• Title/Summary/Keyword: Anode Material

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Charge and Discharge Characteristics of Microencapsulated Hydrogen Storage Alloy Electrodes for Secondary Batteries (마이크로캡슐화한 축전지용 수소저장합금 전극의 충·방전 특성)

  • CHOI, Seong-Soo;CHOI, Byung-Jin;YE, Byung-Joon;KIM, Dai-Ryong
    • Transactions of the Korean hydrogen and new energy society
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    • v.3 no.2
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    • pp.45-54
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    • 1992
  • An applicability microencapsulation, using electroless copper plating, of hydrogen storage alloy powder as an anode material for nickel-hydrogen secondary batteries was investigated. Alloys employed were $LaNi_{4.7}Al_{0.3}$ and $MmNi_{4.5}Al_{0.5}$(Mm=mischmetal) which have an appropriate equilibrium pressure and capacity. The microencapsulation of the alloy powder was found to accelerate initial activation of electrodes and to increase capacity which is about 285mAh/g for $LaNi_{4.7}Al_{0.3}$. In addition, other charge and discharge characteristics, such as polarization and flatness of charge and discharge potential, were improved due to the role of copper layer as a microcurrent collector and an oxidation barrier of the alloy powder. $MmNi_{4.5}Al_{0.5}$ alloy showed lower capacity than $LaNi_{4.7}Al_{0.3}$ because of higher equilibrium pressure. Cyclic characteristics of both alloys were somewhat poor because of mainly shedding and partial oxidation of alloy powder during the cycling. However, it was considered that the microencapsulation method is effective to improve the performances of the hydrogen storage alloy electrodes.

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Generation of Low Temperature Plasma at Atmospheric Pressure and its Application to Si Etching in Open Air (대기압 비평형 플라스마의 발생 및 규소(Si)식각에의 응용)

  • Lee, Bong-Ju
    • Journal of the Korean Ceramic Society
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    • v.39 no.4
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    • pp.409-412
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    • 2002
  • Under atmospheric pressure, apparently homogeneous and stable plasma can be generated from insulator barrier rf plasma generators each of which has an rf powered cathode and a grounded anode covered with a dielectric insulating material. In order to characterize the generating plasma under atmospheric pressure, some basic characteristic have been evaluated by the Langmuire probe method as well as by optical emission spectroscopy. From the result of plasma characteristics, the generated plasma was verified to be nonequilibrium; T(electron)>T(excitation)>T(gas). High rate Si(100) etching (($1.5{\mu}m$/min) were achieved by using He plasma containing a small amount of $CF_4$.

The Electric Properties of Surface Coating with CePO4 and M3(PO4)2 (M=Mg, Zn) on Li4Ti5O12 for Energy Storage Capacitor

  • Lee, Jong-Kyu;Yoon, Jung-Rag
    • Journal of Electrical Engineering and Technology
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    • v.13 no.1
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    • pp.413-417
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    • 2018
  • The $Li_4Ti_5O_{12}$ of anode material for the hybrid capacitor was coated using $CePO_4$, $M_3(PO_4)_2$ (M=Mg, Zn). The capacitance of phosphate coated $Li_4Ti_5O_{12}$ was found to be lower than that of $Li_4Ti_5O_{12}$, whereas the equivalent series resistance was higher than that of $Li_4Ti_5O_{12}$. With an increase in cycle number, the base of cylindrical cell exhibited swelling due to gas generated from the reaction between $Li_4Ti_5O_{12}$ and electrolyte. The swelling cycle number of phosphate coated $Li_4Ti_5O_{12}$ was higher than that of $Li_4Ti_5O_{12}$ due to improvement in electrochemical stability. Based on the results, it is proposed that phosphate coating can be employed as a barrier layer to control the gassing reaction by isolating the $Li_4Ti_5O_{12}$ particle from electrolyte solution.

