• Title/Summary/Keyword: Anode efficiency

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Removal of endocrine disruptive compounds using dimensionally stable anode (DSA) (불용성 전극(DSA)을 이용한 내분비계 장애물질 제거)

  • Kim, Dong-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.5
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    • pp.1368-1373
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    • 2008
  • An electrochemical reactor was designed and operated to treat the solution containing endocrine disruptive compounds such as phenol and bisphenol A. An experiment involving the electrochemical oxidation of bisphenol A was performed with the use of a dimensionally stable anode (DSA). The apparent current, conductivity, and the gap between cathode and anode were selected as design parameters. The phenol removal rate increased with an increase in apparent current. The bisphenol A removal rate increased with an increase in apparent current efficiency. An increase in the conductivity also led to an increase in the rate of removal of bisphenol A. The gap between cathode and anode did not affect the bisphenol A removal rate or the cathodic current efficiency.

The Effect of Direct and Variable Current on Current Efficiency of Copper Anode (조동의 전류효율에 미치는 직류 및 가변전류의 영향)

  • Ahan, Sung-Chen;Lee, Sang-Mun;Kim, Yong-Hwan;Chung, Won-Sub
    • Journal of Surface Science and Engineering
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    • v.39 no.5
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    • pp.223-228
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    • 2006
  • The current efficiency of copper anode containing impurities in copper sulfate solution for electrorefining was studied at various current type such as direct current, variable current and periodic reverse current. The passivity behavior was investigated by galvanostatic technique. The results obtained were that current efficiency of variable current was higher than those of direct current and periodic reverse current. The increased current efficiency could be explained by the formation of slime structure with lower average resistance due to variable current. The frequency of various factors in variable current condition has a greatest effect on current efficiency. It appeared that frequency increased current efficiency when increased from 1 to 4, but further increases did not have an effect.

Emission Characteristics of Blue Fluorescent OLED with Anode Materials (양극 물질에 따른 청색 형광 OLED의 발광 특성)

  • Kong, Do-Hoon;Lee, Yo-Seb;Ju, Sung-Hoo;Yang, Jae-Woong
    • Journal of Surface Science and Engineering
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    • v.48 no.3
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    • pp.121-125
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    • 2015
  • We studied the blue fluorescent OLED with Mg:Ag, Al, Ni as anode materials. Blue fluorescent OLEDs were fabricated using Anode / $MoO_3$ (3 nm) / 2-TNATA (60 nm) / NPB (30 nm) / SH-1 : BD-2 (5 vol.%, 30 nm) / Bphen (40 nm) / Liq (1 nm) / Al (150 nm). Current density of OLED with Mg:Ag was not measured due to too low work function, and that of OLED with Al showed $45.2mA/cm^2$ at 12 V. Luminance and Current efficiency of OLED with Al showed $385.1cd/m^2$ and 0.9 cd/A. Current density of OLED with Ni of 8, 10, 12 nm thickness showed 10, 12.9, $37.2mA/cm^2$, respectively. Luminance and Current efficiency of OLED with Ni of 8, 10, 12 nm thickness showed 670.9, 991.2, $1,320cd/m^2$ and 6.7, 7.7, 3.6 cd/A, respectively. Transmittance of Al was 52.2% at 476 nm wavelength and that of Ni of 8, 10, 12 nm thickness was 79, 77, 74 %, respectively. In spite of best current density, OLED with Al showed the lowest luminance and current efficiency because of low work function and poor transmittance. When thickness of Ni was increased to 12nm, current efficiency was sharply lower owing to bad transmittance and unbalance of holes and electrons. Finally, OLED with Ni of 10 nm thicknes showed the highest current efficiency.

A study of galvanic characteristics of aluminium alloy anode in the Al-Zn-In-Mg system made of the low purity aluminium ingot (저순도 Al지금을 사용한 Al-Zn-In-Mg계 Al합금 유전양극의 특성에 관한 연구)

  • 김원녕;김기준;김영대
    • Journal of Advanced Marine Engineering and Technology
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    • v.9 no.3
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    • pp.240-249
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    • 1985
  • This paper presents the results of the galvanic anode's characteristicsin the Al-Zn-In-Mg and Al-Zn-In-Mg system anodes used aluminium ingot of low purity, 99.5% grade. The results of thses performance tests are as follows: 1) Zn, In and Mg are an available elements to improve the performance of Aluminium alloy anodes. 2) When the range of zinc content in the Al-Zn-In-Mg system anode is 2-5% the more zinc content, the more improve the anode performance. 3) Al-Zn-In-Mg system anode requires a long term over 50 days for the performance test. 4) The composition of Al-Zn-In-Mg system anode which shows the most excellent performance is Al-(2-3%) Zn-(0.02%) In-(1.0%) Mg. 5) When the Al-Zn-In-Mg system anode is annealed for an hour in 500 to 550 .deg. C, the anode performance is improved. 6) The lower average potential and the better corrosion pattern in the Al-Zn-Mg, Al-Zn-In and Al-Zn-In-Mg system anodes, the more current efficiency is improved.

