• Asian Journal of Atmospheric Environment
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• v.12 no.3
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• pp.274-288
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• 2018

Quantitative data of 50 non-polar organic compounds constituting $PM_{2.5}$ were continuously collected and analyzed from June 2016 to October 2017 (approximately 17 months) at Ichihara, one of the largest industrial areas in Japan. Target non-polar organic compounds including 21 species of polycyclic aromatic hydrocarbons (PAHs), 24 species of n-alkanes and 5 species of phthalate esters(PAEs) were simultaneously measured by gas chromatography/mass spectrometry. Basically, the average concentrations of the total PAHs, n-alkanes and PAEs in each season remained nearly level, and seasonal variations were little throughout the study period. These results suggest that the emission sources, which are not influenced by the seasons, are the dominant inputs for the target organic compounds. Diagnostic ratios of PAHs, assessment of n-alkane homologue distributions, carbon preference index, and the contribution of wax n-alkanes from plants were used to estimate source apportionments. These results indicate that anthropogenic sources were the main contributor for most PAHs and n-alkanes throughout the study period. The concentrations of PAEs selected in this study were low because emission amounts of these chemicals were little within the source areas of the sampling site. To our knowledge, this study is the first attempt to simultaneously measure a high number of non-polar organic compounds in $PM_{2.5}$ collected from the ambient air of Japan, and the resultant data will provide valuable data and information for environmental researchers.

• Environmental Engineering Research
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• v.23 no.2
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• pp.143-149
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• 2018

Air quality conditions and pollution status have been evaluated in the industrial area between Sharjah and Ajman border in UAE. Daily concentrations of $O_3$, CO, $NO_2$, $SO_2$, $PM_{2.5}$, $PM_{10}$, Total Volatile Organic Compounds (TVOC) and Total Suspended Particulate (TSP) have been monitored from Sept. 2015 to April 2016. The monthly average concentrations of $O_3$, CO, $NO_2$, $SO_2$, TVOC were within the UAE ambient air quality standards during the survey period. However, $PM_{10}$ and TSP levels exceeded the recommended limits in Sept. 2015, Oct. 2015 and March 2016. Temporal variations in air quality parameters showed highest levels in March 2016 for $PM_{2.5}$, $PM_{10}$, $NO_2$, TVOC and TSP, whereas $O_3$, $SO_2$ and CO showed relatively low values in this month. $PM_{2.5}$ levels in ambient air were above the EPA guideline of $35{\mu}g/m^3$ in all months. $PM_{2.5}$ was the critical ambient air pollutant with Index for Pollutant ($I_p$) values varying from 103-209, indicating Air Quality Index categories of unhealthy for sensitive groups (62.5%) to unhealthy (25%) to very unhealthy (12.5%). The $I_p$ average values of $PM_{2.5}$ decreased from Sept. 2015 to reach lowest value in Dec. 2015 before increasing gradually, peaking in March 2016. These results suggest the potential health risks associated with $PM_{2.5}$ is low in winter, where the prevailing meteorological conditions of lower temperatures, higher humidity, higher wind speed reduced particulate matter. The results revealed the industrial area is impacted by anthropogenic and natural sources of particulate matter.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2003.05a
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• pp.17-20
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• 2003

In a recent paper (Hartwig, ms.) I have shown that it is possible to understand and discuss the changing Austausch (i.e., exchange of air parcels between different atmospheric layers) between the stratosphere and troposphere by means of long-term measurement on series of spallation products. It is well known (Friend 1961; Muet et al. 1966, Hartwig et al. 1969) that there is a seasonal pattern in the 7Be concentration of ground-level air with a maximum during May-June. This maximum is caused by enhanced exchange processes between the atmospheric compartments of the stratosphere and troposphere during this interval. Generally, those exchange processes are a consequence of stability and dynamics of the atmospheric compartments, which themselves result from, among other factors, the distribution of the heat sources in those compartments, namely the ground and the ozone layer. Because of the growing importance of anthropogenic infrared-active gases in the atmosphere, it is to be expected that the relative importance of those original, naturally occurring heat sources will be of lesser significance, thus altering the Austausch. And indeed, it has been shown (Hartwig, ms.) by considering the ratio of the annual maximum and minimum during a 28-yr period of 7Be ground-level concentration at Braunschweig, Germany (10$^{\circ}$33'E, 52$^{\circ}$17'N) (Kolb 1992; Wershofen 1993), that there is a steady decline in that ratio, thus indicating alteration of atmospheric Austausch within the last three decades.(omitted)

• Asian Journal of Atmospheric Environment
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• v.9 no.4
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• pp.259-271
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• 2015

