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A Study on the Organic-Inorganic Multilayer Barrier Thin Films Using R2R Low-Temperature Atmospheric-Pressure Atomic Layer Deposition System (연속공정기반 저온 상압 원자층 증착 시스템을 이용한 유무기 멀티레이어 배리어 박막에 관한 연구)

  • Lee, Jae-Wook;Kim, Hyun-Bum;Choi, Kyung-Hyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.3
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    • pp.51-58
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    • 2018
  • In this paper, the organic material Poly(methyl methacrylate) PMMA is used with inorganic $Al_2O_3$ to fabricate organic-inorganic multilayer barrier thin films. The organic thin films are developed using a roll-to-roll electrohydrodynamic atomization system, whereas the inorganic are grown using a roll-to-roll low-temperature atmospheric pressure atomic layer deposition system. For the first time, these two technologies are used together to develop organic-inorganic multilayer barrier thin films in atmospheric condition. The films are grown under optimized parameters and classified into three classes based on the layer structures, when the total thickness of the barrier is maintained at ~ 160 nm. All classes of barriers show good morphological, optical and chemical properties. The $Al_2O_3$ films with a low average arithmetic roughness of 1.58 nm conceal the non-uniformity and irregularities in PMMA thin films with a roughness of 5.20 nm. All classes of barriers show a notably good optical transmission of ~ 85 %. The hybrid organic-inorganic barriers show water vapor and oxygen permeation in the range of ${\sim}3.2{\times}10^{-2}g/m^2/day$ and $0.015cc/m^2/day$ at $23^{\circ}C$ and 100% relative humidity. It has been confirmed that it can be mass-produced and used as a low-cost barrier thin film in various printing electronic devices.

Studies on the Behaviour of Ozone Concentration and the Influencing Factors (오존농도의 動態 및 影響因子에 關한 硏究)

  • 金旻永;姜熙坤;李完宗;李相七;張鳳勳;朴聖培
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.2
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    • pp.55-71
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    • 1989
  • This study was carried out to determine the ozone concentration to behaviour and the factors to be influenced the variation of its concentration in the ambient air in Seoul. Measurements of ozone concentrations were made at 10 monitoring station to take care of SIHE (Seoul Institute of Health & Environment) during December 1987 to November 1988, also measured the hourly average concentration of sulfur dioxide, total suspended particulate, nitrogen oxide $(NO & NO_2)$, carbon monoxide, hydro carbon $(n-CH_4 & THC)$ and meteorological factors, that is, temperature, humidity, wind velocity wind direction and ultraviolet intensity etc, for the same period at same place. The basis of the data obtained were analyzed statistically along with the various data. The results were as follows; 1. The annually arithmetic mean concentration of ozone for the 10 sites during one years was 10.0 ppb and ranged from 3.1 $\pm$ 4.5ppb at the Kuro industrial complex to 17.2 $\pm$ 18.7 ppb at the Ssangmun site. 2. The frequency of hours on which oxidant concentrations exceeded the present short term standard of ozone (100 ppb) were 78 times. 3. The diurnal patterns of hourly ozone concentrations in Seoul area was a typical bi-modal variation which have 4 to 5 a.m. peak and 3. to 4 p.m peak. 4. The time ozone of highest ozone concentration in a whole day and hight was 1 to 5 p.m and 90.9 percent of appearence rate. 5. The diurnal patterns of hourly ozone concentrations in Seoul were on the whole the order of daytime from 5.8ppb to 28.7 ppb evening from 1.7 to 18.7 ppb night time from 1.9 to 9.3 ppb daybreak from 1.4ppb according to measuring sites, and the highest that observed at the Ssangmun area while the lowest was the Kuro industrial complex monitor sites. 6. The weekly variation of ozone concentration was the higher level ozone concentration in the day of the week occured sunday-monday and weekend but the decrease were observed from wednesday to thursday.

