• Title/Summary/Keyword: Area-specific resistance

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A Study of Weldability for Pure Titanium by Nd:YAG Laser(IV) - Lap Welding and Application for Heat Exchanger - (순티타늄판의 Nd:YAG 레이저 용접성에 관한 연구(IV) - 겹치기 용접 및 실물 열교환기로의 적용 -)

  • Kim, Jong-Do;Kwak, Myung-Sub;Lee, Chang-Je;Kil, Byung-Lea
    • Journal of Welding and Joining
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    • v.28 no.1
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    • pp.66-71
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    • 2010
  • With large specific strength and outstanding corrosion resistance and erosion resistance in sea water, titanium and titanium alloy are widely used in heat exchanger production. In particular, pure titanium demonstrates outstanding molding performance and may be considered optimal for production of heat exchanger. Since titanium is very vulnerable to oxidation and embrittlement during welding, processes with less heat input are widely used, and laser welding is widely applied by considering production performance and shield etc in atmosphere. So far, 1st report and 2nd report compared and analyzed embrittlement degrees by bead colors of weldment through oxygen and nitrogen quantitative analysis and hardness measurement, and evaluated welding performance and mechanical properties of butt welding. This study evaluated field applicability of lap welding to heat exchange plate of LPG re-liquefaction device for ships through tensile stress test, hardness test and internal pressure test etc after deducing optimal weding condition and applying to actual heat exchange plate. In bead overlap area, the experiment produced sound welds with no porosity or defect by increasing and decreasing laser power, and tensile-shear test results indicated virtually the same tension and yield strength as base metal. As a result of measuring hardness at lateral cross section and bead overlap zone of actual heat exchanger welds, hardness difference within 20Hv was produced at base metal, HAZ and weldment, and as a result of pneumatic and hydraulic pressure test, no leakage occurred.

Effects of Attrition Milling in Wheat Flour on Starch Damaged of Dough and Bread Baking Properties (소맥분 제분시 발생되는 손상전분이 제빵 적성에 미치는 영향)

  • 주옥수;정용면
    • Food Science and Preservation
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    • v.8 no.4
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    • pp.434-441
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    • 2001
  • The purpose of this research is the establishment of optimal processing and the quality improvement of confectionary analysis of the damaged starch content of flour. I studied the rheological and bread making properties of the dough containing different damaged starch content. I examined rheological and physico- chemical characteristic farinograph, extensograph and amylograph with DNS, CWRS and SW containing 6.5%, 8.2%, 9.0%, 9.0% and 10.5% of damaged starch. And I measured the hardness and specific volume and performed the functional survey by rheometer for quality control. In the amylogram, at the damaged starch content 9.5% at such the maximum viscosity was 900 B.U. the volume of bread fermention tolerance were increased. In addition, the extensegram after 135 min showed that maximum resistance of the dough were 570 B.U at the damaged starch contents of 9.5% and the bread had homogeneous air cells and internal structures at the damaged starch contents of 9.5% at which the area(A), resistance(R) and R/E value of the dough were highest.

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Liquefaction Assessment Variations with Regard to the Cyclic Resistance Ratio Estimation Methods (전단저항강도비 산정 방법에 따른 액상화 평가의 변화)

  • Song, Sungwan;Kim, Hansaem;Cho, Wanjei
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.1
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    • pp.13-19
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    • 2020
  • Recently, as the number of earthquakes increases in the Korean Peninsula and surrounding area, the importance of earthquake countermeasures and seismic design has been increasing. As a result, interest and concerns about liquefaction, which is one of the problems that concern the earthquake, are increasing. There are various methods that can assess the possibility of liquefaction by using geotechnical information for specific ground. However, direct comparisons of each method are not yet available. In this study, the two methods using the SPT-N value and the shear wave velocity among the methods for estimating the Cyclic Resistance Ratio (CRR) value required for the simplified liquefaction assessment method were compared. And the correction of the ground information required to use the two methods respectively was compared. As a result, more accurate evaluation results were obtained when the CRR value is calculated using the SPT-N values.

