• Title/Summary/Keyword: Apparent electrical conductivity

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Electrical and Rheological Properties of Colloidal of Alumina Suspensions

  • Wang, Xu-Hong;Yoshihiro Hirata
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.215-232
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    • 2000
  • The Valence(Z) of positively and negatively charged alumina particles in the dilute suspensions was analyzed with the electrical conductivity of the suspensions. The mobility of negative particles was lower than that of positive particles at a similar Z value because of the stronger effect of chemical bonding over the hydrated particle surfaces. The apparent viscosity of acidic suspensions of 1-40 vol % solid was lower than that of basic suspensions. This result was discussed based on the three important effects of the valence, concentration and nature of hydrated surface of alumina particles. The density of alumina compacts consolidated by filtration through gypsum molds became lower for the basic suspensions than for the acidic suspensions. This result was correlated to the properties of the colloidal alumina suspensions.

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The Electric Properties And Fabrication of High Temperature Heating Elements of $MoSi_2$ (이규화몰리브덴 고온발열체의 전기적 특성 및 제조에 관한 연구)

  • 이후인;심건주;한상옥
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.605-608
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    • 2001
  • Molybdenum disilicide is widely used for manufacturing high-temperature heating elements owing to its low electrical resistivity, good thermal conductivity, and ability to withstand oxidation at high temperatures. MoSi$_2$heating elements with 4-5wt% of montmorillonite type bentonite as plasticzer and a small amount of Si$_3$N$_4$, ThO$_2$, and B as additives was manufactured. Extruded rods of 3.7mmø and 6.7mmø diameter and 400mm long were fabricated using a vacuum extruder, which were then sinrered for 4-5 hrs. at the max. temperrature of 140$0^{\circ}C$. After 10 minute's oxidation treatment, the diameter of the rod is reduced. The heating elements thus prepared was stable at 1$700^{\circ}C$ and the physical properties such as specific electrical resistivity, hardness, apparent densisty, thermal expansion coefficient, and bending strength were almost identical with thoes of commercial heating elements. In this study we have tried to gain the practical knowledge of manufacturing MoSi$_2$heating elements so that it may be utilized later in a research of pilot scale and eventually be transferred to industry.

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Effects of Deposition Conditions on the Deposition rate and physical properties of $SnO_2$ film produced by CVD (CVD에 의한 $SnO_2$ Film 제조시 증착조건이 Film의 증착속도 및 물리적 성질에 미치는 영향)

  • Lee, Dong-Yun;Lee, Sang-Rae
    • Journal of the Korean institute of surface engineering
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    • v.18 no.3
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    • pp.116-124
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    • 1985
  • Chemical vapor deposition of $SnO_2$ on Pyrex glass substrate has been investigated using $SnCl_4$ and Oxygen at relatively low temperatures(300-500$^{\circ}C$). The critical flow rate, which delineated the surface reaction controlled region from the mass transfer controlled region, was increased with deposition temperature. The apparent activation energy obtained in surface reaction controlled region was about 6Kcal/mole. The results show that deposition rate, electrical conductivity and transmittance were affected mainly by partial pressure of $SnCl_4$, but little by partial pressure f oxygen. The % transmission of 5000A-thick $SnO_2$ film was about 90% in visible spectrum region and sheet resistance was varied in 0.1-10${\Omega}$ per square shaped portion of the outer surface of the oxide.

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Spatial Variability of Soil Properties using Nested Variograms at Multiple Scales