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A Study on the Distribution Environment and Consumer Behavior of Smartphone (스마트폰 유통환경과 소비자 행동에 관한 연구)

  • Kim, Min-Soo
    • Journal of Distribution Science
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    • v.16 no.4
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    • pp.67-74
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    • 2018
  • Purpose - Most of the amendments to the law on the improvement of the distribution structure of mobile communication terminal equipment, the fully self-sufficient system of terminals, and the separated disclosure system on the terminals are aimed at securing transparency of the distribution structure by eliminating or reducing handset subsidies. This study investigates what items are important for the purchase of mobile phones in various and rapidly changing mobile phone markets from the consumer's point of view and tries to make a strategic suggestion for future mobile distribution strategies. Research design, data, and methodology - The procedure of this study takes place in four steps. In step 1, only the SF type respondents selected for this study were extracted through MBTI analysis. In step 2, they were divided into three hierarchies for the AHP analysis and each element was arranged. In step 3, the AHP analysis was converted to a Fuzzy-AHP number using the trigonometric centroid method. This was to eliminate the ambiguity of the response by converting into a fuzzy number even if data consistency was maintained with CI value below 0.1. In step 4, the number of converted 2-layer and 3-layer was combined to derive the priority when the final handset is selected. Results - First, the highest importance among the four items in the second tier was the terminal function item, followed by brand, price, and design item. Second, in the third tier, the highest importance was level of after-sales service, followed by device price, processing speed, ease of use, usefulness, and rate system. Third, the arithmetic average of the determinant of the fuzzy function showed that processing speed, ease of use and usefulness in the function item, level of after-sales service in the brand item, and device price in the price item were the five most important factors among 16 choice factors. Conclusions - First, there will be a change in the consumption patterns of consumers who have compared distributors and dealers to purchase handsets with more subsidies. Second, it is highly likely that people will purchase new handsets only when they need to change their devices because they can not receive subsidies by switching phone brands any more.

Scenario Analysis of Personal Nitrogen Dioxide Exposure with Monte Carlo Simulation on Subway Station Workers in Seoul (확률론적 모의실험 기법을 이용한 일부 지하철 근무자들의 이산화질소 개인노출 시나리오 분석)

  • 손부순;장봉기;양원호
    • Journal of Environmental Science International
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    • v.10 no.3
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    • pp.195-200
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    • 2001
  • The personal exposures of nitrogen dioxide(NO$_2$), microenvironmental levels and daily time activity patterns on Seoul subway station workers were measured from February 10 to March 12, 1999. Personal NO$_2$exposure for 24 hours were 29.40$\pm$9.75 ppb. NO$_2$level of occupational environment were 27.87$\pm$7.15 ppb in office, 33.60$\pm$8.64 ppb in platform and 50.13$\pm$13.04 ppb in outdoor. Personal exposure time of subway station workers was constituted as survey results with $7.94\pm$3.00 hours in office, $2.82\pm$1.63 hours in platform and 1 hours in outdoor. With above results, personal $NO_2$exposure distributions on subway station workers in Seoul were estimated with Monte Carlo simulation which uses statistical probabilistic theory on various exposure scenario testing. Some of distributions which did not have any formal patterns were assumed as custom distribution type. Estimated personal occupational $NO_2$exposure using time weighted average (TWA) model was 31.$29\pm$5.57 ppb, which were under Annual Ambient Standard (50ppb) of Korea. Though arithmetic means of measured personal $NO_2$exposure was lower than that of occupational $NO_2$exposure estimated by TWA model, considering probability distribution type simulated, probability distribution of measured personal $NO_2$exposures for 24 hours was over ambient standard with 3.23%, which was higher than those of occupational exposure(0.02%). Further research is needed for reducing these 24 hour $NO_2$personal excess exposures besides occupational exposure on subway station workers in Seoul.

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Research on Exposure to Total Dust and Endotoxin during Planting and Harvest Tasks at Cucumber, Yellow Melon and Potato Farms (오이, 참외, 감자 작목에서의 정식, 수확작업시 총분진과 엔도톡신 노출 특성에 관한 연구)

  • Kim, Hyo Cher;Lee, Kyung Suk;Chae, Hye Seon;Min, Kyung Doo;Kim, Kyung Ran;Park, Yoon Suk
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.4
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    • pp.412-420
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    • 2013
  • Objectives: This study was conducted in order to evaluate personal and area exposure to airborne total dust and endotoxin during harvest and planting tasks at cucumber, yellow melon and potato farms Materials and Methods: Total dust was measured with NIOSH method 0500. Endotoxin were measured using a 37 mm glass fiber filter which was connected to an air pump calibrated to 2 LPM, and then analyzed with a Turbidmetric kinetic method. Results: The average(arithmetic mean) concentrations of total dust in the personal samples were $0.10-3.81mg/m^3$ for cucumbers, $0.21-1.19mg/m^3$ for yellow melon, and $0.08-2.72mg/m^3$ for potato. There was a significant difference in the harvest task among the three farm types(p=0.019 of personal sample, p=0.048 of area sample), in which the air concentration for potatoes was higher than with cucumbers and yellow melons. Conclusions: It was found that potatoes(planting and harvest) should be considered the first priority for studying and reducing total dust exposure.

