• Title/Summary/Keyword: Aqueous system

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Application of Sulfate Solvent in Acid Bake-water Leaching System for Valuable Metal Leaching from Sulfide Mineral (황화광물로부터 유용금속 침출을 위한 Acid Bake-water Leaching System 내 황산염 용매제의 적용성)

  • Ko, Chin Surk;Togtokhmaa, B.;Park, Cheon-Young
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.2
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    • pp.67-73
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    • 2018
  • The objective of this study was to investigate the application of sulfate solvents for the economic and eco-friendly leaching of valuable metals from Au concentrate using an acid bake-water leaching system (AWS). AWS experiments were performed using an electric furnace with various baking temperatures ($100-500^{\circ}C$) and sulfate solvents ($H_2SO_4$, $K_2SO_4$, $(NH_4)_2SO_4$, $MgSO_4$, and $CaSO_4$). The efficiency of the valuable metal leaching increased as the baking temperature was increased to $400^{\circ}C$. Based on the AWS leaching time experiments, the maximum leaching rate occurred with the aqueous $(NH_4)_2SO_4$ solvent. This study demonstrates that aqueous $(NH_4)_2SO_4$ could be used as an effective solvent for valuable metal leaching using an AWS.

Partition Coefficient of Proteins of Different Surface Hydrophobicity in Poly (ethylene glycol)-Dextran Aqueous Two Phase System (Poly(ethylene glycol)-Dextran 수용액 2상계에서 단백질들의 소수성에 따른 분획계수)

  • Lee, Sam-Pin;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.140-145
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    • 1987
  • The partition coefficient of the proteins of known effective hydrophobicity was determined in a poly (ethylene glycol)-dextran aqueous two-phase system. The changes in the partition coefficient was also determined when a fraction of PEG-palmitate (PEG-P) was added to the system. The partition coefficient of the proteins increased as the concentrations of PEG and dextran increased at a constant phase volume ration irrespective of the effective hydrophobicity of the proteins. When small amounts of PEG-P were added to the PEG phase, the partition coefficients of BSA and ${\beta}-lactoglobulin$, which had relative hydrophobicity (RI) of 700 and 120, respectively, increased more than ten-fold, whereas ovalbumin whose RI was 5 showed little change. The drastic increases m the partition coefficient were observed by the addition of PEG-P in 2% level to the PEG system. Addition of PEG-P over 5% level resulted in a slight further increase in the partition coefficient of all proteins tested.

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Studies on the Anticancer Effect of Broussonetia kazinoki Extracts (닥나무(Broussonetia kazinoki) 추출물의 항암효과에 관한 연구)

  • 민경진;정승희;구성자
    • Korean journal of food and cookery science
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    • v.15 no.3
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    • pp.231-237
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    • 1999
  • The anticancer effect of the bark of Broussonetia kazinoki root extracts (hexane. chloroform, ethylacetate, butanol, aqueous) were studied. The cytotoxicity by MTT assay and inhibitory effect on the growth of sarcoma 180 cells were tested in vitro. The reduction rate of the tumor formation and spleen/body weight rate on BALB/c mouse were tested in vivo. From the tests, each fraction showed the cytotoxic effect against the sarcoma 180 cells. In addition, as the concentration of the fractions increased, cytotoxic effect tendency increased as well. The cytotoxic rate of the hexane, chloroform, ethylacetate, butanol and aqueous fractions showed by 58.7%, 40.1%, 75.7%, 52.6% and 62.7% respectively after testing by MTT assay system. And sarcoma 180 cells were incubated for 6 days at 37$^{\circ}C$ with various concentrations of each fraction. As the incubation days go on, the number of cells increased, while the inhibition rate on the growth of sarcoma 180 cells were decreased. Especially the ethylacetate fraction at the concentration of 1.0 mg/ml strongly inhibited the growth of sarcoma 180 cells by 74% compared with the control for a day 37$^{\circ}C$ The hexane, chloroform, ethylacetate, butanol and aqueous fractions inhibited on the growth of sarcoma 180 cells by 31%, 19%, 60%, 30% and 42% respectively, when sarcoma 180 cells has been incubated for 6 days at 37$^{\circ}C$. The each fraction exhibited the antitumor effect in vivo. The ethylacetate fraction reduced the tumor formation by 41% compared with the control, when sarcoma 180 cells were injected subcutaneously into the left groin of BALB/c mice. Also spleen/body weight rate of ethylacetate fraction was increased by 2.10% compared with the control (1.08%). And it is considered that there would be no toxic effect caused by each fraction of body weight and organ as there was on more changes in mouse' weight compared with the control.

