• Title/Summary/Keyword: Anthropogenic emission

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Estimation of Air Pollutant Emissions for the Application of Photochemical Dispersion Model in the Seoul Metropolitan Area (광화학 확산모델 적용을 위한 수도권지역의 대기오염물질 배출량 산출)

  • 이종범;김용국;김태우;방소영;정유정
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.2
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    • pp.123-135
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    • 1997
  • An air pollutant emission inventory system for the input preparations of photochemical dispersion model was developed. Using the system, anthropogenic emissions as well as biogenic emissions in the Seoul metropolitan area were calculated. Anthropogenic emission by fuel combustion using regional cosumption data, and the laundries and so forth was estimated. The biogenic emission was estimated based upon meteorological data and the distribution of land use type in the study area. The anthropogenic emission of pollutants was highest in Seoul, and the second highest in Inchon. TSP and $SO_2$ were found large quantities during the winter due to increased consumption of heating oil. NOx and THC were emitted without seasonal variation. Among biogenic emissions, PAR was very common while NO was the least common. PAR, OLE, and ALD2 were emitted in large volumes in coniferous forest areas, while ISOP was emitted in deciduous forest areas. Generally, most biogenic emissions increased during daytime, and peaked between oen and two o'clock. Because of strong solar radiation, emission during the summer was high. Biogenic NO emissions were found to be lower compared to anthropogenic emissons, and other VOC was indicated relatively high. In the study area, among biogenic emissions PAR was found to be 3 times, OLE 8 times,and ALD2 12 times more common than among anthropogenic emissions.

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Emission Control Technologies for N2O from Adipic Acid Production Plants (아디픽산 제조공정으로부터 발생되는 N2O에 대한 배출제어기술)

  • Kim, Moon-Hyeon
    • Journal of Environmental Science International
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    • v.20 no.6
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    • pp.755-765
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    • 2011
  • Nitrous oxide ($N_2O$) is one of six greenhouse gases listed up in the Kyoto Protocol, and it effects a strong global warming because of its much greater global warming potential (GWP), by 310 times over a 100-year time horizon, than $CO_2$. Although such $N_2O$ emissions from both natural and anthropogenic sources occur, the latter can be controlled using suitable abatement technologies, depending on them, to reduce $N_2O$ below acceptable or feasible levels. This paper has extensively reviewed the anthropogenic $N_2O$ emission sources and their related compositions, and the state-of-the-art non-catalytic and catalytic technologies of the emissions controls available currently to representative, large $N_2O$ emission sources, such as adipic acid production plants. Challengeable approaches to this source are discussed to promote establishment of advanced $N_2O$ emission control technologies.

Estimation of Mercury Emission from Major Sources in Annex D of Minamata Convention and Future Trend (국내 비의도적 주요 배출원의 지역별 수은 대기 배출량 산정 및 미래 활동도 변화와 최적가용기술 적용 시 배출량 추이)

  • Sung, Jin-Ho;Oh, Joo-Sung;Back, Seung-Ki;Jeong, Bup-Mook;Jang, Ha-Na;Seo, Yong-Chil;Kim, Seong-Heon
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.2
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    • pp.193-207
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    • 2016
  • This study discusses the present status of mercury emission and distribution from major anthropogenic sources in Korea and the future trend of mercury emission by activity changes and application of BATs. Atmospheric mercury emission from major anthropogenic sources based on Annex D of Minamata convention was estimated to around 4.89 tonne in 2012. Emission ratios of cement clinker production, coal-fired power plant, waste incineration and non-ferrous metal smelting were 68.68%, 24.75%, 6.29% and 0.28%, respectively. High mercury emission regions were characterized by the presence of cement clinker production facilities and coal-fired power plants. Prediction of future activities was carried out by linear regression of the previous year data. The (total) mercury emission was estimated to decrease up to 48% Under the scenario of BATs to be applied and the change of future activities. Emissions from coal-fired powerplants and cement clinkers were expected to decrease significantly.

