• Proceedings of the Membrane Society of Korea Conference
• /
• 1998.04a
• /
• pp.99-101
• /
• 1998

1. Introduction : The conventional grafting polymerization technique requires chemically reactive groups on the surface as well as on the polymer chains. For this reason, a series of prefunctionalization steps are necessary for covalent grafting. The surface prefunctionalizational technique for grafting can be used to ionization radiation, UV, plasma, ion beam or chemical initiators. Of these techniques, radiation method is one of the useful methods because of uniform and rapid creation of active radical sites without catalytic contamination in grafted samples. If the diffusion of monomer into polymer is large enough to come to the inside of polymer substrate, a homogeneous and uniform grafting reaction can be carried out throughout the whole polymer substrate. Radiation-induced grafting method may attach specific functional moieties to a polymeric substrate, such as preirradiation and simultaneous irradiation. The former is irradiated at backbone polymer in vacuum or nitrogen gas and air, and then subsequent monomer grafting by trapped or peroxy radicals, while the latter is irradiated at backbone polymer in the presence of the monomer. Therefore, radiation-induced polymerization can be used to modification of the chemical and physical properties of the polymeric materials and has attracted considerable interest because it imparts desirable properties such as blood compatibility. membrane quality, ion excahnge, dyeability, protein adsorption, and immobilization of bioactive materials. Synthesizing biocompatible materials by radiation method such as preirradiation or simultaneous irradiation has often used $\gamma$-rays to graft hydrophilic monomers onto hydrophobic polymer substrates. In this work, in attempt to produce surfaces that show low levels of anti-fouling of bovine serum albumin(BSA) solutions, hydroxyethyl methacrylate(HEMA) was grafted polypropylene membrane surfaces by preirradiation technique. The anti-fouling effect of the polypropylene membrane after grafting was examined by permeation BSA solution.

• Membrane and Water Treatment
• /
• v.13 no.6
• /
• pp.259-290
• /
• 2022

Carbon nanotubes (CNTs), due to their excellent physical, chemical and mechanical properties and their ability to prepare new membranes with attractive properties, have found applications in water and wastewater technology. CNT functionalization, which involves the introduction of different types of functional groups into pure CNTs, improves the capabilities of CNT membranes for water and wastewater treatment. It turns out that CNT-based membranes have many advantages, including enhanced water permeability, high selectivity and anti-fouling properties. However, their full-scale application is still limited by their high cost. With their tremendous separation efficiency, low biofouling potential and ultra-high water flux, CNT membranes have the potential to be a leading technology in water treatment in the future, especially in desalination.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.27 no.8
• /
• pp.516-521
• /
• 2014

An excellent hydrophobic surface has a high contact angle over 147 degree and the contact angle hysteresis below $5^0$ was produced by using roughness combined with hydrophobic PTFE coatings, which were also confirmed to exhibit an extreme adhesion to glass substrate. To form the rough surface, the glass was etched by Ar-plasma. A very thin PTFE film was coated on the plasma etched glass surface. Roughness factors before or after PTFE coating on the plasma etched glass surface, based on Wensel's model were calculated, which agrees well with the dependence of the contact angle on the roughness factor is predicted by Wensel's model. The PTFE films deposited on glass by using a conventional rf-magnetron sputtering. The glass substrates were etched Ar-plasma prior to the deposition of PTFE. Their hydrophobicities are investigated for application as a anti-fouling coating layer on the screen of displays. It is found that the hydrophobicity of PTFE films mainly depends on the sputtering conditions, such as rf-power, Ar gas content introduced during deposition. These conditions are closely related to the deposition rate or thickness of PTFE film. Thus, it is also found that the deposition rate or the film thickness affects sensitively the geometrical morphology formed on surface of the rf-sputtered PTFE films. In particular, 1,950-nm-thick PTFE films deposited for 30 minute by rf-power 50 watt under Ar gas content of 20 sccm shows a very excellent optical transmittance and a good anti-fouling property and a good durability.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2012.11a
• /
• pp.66-67
• /
• 2012

As polymer coatings of nano-structured surface become significant to obtain functionalized materials, catechol derived from a mussel protein has attracted increasing attention for its universal adhesiveness. In addition to the unique adhesion property, its reducing ability of metal ions during oxidative polymerization to polydopamine (pD) widely expands the application of catechol molecules in the field of surface modification. In this study, we present the catechol conjugated smart polymer coatings for regulating surface properties such as wettability and anti-fouling effects. In additino, the in situ silver coating of electrospun polymer nanofibers using a silver-catechol redox reaction is presented as a simple method to produce metal nanostructures.

• Tribology and Lubricants
• /
• v.35 no.2
• /
• pp.94-98
• /
• 2019

The riblet structure like shark skin has been widely studied owing to its drag reduction and anti-fouling properties. In this study we simulated the wettability of an oil droplet on a riblet surface. We developed a numerical analysis method using the Wenzel equation and Cassie-Baxter equation that can estimate the contact angle with a penetrated depth of the droplet on rough surfaces. Riblet surfaces with nine scales composed of five hemi-elliptical ribs are generated numerically. The variation of contact angles with fractional depth of penetration for the generated riblet surfaces with and without coatings is demonstrated in the condition of solid-air-oil and solid-water-oil interfaces. The contact angle for the uncoated surface decreases with increasing fractional depth of penetration more drastically than that for the coated surface. For the effect of surface roughness on the contact angle of the droplet, the oleophilic surface gives lower contact angle when the surface is rougher, whereas the oleoophobic surface gives higher contact angle with higher roughness To verify the analysis results, the wetting angle was measured in the solid-air-oil interface and solid-water-oil interface for the shark-skin template and shark-skin replica. The effects of teflon coating were also evaluated. It is shown that the simulation results cover the experimental ones.

