• Title/Summary/Keyword: Anisotropy profile

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Photodissociation of CINO at 236 nm

  • Kim Hong Lae;Mo Yuxiang;Matsumi Yutaka;Kawasaki Masahiro
    • Bulletin of the Korean Chemical Society
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    • v.13 no.2
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    • pp.162-165
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    • 1992
  • The fine structure branching ratio and Doppler profiles of photofragment Cl ($^{2}P_{j}$) atoms from photodissociation of CINO around 236 nm in the A band have been measured by the two photon resonance enhanced multiphoton ionization technique. The measured branching ratio, $Cl^{\ast} (^{2}P_{1/2})/Cl (^{2}P_{3/2})$ is $0.18{\pm}0.02$. The Doppler profile of Cl is well reproduced assuming that one of the two components in the photofragment translational spectra reported by Haas, Felder, and Huber [Chem. Phys. Lett., 180, 293 (1990)] should correspond to Cl and that an anisotropy parameter $\beta$ for the angular distribution is 0.45. The results suggest that CINO dissociation in the A band should consist of at least two non-crossing electronic states which correlate to the formation of $Cl^* and Cl, respectively.

Seismic motions in a non-homogeneous soil deposit with tunnels by a hybrid computational technique

  • Manolis, G.D.;Makra, Konstantia;Dineva, Petia S.;Rangelov, Tsviatko V.
    • Earthquakes and Structures
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    • v.5 no.2
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    • pp.161-205
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    • 2013
  • We study seismically induced, anti-plane strain wave motion in a non-homogeneous geological region containing tunnels. Two different scenarios are considered: (a) The first models two tunnels in a finite geological region embedded within a laterally inhomogeneous, layered geological profile containing a seismic source. For this case, labelled as the first boundary-value problem (BVP 1), an efficient hybrid technique comprising the finite difference method (FDM) and the boundary element method (BEM) is developed and applied. Since the later method is based on the frequency-dependent fundamental solution of elastodynamics, the hybrid technique is defined in the frequency domain. Then, an inverse fast Fourier transformation (FFT) is used to recover time histories; (b) The second models a finite region with two tunnels, is embedded in a homogeneous half-plane, and is subjected to incident, time-harmonic SH-waves. This case, labelled as the second boundary-value problem (BVP 2), considers complex soil properties such as anisotropy, continuous inhomogeneity and poroelasticity. The computational approach is now the BEM alone, since solution of the surrounding half plane by the FDM is unnecessary. In sum, the hybrid FDM-BEM technique is able to quantify dependence of the signals that develop at the free surface to the following key parameters: seismic source properties and heterogeneous structure of the wave path (the FDM component) and near-surface geological deposits containing discontinuities in the form of tunnels (the BEM component). Finally, the hybrid technique is used for evaluating the seismic wave field that develops within a key geological cross-section of the Metro construction project in Thessaloniki, Greece, which includes the important Roman-era historical monument of Rotunda dating from the 3rd century A.D.

Application of electrical resistivity in determining diagenetic stage of deep-sea carbonate sediments : A new variable (深海底 炭酸염 堆積物의 續成作용의 程度를 決定할 수 있는 새로운 變數로서 의 電氣 抵抗度의 應용 可能性)

  • 김대철
    • 한국해양학회지
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    • v.21 no.2
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    • pp.92-100
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    • 1986
  • Laboratory investigations of physical (density and porosity), acoustic (velocity and velocity anisotropy), and electrical (resistivity and resistivity anisotropy) properties in deep-sea carbonate sequences at DSDPsites 288 and 289 in the western equatorial Pacific were made and correlated as a function of diagenesis. Profile of resistivity shows almost a mirror image of velocity indicating that electrical resistivity can be a useful variable to determine the diagenetic stage. Some fluctuations in acoustic and electrical properties near the zones of cherty and siliceous limestones for both sites imply significant changes in pore geometry due to interbedded silica. The significantly reduced pore throat size by the presence of silica which provides excess calcium carbonate to adjacent pore spaces is partly responsible for several jumps in acoustic and electrical properties of the zones. These observed geophysical data are interpreted as the result of silica diagenesis influencing carbonate diagenesis.

