• Journal of the Mineralogical Society of Korea
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• v.26 no.2
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• pp.101-110
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• 2013

Due to the large specific surface area and great reactivity toward environmental contaminants, nanocrystalline mackinawite (FeS) has been widely applied for the remediation of contaminated groundwater and soil. Furthermore, nanocrystalline FeS is rather thermodynamically stable against anoxic corrosion, and its reactivity can be regenerated continuously by the activity of sulfate-reducing bacteria. However, nanocrystalline mackinawite is prone to either spread out along the groundwater flow or cause pore clogging in aquifers by particle aggregation. Accordingly, this mineral should be modified for the application of permeable reactive barriers (PRBs). In this study, coating methods were investigated by which mackinawite nanoparticles were deposited on the surface of alumina or activated alumina. The amount of FeS coating was found to significantly vary with pH, with the highest amount occurring at pH ~6.9 for both minerals. At this pH, the surfaces of mackinawite and alumina (or activated alumina) were oppositely charged, with the resultant electrostatic attraction making the coating highly effective. At this pH, the coating amounts by alumina and activated alumina were 0.038 and 0.114 $mmol{\cdot}FeS/g$, respectively. Under anoxic conditions, arsenite sorption experiments were conducted with uncoated alumina, uncoated activated alumina, and both minerals coated with FeS at the optimal pH for comparison of their reactivity. Uncoated activated alumina showed the higher arsenite removal compared to uncoated alumina. Notably, the arsenite sorption capacity of activated alumina was little changed by the coating with FeS. This might be attributed to the abundance of highly reactive hydroxyl functional groups (${\equiv}$AlOH) on the surface of activated alumina, making the arsenite sorption by the coated FeS unnoticeable. In contrast, the arsenite sorption capacity of alumina was found to increase substantially by the FeS coating. This was due to the consumption of the surface hydroxyl functional groups on the alumina surface and the subsequent occurrence of As(III) sorption by the coated FeS. Alumina, on the surface area basis, has about 8 times higher FeS coating amount and higher As(III) sorption capacity than silica. This study indicates that alumina is a better candidate than silica for the coating of nanocrystalline mackinawite.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.6
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• pp.320-324
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• 2013

The effects of $CeO_2$ on catalytic activity of $CeO_2-TiO_2$ for the selective catalytic reduction (SCR) of $NO_x$ were investigated in terms of structural, morphological, and physico-chemical analyseis. $CeO_2-TiO_2$ catalysts were synthesized with three different additions, 10, 20, and 30 wt% of $CeO_2$, by the sol-gel method. The XRD peaks of all specimens were assigned to a $TiO_2$ phase (anatase) and the peaks became broader with the addition of $CeO_2$ because it was dispersed as an amorphous phase on the surface of $TiO_2$ particles. The specific surface area of $TiO_2$ increased with the addition of $CeO_2$ from $60.6306m^2/g$ to $116.2791m^2/g$ due to suppression of $TiO_2$ grain growth by $CeO_2$. The 30 wt% $CeO_2-TiO_2$ catalyst, having the strongest catalytic acid sites ($Br{\Phi}nsted$ and Lewis), showed the highest $NO_x$ conversion efficiency of 98 % at $300^{\circ}C$ among the specimens. It was considered that $CeO_2$ contributes to the improvement of the $NO_x$ conversion of $CeO_2-TiO_2$ catalyst by increasing specific surface area and catalytic acid sites.

• Journal of the Korean Chemical Society
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• v.64 no.6
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• pp.416-428
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• 2020

This study analyzed the uses of external representations presented in the matter units of the 7th-grade science digital textbooks developed under the 2015 revised national curriculum. The level, form, presentation, and interactivity of external representations presented in 5 types of digital textbooks were analyzed. As for the level, the macroscopic level of representations was mainly presented. The macroscopic level and microscopic level of representations were presented together in the particle description. As for the form, visual-verbal and visual-nonverbal representations were usually presented across the board. Very few audial-verbal and audial-nonverbal representations were presented. Visual-verbal and audial-verbal representations were mostly presented in formal form, and visual-nonverbal representations were mostly presented in illustration without movement. The presentation of representations was analyzed in three aspects. First, visual-verbal and visual-nonverbal representations were mainly presented together and none of audial-verbal and visual-nonverbal representations were presented together. When the representations of the audial-verbal, visual-nonverbal, and visual-verbal were presented together, some of the information presented in audial-verbal representations was repeatedly presented in the visual-verbal representations. Second, audial-nonverbal representations not related to learning content were presented along with other representations. Third, there were few cases of arranging visual-verbal and visual-nonverbal representations on the next pages. Audialverbal and visual-nonverbal representations were always presented synchronized. As for the interactivity, the manipulation level was mainly presented in the main area, and the feedback level was mainly presented in the activity area. The adaptation level and the communication level of interactivity were presented very few. Based on the results, the implications for the direction of constructing digital textbooks were discussed.