• Journal of the Korean institute of surface engineering
• /
• v.55 no.6
• /
• pp.425-432
• /
• 2022

Antifouling paints that inhibit the attachment and contamination of marine organisms mainly use TBT compounds, but because of their toxic components, they cause ecosystem disturbance and environmental destruction problems, so It is necessary to research eco-friendly antifouling paints that are easy to maintain and effective antifouling technologies. In this study, physical surface treatment of silane coating and chemical antifouling technology were applied to the metal surface to secure the stability of the surface of the marine structure and inhibit the attachment and growth of marine organisms. Adhesion of marine organisms was evaluated according to the coating conditions through surface evaluation of the charged material for 15 months in the waters of the west coast of Korea. In accordance with ASTM D6990-05, antifouling properties fouling rates (FR) and physical degradation rates(PDR) were evaluated through visual inspection of the evaluation specimens. As a result of evaluating the antifouling performance of the coated surface, it was confirmed that the antifouling performance was maintained at the 50% level even after 15 months in the sample subjected to physical processing and silane coating.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.22 no.2
• /
• pp.253-258
• /
• 2016

The $MnO_x-WO_3-TiO_2$ nanoscale powders were synthesized by sol-gel method in order to prevent the biological fouling on the ships and offshore structures. Powder characteristics and antifouling performance were investigated with respect to the crystalline, microstructure and surface property for application in self-polishing copolymer resins. The high antifouling activity of $TiO_2$-system biocide was attributed to its redox potential and soluble metal ions originating from tungsten oxides according to the improvements in the powder characteristics. Based on their physio-chemical characterizations, the specific surface areas of powders were about $90m^2/g$ and the grain size was in the region 100 ~ 150 nm. Powder characteristics and surface properties were improved by the addition of $WO_3$. Antifouling performance were analyzed according to their surface properties and static immersion tests to determine the effects of the $TiO_2$-system compounds. The surface of 2 wt. % added sample was clean for 5 month. This may be attributed to the ability of $MnO_x-WO_3-TiO_2$ powders to act as a promoter in antifouling agents.

• Science of Emotion and Sensibility
• /
• v.17 no.1
• /
• pp.29-38
• /
• 2014

In recent days, according as ergonomics and aesthetic engineering are important factors in the product market, there is a demand to develop automobile seat and interior designs which are focused on sensitive elements such as aesthetic and comfort features in order to satisfy the sensitive needs of consumers. To meet such demands, car seats are turning into functional and sensitive products that reflect elements of function and entertainment. According to such trends, this research is aimed to develop the illuminating car seat fabric that serve such functions as recognizing and reacting to car environments, which includes sensing over-speed, open doors, and unfastened safety belts through the illuminating car seat fabrics by optical fiber. For this purpose, basic physical properties of optical fiber are analyzed, appropriate weaving and etching technologies are applied, and the woven fabric of optical fiber for car seats are illuminating depend upon car environments. Moreover, the applicable woven fabric of optical fiber is deduced after evaluating the physical properties (such as tensile strength, heatproof, anti-fouling, washable and combustible traits) for the appropriateness of applying the woven fabric of optical fiber to car seats. For this purpose, the woven fabric of optical fiber is covered according to car seat processes; the optical fiber applied to seats is composed that it may be connected to one end of the connector linked to a LED so that it may perform functions like sensing over-speed, open doors, and unfastened safety belts; the sensed signals are transmitted to the control part, and luminescent signals are transmitted to LED.

• Applied Chemistry for Engineering
• /
• v.23 no.1
• /
• pp.71-76
• /
• 2012

Biofouling by marine organisms such as algae and barnacles causes lots of significant problems in marine systems such as a rise of the maintenance-repair cost for the ship and the marine structures. In this work, a fluoropolymer, perfluoropolyether (PFPE), was applied as an anti-biofouling coating material that prevents the adhesion of marine organisms and facilitates the removal of them. Water contact angles of various surfaces were tested to examine the hydrophobicity of the PFPE-modified surface. The PFPE-modified surface showed the water contact angle of $64.5^{\circ}$ which is a remarkable rise from $46.7^{\circ}$ of amine-treated surface. When the substrate was treated with PFPE, the adhesion on the of the barnacle and other marine organisms were repressed around 15% by the enhanced hydrophobicity. In addition, the removal the of the adhered marine organisms were better comparing to that of the surface prepared by PDMS. Surfaces of the substrate treated by PFPE were characterized through physical and chemical methods to analyze the biofouling results. Degree of biomolecular adhesion to the substrate was quantified by the measurement the fluorescence intensity of marine organisms dyed with green fluorescence. PFPE is expected to be applicable not only to anti-biofouling systems but also to medical devices where the prevention of protein adhesion is required.

• Journal of Ocean Engineering and Technology
• /
• v.30 no.6
• /
• pp.520-525
• /
• 2016

In this study, a mixture of polypropylene fibers and glass fibers were used to weave polypropylene/glass fiber-reinforced composite panels with characteristics such as highly elongated short fibers, high ductility, anti-fouling, and hydrophobicity as a result of a directional property. Mechanical and environmental tests were carried out with specimens fabricated with this composite panel, and its applicability to shipbuilding and ocean leisure industries was evaluated through a comparison with existing glass fiber-reinforced composite materials. The results of this experiment verified the excellence of the polypropylene/glass-mixed woven fiber-reinforced composite material compared to the existing glass fiber-reinforced composite material. However, the forming process needs to be changed to improve the weak interfacial bonding, and the properties of the composite material itself could be improved through mixed weaving with other fibers after development. Maximizing of the advantages of the polypropylene fibers and overcoming their shortcomings will improve their applicability to the shipbuilding, ocean leisure, and other industries, and increase the value of polypropylene fibers in the composite material market.