Departments of Dental Technology An improvement plan of Curriculum - Focus on graduated students - (치기공과 교육과정의 개선 방안 - 졸업생을 중심으로 -)

  • Bae, Bong-Jin;Lee, Hwa-Sik;Park, Myung-Ho
    • Journal of Technologic Dentistry
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    • v.30 no.2
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    • pp.93-103
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    • 2008
  • This research is designed for a consumer, not a supplier when it was designed. And the purpose is to present the reference data which is in order to improve the curriculum by analyzing the present subject of the curriculum. The research collected the curriculum for Dental Technology from a total of 20 schools --3-year colleges and 4-year colleges-- all in Korea. And we analyzed the average credits of subjects from students. As a result of this analysis, we get the conclusion below: 1. In a distribution which students answered about each subjects; Dental esthetic, Dental morphology I II, Dental morphology practice I II, and Seminar don't have many credits and mostly have a converged tendency in high points, according to the arithmetic mean of the major basis subjects. 2. In an analysis of the correlation which is based on the distinction of sex; Dental ceramics practice III, Medical terminology, Seminar, and The major basis subjects have a meaningful difference. (${\rho}$ < 0.05) 3. In an analysis of the correlation which is based on an age; The major basis subjects, and the application subjects have meaningful difference. (${\rho}$ < 0.05) 4. In a correlation coefficient between subjects; The correlation coefficient of the major application subjects is higher than the major basis subjects. According to the student ? t, we found that the level of significance is ${\rho}$ < 0.001, which is meaningful. We feel that Department of Dental Technology also highly need to design, and conduct focusing on a consumer who is working at the society, not a supplier. And we need to increase or decrease credits which have a meaningful difference.

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Departments of Dental Technology An improvement plan of Curriculum - Focus on students who being in college - (치기공과 교육과정의 개선 방안 - 재학생을 중심으로 -)

  • Bae, Bong-Jin;Lee, Hwa-Sik;Park, Myung-Ho
    • Journal of Technologic Dentistry
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    • v.29 no.2
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    • pp.49-64
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    • 2007
  • This research collected the curriculum for Dental Technology from a total of 20 schools -3-year colleges and 4-year colleges- all in Korea. And we analyzed the average credits of subjects from students. As a result of this analysis, we get the conclusion below: 1. In a distribution which students answered about each subjects; Seminar, Dental morphology I II, Dental morphology practice I II, and Dental devices & instruments don't have many credits and mostly have a converged tendency in high points, according to the arithmetic mean of the major basis subjects. 2. In an analysis of the correlation which is based on the distinction of sex: Complete denture prosthodontics I II III, Dental orthodontics I II, Dental orthodontics practice I II, and Dental orthodontics & practice III have a meaningful difference. ($\rho$< 0.05 ) 3. In an analysis of the correlation which is based on an age The major basis subjects -Introduction to dental technology, Dental esthetic, and Dental casting procedure-, and the major application subjects -Crown and bridge prosthodontics practice, Complete denture prosthodontics, Dental orthodontics, Dental orthodontics practice, and Operative dentistry laboratory technology- have meaningful difference. ($\rho$< 0.05 ) 4. In a correlation coefficient between subjects; The correlation coefficient of the major application subjects is higher than the major basis subjects. According to the student - t, we found that the level of significance is $\rho$< 0.001, which is meaningful. We feel the lack of a limitation which we didn't survey all students who are major in Department of Dental Technology. And we also feel that we'd better to consider not only students who being in college but also graduated students.