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Solubility Study of Nickel Ferrite in Boric Acid Using a Flow-Through Autoclave System under High Temperature and High Pressure

  • Park, Yong Joon;Choi, Ke-Chon;Ha, Yeong-Keong
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.554-558
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    • 2016
  • The solubility of nickel ferrite in an aqueous solution of boric acid was studied by varying the pH at the temperatures ranging from $25^{\circ}C$ to $320^{\circ}C$. A flow-through autoclave system was specially designed and fabricated to measure the solubility of Fe in hydrothermal solutions under high temperature and pressure. The performance of this flow-through system was directly compared with the conventional static state technique using a batch-type autoclave system. The stability of fluid velocity for the flow-through autoclave system was verified prior to the solubility measurement. The influence of chemical additives, such as boric acid and $H_2$, on the solubility of nickel ferrite was also evaluated.

Modeling Bacteria Facilitated Contaminant Transport in Porous Media with Kinetic Adsorption Relationships (동역학적 흡착 관계식을 이용한 다공 매질에서의 유동세균에 의한 유기성 오염물의 가속이송 예측 모델)

  • 김승현
    • Journal of the Korean Society of Groundwater Environment
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    • v.2 no.1
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    • pp.22-29
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    • 1995
  • Mobile bacterial particles can act as carriers and enhance the transport of hydrophobic contaminants in ground water by reducing retardation effects. Because of their colloidal size and favorable surface conditions, bacteria can act as efficient contaminant carriers. When such carriers exist in a porous medium, the system can be thought of as three phases: an aqueous phase, a carrier phase, and a stationary solid matrix phase. Contaminant can be present in either or all of these phases. In this study, a mathematical model based on mass balances is developed to describe the transport and fate of biodegradable contaminant in a porous medium. Bacterial mass transfer mechanism between aqueous and solid matrix phases, and contaminant mass transfer between aqueous and bacterial phases are represented by kinetic models. Governing equations are non-dimensionalized and solved to analyze the bacteria facilitated contaminant transport. The numerical results of the facilitation effect match favorably with experimental data reported in the literature. Results show that the contaminant transport can be described by local equilibrium assumption when Damkohler numbers are larger than 10. Significant sensitivities to model parameters, particularly bacterial growth rate and influent bacterial concentration, were discovered.

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Relation between Huggins Constant and Compatibility of Binary Polymer Mixtures in the Aqueous Ternary Systems

  • Isamu Inamura;Makoto Kittaka;Tatsuya Aikou;Kazuhiko Akiyama;Tomoyuki Matsuyama;Masatsugu Hiroto;Hirade, Ken-ichi;Yuji Jinbo
    • Macromolecular Research
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    • v.12 no.2
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    • pp.246-250
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    • 2004
  • We have classified a number of aqueous ternary systems containing two different polymers into three types by focusing on the deviation of the Huggins constant k'from the additivity line. Systems of type I have negative deviations of k'; the repulsive interaction between the two different polymers dominates. In systems of type II, k' almost follows the additivity relation; the repulsive and attractive interactions between the two different polymers are balancing. Type III systems have positive deviations of k'; the attractive interactions are relatively dominant. This classification of systems is supported by the fact that the positive and negative deviations of k' from the additivity line also correspond to the sign of interaction parameter between polymer 2 and 3, Δb$\_$23/. Furthermore, we have verified the relatively high compatibility between dextran and poly(vinyl alcohol) by determining the binodal concentration of a liquid-liquid phase separation for a water/dextran/poly(vinyl alcohol) system, which is classified as type III. Thus, we found that the compositional dependence of k' closely relates to the compatibility of binary polymer mixtures in aqueous ternary systems.

