• Title/Summary/Keyword: Antiferromagnetic materials

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SPIN GLASS BEHAVIOR AND ANTIFERROMAGNETIC EXCHANGE COUPLING IN LASER-DEPOSITED $Zn_{1-x}Co_xO$ THIN FILMS

  • Kim, Hyojin;Kim, Dojin;Ihm, Young-Eon;Kim, Jae-Hyun;Choo, Woong-Kil
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.94-95
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    • 2002
  • Recently, we have seen a rapid advance in the evolving field of spin electronics (or spintronics). In spintronics, some feasibilities of new electronic applications utilizing spin degree of freedom have been explored. Diluted magnetic semiconductors (DMSs) are premising materials for spintronics because they have both charge and spin degree of freedom in a single substance. DMSs are refereed to semiconductor alloys in which some atoms are randomly substituted for by magnetic atoms. (omitted)

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NMR for magnetite

  • Lee, Soonchil
    • Journal of the Korean Magnetic Resonance Society
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    • v.22 no.4
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    • pp.101-106
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    • 2018
  • Magnetite is the oldest magnet material known to mankind. It is getting attention again from solid state physics researchers now a days because it is one of the most strongly correlated electron systems. Spin, charge, and orbital orders are interplaying with lattice and involved in the Verwey transition where magnetization, conductivity, and structure changes suddenly. The peculiar ordering states above and below the transition temperature mainly originate from the coexistence of $Fe^{2+}$ and $Fe^{3+}$ ions in the B site of the inverse spinel structure. In particular, the state of the charge and orbital order was the oldest and most intriguing problem. NMR has made significant contribution to the investigation of this question. A. Abragam stated that there is no doubt that NMR is a very powerful tool for the study of ferromagnetic and antiferromagnetic materials. In this mini-review, a short history of NMR investigation of magnetite is presented, providing a support to Abragam's claim.

Study of the Magnetization Reversal Behavior of exchange-Biased System Using Polarized Neutron Reflectometry

  • Park, Sung-Kyun;Kim, Ki-Yeon;Kim, Ji-Wan;Choi, Hyeok-Cheol;Teichert, A.;You, Chun-Yeol;Shin, Sung-Cheol;Lee, Jeong-Soo;Fitzsimmons, M.R.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2011.06a
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    • pp.3-3
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    • 2011
  • Since the first discovery of exchange anisotropy on Co/CoO system[1], there have been numerous studies to explore the physical origin of exchange-biased system[2,3]. In this presentation, we report that how the polarized neutron reflectomery can be applied to study the magnetization reversal behavior of the exchange biased system. As an example, the detailed magnetization reversal mechanism of the exchange-biased Py(30 nm)/FeMn (0, 15, 30 nm)/CoFe(30 nm) trilayers was studied and found that the 15 nm antiferromagnetic FeMn layer mediates the magnetization reversal behaviors of both Py and CoFe layers through interlayer exchange bias coupling. We also update the current activities in polarized neutron reflectometer in HANARO.

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[ $^{11}B$ ] Nuclear Magnetic Resonance Study of Spin Structures in Terbium Tetraboride

  • Mean, B.J.;Kang, K.H.;Kim, J.H.;Hyun, I.N.;Lee, Moo-Hee;Cho, B.K.
    • Journal of the Korean Magnetic Resonance Society
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    • v.10 no.2
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    • pp.197-202
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    • 2006
  • [ $^{11}B$ ] nuclear magnetic resonance (NMR) measurements were performed on the single crystals of $TbB_4$ to investigate local electronic structure and 4f spin dynamics. $^{11}B$ NMR spectrum, Knight shift, spin-lattice and spin-spin relaxation rates were measured down to 4K at 8T. $^{11}B$ NMR shift and linewidth are huge and strongly temperature dependent due to the 4f moments. In addition, both are proportional to magnetic susceptibility, indicating that the hyperfine field at the boron site originates from the 4f spins of Tb. Below $T_N$, the single broad resonance peak of $^{11}B$ NMR splits into several peaks reflecting the local magnetic fields due to antiferromagnetic spin arrangements. The longitudinal and the transverse relaxation rates, $1/T_1\;and\;1/T_2$, independent of temperature above $T_N$, decreases tremendously confirming huge suppression of spin fluctuation below $T_N$.

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Crystal Structure and Microstructure Variation of Nonstoichiometric Bi1±xFeO3±δ and Ti-doped BiFeO3 Ceramics under Various Sintering Conditions (비화학양론적 Bi1±xFeO3±δ와 Ti가 첨가된 BiFeO3의 소결조건에 따른 결정구조와 미세구조 변화)

  • Bae, Jihee;Kim, Jun Chan;Kim, Myong-Ho;Lee, Soonil
    • Korean Journal of Materials Research
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    • v.30 no.2
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    • pp.61-67
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    • 2020
  • BiFeO3 with perovskite structure is a well-known material that has both ferroelectric and antiferromagnetic properties called multiferroics. However, leaky electrical properties and difficulty of controlling stoichiometry due to Bi volatility and difficulty of obtaining high relative density due to high dependency on the ceramic process are issues for BiFeO3 applications. In this work we investigated the sintering behavior of samples with different stoichiometries and sintering conditions. To understand the optimum sintering conditions, nonstoichiometric Bi1±xFeO3±δ ceramics and Ti-doped Bi1.03Fe1-4x/3TixO3 ceramics were synthesized by a conventional solid-state route. Dense single phase BiFeO3 ceramics were successfully fabricated using a two-step sintering and quenching process. The effects of Bi volatility on microstructure were determined by Bi-excess and Ti doping. Bi-excess increased grain size, and Ti doping increased sintering temperature and decreased grain size. It should be noted that Ti-doping suppressed Bi volatility and stabilized the BiFeO3 phase.