• Journal of Environmental Impact Assessment
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• v.24 no.6
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• pp.578-592
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• 2015

To investigate characteristics and seasonal variations of carbonaceous species for $PM_{2.5}$ in Seoul metropolitan area, Korea, we measured organic carbon (OC) and elemental carbon (EC) from January 2014 to December 2014 using a semi-continuous OC/EC Analyzer (Model-4, Sunset Lab.). Mean concentrations of OC and EC were estimated $4.1{\pm}2.7{\mu}g/m^3$ and $1.6{\pm}1.0{\mu}g/m^3$, respectively. The annual averaged OC/EC ratio was $2.9{\pm}2.7$. Concentrations of OC and EC comprised 13% and 5% of $PM_{2.5}$ and the mass fraction of both was the highest in fall. OC and EC showed similar trend in seasonal variations. Concentrations of those showed a clear seasonal variation with the highest in winter and the lowest in summer. The correlations between the two were the best during the winter ($r^2=0.88$). As results of carbonaceous species analysis, the dominant factor in view of fine particle ($PM_{2.5}$) is primary emission source such as mobile, fossil fuel combustion during commute time(08:00~10:00 or 17:00~21:00) and winter season. Continuous monitoring of atmospheric carbonaceous species is essential to provide the science-based data to policy-maker establishing the air quality improvement policy.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.633-638
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• 2011

Mn substituted La, Sr or Ba-hexaaluminate were prepared by $(NH_4)_2CO_3$ co-precipitate method and calcined at $1,200^{\circ}C$ for 5 h. Catalysts were characterized by X-ray diffraction and $N_2$ physisorption and scanning electron microscope (SEM). Compared to $SrMnAl_{11}O_{19}$ and $BaMnAl_{11}O_{19}$, $LaMnAl_{11}O_{19}$ in which La located at mirror plane showed better crystallinity and high surface area, 13 $m^2/g$. $LaMnAl_{11}O_{19}$ revealed well developed plate-like structure which is characteristic structure of hexaaluminate. The catalytic activity of methane combustion increased in the following order: $LaMnAl_{11}O_{19}$ > $SrMnAl_{11}O_{19}$ > $BaMnAl_{11}O_{19}$ and was dependent on surface area of catalysts. 60 wt% $CeO_2/LaMnAl_{11}O_{19}$ calcined at $700^{\circ}C$ showed enhanced methane activity and methane was oxidized completely at low temperature ($700^{\circ}C$). It was confirmed that addition of ceria seems to be effective for the low and middle temperature combustion of methane. But, after calcination at high temperature of $1,200^{\circ}C$, it lost the promoting effect of ceria due to increase of ceria particle size and it had a limit to applying to the high temperature catalytic combustion.

• Journal of Radiation Protection and Research
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• v.41 no.1
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• pp.31-39
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• 2016

Background: It is necessary to consider the overall countermeasure for analysis of nuclear activities according to the increase of the nuclear facilities like nuclear power and reprocessing plants in the neighboring countries including China, Taiwan, North Korea, Japan and South Korea. South Korea and comprehensive nuclear-test-ban treaty organization (CTBTO) are now operating the monitoring instruments to detect radionuclides released into the air. It is important to estimate the origin of radionuclides measured using the detection technology as well as the monitoring analysis in aspects of investigation and security of the nuclear activities in neighboring countries. Materials and methods: A three-dimensional forward/backward trajectory model has been developed to estimate the origin of radionuclides for a covert nuclear activity. The developed trajectory model was composed of forward and backward modules to track the particle positions using finite difference method. Results and discussion: A three-dimensional trajectory model was validated using the measured data at Chernobyl accident. The calculated results showed a good agreement by using the high concentration measurements and the locations where was near a release point. The three-dimensional trajectory model had some uncertainty according to the release time, release height and time interval of the trajectory at each release points. An atmospheric dispersion model called long-range accident dose assessment system (LADAS), based on the fields of regards (FOR) technique, was applied to reduce the uncertainties of the trajectory model and to improve the detective technology for estimating the radioisotopes emission area. Conclusion: The detective technology developed in this study can evaluate in release area and origin for covert nuclear activities based on measured radioisotopes at monitoring stations, and it might play critical tool to improve the ability of the nuclear safety field.

• Progress in Medical Physics
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• v.10 no.1
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• pp.1-7
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• 1999

In this study, the dose distributions of a $^{32}$ p uniform cylindrical volume source and a surface source, a pure $\beta$emitter, were calculated in order to obtain information relevant to the utilization of a balloon catheter and a radioactive stent. The dose distributions of $^{32}$ p were calculated by means of the EGS4 code system. The sources are considered to be distributed uniformly in the volume and on the surface in the form of a cylinder with a radius of 1.5 mm and length of 20 mm. The energy of $\beta$particles emitted is chosen at random in the $\beta$ energy spectrum evaluated by the solution of the Dirac equation for the Coulomb potential. Liquid water is used to simulate the particle transport in the human body. The dose rates in a target at a 0.5mm radial distance from the surface of cylindrical volume and surface source are 12.133 cGy/s per GBq (0.449 cGy/s per mCi, uncertainty: 1.51%) and 24.732 cGy/s per GBq (0.915 cGy/s per mCi, uncertainty: 1.01%), respectively. The dose rates in the two sources decrease with distance in both radial and axial direction. On the basis of the above results, the determined initial activities were 29.69 mCi and 1.2278 $\mu$Ci for the balloon catheter and the radioactive stent using $^{32}$ P isotope, respectively. The total absorbed dose for optimal therapeutic regimen is considered to be 20 Gy and the treatment time in the case of the balloon catheter is less than 3 min. Absorbed doses in targets placed in a radial direction for the two sources were also calculated when it expressed initial activity in a 1 mCi/ml volume activity density for the cylindrical volume source and a 0.1 mCi/cm$^2$ area activity density for the surface source. The absorbed dose distribution around the $^{32}$ P cylindrical source with different size can be easily calculated using our results when the volume activity density and area activity density for the source are known.

