• Title/Summary/Keyword: Arc pressure

Search Result 379, Processing Time 0.025 seconds

Catalytic Activity of Au/$TiO_2$ and Pt/$TiO_2$ Nanocatalysts Synthesized by Arc Plasma Deposition

  • Jung, Chan-Ho;Kim, Sang-Hoon;Reddy, A.S.;Ha, H.;Park, Jeong-Y.
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.245-245
    • /
    • 2012
  • Syntheses of oxide supported metal catalysts by wet-chemical routes have been well known for their use in heterogeneous catalysis. However, uniform deposition of metal nanoparticles with controlled size and shape on the support with high reproducibility is still a challenge for catalyst preparation. Among various synthesis methods, arc plasma deposition (APD) of metal nanoparticles or thin films on oxide supports has received great interest recently, due to its high reproducibility and large-scale production, and used for their application in catalysis. In this work, Au and Pt nanoparticles with size of 1-2 nm have been deposited on titania powder by APD. The size of metal nanoparticles was controlled by number of shots of metal deposition and APD conditions. These catalytic materials were characterized by x-ray diffraction (XRD), inductively coupled plasma (ICP-AES), CO-chemisorption and transmission electron microscopy (TEM). Catalytic activity of the materials was measured by CO oxidation using oxygen, as a model reaction, in a micro-flow reactor at atmospheric pressure. We found that Au/$TiO_2$ is reactive, showing 100% conversion at $110^{\circ}C$, while Pt/$TiO_2$ shows 100% conversion at $200^{\circ}C$. High activity of metal nanoparticles suggests that APD can be used for large scale synthesis of active nanocatalysts. We will discuss the effect of the structure and metal-oxide interactions of the catalysts on catalytic activity.

  • PDF

Influence of Discharge Voltage-Current Characteristics on CO2 Reforming of Methane using an Elongated Arc Reactor (신장 아크 반응기를 이용한 메탄 CO2 개질반응에서 방전 전압-전류특성의 영향)

  • Kim, Kwan-Tae;Hwang, Na-Kyung;Lee, Jae-Ok;Lee, Dae-Hoon;Hur, Min;Song, Young-Hoon
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.26 no.6
    • /
    • pp.683-689
    • /
    • 2010
  • Reforming of methane with carbon dioxide has been carried out using a bipolar pulse driven elongated arc reactor operating at atmospheric pressure and non-equilibrium regime. This plasma reactor is driven by two kinds of power supply, characterized by different voltage-current characteristics under the same operating power and frequency. Varying the $CO_2/CH_4$ ratio and the discharge power, the conversion rate, yield, and reforming efficiency for the two power supplies are investigated in conjunction with the static and dynamic behaviors of voltage and current. It is found that not only the values of voltage and current but also their shapes give an influence on the reforming performances. Finally, a better electrical operation regime for the efficient plasma reforming is proposed based on the relationship between the voltage-current characteristics and the reforming performance.

Effect of Working Pressure and Substrate Bias on Phase Formation and Microstructure of Cr-Al-N Coatings

  • Choi, Seon-A;Kim, Seong-Won;Lee, Sung-Min;Kim, Hyung-Tae;Oh, Yoon-Suk
    • Journal of the Korean Ceramic Society
    • /
    • v.54 no.6
    • /
    • pp.511-517
    • /
    • 2017
  • With different working pressures and substrate biases, Cr-Al-N coatings were deposited by hybrid physical vapor deposition (PVD) method, consisting of unbalanced magnetron (UBM) sputtering and arc ion plating (AIP) processes. Cr and Al targets were used for the arc ion plating and the sputtering process, respectively. Phase analysis, and composition, binding energy, and microstructural analyses were performed using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (FESEM), respectively. Surface droplet size of Cr-Al-N coatings was found to decrease with increasing substrate bias. A decrease of the deposition rate of Cr-Al-N films was expected due to the increase of substrate bias. The coatings were grown with textured CrN phase and (111), (200), and (220) planes. X-ray diffraction data show that all Cr-Al-N coatings shifted to lower diffraction angles due to the addition of Al. The XPS results were used to determine the $Cr_2N$, CrN, and (Cr,Al)N binding energies. The compositions of the Cr-Al-N films were measured by XPS to be Cr 23.2~36.9 at%, Al 30.1~40.3 at%, and N 31.3~38.6 at%.