Phase Evolution Behavior of (Bi,Nd)(Fe,Ti)$O_3$ Ceramics and Thin Films

  • Kim, Kyung-Man;Byun, Seung-Hyun;Yang, Pan;Lee, Yoon-Ho;Lee, Jai-Yeoul;Lee, Hee-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.331-332
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    • 2008
  • Couplings between electric, magnetic, and structural order parameters result in the so-called multiferroic phenomena with two or more ferroic phenomena such as ferroelectricity, ferromagnetism, or ferroelasticity. The simultaneous ferroelectricity and ferromagnetism (magnetoelectricity) permits potential applications in information storage, spintronics, and magnetic or electric field sensors. The perovskite BiFeO3(BFO) is known to be antiferromagnetic below the Neel temperature of 647K and ferroelectric with a high Curie temperature of 1043K. It exhibits weak magnetism at room temperature due to the residual moment from a canted spin structure. It is likely that non-stoichiometry and second-phase formation are the factors responsible for leakage current in BFO. It has been suggested that oxygen non-stoichiometry leads to valence fluctuations of Fe ions in BFO, resulting in high conductivity. To reduce the large leakage current of BFO, one attempt is to make donor-doped BFO compounds and thin films. In this study, (Bi1-x,Ndx)(Fe1-y,Tiy)O3 thin films have been deposited on Pt(111)/TiO2/SiO2/Si substrates by pulsed laser deposition. The effect of dopants on the phase evolution and surface morphology are analyzed. Furthermore, electrical and magnetic properties are measured and their coupling characteristics are discussed.

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Hysteresis Loops of Magnetically Coupled Multilayers - Experiment and Calculations

  • Czapkiewicz, M.;Stobiecki, T.;Rak, R.;Wrona, J.;Kim, C.G.
    • Journal of Magnetics
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    • v.9 no.2
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    • pp.60-64
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    • 2004
  • In this paper calculations of magnetisation and magnetoresistance characteristics of the Spin Valve (SV) and Pseudo Spin Valve (PSV) spintronics structures are reported and compared with the experimental data. The magnetisation reversal process was analysed with respect to the Stoner- Wohlfahrt model of total surface energy in terms of uniaxial anisotropy, exchange coupling between ferromagnetic layers, unidirectional exchange anisotropy of pinned layer (modelled by exchange coupling between magnetisation of pinned layer and net magnetisation of antiferromagnetic layer with high anisotropy). The numerical simulation of the model to the experimental magnetisation data yielded the above parameters for SV and PSV structures. These parameters were used to more sophistically micromagnetic modelling tool originating from the project called Object Oriented Micromagnetic Framework. Influence of the shape anisotropy of the Magnetic Tunnelling Junction cell used in MRAM was simulated by means of micromagnetic simulations. Results were compared to those obtained from the spot Kerr measurements.

Electron Spin Resonance Study of Fe3+ in (40-x)BaO⋅xFe2O3⋅60P2O5 Glasses ((40-x)BaO⋅xFe2O3⋅60P2O5 유리의 Fe3+이온에 관한 전자스핀공명 연구)

  • Kang, Eun-Tae
    • Journal of the Korean Ceramic Society
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    • v.45 no.3
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    • pp.179-184
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    • 2008
  • (40-x)BaO${\cdot}xFe_2O_3{\cdot}60P_2O_5$ glasses with $5{\leq}x{\leq}35mol%$ were investigated by ESR spectroscopy. Two resonances observed near g=2.0 and g=4.3. The line at g=4.3 disappeared with the increase of the $Fe_2O_3$ content. The resonance at $g{\approx}2.0$ displayed characteristic signal consisting of superposed extremely broad and narrow components. The broader one indicates the presence of the association of two or more $Fe^{3+}$ ions, antiferromagnetically and the narrow one is related to the microclusters involving iron ions. Temperature dependence of the ESR integrated intensity revealed short-range antiferromagnetic character for $x{\geq}15mol%$.

The Electronic Structure Calculations for Hexagonal Multiferroic Materials (다중강전자 상태를 가진 육방정계물질의 전자구조 계산)

  • Park, Key-Taeck
    • Journal of the Korean Magnetics Society
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    • v.17 no.4
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    • pp.152-155
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    • 2007
  • We have studied electronic structures and magnetic properties of $YMnO_3,\;ScManO_3$ with hexagonal structure using Full Potential Linearized Augmented Plane Wave (FLAPW) method based on LSDA method. LSDA calculation results show that multiferroic $YMnO_3$ shows energy gap due to hexagonal symmetry and magnetic interaction. Because of insulating gap and small Y ion, $YMnO_3$ shows magnetic and ferroelectric state. However, $ScMnO_3$ does not show the energy gap because of strong hybridization of Mn-O for LSDA calculation. We confirmed the stability of multiferroic state for $YMnO_3\;and\;ScManO_3$ using total energy calculations. The antiferromagnetic and ferroelectric states have the lowest energy about 100 meV.