Surface treatment of ITO with Nd:YAG laser and OLED device characteristic (Nd:YAG 레이저로 표면처리된 ITO를 전극으로 한 유기EL 소자의 특성)

  • No, I.J.;Shin, P.K.;Kim, H.K.;Kim, Y.W.;Lim, Y.C.;Park, K.S.;Chung, M.Y.
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1359-1360
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    • 2006
  • lTO(Indium-Tin-Oxide) was used as anode material for OLED. Characteristics of ITO have great effect on efficiency of OLEDS(Organic light emitting diodes). ITO surface was treated by Nd:YAG laser in order to improve its chemical properties, wettability, adhesive property and to remove the surface contaminants while maintaining its original function. In this study, main purpose was to improve the efficiency of OLEDs by the ITO surface treatment: ITO surface was treated using a Nd:YAG(${\lambda}=266nm$, pulse) with a fixed power of 0.06[w] and various stage scanning velocities. Surface morphology of the ITO was investigated by AFM. Test OLEDs with surface treated ITO were fabricated by deposition of TPD (HTL), Ald3 (ETL/TML) and Al (cathode) thin films. Device performance of the OLEDs such as V-I-L was investigated using Source Measurement Unit (SMU: Keithly. Model 2400) and Luminance Measurement (TOPCON. BM-8).

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Preparation and Characteristics of Li4Ti5O12 Anode Material for Hybrid Supercapacitor

  • Lee, Byung-Gwan;Yoon, Jung-Rag
    • Journal of Electrical Engineering and Technology
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    • v.7 no.2
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    • pp.207-211
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    • 2012
  • Spinel-$Li_4Ti_5O_{12}$ was successfully synthesized by a solid-phase method at 800, 850, and $900^{\circ}C$ according to the $Li_4Ti_5O_{12}$ cubic spinel phase structure. To achieve higher EDLC energy density with the $Li_4Ti_5O_{12}$, the negative electrode of the hybrid supercapacitor was studied in this work. The electrochemical performances of the hybrid supercapacitor and EDLC were characterized by constant current discharge curves, c-rate, and cycle performance testing. The capacitance (1st cycle) of the hybrid supercapacitor and EDLC was 209 and 109 F, respectively, which is higher than EDLC. The capacitance of the hybrid supercapacitor decreases from 209 F to 101 F after 20 cycles when discharged at several specific current densities ranging from 1 to 10 A. In contrast, capacitance of the EDLC hardly decreases after 20 cycles. Results show that hybrid supercapacitor benefits from the high rate capability of supercapacitor and high capacity of the battery. Findings also prove that the hybrid supercapacitor is an energy storage device where the supercapacitor and the Li ion secondary battery coexist in one cell system.

Study of New Light Source with Nano Carbon Material (나노카본을 이용한 조명용 신광원에 관한 연구)

  • Kim, Kwang-Bok;Kim, Yong-Won;Jung, Han-Gi;Song, Yoon-Ho
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2006.05a
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    • pp.31-34
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    • 2006
  • The characteristic of carbon nano fiber (CNF) as electron emitters was described. Carbon nano fiber (CNF) of herringbone was prepared by thermal chemical vapor deposition(CVD), mixed with binders and conductive materials, and then were formed by screen-printing process. In order to increase effectively field emissions, the surface treatment of rubbing & peel-off was applied to the printed CNF emitters on cathode electrode. The measurements of field emission properties were carried out by using a diode structure inline vacuum chamber. CNF of herringbone type showed good emission properties that a turn on field was as low as $2.5V/{\mu}m$ and current density was as large as $0.15mA/cm^2$ of $4.5V/{\mu}m$ with electric field. After the vacuum packaged panel of 5-inch in diagonal, the measured white brightness was as high as $7000cd/m^2$ at 1900V of anode and 700V of gate voltage.