A Fluid inclusion study of the Sannae granite and the associated Sannae W-Mo deposit, Southeastern Kyongsang Basin (경상분지 남동부의 산내화강암과 산내 W-MO 광상에 관한 유체포유물 연구)

  • 양경희;이준동
    • The Journal of the Petrological Society of Korea
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    • v.8 no.1
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    • pp.46-55
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    • 1999
  • Fluid inclusions in granite and hydrothermal quartz indicate that three fluids have affected the Sannae granite. The earliest fluid is represented by three-phase aqueous fluid inclusions with high salinity (38 to 46 wt.% NaCl equiv.). It was exsolves from a crystallizing melt and trapped at a relatively high-pressure condition. The secong fluid is represented by two-phase aqueous fluid inclusion with low entectic temperatures (< $-40^{\circ}C$). low- to moderate salinity (3 to 24.0 wt.% NaCl equiv.) and high homogenization temperatures$ ($309^{\circ}C$$473^{\circ}C$)($. This fluid was trapped at higher pressures than 300-500 bars and precipitated molybdenite and wolframite in quartz veins. It was probably generted by fluid-host rock interactions since they show a wide range of salinity within a narrow range of homogenization temperatures. The final fluid is represented by an aquenous fluid boiling that separated into high-salinity (34-38 wt.% NaCl equiv.) and low-salinity fluid (0 to 8.7 wt.%) at $303-376^{\circ}C$ and 50-150 bars. These boiling fluids precipitated euhedral quartz in miarolitic cavities. The compositions of the final fluid was rather complex in the $H_2$O-NaCl-KCI-$FeCl_2$ system. The Sannae granite was a locus for repeated fluid events including magmatic fluids during the final stage of crystallization, the convection of hydrothermal fluids causing a fluid ascending, fluid boiling, and the local W-Mo mineralization and formation of miarolitic cavities due to thermal, tectonic and compositional properties of the felsic granite.

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Effects of the Aqueous Extract of Epimedii Herba on the Production of Antibodies in Mice (음양곽(淫羊藿) 수추출물(水抽出物)이 생쥐의 항체생성(抗體生成)에 미치는 영향(影響))

  • Kim Joung-Hoon;Park Joung-Suk;Lee Kwan-Sun;Lim Kyu-Sang;Lee Kwang-Gyu;Woo Won-Hong
    • Herbal Formula Science
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    • v.8 no.1
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    • pp.343-358
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    • 2000
  • Epimedii Herba is an important traditional herb medicine widely used as a tonic. However, the mechanism of action of this drug on the immune system is not well studied. This study was performed to elucidate the effects of the aqueous extract of Epimedii Herba on the production of antibodies in mice. Antibodies in serum were detected in male ICR mice treated with the aqueous extract of Eplmedii Herba (AEEH) at a dosage of 40, 120, and 360mg/kg orally for 2 weeks. Effects of oral administration of AEEH on antibody forming responses were measured by enzyme linked immunosorbent assay (ELISA) of immunoglobulin (Ig) levels in serum. The results were as follows; 1. Epimedii Herba slightly decreased body weight gain. 2. Epimedii Herba significantly increased the relative spleen weight. 3. Epimedii Herba significantly increased total serum IgG levels. 4. Epimedii Herba significantly enhanced total serum IgG1 levels. 5. Epimedii Herba significantly increased total serum IgG2a levels. 6. Epimedii Herba markedly increased total serum IgM levels. These findings demonstrate that Epimedii Herba significantly enhances the production of antibodies at therapeutic concentrations, and suggest that administration of Epimedii Herba may prevent the host from immunologic diseases.