Numerical Method for Nonlinear Analysis of Composite Shells under Constant Lateral Pressure and Incremented In-plane Compression (일정 횡압력과 증분 압축하중을 동시에 받는 복합재 쉘의 비선형 해석을 위한 수치기법 연구)

  • 김진호;권진희
    • Composites Research
    • /
    • v.13 no.1
    • /
    • pp.69-77
    • /
    • 2000
  • This paper presents a modified arc-length method for the nonlinear finite element analysis of a structure which is loaded in incremental and fixed forces, simultaneously. The main idea of the method is to separate the displacement term by the constant force from that by the incremental force. Presented method is applied to the nonlinear analysis of isotropic shell structures separately loaded by lateral pressure or compression, and shows the excellent agreement with previous results. As an illustrative example of the applicability of the present algorithm, a parametric study is performed on the nonlinear buckling analysis of composite cylindrical panels under the combined load of the incremented compression and the constant lateral pressure.

  • PDF

Effects of a Flow Guide on the Arcing History in a Thermal Puffer Plasma Chamber (유동 가이드가 열파퍼 플라즈마 챔버의 아크현상 이력에 미치는 영향)

  • Lee, Jong-Chul;Kim, Youn-Jea
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.31 no.10
    • /
    • pp.832-839
    • /
    • 2007
  • The geometry and dimensions of an expansion chamber are decisive factors in thermal puffer plasma chamber designs. Because they together dominate the temperature and speed at which the cooling gas from the chamber flows back through a flow channel to the arcing zone for the successful interruption of fault currents. In this study, we calculated the flow and mass transfer driven by arc plasma, and investigated the effects of a flow guide installed inside a thermal puffer plasma chamber. It is found that the existing cold gas of the chamber mixes with hot gases entrained from the arcing zone and is subjected to compression due to pressure build-up in the chamber. The pressure build-up with the flow guide is larger than that without due to a vortex which rotates clockwise around the chamber center. By the reverse pressure gradient, the mixing gas of the chamber flows back out for cooling down the residual plasma near current zero. In the case with the flow guide, the temperature just before current zero is lower than that without, and the Cu concentration with high electrical conductivity is also less than that without the flow guide.

Parameter Study for the Analysis of Impact Characteristics considering Dynamic Material Properties (동적 물성치를 고려한 V.I. 충격인자의 영향 분석)

  • Lim, J.H.;Song, J.H.;Huh, H.;Park, W.J.;Oh, I.S.;Choe, J.W.
    • Proceedings of the KSME Conference
    • /
    • 2001.06a
    • /
    • pp.945-950
    • /
    • 2001
  • Vacuum interrupters that is used in various switchgear components such as circuit breakers, distribution switches, contactors, etc. spreads the arc uniformly over the surface of the contacts. The electrode of vacuum interrupters is used sintered Cu-Cr material satisfied with good electrical and mechanical characteristics. Because the closing velocity is 1-3m/s, the deformation of the material of electrodes depends on the strain rate and the dynamic behavior of the sintered Cu-Cr material is a key to investigate the impact characteristics of the electrodes. The dynamic response of the material at the high strain-rate is obtained from the split Hopkinson pressure bar test using cylinder type specimens. Experimental results from both quasi-static and dynamic compressive tests with the split Hopkinson pressure bar apparatus are interpolated to construct the Johnson-Cook equation as the constitutive relation that should be applied to simulation of the dynamic behavior of electrodes. To evaluate impact characteristic of a vacuum interrupter, simulation is carried out with five parameters such as initial velocity, added mass of a movable electrode, wipe spring constant, initial offset of a wipe spring and virtual fixed spring constant.

  • PDF

The measurement of three-dimensional temporal behavior according to the pressure in the plasma display panel (플라즈마 디스플레이 패널의 압력별 3차원 시간 분해 측정)

  • Kim, Son-Ic;Choi, Hoon-Young;Lee, Seok-Hyun;Lee, Seung-Gol
    • Proceedings of the KIEE Conference
    • /
    • 2002.07c
    • /
    • pp.1628-1630
    • /
    • 2002
  • In this paper, we measured 3-dimensional temporal behavior of the light emitted from discharge cell of plasma display panel(PDP) as a function of the pressure using the scanned point detecting system. The detected light signal through the PM tube is sent on the oscilloscope and oscilloscope which is connected to PC with GPIB. The whole system is controlled by a PC. From the temporal behavior results, we could analyze the discharge behavior of panel with Ne-Xe(4%) mixing gas and 300torr, 400torr, 500torr pressure. The top view of panel shows that the discharge moves from inner edge of cathode electrode to outer cathode electrode forming arc type. At the 300torr, initial emission time is very fast. The side view of panel shows that the light is detected up to $150{\mu}m$ height of barrier rib. In the panel of 300torr, emission distribution is wider than the others.