This study conducted analyses on biogenic volatile organic compounds (BVOC) emission sources contributing to urban ozone ($O_3$) concentration in Osaka Prefecture, Japan in summer 2010 by using the Weather Research and Forecasting model (WRF) version 3.5.1 and the Community Multiscale Air Quality model (CMAQ) version 5.0.1. This prefecture is characterized by highly urbanized area with small forest area. The contributions of source regions surrounding Osaka were estimated by comparing the baseline case and zero-out cases for BVOC emissions from each source region. The zero-out emission runs showed that the BVOC emissions substantially contributed to urban $O_3$ concentration in Osaka (10.3 ppb: 15.9% of mean daily maximum 1-h $O_3$ concentration) with day-by-day variations of contributing source regions, which were qualitatively explained by backward trajectory analyses. Although $O_3$ concentrations were especially high on 23 July and 2 August 2010, the contribution of BVOC on 23 July (35.4 ppb: 25.6% of daily maximum $O_3$) was much larger than that on 2 August (20.9 ppb: 14.2% of daily maximum $O_3$). To investigate this difference, additional zero-out cases for anthropogenic VOC (AVOC) emissions from Osaka and for VOC emissions on the target days were performed. On 23 July, the urban $O_3$ concentration in Osaka was dominantly increased by the transport from the northwestern region outside Osaka with large contribution of $O_3$ that was produced through BVOC reactions by the day before and was retained over the nocturnal boundary layer. On 2 August, the concentration was dominantly increased by the local photochemical production inside Osaka under weak wind condition with the particularly large contribution of AVOC emitted from Osaka on the day.

• Journal of Soil and Groundwater Environment
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• v.23 no.4
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• pp.48-59
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• 2018

Beryllium (Be), cobalt (Co), thallium (Tl) and vanadium (V) are candidates of 21 priority soil pollutants in Korea. The distribution of their concentration in soils from three contamination sources including industrial, roadside and mining areas was investigated. Concentrations of the metals were evaluated quantitatively using pollution indices and the fractionation of metals was conducted using modified SM&T (Standards Measurements and Testing programme) sequential extraction. Concentrations of the metals for all samples from industrial and roadside soils were within the range of natural background levels, while some of Be in soils from abandoned mines exceeded that the range. Enrichment Factor (EF) and Nemerow Integrated Pollution Index (NIPI) for Be, Co, Tl and V showed that there are effects or possibilities of anthropogenic activities. Pollution Load Index (PLI) analyses indicated all investigated sites needed further monitoring. The results of sequential extractions indicated mobile fractions (F1+F2) of Be, Tl and V were below 30% except some of Co in soil, which implies their low mobility to neighboring environment media. Variable tools like sequential extraction, comparison with background/actual concentration and pollution indices, as well as aqua regia extraction should be considered when evaluating Be, Co, Tl, V in soil.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.E4
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• pp.177-186
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• 2003

The total of 1,454 aerosol samples were collected by high volume tape sampler at the Gosan Site in Jeju Island from 1992 to 1999, and the major water-soluble ionic components were chemically analyzed. The mean concentrations of nss-S $O_4$$^{2-}$, N $H_4$$^{＋}$, and N $O_3$$^{[-10]}$ showed high values, which were 6.73, 1.45, and 1.45 ${\mu}{\textrm}{m}$/㎥, respectively, while $Ca^{2+}$ and $K^{+}$ concentrations were low with the values of 0.49 and 0.42 $\mu\textrm{g}$/㎥. The concentrations of most components increased in spring but decreased in summer, especially with the remarkable increase of $Ca^{2+}$ and N $O_3$$^{[-10]}$ concentrations in spring. The seasonal comparison of nss-S $O_4$$^{2-}$ concentrations showed higher values with the order of spring > fall 〉 winter〉 summer, but spring 〉 winter〉 fall 〉 summer for N $O_3$$^{[-10]}$ Meanwhile, the concentration levels of N $a^{+}$ and C $l^{[-10]}$ increased more in winter season. According to the investigation of wind direction effect, the concentrations of most aerosol ionic components showed higher values consistently at the westerly and northerly wind conditions. Based on the factor analysis, the atmospheric aerosols in the Gosan Site are considered to be largely affected by marine sources, followed by anthropogenic and soil sources.urces..

• Asian Journal of Atmospheric Environment
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• v.11 no.1
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• pp.29-32
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• 2017

Ozone concentration in Tokyo Metropolitan area is one of the most serious issues of the local air quality. Tropospheric ozone is formed by radical reaction including volatile organic compound (VOC) and nitrogen oxides ($NO_x$). Reduction of the emission of reactive VOC is a key to reducing ozone concentrations. VOC is emitted from anthropogenic sources and also from vegetation (biogenic VOC or BVOC). BVOC also forms ozone through $NO_x$ and radical reactions. Especially, in urban area, the BVOC is emitted into the atmosphere with high $NO_x$ concentration. Therefore, trees bordering streets and green spaces in urban area may contribute to tropospheric ozone. On the other hand, not all trees emit BVOC which will produce ozone locally. In this study, BVOC emissions have been investigated (terpenoids: isoprene, monoterpenes, sesquiterpenes) for 29 tree species. Eleven in the 29 species were tree species that did not emit BVOCs. Three in 12 cultivars for future planting (25 %) were found to emit no terpenoid BVOCs. Eight in 17 commonly planted trees (47%) were found to emit no terpenoid BVOC. Lower-emitting species have many advantages for urban planting. Therefore, further investigation is required to find the species which do not emit terpenoid BVOC. Emission of reactive BVOC should be added into guideline for the urban planting to prevent the creation of sources of ozone. It is desirable that species with no reactive BVOC emission are planted along urban streets and green areas in urban areas, such as Tokyo.