Properties of Synthesis (BaSr)$(CoFe)O_3$ Cathode for IT-SOFC by GNP (GNP 법을 이용한 저온형 SOFC용 (BaSr)$(CoFe)O_3$ 공기극의 제조 및 특성 평가)

  • Lee, Mi-Jai;Moon, Ji-Woong;Kim, Sei-Ki;Ji, Mi-Jung;Hwang, Hae-Jin;Lim, Yong-Ho;Choi, Byung-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.51-54
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    • 2006
  • Cathode material, $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$, for low temperature SOFC was prepared by the glycine-nitrate synthesis process (GNP). The characteristics of the synthesized powders were studied with controlling pH of a precursor. The synthesis BSCF powders with pH were agglomeration state and calcinations temperature has not influence on particles. Highly acidicprecursor solution increased a single phase forming the temperature. Also, synthesis BSCF powder was show result for thermal analysis and alteration of difference crystal with pH. It is considered that Ba and Sr cannot complex by carboxylic acid group of glycine, because under highly acidic condition the caboxylic group mainly combined with $H^+$ insead of alkali and alkaline earth cations. In case of using precursor solution with pH $2{\sim}3$, a single perovskite phase was obtained at $1000^{\circ}C$. Polarization resistance of $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ was measured by AC impedance spectroscopy from the two electrode symmetric cell. Area specific resistance of the $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ air electrode at $500^{\circ}C\;and\;600^{\circ}C$ were $0.96{\Omega}?cm^2$ and $0.16{\Omega}?cm^2$, respectively.

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Nickel Oxide Nano-Flake Films Synthesized by Chemical Bath Deposition for Electrochemical Capacitors (CBD(Chemical Bath Deposition) 법으로 제조된 전기화학식 캐패시터용 NiO 나노박편 필름)

  • Kim, Young-Ha;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.163.2-163.2
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    • 2010
  • In this work, nano-flake shaped nickel oxide (NiO) films were synthesized by chemical bath deposition technique for electrochemical capacitors. The deposition was carried out for 1 and 2 h at room temperature using nickel foam as the substrate and the current collector. The structure and morphology of prepared NiO film were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). And, electrochemical properties were characterized by cyclic voltammetry, galvanostatic charge-discharge, and AC impedence measurement. It was found that the NiO film was constructed by many interconnected NiO nano-flakes which arranged vertically to the substrate, forming a net-like structure with large pores. The open macropores may facilitate the electrolyte penetration and ion migration, resulted in the utilization of nickel oxide due to the increased surface area for electrochemical reactions. Furthermore, it was found that the deposition onto nickel foam as substrate and curent collector led to decrease of the ion transfer resistance so that its specific capacitance of a NiO film had high value than NiO nano flake powder.

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Surface Treatment of LiFePo4 Cathode Material for Lithium Secondary Battery

  • Son, Jong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.13 no.4
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    • pp.246-250
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    • 2010
  • In this study, nano-crystallized $Al_2O_3$ was coated on the surface of $LiFePO_4$ powders via a novel dry coating method. The influence of coated $LiFePO_4$ upon electrochemical behavior was discussed. Surface morphology characterization was achieved by transmission electron microscopy (TEM), clearly showing nano-crystallized $Al_2O_3$ on $LiFePO_4$ surfaces. Furthermore, it revealed that the $Al_2O_3$-coated $LiFePO_4$ cathode exhibited a distinct surface morphology. It was also found that the $Al_2O_3$ coating reduces capacity fading especially at high charge/discharge rates. Results from the cyclic voltammogram measurements (2.5-4.2 V) showed a significant decrease in both interfacial resistance and cathode polarization. This behavior implies that $Al_2O_3$ can prevent structural change of $LiFePO_4$ or reaction with the electrolyte on cycling. In addition, the $Al_2O_3$ coated $LiFePO_4$ compound showed highly improved area-specific impedance (ASI), an important measure of battery performance. From the correlation between these characteristics of bare and coated $LiFePO_4$, the role of $Al_2O_3$ coating played on the electrochemical performance of $LiFePO_4$ was probed.

Interconnected meso/microporous carbon derived from pumpkin seeds as an efficient electrode material for supercapacitors

  • Gopiraman, Mayakrishnan;Saravanamoorthy, Somasundaram;Kim, Seung-Hyun;Chung, Ill-Min
    • Carbon letters
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    • v.24
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    • pp.73-81
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    • 2017
  • Interconnected meso/microporous activated carbons were prepared from pumpkin seeds using a simple chemical activation method. The porous carbon materials were prepared at different temperatures (PS-600, PS-700, PS-800, and PS-900) and demonstrated huge surface areas ($645-2029m^2g^{-1}$) with excellent pore volumes ($0.27-1.30cm^3g^{-1}$). The well-condensed graphitic structure of the prepared activated carbon materials was confirmed by Raman and X-ray diffraction analyses. The presence of heteroatoms (O and N) in the carbon materials was confirmed by X-ray photoemission spectroscopy. High resolution transmission electron microscopic images and selected area diffraction patters further revealed the porous structure and amorphous nature of the prepared electrode materials. The resultant porous carbons (PS-600, PS-700, PS-800, and PS-900) were utilized as electrode material for supercapacitors. To our delight, the PS-900 demonstrated a maximum specific capacitance (Cs) of $303F\;g^{-1}$ in 1.0 M $H_2SO_4 $ at a scan rate of 5 mV. The electrochemical impedance spectra confirmed the poor electrical resistance of the electrode materials. Moreover, the stability of the PS-900 was found to be excellent (no significant change in the Cs even after 6000 cycles).

