• Title/Summary/Keyword: Area-specific resistance

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Nickel Silicide Nanowire Growth and Applications

  • Kim, Joondong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.215-216
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    • 2013
  • The silicide is a compound of Si with an electropositive component. Silicides are commonly used in silicon-based microelectronics to reduce resistivity of gate and local interconnect metallization. The popular silicide candidates, CoSi2 and TiSi2, have some limitations. TiSi2 showed line width dependent sheet resistance and has difficulty in transformation of the C49 phase to the low resistive C54. CoSi2 consumes more Si than TiSi2. Nickel silicide is a promising material to substitute for those silicide materials providing several advantages; low resistivity, lower Si consumption and lower formation temperature. Nickel silicide (NiSi) nanowire (NW) has features of a geometrically tiny size in terms of diameter and significantly long directional length, with an excellent electrical conductivity. According to these advantages, NiSi NWs have been applied to various nanoscale applications, such as interconnects [1,2], field emitters [3], and functional microscopy tips [4]. Beside its tiny geometric feature, NW can provide a large surface area at a fixed volume. This makes the material viable for photovoltaic architecture, allowing it to be used to enhance the light-active region [5]. Additionally, a recent report has suggested that an effective antireflection coating-layer can be made with by NiSi NW arrays [6]. A unique growth mechanism of nickel silicide (NiSi) nanowires (NWs) was thermodynamically investigated. The reaction between Ni and Si primarily determines NiSi phases according to the deposition condition. Optimum growth conditions were found at $375^{\circ}C$ leading long and high-density NiSi NWs. The ignition of NiSi NWs is determined by the grain size due to the nucleation limited silicide reaction. A successive Ni diffusion through a silicide layer was traced from a NW grown sample. Otherwise Ni-rich or Si-rich phase induces a film type growth. This work demonstrates specific existence of NiSi NW growth [7].

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Effect of Cell Size on the High Temperature Oxidation Properties of Fe-Cr-Al Powder Porous Metal Manufactured by Electro-spray Process (정전 분무 공정으로 제조된 Fe-Cr-Al 분말 다공체 금속의 고온 산화 특성에 미치는 기공 크기의 영향)

  • Oh, Jae-Sung;Kong, Young-Min;Kim, Byoung-Kee;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.21 no.1
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    • pp.55-61
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    • 2014
  • Fe-Cr-Al powder porous metal was manufactured by using new electro-spray process. First, ultra-fine fecralloy powders were produced by using the submerged electric wire explosion process. Evenly distributed colloid (0.05~0.5% powders) was dispersed on Polyurethane foam through the electro-spray process. And then degreasing and sintering processes were conduced. In order to examine the effect of cell size ($200{\mu}m$, $450{\mu}m$, $500{\mu}m$) in process, pre-samples were sintered for two hours at temperature of $1450^{\circ}C$, in $H_2$ atmospheres. A 24-hour thermo gravimetric analysis test was conducted at $1000^{\circ}C$ in a 79% $N_2$ + 21% $O_2$ to investigate the high temperature oxidation behavior of powder porous metal. The results of the high temperature oxidation tests showed that oxidation resistance increased with increasing cell size. In the $200{\mu}m$ porous metal with a thinner strut and larger specific surface area, the depletion of the stabilizing elements such as Al and Cr occurred more quickly during the high-temperature oxidation compared with the 450, $500{\mu}m$ porous metals.