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The Modification of Magnetic Properties of Co73Pt27-TiO2 Perpendicular Magnetic Recording Media with Ga+ Ion Irradiation (Ga+ 이온 조사를 통한 Co73Pt27-TiO2 수직자기 기록매체의 자기적 특성 변화)

  • Kim, Sung-Dong;Park, Jin-Joo
    • Journal of the Korean Magnetics Society
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    • v.17 no.6
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    • pp.221-225
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    • 2007
  • The effects of $Ga^+$ ion irradiation on the magnetic properties of the $Co_{73}Pt_{27}-TiO_2$ perpendicular magnetic recording media were investigated. As $Ga^+$ ion dose increased from $1\times10^{15}ions/cm^2\;to\;30\times10^{15}ions/cm^2$, the perpendicular magnetic anisotropy was degraded and no longer observed above $20\times10^{15}ions/cm^2$ dose. The deterioration of the perpendicular magnetic anisotropy and ferromagnetic properties can be attributed to the concentration profile change due to Ga+ ion implantation. The magnetic islands of $70\times70nm^2\;and\;100\times100nm^2$ size were successfully fabricated with $Ga^+$ ion irradiation.

The effect of the system factors on the shape of the S/L interface in GaAs single crystal grown by VGF method (VGF법을 사용한 GaAs 단결정 성장시 계의 구성요소가 고액계면의 형상에 미치는 영향)

  • Seung-Ho Hahn;Hyung-Tae Chung;Young-Kyu Kim;Jong-Kyu Yoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.1
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    • pp.33-41
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    • 1994
  • It is well known that the position and the shape of the S/L interface affect the qualities of the single crystal in the growth process. Thus the information of the temperature profile in the growth system is very important. In this study, we developed the program to predict the temperature profile from the setting values of the heating blocks in VGF(vertical gradient freezing) single crystal growth system. With this program, we studied the effects of the materials and the sizes of support rod, the materials of the crucible on the S/L interface shape. The larger radius and/or smaller thermal diffusivity support rod was, the flatter the S/L interface was. When the thermal conductivity of crucible was isotropic, the S/L interface was more concave downward to the solid phase in proportional to the increase of thermal diffusivity of the crucible. By the comparison of the S/L interface shape between PBN crucible and quartz crucible for the same condition, the effect of anisotropy of thermal conductivity of crucible showed different trends with respect to the position of the S/L interface.

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Second Harmonic Rotational Anisotropy of Polycrystalline Fe Films on Glass Substrates (유리 위에 증착된 다결정 Fe 자성박막의 이차조화파 회전 이방성)

  • Lee, Feel;Jeong, Jae-Woo;Lee, Hun-Sung;Lee, Kyung-Dong;Kim, Ji-Wan;Shin, Sung-Chul
    • Journal of the Korean Magnetics Society
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    • v.19 no.2
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    • pp.47-51
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    • 2009
  • The surface structure of polycrystalline Fe films of various thicknesses on glass substrates have been studied using a Ti: Sapphire laser at 780 nm. We found that the surface structure possesses C$_s$ crystal structure close to $C_{2v}$ through symmetry consideration. We present one-fold intensity profile with one mirror plane in second harmonic (SH) intensity as a proof of $C_s$ symmetry. $C_s$ and $C_{2v}$ surface symmetries usually appear at the (110) surface of a cubic diamond single crystal [1]. Therefore this surface symmetry would be related to bcc (110) growth orientation coinciding with XRD measurement. Further we treated surface normalized SH asymmetry with various thicknesses. The SH asymmetry increases with increasing of film thickness. From these results, it is observed that the surface structure of thin polycrystalline Fe film below 5 nm is almost isotropic, while in the case of the thicker Fe films, surface structure have $C_s$ symmetry structure close to $C_{2v}$.

Effect of Basal-plane Stacking Faults on X-ray Diffraction of Non-polar (1120) a-plane GaN Films Grown on (1102) r-plane Sapphire Substrates