Surface Flux Measurements of Methane from Lamdfills by Closed Chamber Technique and its Validation (플럭스챔버에 의한 매립지표면 메탄의 배출량 측정과 분석)

  • 김득수;장영기;전의찬
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.5
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    • pp.499-509
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    • 2000
  • Next to carbon dioxide, methane is the second largest contributor to global warming among anthropogenic greenhouse gases. Methane is emitted into the atmosphere from both natural and anthropogenic sources. Natural sources include wetlands, termites, wildries, ocean and freshwater. Anthropogenic sources include landfill, natural gas and oil production, and agriculture. These manmade sources account for about 70% of total global methane emissions; and among these, landfill accounts for approximately 10% of total manmade emissions. Solid waste landfills produce methane as bacteria decompose organic wastes under anaerobic conditions. Methane accounts for approximately 45 to 50 percent of landfill gas, while carbon dioxide and small quantities of other gases comprise the remaining to 50 to 55 percent. Using the closed enclosure technique, surface emission fluxes of methane from the selected landfill sites were measured. These data were used to estimate national methane emission rate from domestic landfills. During the three different periods, flux experiments were conducted at the sites from June 30 through December 26, 1999. The chamber technique employed for these experiments was validated in situ. Samples were collected directly by on-site flux chamber and analyzed for the variation of methane concentration by gas chromatography equipped with FID. Surface emission rates of methane were found out to vary with space and time. Significant seasonal variation was observed during the experimental period. Methane emission rates were estimated to be 64.5$\pm$54.5mgCH$_4$/$m^2$/hr from Kimpo landifll site. 357.4$\pm$68.9mgCH$_4$/$m^2$/hr and 8.1$\pm$12.4mgCH$_4$/$m^2$/hr at KwanJu(managed and unmanaged), 472.7$\pm$1056mgCH$_4$/$m^2$/hr at JonJu, and 482.4$\pm$1140 mgCH$_4$/$m^2$/hr at KunSan. These measurement data were used for the extrapolation of national methane emission rate based on 1997 national solid waste data. The results were compared to those derived by theoretical first decay model suggested by IPCC guidelines.

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Estimation of the Temporal and Spatial Distribution of Anthropogenic Heat in Daegu (대구지역 인공열의 시공간적 분포 추정에 관한 연구)

  • 안지숙;김해동;홍정혜
    • Journal of Environmental Science International
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    • v.11 no.10
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    • pp.1045-1054
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    • 2002
  • Urban atmospheric conditions are usually settled as warmer, drier and dirtier than those of rural counterpart owing to reduction of green space and water space area heat retention in surfaces such as concrete and asphalt, and abundant fuel consumption. The characteristics of urban climate has become generally known as urban heat island. The purpose of this study is to investigate the temporal and spatial distribution of the heat emission from human activity, which is a main factor causing urban heat island. In this study, the anthropogenic heat fluxes emitted from vehicles and constructions are estimated by computational grid mesh which is divided by 1km $\times$ 1km. The anthropogenic heat flux by grid mesh can be applied to a numerical simulation model of the local circulation model. The constructions are classified into 9 energy-consumption types - hospital, hotel, office, department store, commercial store, school, factory, detached house and flat. The vehicles classified into 4 energy-consumption types - car, taxi, truck and bus. The seasonal mean of anthropogenic heat flux around central Daegu exceeded $50 W/m^2$ in winter. The annual mean anthropogenic heat flux exceeded $20 W/m^2$. The values are nearly equivalent to the anthropogenic heat flux in the suburbs of Tokyo, Japan.

Trends and Control Technologies of Volatile Organic Compound (국내의 휘발성유기화합물(VOC) 현황 및 관리기술)

  • Kim, Jo-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.743-757
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    • 2006
  • Volatile organic compound (VOC) has been well-known to Korea since the end of 1990's however, it has not been well documented until now. In this study, present ambient VOC levels, VOC emission sources, and VOC control technologies were reviewed and discussed. In addition, VOC management strategies to cut down ozone concentrations were suggested based on the present VOC database. For anthropogenic VOC reduction, VOC emitted from painting processes and automobiles should be controlled in the first place in large cities such as Seoul, Daegu, and Incheon. For natural VOC management, low emission trees need to be planted in those cities. It is also very significant to keep updating present and future VOC emission inventories for efficient VOC control strategies. As a conclusion, more systematic VOC control road-map based on BACT (best available control technology) needs to be made up. and more economical and efficient VOC control techniques have to be developed under strong national support in order to lower toxic VOC and photochemical oxidant levels.