The Role of Gut Microbiota in Obesity and Utilization of Fermented Herbal Extracts (비만에서 장내 미생물 균총의 역할과 발효 한양의 활용)

  • Park, Jung-Hyun;Kim, Ho-Jun;Lee, Myeong-Jong
    • Journal of Korean Medicine for Obesity Research
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    • v.9 no.1
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    • pp.1-14
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    • 2009
  • Complex microbial communities play an important role in the human health and co-evolved with human in the form of symbiosis. Many literatures provide new evidences that the increased prevalence of obesity cannot be attributed solely to changes in the human genome, nutritional habits, or reduction of physical activity in our daily lives. The intestinal flora was recently proposed as an environmental factor responsible for the control of body weight and energy metabolism. A number of studies suggest that the modulation of gut microbiota affects host metabolism and has an impact on energy storage and demonstrated a role for the gut microbiota in weight gain, fat increase, and insulin resistance. Variations in microbiota composition are found in obese humans and mice and the microbiota from an obese mouse confers an obese phenotype when transferred to an axenic mouse. As well, the gut microbial flora plays a role in converting nutrients into calories. Specific strategies for modifying gut microbiota may be a useful means to treat or prevent obesity. Dietary modulations of gut microbiota with a view to increasing bifidobacteria have demonstrated to reduce endotoxemia and improve metabolic diseases such as obesity. The fermentation of medicinal herbs is intended to exert a favorable influence on digestability, bioavailability and pharmacological activity of herbal extract. Therefore we also expect that the fermented herbal extracts may open up a new area to treat obesity through modulating gut microbiota.

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Synthesis of nickel fine powder in the mixed solvent of water and ethanol and ie oxidation behaviors (물과 에탄올의 혼합용매로부터 니켈 미분말의 합성 및 산화특성)

  • 이상근;최은영;이윤복;김광호;박희찬
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.3
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    • pp.139-144
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    • 2003
  • Nickel fine powders were prepared from nickel chloride aqueous solution containing ethanol as an organic solvent, and their oxidation behaviors were investigated. The reduction reaction by hydrazine from nickel chloride aqueous solution containing ethanol depend on reaction temperature. The reduction reaction time by hydrazine decreased with the increase of reaction temperature. By controlling reaction temperature, the products could be obtained spherical particles in the range of 0.1 $\mu\textrm{m}$~1.0 $\mu\textrm{m}$. Also, As reaction temperature increased from $40^{\circ}C$ to $80^{\circ}C$, the particle size slightly increased and had a broad size distribution owing to the presence of the coarse particles. The mean particle size and specific surface area of nickel powders prepared at $60^{\circ}C$ were 0.3 $\mu\textrm{m}$ and 31.8 $\m^2$/g, respectively. Weight loss of the powders at $300^{\circ}C$ was due to composition of $_Ni(OH)2$. In case of heat treatment at $200^{\circ}C$ in air, oxidation resistance of nickel powders was remarkable than that of as-synthesized.

Effects of Cobalt Protective Coating Prepared by DC Electroplating on Ferritic Stainless Steel for SOFC Interconnect (직류 전기도금을 이용한 고체산화물 연료전지 금속연결재용 페라이트계 스테인리스 스틸의 코발트 보호막 코팅 효과)

  • Hong, Jong-Eun;Lim, Tak-Hyung;Song, Rak-Hyun;Lee, Seung-Bok;Shin, Dong-Ryul;Yoo, Young-Sung;Lee, Dok-Yol
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.2
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    • pp.116-124
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    • 2009
  • We investigated the influences of cobalt coating deposited by DC electroplating on the ferritic stainless steel, STS 430, as a protective layer on a metallic interconnect for SOFC applications. Cobalt coated STS 430 revealed a uniform and denser-packing oxide surface and a reduced growth rate of $Cr_2O_3$ scales after oxidation at $800^{\circ}C$in air. Cobalt coating layer was oxidized to $CoCo_2O_4$ and Co containing mixed oxide spinels such as $Co_2CrO_4$, $CoCr_2O_4$, and $CoCrFeO_4$. The area specific resistance value of Co coated sample was $0.020\;{\Omega}cm^2$ lower than that of uncoated at $800^{\circ}C$ in air during 500 h. After 1000 h oxidation, cobalt oxide coating layer suppressed chromium outward diffusion.