Velocity and temperature profiles of Al/water micro fluid in a circular tube with swirl

  • Chang, Tae-Hyun;Lee, Kwon Soo;Lee, Chang-Hoan
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.7
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    • pp.677-684
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    • 2013
  • A lot study of convection heat transfer on internal flow has been extensively conducted in the past decades using of high specific surface area, increasing heat transfer coefficient, swirling flow and improving the transport properties. This study concerned with the application of a tangential slot swirl generator for improving heat transfer in a horizontal circular copper tube. The Al particles(about $100{\sim}130{\mu}m$) was employed for this experimental work. 3D PIV(particle image velocimetry) technique has employed to measure velocity profiles of Al particles with and without swirl flow. The copper tube is heated uniformly by winding of a heating coil for heat transfer work, having a resistance of 9 ohm per meter. Experiments are performed in the Reynolds number range of 6,800~12,100 with swirl and without swirl using Al particles. Experimental data for comparison of Nusselt number is presented that of with swirl and without swirl along the test tube for the Reynolds numbers. The Nusselt number is improved with increasing of Reynolds numbers or swirl intensities along the test tube. The Nusselt number with swirl flow is about 60.0% to 119.0% higher than that obtained by the Dittus-Boelter equation.

Study of $Pr_{0.3}Sr_{0.7}CO_{x}Fe_{(1-x)}O_{3-\delta}$ (x=0, 0.3, 0.5, 0.7, 1) as the cathode materials for intermediate temperature SOFC (${\cdot}$저온형 고체 산화물 연료전지의 공기극 물질로 사용되는 $Pr_{0.3}Sr_{0.7}CO_{x}Fe_{(1-x)}O_{3-\delta}$ (x=0, 0.3, 0.5, 0.7, 1) 에 관한 연구)

  • Park, Kwang-Jin;Kim, Jung-Hyun;Lee, Chang-Bo;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.125-128
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    • 2007
  • The influence of Co substitution in B-site at perovskite PSCF($Pr_{0.3}Sr_{0.7}CO_{x}Fe_{(1-x)}O_{3}$) was investigated in this study. The PSCF series exhibits excellent MIEC(mixed ionic electronic conductor) properties. ASR(area specific resistance) of PSCF3737 was 0.137 ${\Omega}{\cdot}cm^{2}$ at $700^{\circ}C$. The activation energy of PSCF3737 was also lower than other compositions of PSCF. ASR of PSCF3737 was analysed as two parts at different part of frequency region. Responses at middle frequency part (${\sim}10^2$ Hz) were concerned with oxygen reduction reaction and those at low frequency part (${\sim}10^{-1}$ Hz) were related with oxygen diffusion.

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Cathode Properties of Sm-Sr-(Co,Fe,Ni)-O System with Perovskite and Spinel Structures for Solid Oxide Fuel Cell (고체산화물 연료전지의 페로브스카이트와 스피넬 구조를 갖는 Sm-Sr-(Co,Fe,Ni)-O 시스템의 공기극 특성)

  • Baek, Seung-Wook;Kim, Jung-Hyun;Baek, Seung-Whan;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.133-136
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    • 2007
  • Perovskite-structured samarium strontium cobaltite (SSC), which is mixed ionic electronic conductor (MIEC), is considered as a promising cathode material for intermediate temperature-operating solid oxide fuel cell (SOFC) due to its high electrocatalytic property. Cathode material containing cobalt (Co) is unstable at high temperature and has a relatively high thermal expansion property. In this paper, Sm-Sr-(Co,Fe,Ni)-O system with perovskite and spinel structures was investigated in terms of electrochemical property and thermal expansion property, respectively. Area specific resistance (ASR) was measured by ac impedance spectroscopy to investigate the electrochemical property of cathode, and thermal expansion coefficient (TEC) was measured by using dilatometer. Micro structure of cathode was observed by scanning electron microscopy. Perovskite-structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ showed the ASR of $0.87{\Omega}/cm^{2}$, and $Sm_{0.5}Sr_{0.5}NiO_{3-\delta}$, which actually has a spinel structure, showed the lowest TEC value of $13.3{\times}10^{-6}/K$.

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