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Preparation and Electrochemical Characteristics of Mg-Sn Nanoparticles as an Anode Material for Li-ion Batteries

  • Tulugan, Kelimu;Lei, Jun-Peng;Dong, Xin-Long;Park, Won-Jo
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.146-152
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    • 2014
  • Mg-Sn nanoparticles were prepared by an arc-discharge method in a mixture atmosphere of argon and hydrogen gases. Phases, morphologies, and microstructures of the nanoparticles were investigated by means of X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). It was found that the intermetallic compound of $Mg_2Sn$ was generated and coexisted with metallic phases of Mg and Sn within nanoparticles. Basedon the model cell, the electrochemical properties were also explored by discharge-charge cycling, cyclic voltammetry, and electrochemical impedance spectroscopy. The initial capacity of the first cycle reached 430 mAh/g. Two visible plateaus at 0.2-0.3 and 0.5-0.75V were observed in the potential profiles, which can attributed to alloying/de-alloying reactions between Li and Mg2Sn, respectively.

Physical Mechanism of Light emission from Discharge Cells in the Plasma Display Panel (PDP 방전 셀에서 빛이 방출되는 물리적 메커니즘)

  • Uhm, Han-S.;Choi, Eun-H.
    • Journal of the Korean Vacuum Society
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    • v.15 no.6
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    • pp.556-562
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    • 2006
  • The plasma display panel is made of many small discharge cells, which consist of a discharge space between the cathode and anode. An electrical discharge occurs in the discharge space filled by neon and xenon gases. The electron temperature is determined from the sparking criterion, which theoretically estimates the electrical breakdown voltage in terms of the xenon mole fraction. The plasma in the cell emits vacuum ultraviolet lights of 147 nm and 173 nm, exciting fluorescent material and converting VUV lights to visible lights. The physical mechanisms of all these processes have been theoretically modeled and experimentally measured. The theory and experimental data agree reasonably well. However, new materials and better configuration of cells are needed to enhance discharge and light emission efficiency and to improve the PDP performance.

Anodic Oxidation of Furfuryl Alcohol Using Metal Oxide Electrodes (금속산화물 전극을 사용한 Furfuryl Alcohol의 양극산화)

  • Yoo, Kwang-Sik;Lee, Yong-Taek
    • Applied Chemistry for Engineering
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    • v.3 no.3
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    • pp.482-490
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    • 1992
  • 2,5-dimethoxy-2,5-dihydrofurfuryl alcohol was electrosynthesized from furfuryl alcohol in methanol solution by using three kinds of metal oxide anode. The electrods were prepared by the following process : Thin layer of semiconducting material such as tin(IV)oxide and antimony(III)oxide was made on the titanium base metal in an electric furnace. The titanium metal block with the layer was coated with ${\alpha}-PbO_2$, ${\beta}-PbO_2$, and $MnO_2$ in each electrolytes by anodic deposition, respectively. The lead dioxide electrodes showed better anti-corrosive property than the manganase dioxide electrode. The yield of the product was 92% which is almost the same as the one with conventional platinum electrodes.

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Fabrication and Characteristics of Organic EL Devices using Conducting Polymer as an Electrode (전도성 고분자를 전극으로 한 유기 전기발광 소자의 제작 및 특성)

  • Lee, Kwang-Youn;Kim, Young-Kwan;Kwon, Oh-Kwan;Sohn, Byoung-Chong;Kim, Ok-Byoung
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.4
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    • pp.323-327
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    • 1999
  • A water-soluble conducting polymer (CPP400 Paste) containing a derivative of polythiophene with several dopant was investigated as an anode material for organic electroluminescent devices. The device of ITO/CPP 400 Paste/TPD/$Alq_3$/Li:Al was fabricated, where CPP 400 Paste films were prepared by spin coating and TPD and $Alq_3$, films were prepared by vacuum evaporation. It was found that the turn-on voltage, current density, and luminance of the devices were dependent upon the thickness of CPP 400 Paste film in the Electroluminescent and current-voltage characteristics of the devices. This phenomena were explained by the energy level diagram of the device with the energy levels of the CPP400 Paste obtained by cyclic voltammetric method.