Aerosol Characteristics at Tokchok Island in the Yellow Sea (황해상 덕적도의 대기 에어로졸 특성)

  • 이승복;배귀남;김용표;진현철;윤용석;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.4
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    • pp.305-316
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    • 2002
  • Various air pollutants were measured at Tokchok Island in the Yellow Sea that is about 50 km distant from Incheon since April 1999. This study was undertaken to help understanding the level of air pollution and its distribution characteristics over the Yellow Sea. The geographical characteristics of the air pollution monitoring station and emission inventories of Tokchok Island are introduced. The mass concentrations and chemical compositions of TSP and P $M_{2.5}$ measured until March 2000 are discussed in this paper. The overall average mass concentrations are about 37.2 $\mu\textrm{g}$/㎥ for TSP and 18.7 $\mu\textrm{g}$/㎥ for P $M_{2.5}$ , respectively, which are similar to or a little lower than the values observed in other background sites at Kangwha and Taean. However, they are much lower than those observed at Qingdao in China. The low mass concentration and major anthropogenic ion concentrations in aerosols collected at Tokchok Island show that local sources are not dominant at Tokchok Island. The estimated average fractions of anthropogenic non-sea-salt sulfate to the total sulfate concentration of TSP and P $M_{2.5}$ are greater than 80% for both sizes. It hence suggests that the sulfate be mainly affected by anthropogenic sources. If we consider the average mass ratio of P $M_{2.5}$ to TSP, the mass fractions of anthropogenic species to P $M_{2.5}$ , and the molar ratio of nss S $O_4$$^{2-}$ to total N $O_{3-}$, it may be possible to infer that a part of anthropogenic species measured at Tokchok Island be transported from China. The characteristics of neutralization of nss S $O_4$$^{2-}$ and the particle size of major ions are also discussed.

Impacts of anthropogenic heating on urban boundary layer in the Gyeong-In region (인공열이 도시경계층에 미치는 영향 - 경인지역을 중심으로 -)

  • Koo, Hae-Jung;Ryu, Young-Hee
    • Journal of Environmental Impact Assessment
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    • v.21 no.5
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    • pp.665-681
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    • 2012
  • This study investigates the influence of anthropogenic heat (AH) release on urban boundary layer in the Gyeong-In region using the Weather Research and Forecasting model that includes the Seoul National University Urban Canopy Model (SNUUCM). The gridded AH emission data, which is estimated in the Gyeong-In region in 2002 based on the energy consumption statistics data, are implemented into the SNUUCM. The simulated air temperature and wind speed show good agreement with the observed ones particularly in terms of phase for 11 urban sites, but they are overestimated in the nighttime. It is found that the influence of AH release on air temperature is larger in the nighttime than in the daytime even though the AH intensity is larger in the daytime. As compared with the results with AH release and without AH release, the contribution of AH release on urban heat island intensity is large in the nighttime and in the morning. As the AH intensity increases, the water vapor mixing ratio decreases in the daytime but increases in the nighttime. The atmospheric boundary layer height increases greatly in the morning (0800 - 1100 LST) and midnight (0000 LST). These results indicate that AH release can have an impact on weather and air quality in urban areas.

HCCI Combustion Engines with Ultra Low CO2 and NOx Emissions and New Catalytic Emission Control Technology (CO2/NOx 초저배출형 HCCI 엔진 연소기술과 신촉매제어기술)

  • Kim, Moon-Hyeon
    • Journal of Environmental Science International
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    • v.17 no.12
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    • pp.1413-1419
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    • 2008
  • The Kyoto Protocol, that had been in force from February 16, 2005, requires significant reduction in $CO_2$ emissions for all anthropogenic sources containing transportation, industrial, commercial, and residential fields, etc, and automotive emission standards for air pollutants such as particulate matter (PM) and nitrogen oxides $(NO_x)$ become more and more tight for improving ambient air quality. This paper has briefly reviewed homogeneous charge compression ignition (HCCI) combustion technology offering dramatic reduction in $CO_2,\;NO_x$ and PM emissions, compared to conventional gasoline and diesel engine vehicles, in an effort of automotive industries and their related academic activities to comply with future fuel economy legislation, e.g., $CO_2$ emission standards and corporate average fuel economy (CAFE) in the respective European Union (EU) and United States of America (USA), and to meet very stringent future automotive emission standards, e.g., Tier 2 program in USA and EURO V in EU. In addition, major challenges to the widespread use of HCCI engines in road applications are discussed in aspects of new catalytic emissions controls to remove high CO and unburned hydrocarbons from such engine-equipped vehicles.