  • Kim, Ji Hoon;Hwang, Sung-Min;Baik, Kwang Hyeon;Park, Jung Ho
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.14 no.5
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    • pp.557-565
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    • 2014
  • We report the effect of basal-plane stacking faults (BSFs) on X-ray diffraction (XRD) of non-polar (11$\underline{2}$0) a-plane GaN films with different $SiN_x$ interlayers. Complete $SiN_x$ coverage and increased three-dimensional (3D) to two-dimensional (2D) transition stages substantially reduce BSF density. It was revealed that the Si-doping profile in the Si-doped GaN layer was unaffected by the introduction of a $SiN_x$ interlayer. The smallest in-plane anisotropy of the (11$\underline{2}$0) XRD ${\omega}$-scan widths was found in the sample with multiple $SiN_x$ layers, and this finding can be attributed to the relatively isotropic GaN mosaic resulting from the increase in the 3D-2D growth step. Williamson-Hall (WH) analysis of the (h0$\underline{h}$0) series of diffractions was employed to determine the c-axis lateral coherence length (LCL) and to estimate the mosaic tilt. The c-axis LCLs obtained from WH analyses of the present study's representative a-plane GaN samples were well correlated with the BSF-related results from both the off-axis XRD ${\omega}$-scan and transmission electron microscopy (TEM). Based on WH and TEM analyses, the trends in BSF densities were very similar, even though the BSF densities extracted from LCLs indicated that the values were reduced by a factor of about twenty.

Spatial distribution of sediments in the Soyang Lake based on geostatistical analyses (지구통계기법을 이용한 소양호퇴적물 분포연구)

  • Kim, Ki-Young;Hwang, Yoon-Gu
    • 한국지구물리탐사학회:학술대회논문집
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    • 2006.06a
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    • pp.285-290
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    • 2006
  • To access the volume of sediments deposited after construction of the Soyang Dan and to understand their distribution in the Soyang lake, acoustic profiling using a 10-20 kHz system was conducted along profiles of 227 km length. Profile intervals are approximately 50 and 500 m for longitudinal and cross lines, respectively. The data were gain-controlled and then migrated using the f-k algorithm. After digitization of boundaries of the sediments, the acoustic interpretation was verified through correlating with 38 core samples. Thickness of the sediments averages 0.25 m and reaches to 8.25 m at maximum. Estimated total volume of the sediments based on anisotropic models in geostatistical methods is approximately $5.9{\times}10^6\;m^3$, which is more than twice greater than the earlier estimation based on an isotropic model.

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Measurement of residual stresses in injection molded short fiber composites considering anisotropy and modulus variation

  • Kim, Sang-Kyun;Lee, Seok-Won;Youn, Jae-Ryoun
    • Korea-Australia Rheology Journal
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    • v.14 no.3
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    • pp.107-114
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    • 2002
  • Residual stress distribution in injection molded short fiber composites is determined by using the layer-removal method. Polystyrene is mixed with carbon fibers of 3% volume fraction (4.5% weight fraction) in an extruder and the tensile specimen is injection-molded. The layer-removal process, in which removing successive thin uniform layers of the material from the surface of the specimen by a milling machine, is employed and the resulting curvature is acquired by means of an image processing. The isotropic elastic analysis proposed by Treuting and Read which assumes a constant Yaung’s modulus in the thickness direction is one of the most frequently used methods to determine residual stresses. However, injection molded short fiber composites experience complex fiber orientation during molding and variation of Yaung’s modulus distribution occurs in the specimen. In this study, variation of Yaung’s modulus with respect to the thickness direction is considered for calculation of the residual stresses as proposed by White and the result is compared with that by assuming constant modulus. Residual stress distribution obtained from this study shows a typical stress profile of injection-molded products as reported in many literatures. Young’s modulus distribution is predicted by using numerical methods instead of experimental results. For the numerical analysis of injection molding process, a hybrid FEM/FDM method is used in order to predict velocity, temperature field, fiber orientation, and resulting mechanical properties of the specimen at the end of molding.

Attachment Energy of Janus Particles at Fluid-Fluid Interfaces (유체 계면에서 야누스 입자의 흡착 에너지)

  • Park, Bum Jun
    • Korean Chemical Engineering Research
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    • v.51 no.6
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    • pp.655-660
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    • 2013
  • In this review, I present the configuration behaviors of various Janus particles at fluid-fluid interfaces. As a model system, Janus spheres, Janus ellipsoids, and Janus dumbbells are selected to investigate the effect of shape, size, and wettability on their configurations. In particular cases, Janus ellipsoids can adopt two distinct configurations (i.e., upright and tilted configurations) due to the presence of two energy minima in the attachment energy profile. On the contrary, a single energy minimum is found in the case of Janus dumbbells such that they adopt either the upright or tilted configuration. Interestingly, the geometric and chemical asymmetry and anisotropy in the characteristic properties of Janus dumbbells lead to an intermediate state in which the particles can rotate freely in a certain range of orientation angles.