Biomechanical Analysis at the Start of Bobsleigh Run in Preparation for the 2018 Pyeongchang Winter Olympics

  • Park, Seungbum;Lee, Kyungdeuk;Kim, Daewoong;Yoo, Junghyeon;Jung, Jaemin;Park, Kyunghwan
    • Korean Journal of Applied Biomechanics
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    • v.27 no.4
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    • pp.239-245
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    • 2017
  • Objective: The bobsleigh shoes used in the start section are one of the most important equipment for improving the competition. Despite the importance of the start section, there are no shoes that are specific for bobsleigh athletes in Korea and Korean athletes have to wear sprint spike shoes and practice the start instead of wearing bobsleigh shoes. The objective of the present study was to provide data for improving the performance of Korean bobsleigh athletes by investigating the differences in their split time, plantar pressure, and forefoot bending angle based on skill levels at the start of a run under the same conditions as training conditions. Method: Six Korean bobsleigh athletes were divided into two groups, superior (n=3) and non-superior (n=3). A digital speedometer measured the split time at the start; the Pedar-X system (Novel, Germany) measured plantar pressure. Plantar pressures and split times were measured as the athletes pushed a bobsleigh and sprinted at full speed from the start line to the 10-m mark on the bobsleigh track. An ultra-high-speed camera was used to measure the forefoot bending angle during the start phase. Results: Significant between-group differences were found in split times (p<.000; superior = 2.38 s, non-superior = 2.52 s). The superior group had a larger rearfoot (p<.05) contact area, maximum rearfoot force (p<.01), and a larger change in angles 3 and 4 (p<.05). Conclusion: At the start of a bobsleigh run, proper use of the rearfoot for achieving effective driving force and increasing frictional resistance through a wider frictional force can shorten start time.

Preparation of Gas Sensor from Pitch-based Activated Carbon Fibers and Its Toxic Gas Sensing Characteristics (피치계 활성탄소섬유기반 가스센서 제조 및 유해가스 감응 특성)

  • Kim, Min Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.193-197
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    • 2014
  • The electrode for gas sensor was prepared by using pitch-based activated carbon fibers and polyvinyl alcohol (PVA) to investigate the toxic gas sensing characteristics. The physicochemical properties of activated carbon fibers electrode for gas sensor were analyzed with SEM and BET. Toxic gases sensing property of the electrode was also identified by different toxic gases such as $NH_3$, NO and $CO_2$. The specific surface area of activated carbon fibers electrode for gas sensor was decreased by 33% owing to PVA used as a binder compared with the activated carbon fibers. However, its pore size distribution of the ACF electrode was not greatly influenced by PVA. The activated carbon fibers electrode for gas sensor responded to toxic gases by electron hopping unlike semiconductor based gas sensors. In this study, activated carbon fibers electrode was decreased to 7.5% in resistance for the NH3 gas of the 100 ppm concentration and its $NH_3$ gas sensing property was confirmed the most excellent compared with other toxic gases.

Enhancement of Power Conversion Efficiency from Controlled Nanostructure in Polymer Bulk-Hetero Junction Solar Cells

  • Wang, Dong-Hwan;Park, O-Ok;Park, Jong-Hyeok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.76-76
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    • 2011
  • Polymer-fullerene based bulk heterojunction (BHJ) solar cells can be fabricated in large area using low-cost roll-to-roll manufacturing methods. However, because of the low mobility of the BHJ materials, there is competition between the sweep-out of the photogenerated carriers by the built-in potential and recombination within the thin BHJ film [12-15]. Useful film thicknesses are limited by recombination. Thus, there is a need to increase the absorption by the BHJ film without increasing film thickness. Metal nanoparticles exhibit localized surface plasmon resonances (LSPR) which couple strongly to the incident light. In addition, relatively large metallic nanoparticles can reflect and scatter the light and thereby increase the optical path length within the BHJ film. Thus, the addition of metal nanoparticles into BHJ films offers the possibility of enhanced absorption and correspondingly enhanced photo-generation of mobile carriers. In this work, we have demonstrated several positive effects of shape controlled Au and Ag nanoparticles in organic P3HT/PC70BM, PCDTBT/PC70BM, Si-PCPDTBT/PC70BM BHJ-based PV devices. The use of an optimized concentration of Au and Ag nanomaterials in the BHJ film increases Jsc, FF, and the IPCE. These improvements result from a combination of enhanced light absorption caused by the light scattering of the nanomaterials in an active layer. Some of the metals induce the plasmon light concentration at specific wavelength. Moreover, improved charge transport results in low series resistance.