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Removal of different anionic dyes from aqueous solution by anion exchange membrane

  • Khan, Muhammad Ali;Khan, Muhammad Imran;Zafar, Shagufta
    • Membrane and Water Treatment
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    • v.8 no.3
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    • pp.259-277
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    • 2017
  • Adsorption is a widely used technique for the removal of dyes from wastewaters by variety of adsorbents. In this work, the main focus is on the potential assessment of anion exchange membrane for the removal of different dyes using batch system and investigation of experimental data by applying various kinetic and thermodynamic models. The removal of anionic dyes i.e., Eosin-B, Eriochrome Black-T and Congo Red by anion exchange membrane BII from aqueous solution was carried out and effect of various parameters such as contact time, membrane dosage, temperature and ionic strength on the percentage removal of anionic dyes was studied. The experimental data was assessed by kinetic models namely pseudo-first-order, pseudo-second-order, Elovich liquid film diffusion, Bangham and the modified Freundlich models equation have been used to analyze the experimental data. These results indicate that the adsorption of these anionic dyes on BII follows pseudo-second-order kinetics with maximum values of regression coefficient (0.992-0.998) for all the systems. The adsorption of dyes was more suitable to be controlled by a liquid film diffusion mechanism. The adsorptive removal of dye Eosin-B and Eriochrome Black-T were decreased with temperature and thermodynamic parameters such as free energy (${\Delta}G^o$), enthalpy (${\Delta}H^o$) and entropy (${\Delta}S^o$) for adsorption of dyes on membrane BII were calculated at 298 K, 308 K and 318 K. The values of enthalpy and entropy were negative for EB and EBT representing that the adsorption of these dyes on BII is physiosorptive and exothermic in nature. Whereas the positive values of enthalpy and entropy for CR adsorption on BII, indicating that its adsorption is endothermic and spontaneous in nature. It is evident from this study that anion exchange membrane has shown good potential for the removal of dyes from aqueous solution and it can be used as adsorbent for dues removal on commercial levels.

Study on the Compositions of Photosensitive Resistor Paste Using Epoxy Acrylate Oligomers and Conductive Carbonblack (에폭시 아크릴레이트 올리고머와 전도성 카본블랙을 이용한 감광성 저항 페이스트 조성 연구)

  • Park, Seong-Dae;Kang, Nam-Kee;Lim, Jin-Kyu;Kim, Dong-Kook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.421-421
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    • 2008
  • Generally, the polymer thick-film resistors for embedded organic or hybrid substrate are patterned by screen printing so that the accuracy of resistor pattern is not good and the tolerance of resistance is too high(${\pm}$20~30%). To reform these demerits, a method using Fodel$^{(R)}$ technology, which is the patterning method using a photosensitive resin to be developable by aqueous alkali-solution as a base polymer for thick-film pastes, was recently incorporated for the patterning of thermosetting thick-film resistor paste. Alkali-solution developable photosensitive resin system has a merit that the precise patterns can be obtained by UV exposure and aqueous development, so the essential point is to get the composition similar to PSR(photo solder resist) used for PCB process. In present research, we made the photopatternable resistor pastes using 8 kinds of epoxy acrylates and a conductive carbonblack (CDX-7055 Ultra), evaluated their developing performance, and then measured the resistance after final curing. To become developable by alkali-solution, epoxy acrylate oligomers with carboxyl group were prepared. Test coupons were fabricated by patterning copper foil on FR-4 CCL board, plating Ni/Au on the patterned copper electrode, applying the resistor paste on the board, exposing the applied paste to UV through Cr mask with resistor patterns, developing the exposed paste with aqueous alkali-solution (1wt% $Na_2CO_3$), drying the patterned paste at $80^{\circ}C$ oven, and then curing it at $200^{\circ}C$ during 1 hour. As a result, some test compositions couldn't be developed according to the kind of oligomer and, in the developed compositions, the measured resistance showed different results depending on the paste compositions though they had the same amount of carbonblack.

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