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Benzene Exposure Matrices Using Employees's Exposure Assessment Data (작업환경측정 결과를 활용한 벤젠 노출 매트릭스에 대한 연구)

  • Baek, Kyunghee;Park, Donguk;Ha, Kwonchul
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.2
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    • pp.146-155
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    • 2015
  • Objectives: The aims of this study were to set up benzene exposure matrices according to industry and process and to assess the risk of those occupational exposure to benzene. Methods: The benzene exposure matrices were assembled depending on industry and process, based on an exposure database provided by KOSHA(the Korean Occupational Safety and Health Agency), which was gathered from a workplace hazards evaluation program in Korea. These exposure matrices were assessed by Hallmark Risk Assessment tool. Results: The benzene was treated 412 industries sector(36%), 2,747 business places, and 471 industrial processes according to database. The arithmetic mean of past decade 8 hours time-weighted average of airborne benzene concentrations in the workplace was 0.10722 ppm. 1.07% of the total sample were greater than OEL, and 59.8% were showed less than the limit of detection. The highest risk values(Danger Value) were seen 36 industries including manufacture of general paints and similar product and 12 processes, such as other painting of manufacture of metal fabricated members. Exposure matrices based on employee exposure data base may provide exposure histories and can be used in epidemiological studies. Conclusions: It was found that more attentions should be paid to 36 among 412 industries and 12 of 471 processes, with a higher risk value.

Microbial Assessment in Metal-Working Fluids Handling Industry (금속가공유 취급 작업장의 생물학적 인자 노출평가)

  • Park, Hyunhee;Park, Dongjin;Park, Hae Dong
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.3
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    • pp.300-309
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    • 2014
  • Objectives: The objective of this study is to evaluate microbial exposure hazards in the metal-working fluids(MWF) handling industry. Methods: Air quality parameters(airborne bacteria, fungi, endotoxin and oil mist) and bulk MWF in storage tanks were evaluated at 54 points at nine sites in South Korea. Results: The geometric means(GM) of culturable airborne bacteria, fungi, endotoxin and oil mist concentration were $133CFU/m^3$(n=376, range $7{\sim}6,510CFU/m^3$), $159CFU/m^3$(n=381, range $7{\sim}8,469CFU/m^3$), $8.06EU/m^3$(n=103, range $0.34{\sim}280.4EU/m^3$) and $0.20mg/m^3$(n=104, range $0.01{\sim}2.87mg/m^3$), respectively. The ratio of indoor to outdoor concentration was 2.7 for bacteria, 6.1 for endotoxin, and 4.8 for oil mist. Even though average airborne bacteria concentration did not exceed recommended exposure limits($1,000CFU/m^3$), MWF in the storage tanks was highly contaminated with bacteria(arithmetic mean $2.1{\times}10^6CFU/ml$) and exceeded recommended bacteria limits($10^5CFU/ml$). Conclusions: It is necessary for MWF handling workplaces to conduct periodical biohazard inspection of MWF storage tanks. Additionally, further research may be necessary to establish biological occupational exposure limits.

Teaching Status and Knowledge of Elementary School Teachers of Children with Attention Deficit Hyperactivity Disorder (주의력결핍과잉행동장애 아동에 대한 초등교사의 지도실태와 지식)

  • Kang, Kyoung-Rim;Kim, Young-Hae;Yang, Young-Ok
    • Child Health Nursing Research
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    • v.17 no.2
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    • pp.136-144
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    • 2011
  • Purpose: The purpose of this study was to analyze teaching status and knowledge about children with Attention Deficit Hyperactivity Disorder (ADHD) in elementary school teachers. Methods: The participants of this study were 204 elementary school teachers in Busan. From July to September 2010, the researchers collected data by using self-report questionnaires consisted of questions about their teachers' characteristics and teaching status and KADDS (36 items) developed by Sciutto, Terjesen and Frank. Frequency, percentage, arithmetic mean, standard deviation, t-test and ANOVA were used to analyze the data using SPSS WIN 16.0 program. Results: Less than 50% of the participants had previous education on ADHD. According to this experience, there were significant differences in participants' knowledge about children with ADHD (t=4.703, p<.001). For the 36 items, participants had an average of $19.19{\pm}4.58$ points out of a possible 36. Moreover, lack of knowledge about teaching children with ADHD and communication problems with the parents of these children were considered to be the most disturbing factors. Conclusion: These results suggest that networks among teachers, parents and medical care professionals should be established. The results also indicate that educational programs for elementary school teachers should be developed in order to identify and teach children with ADHD appropriately.