• Title/Summary/Keyword: Anode Voltage

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Degradation Comparison of Hydrogen and Internally Reformed Methane-Fueled Solid Oxide Fuel Cells

  • Kim, Young Jin;Lee, Hyun Mi;Lim, Hyung-Tae
    • Journal of the Korean Ceramic Society
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    • v.53 no.5
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    • pp.483-488
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    • 2016
  • Anode supported solid oxide fuel cells (SOFCs), consisting of Ni+YSZ anode, YSZ electrolyte, and LSM+YSZ cathode, were fabricated and constant current tested with direct internal reforming of methane (steam to carbon ratio ~ 2) as well as hydrogen fuel at $800^{\circ}C$. The cell, operated under direct internal reforming conditions, showed relatively rapid degradation (~ 1.6 % voltage drop) for 95 h; the cells with hydrogen fuel operated stably for 170 h. Power density and impedance spectra were also measured before and after the tests, and post-test analyses were conducted on the anode parts using SEM / EDS. The results indicate that the performance degradation of the cell operated with internal reforming can be attributed to carbon depositions on the anode, which increase the resistance against anode gas transport and deactivate the Ni catalyst. Thus, the present study shows that direct internal reforming SOFCs cannot be stably operated even under the condition of S/C ratio of ~ 2, probably due to non-uniform mixture (methane and steam) gas flow.

Modifications of ITO Surfaces in Organic EL Devices by $O_2$ Plasma Treatment (O$_2$ 플라즈마 처리에 의한 ITO 표면개질 변화에 따른 유기 EL 소자 특성)

  • 박상무;김형권;이덕출
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.6
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    • pp.261-266
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    • 2003
  • We investigated the effect of oxygen plasma treatment of indium-tin oxide(ITO) surface on the performance of electroluminescence(EL) devices. ITO surface treated oxygen plasma has been analyzed using atomic force microscope(AFM) and X-ray photoelectron spectroscopy(XPS), to investigate the relations between the properties of the ITO surface and the properties of the current-voltage-luminance(I-V-L) characteristics of the fabricated OLED with the structure of ITO(plasma treatment) / TPD / Alq$_3$/ Al. It is found that the oxygen plasma treatment of ITO anode improve the hole injection of the OLED due to the modification of the surface states. The treated ITO anode nay be low voltage with high luminance efficiency.

Fabrication of Carbon Nanotube Field Emitters

  • Yoon, Hyeun-Joong;Jeong, Dae-Jung;Jun, Do-Han;Yang, Sang-Sik
    • Journal of Electrical Engineering and Technology
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    • v.3 no.1
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    • pp.121-124
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    • 2008
  • This paper presents the fabrication and field emission of carbon nanotube field emitters for a micro mass spectrometer. The carbon nanotube is an adequate material as a field emitter since it has good characteristics. We have successfully fabricated a diode field emitter and a triode field emitter. Each field emitter has been constructed using several micromachining processes and a thermal CVD process. In the case of the diode field emitter, to increase the electric field, the carbon nanotubes are selectively grown on the patterned nickel catalyst layer. The electron current of the diode field emitter is 73.2 ${\mu}A$ when the anode voltage is 1100V. That of the triode field emitter is 3.4 pA when the anode voltage is 1000V.

Study on Characteristic by ITO Surface Treatment and Cathode Change of Organic Light Emitting Diodes (ITO 표면 처리와 음전극 변화에 따른 OLEDs의 특성 연구)

  • Kim, Doo-Seok;Jang, Yoon-Ki;Kwon, Young-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.12
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    • pp.1143-1147
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    • 2005
  • In this study, we report an improved efficiency of Organic light emitting diodes(OLEDs), using $UV/O_3$ treated anode and different cathode. We investigated the efficiency of OLEDs by $UV/O_3$ treatment of ITO surface. We Performed $UV/O_3$ treatment and found that $UV/O_3$ treatment enhanced the performance of OLEDs. The fundamental structure of the OLEDs was ITO $anode/{\alpha}-NPD/Alq_3/Al$ or Li:Al cathode. The Li:Al can improve the OLEDs efficiency dramatically in cathode because it has lower work function than Al. Current-voltage, Luminance-voltage characteristics and luminance efficiency were measured at room temperature.

A New EST with Dual Trench Gate Electrode (DTG-EST)

  • Kim, Dae-Won;Sung, Man-Young;Kang, Ey-Goo
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.2
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    • pp.15-19
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    • 2003
  • In this paper, the new dual trench gate Emitter Switched Thyristor (DTG-EST) is proposed for improving snap-back effect which leads to a lot of serious problems of device applications. Also the parasitic thyristor that is inherent in the conventional EST is completely eliminated in this structure, allowing higher maximum controllable current densities for ESTs. The conventional EST exhibits snap-back with the anode voltage and current density 2.73V and 35A/$\textrm{cm}^2$, respectively. But the proposed DTG-EST exhibits snap-back with the anode voltage and current density 0.96V and 100A/$\textrm{cm}^2$, respectively.