  • PDF

The Measurement of Three-Dimensional Temporal Behavior According to the Pressure in the Plasma Display Panel (플라즈마 디스플레이 패널에서 압력에 3차원 시간 분해 측정)

  • 최훈영;이석현;이승걸
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.52 no.10
    • /
    • pp.476-480
    • /
    • 2003
  • In this paper, we have performed 3-dimensional time-resolving measurement of the Ne light emitted from the cell of plasma display panel(PDP) as a function of the pressure using the scanned point detecting system. From the temporal behavior results, we could analyze the discharge behavior of panel with Ne-Xe(4%) mixing gas and 300 torr, 400 torr and 500 torr pressure. At the top view of panel, the discharge of 300 torr panel starts at the 634 ns and ends at the 722 ns. The emission duration time is about 90 ns. The discharge of 400 torr panel starts at the 682 ns and ends at the 786 ns. the emission duration time is about 100 ns. Also, the discharge of 500 torr panel starts at the 770 ns and ends at the 826 ns. the emission duration time is about 56 ns. The discharge moves from inner edge of cathode electrode to outer cathode electrode forming arc type. In the side view of 300 torr, 400 torr and 500 torr an emission shows that the light is detected up to 180${\mu}{\textrm}{m}$, 150${\mu}{\textrm}{m}$ and 70${\mu}{\textrm}{m}$ height of barrier rib and the emission distribution of the 300 torr is wider than 400 torr, 500 torr.

Reconstruction of Sacral Pressure Sores Using Perforator-Based Island Skin Flaps (천공분지에 기저를 둔 도서형 피부피판을 이용한 천골부 욕창의 재건)

  • Moon, Ji Hyun;Lee, Nae Ho
    • Archives of Reconstructive Microsurgery
    • /
    • v.9 no.1
    • /
    • pp.62-67
    • /
    • 2000
  • Recently, the incidence of pressure sore has been increased, due to increased number of patients with central nervous system injuries after traffic and industrial accidents or with long term loss of consciousness due to drug intoxication. The management of sacral pressure sore has been improved through the development of myocutaneous flap. However, sacrifice of the deep muscle cause some problems such as intraoperative bleeding, functional disabilities of donor site and further limitation of reconstruction for recurrent pressure sores in paraplegic patients. The development of perforator-based island skin flap introduce a new treatment modality for sacral pressure sores. We used perforator-based island skin flap in 15 cases with reasonable result from January 1998 to February 2000. This flap has a many advantages such as no significant sacrifice of the gluteus maximus muscle, wide rotation arc, reliable blood flow of the perforator, short elevation time for the flap, and no post-operative hindrance to walking in patients who are not paraplegic. There was no significant complication without significant sequelae and donor sites could be repaired primarily.

  • PDF

Filtration-induced pressure evolution in permeation grouting

  • Zhou, Zilong;Zang, Haizhi;Wang, Shanyong;Cai, Xin;Du, Xueming
    • Structural Engineering and Mechanics
    • /
    • v.75 no.5
    • /
    • pp.571-583
    • /
    • 2020
  • Permeation grouting is of great significance for consolidating geo-materials without disturbing the original geo-structure. To dip into the filtration-induced pressure increment that dominates the grout penetration in permeation grouting, nonlinear filtration coefficients embedded in a convection-filtration model were proposed, in which the volume of cement particles in grout and the deposited particles of skeleton were considered. An experiment was designed to determine the filtration coefficients and verify the model. The filtration coefficients deduced from experimental data were used in simulation, and the modelling results matched well with the experimental ones. The pressure drop revealed in experiments and captured in modelling demonstrated that the surge of inflow pressure lagged behind the stoppage of flow channels. In addition, both the consideration of the particles loss in liquid grout and the number of filtrated particles on pore walls presented an ideal trend in filtration rate, in which the filtration rate first rose rapidly and then reached to a steady plateau. Finally, this observed pressure drop was extended to the grouting design which alters the water to cement (W/C) ratio so as to alleviate the filtration effect. This study offers a novel insight into the filtration behaviour and has a practical meaning to extend penetration distance.