  • Chung, Sun-Ok;Sudduth, Kenneth A.;Drummond, Scott T.;Kitchen, Newell R.
    • Journal of Biosystems Engineering
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    • v.39 no.4
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    • pp.377-388
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    • 2014
  • Purpose: Determining the spatial structure of data is important in understanding within-field variability for site-specific crop management. An understanding of the spatial structures present in the data may help illuminate interrelationships that are important in subsequent explanatory analyses, especially when site variables are correlated or are a combined response to multiple causative factors. Methods: In this study, correlation, principal component analysis, and single and nested variogram models were applied to soil electrical conductivity and chemical property data of two fields in central Missouri, USA. Results: Some variables that were highly correlated, or were strongly expressed in the same principal component, exhibited similar spatial ranges when fitted with a single variogram model. However, single variogram results were dependent on the active lag distance used, with short distances (30 m) required to fit short-range variability. Longer active lag distances only revealed long-range spatial components. Nested models generally yielded a better fit than single models for sensor-based conductivity data, where multiple scales of spatial structure were apparent. Gaussian-spherical nested models fit well to the data at both short (30 m) and long (300 m) active lag distances, generally capturing both short-range and long-range spatial components. As soil conductivity relates strongly to profile texture, we hypothesize that the short-range components may relate to the scale of erosion processes, while the long-range components are indicative of the scale of landscape morphology. Conclusion: In this study, we investigated the effect of changing active lag distance on the calculation of the range parameter. Future work investigating scale effects on other variogram parameters, including nugget and sill variances, may lead to better model selection and interpretation. Once this is achieved, separation of nested spatial components by factorial kriging may help to better define the correlations existing between spatial datasets.

MT response on the two dimensional anisotropic structure (2차원 이방성 구조의 MT 반응)

  • Lee, Chun Gi;Gwon, Byeong Du
    • Journal of the Korean Geophysical Society
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    • v.2 no.2
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    • pp.123-134
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    • 1999
  • Magnetotelluric responses may be affected by strong anisotropy of the high-conductivity layers (HCL) in the upper mantle or lower crust. We have studied two-dimensional anisotropy MT modelling to examine the effect of high anisotropic media. Electrical properties of a homogeneous anisotropic body are defined by a symmetric conductivity tensor and the problem is described by coupled diffusion equation in the frequency domain. In two-dimensional anisotropic environments, diagonal elements of the impedance tensor have higher values than those in isotropic environments. In some cases, TM mode phases reach more than 90°and apparent resistivities decrease for some frequency range because of telluric distortion. GB decomposition may be used to recover regional responses, but can be affected by the regional anisotropic effect. Considering these results, BC87 dataset was interpreted with a modified anisotropic model.

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Synthesis and Crystallization of Amorphous Calcium Carbonate by Gas-Liquid Reaction of System Ca($OH_2 O$)-$H_2$-$CO_2$ (Ca($OH_2$)-$H_2 O$-$CO_2$계의 기액반응으로부터 비정질 탄산칼슘의 합성 및 결정화)

  • Im, Jae-Seok;Kim, Ga-Yeon;Im, Goeng
    • The Journal of Engineering Research
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    • v.5 no.1
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    • pp.73-87
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    • 2004
  • The synthesis and crystallization of amorphous calcium carbonate($CaCO_3$.$nH_2 O$) obtained from gas-liquid reaction between aqueous solution of calcium hydroxide and carbon dioxide at 15~$50^{\circ}C$ are investigated by electrical conductometry, XRD and TEM. The results are as follows: The initial reaction products prior to the formation of precipitated calcium carbonate is amorphous calcium carbonate. The electrical conductivity values in the slurry are decreased during the formation of amorphous calcium carbonate which covers particle surface of calcium hydroxide and retard the dissolution of calcium hydroxide into the solution. that amorphous calcium carbonate is unstable in the aqueous solution and crystallizes finally to calcite by the through-solution reaction. While amorphous calcium carbonate crystallizes into chain-like calcite, the conductivity values are recovered rapidly and the apparent viscosity of slurry containing higher concentration of calcium hydroxide increase. At below pH 9.5, chain-like calcite separates into individual particles to form precipitated calcium carbonate. The formation and synthetic temperature range of amorphous calcium carbonate is most suitable a primary decreasing step(a-step) at $15^{\circ}C$ in the electrical conductometry.