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Electrochemical Properties of La4Ni3O10-GDC Composite Cathode by Facile Sol-gel Method for IT-SOFCs

  • Choi, Sihyuk;Kim, Guntae
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.265-270
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    • 2014
  • Among the Ruddlesden-Popper series, $La_4Ni_3O_{10}$ has received widespread attention as a promising cathode material by reason of its favorable properties for realizing high performance of intermediate temperature solid oxide fuel cells (IT-SOFCs). The $La_4Ni_3O_{10}$ cathode is prepared using the facile sol-gel method by employing tri-blockcopolymer (F127) to obtain a single phase in a short sintering time. There are no reactions between the $La_4Ni_3O_{10}$ cathode and the $Ce_{0.9}Gd_{0.1}O_{2-\delta}$ (GDC) electrolyte upon sintering at $1000^{\circ}C$, indicating that the $La_4Ni_3O_{10}$ cathode has good chemical compatibility with the GDC electrolyte. The maximum electrical conductivity of $La_4Ni_3O_{10}$ reaches approximately 240 S $cm^{-1}$ at $100^{\circ}C$ and gradually decreases with increasing temperaturein air atmosphere. The area specific resistance value of $La_4Ni_3O_{10}$ composite with 40 wt% GDC is $0.435{\Omega}cm^2$ at $700^{\circ}C$. These data allow us to propose that the $La_4Ni_3O_{10}$-GDC composite cathode is a good candidate for IT-SOFC applications.

Predictive value of C-reactive protein in response to macrolides in children with macrolide-resistant Mycoplasma pneumoniae pneumonia

  • Seo, Young Ho;Kim, Jang Su;Seo, Sung Chul;Seo, Won Hee;Yoo, Young;Song, Dae Jin;Choung, Ji Tae
    • Clinical and Experimental Pediatrics
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    • v.57 no.4
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    • pp.186-192
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    • 2014
  • Purpose: The prevalence of macrolide-resistant Mycoplasma pneumoniae (MRMP) has increased worldwide. The aim of this study was to estimate the proportion of MRMP in a tertiary hospital in Korea, and to find potential laboratory markers that could be used to predict the efficacy of macrolides in children with MRMP pneumonia. Methods: A total of 95 patients with M. pneumoniae pneumonia were enrolled in this study. Detection of MRMP was based on the results of specific point mutations in domain V of the 23S rRNA gene. The medical records of these patients were reviewed retrospectively and the clinical course and laboratory data were compared. Results: The proportion of patients with MRMP was 51.6% and all MRMP isolates had the A2063G point mutation. The MRMP group had longer hospital stay and febrile period after initiation of macrolides. The levels of serum C-reactive protein (CRP) and interleukin-18 in nasopharyngeal aspirate were significantly higher in patients who did not respond to macrolide treatment. CRP was the only significant factor in predicting the efficacy of macrolides in patients with MRMP pneumonia. The area under the curve for CRP was 0.69 in receiver operating characteristic curve analysis, indicating reasonable discriminative power, and the optimal cutoff value was 40.7 mg/L. Conclusion: The proportion of patients with MRMP was high, suggesting that the prevalence of MRMP is rising rapidly in Korea. Serum CRP could be a useful marker for predicting the efficacy of macrolides and helping clinicians make better clinical decisions in children with MRMP pneumonia.