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Removing nitrogenous compounds from landfill leachate using electrochemical techniques

  • Nanayakkara, Nadeeshani;Koralage, Asanga;Meegoda, Charuka;Kariyawasam, Supun
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.339-346
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    • 2019
  • In this research, applicability of electrochemical technology in removing nitrogenous compounds from solid waste landfill leachate was examined. Novel cathode material was developed at laboratory by introducing a Cu layer on Al substrate (Cu/Al). Al and mild steel (MS) anodes were investigated for the efficiency in removing nitrogenous compounds from actual leachate samples collected from two open dump sites. Al anode showed better performances due to the effect of better electrocoagulation at Al surface compared to that at MS anode surface. Efficiency studies were carried out at a current density of $20mA/cm^2$ and at reaction duration of 6 h. Efficiency of removing nitrate-N using Al anode and developed Cu/Al cathode was around 90%. However, for raw leachate, total nitrogen (TN) removal efficiency was only around 30%. This is due to low ammonium-N removal as a result of low oxidation ability of Al. In addition to the removal of nitrogenous compounds, reactor showed about 30% removal of total organic carbon. Subsequently, raw leachate was diluted four times, to simulate pre-treated leachate. The diluted leachate was treated and around 88% removal of TN was achieved. Therefore, it can be said that the reactor would be good as a secondary or tertiary treatment step in a leachate treatment plant.

Study on Characteristic by ITO Surface Treatment and Cathode Change of Organic Light Emitting Diodes (ITO 표면 처리와 음전극 변화에 따른 OLEDs의 특성 연구)

  • Kim, Doo-Seok;Jang, Yoon-Ki;Kwon, Young-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.12
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    • pp.1143-1147
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    • 2005
  • In this study, we report an improved efficiency of Organic light emitting diodes(OLEDs), using $UV/O_3$ treated anode and different cathode. We investigated the efficiency of OLEDs by $UV/O_3$ treatment of ITO surface. We Performed $UV/O_3$ treatment and found that $UV/O_3$ treatment enhanced the performance of OLEDs. The fundamental structure of the OLEDs was ITO $anode/{\alpha}-NPD/Alq_3/Al$ or Li:Al cathode. The Li:Al can improve the OLEDs efficiency dramatically in cathode because it has lower work function than Al. Current-voltage, Luminance-voltage characteristics and luminance efficiency were measured at room temperature.

Characteristics of LPB Having Gold Anode Fabricated by Sputtering Methode. (스퍼트링법에 의해 부극을 금으로 코팅시킨 LPB의 특성 연구)

  • 정재국;남효덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1043-1046
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    • 2001
  • In this study, characteristics of LPB having gold anode fabricated by sputtering methode were analyzed. As results, The 1st efficiency and the impedance characteristics of LPB decreased with increased gold coated on anode and current collector. But the rate characteristics and charge-discharge cycling characteristics increased with increased gold coated on anode and current collector. During 2C discharge of the rate characteristics test, the rate characteristics of LPB without gold coated and the rate characteristics of LPB with gold coated in twice were 159mAh/g and 189mAh/g, respectively. The discharge capacity was gradually degreased with the discharge cycling to about 20th cycles. But LPB with gold coated in twice was stabilized than LPB without gold coated.

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Characteristics of Anode Electrode According to Ni Content for Solid Oxide Fuel Cell (고체전해질형 연료전지의 Ni 함량에 따른 연료극 특성)

  • 김귀열;엄승욱;문성인
    • Electrical & Electronic Materials
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    • v.10 no.6
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    • pp.528-532
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    • 1997
  • The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way, Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by testing expansion coefficient, impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(40vol%) was better excellent than the others.

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Electric Conduction Properties of NaCl Electrolyte as a Function of Electrode Materials (전극재료에 따른 NaCl 전해질의 전기전도특성)

  • Kim, Yong-Hyuk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.11
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    • pp.2026-2031
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    • 2010
  • The electrical characteristics of galvanic cell which is composed of the cathode electrode(graphite, carbon and copper) and the anode electrode(Zn and Mg) were investigated. For this research as electrolyte 2~12 wt% NaCl aqueous solution were used. At graphite cathode electrodes which use Zn and Mg with the anode electrode, the open circuit voltage was 1.3V most highly. The maximum output power increased as the electrolyte concentration increased, due to a increase in ion density. When Zn and Mg with the anode electrode, the maximum output power respectively was evaluated as 2.2mW and 5.5mW about the graphite cathode electrode in the NaCl 4wt%. The research results indicated that the output power of cell which is composed with graphite with the cathode and Mg with the anode was most excellent and the efficiency of the cell could be enhanced by increasing the electrolyte concentration.

Synthesis of Cyclitol Derivatives (Ⅲ). Electrolytic Oxidation of myo-Inositol (Cyclitol 유도체 합성에 관한 연구 (제3보)-myo-Inositol의 전해 산화-)

  • Joo Hwan Sohn;Chong Woo Nam;Yu Ok Kim
    • Journal of the Korean Chemical Society
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    • v.15 no.3
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    • pp.127-132
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    • 1971
  • To obtain the various kinds of inosose stereomers, the process of electrochemical oxidation is more effective than chemical oxidation of myo-inositol. So that myo-inositol aqueous solution was electrolyzed by platinum and lead peroxide anode to confirming the occurrence of electrochemical oxidation. The result is that myo-inosose-2 is producing with high yield comparatively by electrolytic oxidation of myo-inositol. Also we studied about the relation between the electrolytic current efficiency and electrolytic temperature and anodic current density. The current efficiency is rising with lowering of electrolytic temperature identically in both anode such as platinum and lead peroxide and also rising with increasing of anodic current density in platinum anode, but inversely in lead peroxide.

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