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Effect of the Temperature on Resistivity of Carbon Black-Polyethylene Composites Below and Above Percolation Threshold (Carbon Black-Polyethylene복합재료의 Percolation Threshold 전후 저항율에 미치는 온도의 영향)

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.19 no.12
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    • pp.644-648
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    • 2009
  • Temperature dependency of resistivity of the carbon black-polyethylene composites below and above percolation threshold is studied based on the electrical conduction mechanism. Temperature coefficient of resistance of the composites below percolation threshold changed from minus to plus, increasing volume fraction of carbon black; this trend decreased with increasing volume fraction of carbon black. The temperature dependence of resistivity of the composites below percolation threshold can be explained with a tunneling conduction model by incorporating the effect of thermal expansion of the composites into a tunneling gap. Temperature coefficient of resistance of the composites above percolation threshold was positive and its absolute value increased with increasing volume fraction of carbon black. By assuming that the electrical conduction through percolating paths is a thermally activated process and by incorporating the effect of thermal expansion into the volume fraction of carbon black, the temperature dependency of the resistivity above percolation threshold has been well explained without violating the universal law of conductivity. The apparent activation energy is estimated to be 0.14 eV.

Determination of Refreshing Time of Natural Zeolite Used for Livestock Waste Water Clearing Based on Electrical Conductivity (축산폐수(畜産廢水) 처리시(處理時) 전기전도도(電氣傳導度)를 기준(基準)한 천연(天然) Zeolite의 교환시기(交換時期) 결정(決定))

  • Choi, Jyung;Seo, Young-Jin;Lee, Dong-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.2
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    • pp.130-136
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    • 1996
  • This study was carried out easily to determine the refreshing time of natural Zeolite used for the clearing of Livestock waste water and to investigate the relationship between EC of solution and adsorption amount on Zeolite. During the adsorption reaction, EC of supernatant solution decreased till the equilibrium was reached and kept a constant level after it. EC was greatly decreased with the concentration of solution and the magnitude of adsorbent. Decrease in EC of suspension was found to be lesser in addition of Na-Zeolite than Ca-Zeolite. EC change of Livestock waste water was shown to be similar tendency to that of the simulated waste water. On the cumulative adsorption isotherm, the EC of suspension increased until the EC value of the initial solution as the increase in treatment times. Therefore, it is apparent that the exchange point of natural zeolite should be in the vicinity of the EC value of initial waste water.

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Soil Properties of Reclaimed Tidel Lands and Tidelands of Western Sea Coast in Korea (우리나라 서해안 간척지 및 간석지 토양의 이화학적 특성)

  • Koo, Ja-Woong;Choi, Jin-Kyu;Son, Jae-Gwon
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.2
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    • pp.120-127
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    • 1998
  • This study was performed to produce basic data for developing prediction techniques of desalinization through analyzing soil properties of reclaimed tidal lands, using soil samples collected in 11 units of tidal land reclamation projects. The average apparent specific gravity (bulk density), real specific gravity (particle density), porosity, and saturation percentage were measured to be 1.33, 2.64, 49.6%, and 56.3%, respectively. It was estimated that the soil texture class of reclaimed tidal lands would be silt or silt loam. The electrical conductivity and exchangeable sodium percentage were estimated to be $20{\sim}40dS\;m^{-1}$ and 30~50% in the beginning of tidal land reclamation, and the value of pH was measured to be 6.5~7.9. In conclusion, the soil properties of reclaimed tidal lands could be descrived to be saline-sodic soils with the high electrical conductivity and exchangeable sodium percentage.

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Influence of Graphite Epoxy Composite Material on the Electrochemical Galvanic Corrosion of Metals (금속재료의 전기화학적 갈바닉 부식에 미치는 GECM의 영향)

  • Yoo, Y.R.;Son, Y.I.;Shim, G.T.;Kwon, Y.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.8 no.1
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    • pp.27-39
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    • 2009
  • Non metallic composite materials, for example, GECM(graphite epoxy composite material) show high specific strength because of low density. These kinds of non metallic composite materials improved the structural effectiveness and operation economics. However, if these materials contacted several metals, corrosion can be arisen since non metallic composite materials have electrical conductivity. This paper dealt with galvanic corrosion between graphite epoxy composite material and several metals. Base on the electrochemical galvanic corrosion test between GECM and metals, corrosion current of carbon steel and aluminium increased with time but corrosion current of stainless steels and titanium decreased and galvanic potential increased. This behavior shows the galvanic corrosion depends upon the presence of passive film. Also, galvanic effect of GECM coupled with ferrous alloys and non-ferrous alloys was lower than that of 100% graphite, which is attributed to lower exposed area of graphite fiber in the GECM than apparent area of the GECM specimen used for the calculation of galvanic current in this work.