• Korean Journal of Environmental Biology
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• v.40 no.2
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• pp.125-137
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• 2022

To assess the characteristics of meiofaunal community fluctuations related to environmental factors, seasonal surveys were conducted in the subtidal zone of Hallyeohaesang National Park. The average depth of the study area was about 20 m, and the average water temperature at the bottom was low in winter(11.33℃) and high in summer(17.95℃). The sedimentary particles mainly comprised silt and clay at most stations. The abundance of meiofauna ranged from 81.7 to 1,296.5 Inds. 10 cm^-2, and the average abundance was 589.3 Inds. 10 cm^-2. The average abundance of meiofauna in each season was the lowest at 416.5 Inds. 10cm^-2 in winter and the highest at 704.5Inds.10 cm^-2 in spring. The dominant taxa were nematodes (about 92%) and harpacticoids (about 5%). In the cluster analysis of meiofaunal communities, they were divided into four significant groups. The largest group mainly contained spring and summer samples, and contained stations with a high nematode density of over 500 Inds. 10 cm^-2 and harpacticoids below 50 Inds. 10 cm^-2 with a high composition ratio of nematodes. In the cluster analysis, no regional division was found between the stations, and it was thought to be divided by the seasons with high abundance according to seasonal variation and the composition ratio of nematodes and harpacticoids. In the Spearman rank correlation analysis, the density of total meiofauna and the most dominant taxa, nematodes, was not significantly related to environmental factors. However, the density of harpacticoids had a significant positive correlation with water depth and a negative correlation with sediment particle size.

• Korean Journal of Remote Sensing
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• v.33 no.5_1
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• pp.587-598
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• 2017

Volcanic ash is a fine particle smaller than 2 mm in diameters. It falls after the volcanic eruption and causes various damages to transportation, manufacturing industry and respiration of living things. Therefore diffusion information of volcanic ash is highly significant for preventing the damages from it. It is advantageous to utilize satellites for observing the widely diffusing volcanic ash. In this study volcanic ash diffusion information about two eruptions of Mt. Sakurajima were calculated using the geostationary satellite, Communication, Ocean and Meteorological Satellite (COMS) Meteorological Imager (MI) and polar-orbiting satellite, Landsat-8 Operational Land Imager (OLI) and the Thermal InfraRed Sensor (TIRS). The direction and velocity of volcanic ash diffusion were analyzed by extracting the volcanic ash pixels from COMS-MI images and the height was retrieved by adjusting the shadow method to Landsat-8 images. In comparison between the results of this study and those of Volcanic Ash Advisories center (VAAC), the volcanic ash tend to diffuse the same direction in both case. However, the diffusion velocity was about four times slower than VAAC information. Moreover, VAAC only provide an ash height while our study produced a variety of height information with respect to ash diffusion. The reason for different results is measured location. In case of VAAC, they produced approximate ash information around volcano crater to rapid response, while we conducted an analysis of the ash diffusion whole area using ash observed images. It is important to measure ash diffusion when large-scale eruption occurs around the Korean peninsula. In this study, it can be used to produce various ash information about the ash diffusion area using different characteristics satellite images.

• Journal of Wetlands Research
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• v.15 no.4
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• pp.555-566
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• 2013

Total maximum daily load enforced in 2004 is a program to evaluate the amount of pollutants by each land use type and manage to meet a target water quality of each waterbody. The many research to calculate runoff load of pollutants by landuse type have been studied. This study was conducted to calculate pollutants EMC, load and unit load in stormwater runoff generated from tomato growing area. Monitoring was conducted about 32 event during 4years and water quality parameters such as BOD, $COD_{Mn}$, TOC, TSS, TN, TP, $NH_3-N$, $NO_3-N$, $PO_4-P$ were analyzed at the laboratory. The average EMC were measured as follows: 9.6 BOD mg/L, 17.2 $COD_{Mn}$ mg/L, 5.5 TOC mg/L, 319.4 TSS mg/L, 4.4 T-N mg/L, 2.6 T-P mg/L, 0.5 $NH_3-N$ mg/L, 0.04 $NO_2-N$ mg/L, 2.6 $NO_3-N$ mg/L, 0.8 $PO_4-P$ mg/L. TN and TP is dichargeed as $NO_3-N$ and particle phosphorus type, respectively.