700V Emitter Switched Thyristor(EST) with Dual Trench Gate (700V급 듀얼 트랜치 게이트를 가지는 Emitter Switched Thyristor(EST))

  • Kim, Dae-Won;Sung, Man-Young;Kang, Ey-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05b
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    • pp.27-30
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    • 2003
  • In this paper, the new dual trench gate Emitter Switched Thyristor (DTG-EST) is proposed for improving snap-back effect which leads to a lot of serious problems of device applications. And the parasitic thyristor that is inherent in the conventional EST is completely eliminated in this structure, allowing higher maximum controllable current densities for ESTs. The conventional EST exhibits snap-back with the anode voltage and current density 2.73V and $35A/cm^2$, respectively. But the proposed DTG-EST exhibits snap-back with the anode voltage and current density 0.96V and $100A/cm^2$, respectively.

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Effects of Electrolyte Concentration and Relative Cathode Electrode Area Sizes in Titania Film Formation by Micro-Arc Oxidation

  • Lee, Yong-K.;Lee, Kang-Soo
    • Corrosion Science and Technology
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    • v.9 no.4
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    • pp.171-174
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    • 2010
  • MAO (micro-arc oxidation) is an eco-friendly convenient and effective technology to deposit high-quality oxide coatings on the surfaces of Ti, Al, Mg and their alloys. The roles of the electrolyte concentration and relative cathode electrode area sizes in the grown oxide film during titanium MAO were investigated. The higher the concentration of the electrolyte, the lower the $R_{total}A$ value. The oxide film produced by the lower concentration of the electrolyte is thinner and less uniform than the film by the higher concentration, which is thick and porous. The cathode area size must be bigger than the anode area size in order to minimize the voltage drop across the cathode. The ratio of the cathode area size to the anode area size must be bigger than 8. Otherwise, the cathode will be another source for voltage drop, which is detrimental to and slows down the oxide growth.

A study on development of bipolar metal surface anodizing equipment using H-bridge (H-브리지를 이용한 양극성 금속표면 양극산화장치 개발에 관한 연구)

  • Yang, Keun-Ho
    • The Journal of the Korea institute of electronic communication sciences
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    • v.6 no.3
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    • pp.355-362
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    • 2011
  • In this paper, we developed the equipment to forming the insulation film which there are operated an electrolysis principles in particular solution. In the earlier, there are supplied the anode by unipolar voltage with pulse, in this paper, there are supplied the anode by bipolar voltage with pulse, alternately. And then, we examinate the system that there are developed the bipolar anodizing equipment using H-bridge. There are modulated pulse width for the variable current. In the results, we obtained the results of the uniform film surface that compared with the unipolar anodizing.

Switch-on Phenomena and Field Emission from Multi-Walled Carbon Nanotubes Embedded in Glass

  • Bani Ali, Emad S;Mousa, Marwan S
    • Applied Microscopy
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    • v.46 no.4
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    • pp.244-252
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    • 2016
  • This paper describes a new design of carbon nanotube tip. $Nanocly^{TM}$ NC 7000 Thin Multiwall Carbon Nanotubes of carbon purity (90%) and average diameter tube 9.5 nm with a high aspect-ratio (>150) were used. These tips were manufactured by employing a drawing technique using a glass puller. The glass microemitters with internal carbon nanotubes show a switch-on effect to a high current level (1 to $20{\mu}A$). A field electron microscope with a tip (cathode)-screen (anode) separation at ~10 mm was used to characterize the electron emitters. The system was evacuated down to a base pressure of ${\sim}10^{-9}$ mbar when baked at up to ${\sim}200^{\circ}C$ overnight. This allowed measurements of typical Field Electron Emission characteristics; namely the current-voltage (I-V) characteristics and the emission images on a conductive phosphorus screen (the anode). Fowler-Nordheim plots of the current-voltage characteristics show current switch-on for each of these emitters.

Functional Analysis of Electrode and Small Stack Operation in Solid Oxide Fuel Cell (고체산화물 연료전지의 전극과 스택운영의 기능적 분석)

  • Bae, Joong-Myeon;Kim, Ki-Hyun;Ji, Hyun-Jin;Kim, Jung-Hyun;Kang, In-Yong;Lim, Sung-Kwang;Yoo, Young-Sung
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.812-822
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    • 2006
  • This study amis to investigate the functional analysis of anode and cathode materials in Anode supported Solid Oxide Fuel Cell. The concentration polarization of single cell was investigated with CFD (Computational Fluid Dynamics) method for the case of the different morphology by using four types of unit cell and discussed to reduce the concentration polarization. The concentration polarization at anode side effected the voltage loss in Anode supported Solid Oxide Fuel Cell and increased contact areas between fuel gas and anode side could reduce the concentration polarization. For intermediate temperature operation, Anode-supported single cells with thin electrolyte layer of YSZ (Yttria-Stabilized Zirconia) were fabricated and short stacks were built and evaluated. We also developed diesel and methane autothermal reforming (ATR) reactors in order to provide fuels to SOFC stacks. Influences of the $H_2O/C$ (steam to carbon ratio), $O_2/C$ (oxygen to carbon ratio) and GHSV (Gas Hourly Space Velocity) on performances of stacks have been investigated. Performance of the stack operated with a diesel reformer was lower than with using hydrogen as a fuel due to lower Nernst voltage and carbon formation at anode side. The stack operated with a natural gas reformer showed similar performances as with using hydrogen. Effects of various reformer parameters such as $H_2O/C$ and $O_2/C$ were carefully investigated. It is found that $O_2/C$ is a sensitive parameter to control stack performance.