the emission sources, which are not influenced by the seasons, are the dominant inputs for the target organic compounds. Diagnostic ratios of PAHs, assessment of n-alkane homologue distributions, carbon preference index, and the contribution of wax n-alkanes from plants were used to estimate source apportionments. These results indicate that anthropogenic sources were the main contributor for most PAHs and n-alkanes throughout the study period. The concentrations of PAEs selected in this study were low because emission amounts of these chemicals were little within the source areas of the sampling site. To our knowledge, this study is the first attempt to simultaneously measure a high number of non-polar organic compounds in $PM_{2.5}$ collected from the ambient air of Japan, and the resultant data will provide valuable data and information for environmental researchers.

Antimicrobial Activities of Volatile Essential Oils from Korean Aromatic Plants

  • Shin, Kuk-Hyun;Chi, Hyung-Joon;Lim, Soon-Sung;Cho, Seon-Haeng;Moon, Hyung-In;Yu, Jae-Hyeun
    • Natural Product Sciences
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    • v.3 no.2
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    • pp.141-147
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    • 1997
  • Volatile essential oils obtained by steam distillation from 55 plant parts of 42 species of representative aromatic plants newly collected in Korean peninsula have been evaluated for antimicrobial activity against 5 microorganisms. The essential oils derived from 15 plant parts and 9 plant parts were found to exhibit very strong antimicrobial activities by more than 95% inhibition at 100 ${\mu}g/ml$ against Staphylococcus aureus and Pseudomonas aeruginosa, respectively. Essential oil components such as l-limonene, ${\beta}-myrcene$, linalool, ${\gamma}-terpinene$, ${\alpha},{\beta}-phellandrene$, 1,8-cineole, l-borneol and bornylacetate, as a whole, have primarily contributed to the manifestation of the antimicrobial activity.

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