• Journal of Environmental Impact Assessment
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• v.14 no.5
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• pp.355-363
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• 2005

We studied the concentrations of $PM_{10}$ and heavy metal in the incinerators around Dong-hae from December 2003 to April 2004. The seasonal mean of $PM_{10}$ concentration was less than the value of environmental standard, the lowest ($36.59mg/m^3$) in spring and the highest ($78.54mg/m^3$) in fall. The measured seasonal heavy metals were Fe $503,44ng/m^3$, Mg $410.85ng/m^3$, Na $134.14ng/m^3$, Zn $24.58ng/m^3$ in spring and Na $315.29ng/m^3$, Mg $48.36ng/m^3$, Fe $44.78ng/m^3$, Zn $23.34ng/m^3$ in summer and Na $88.53ng/m^3$, Fe $33.80ng/m^3$, Zn $20,43ng/m^3$, Pb $6.16ng/m^3$ in fall and Na $4603.72ng/m^3$, Fe $575,26ng/m^3$, Al $411.01ng/m^3$, Cr $203.51ng/m^3$ in winter. The relationship between measured metals concentrations showed that Na and Fe were associated with natural sources such as soil. Pb, Cr and Zn were strongly related to urban anthropogenic sources such as fuel combustion.

• Ocean and Polar Research
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• v.40 no.2
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• pp.77-85
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• 2018

We observed the concentrations of Dissolved Organic Carbon (DOC) and Colored Dissolved Organic Matter (CDOM) in coastal seawater and groundwater around a volcanic island, Jeju, Korea. The sampling of surface seawater and coastal groundwater was conducted in Woljeongri, Pyoseon, and Kwakgi beaches, in three sampling campaigns (June, July, and October 2016). The concentrations of DOC in groundwater were relatively higher in June and October than in July. Salinity and DOC concentrations in the coastal groundwater of Woljeongri and Pyoseon beaches did not show a marked relationship, whereas those in Kwakgi beach showed a good positive correlation (July: $R^2=0.64$, P < 0.01; October: $R^2=0.95$, P < 0.01). In addition, the concentrations of CDOM (C and M peaks) in the groundwater of Woljeongri and Pyoseon beaches, where saline groundwater discharge dominates, were relatively higher than those of Kwakgi beach, where fresh groundwater discharge dominates. The relatively higher DOC concentrations in the coastal groundwater of Woljeongri and Pyoseon, with higher CDOM concentrations, seem to be mainly from anthropogenic sources such as local pollution sources (i.e., aquaculture wastewater or domestic sewage). In order to understand the behavior of DOC in the coastal groundwater of a volcanic island, extensive studies are necessary in the future over a larger-area and greater time-scales using various isotopic tracers.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.3
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• pp.263-273
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• 2003

P $M_{2.5}$ fine particles have been collected at the Cosan measurement station in Jeju Island, and the major water-soluble components have been analyzed in order to Investigate the aerosol compositions and pollution characteristics. The mean concentrations of the components were in the order of S $O_4$$^{2-}$> N $H_4$$^{+}$> N $O_3$$^{[-10]}$ > N $a^{+}$> $K^{+}$>C $l^{[-10]}$ >C $a^2$$^{+}$>M $g^2$$^{+}$. The major components were S $O_4$$^{2-}$, N $H_4$$^{+}$ and N $O_3$$^{[-10]}$ , whose compositions were 58％, 18％ and 10％ of the total ions, respectively. Most of the components showed higher concentrations in spring season, and especially $Ca^2$$^{+}$, N $O_3$$^{[-10]}$ and S $O_4$$^{2-}$ concentrations were increased 2.8, 1.9 and 1.2 times higher than the annual mean concentrations. The most parts of S $O_4$$^{2-}$ and N $H_4$$^{+}$ were distributed in fine particles below 2.1 ${\mu}{\textrm}{m}$ size, but the $Ca^2$$^{+}$, N $a^{+}$ and C $l^{[-10]}$ showed relatively higher concentrations in coarse particles. Based on the factor analysis, the P $M_{2.5}$ fine particles were considered to be largely influenced by anthropogenic sources, and followed by sea salt and soil sources. In the variations of concentrations as a function of wind direction, most components have shown higher concentrations notably as the northwesterly prevails.thwesterly prevails.