• 제목/요약/키워드: Anisotropic orientation

검색결과 144건 처리시간 0.095초

The Interfacial Electronic Structure of Organic-organic Heterojunction: Effect of Molecular Orientation

  • 조상완
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.114.2-114.2
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    • 2014
  • The orientation of the constituent molecules in organic thin film devices can affect significantly their performance due to the highly anisotropic nature of ${\pi}$-conjugated molecules. We report here an angle dependent x-ray absorption study of the control of such molecular orientation using well-ordered interlayers for the case of a bilayer heterojunction of chloroaluminum phthalocyanine (ClAlPc) and C60. Furthermore, the orientation-dependent energy level alignment of the same bilayer heterojunction has been measured in detail using synchrotron radiation-excited photoelectron spectroscopy. Regardless of the orientation of the organic interlayer, we find that the subsequent ClAlPc tilt angle improves the ${\pi}-{\pi}$ interaction at the interface, thus leading to an improved short-circuit current in photovoltaic devices based on ClAlPc/C60. The use of the interlayers does not change the effective band gap at the ClAlPc/C60 heterointerface, resulting in no change in open-circuit voltage.

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장섬유강화 고분자복합판의 압축성형에 있어서 섬유의 분리와 배향의 상관관계에 관한 연구 (A Study on Correlation Between Separation and Orientation of Fibres During Compression Molding of Long Fibre-Reinforced Polymeric Composites)

  • 이동기;유정훈;김이곤
    • 대한기계학회논문집
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    • 제17권1호
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    • pp.62-68
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    • 1993
  • 본 연구에서는 장섬유강화 고분자복합판을 고온압축성형할 때 섬유의 분리 및 배향은 서로 불가분의 관계가 있으므로, 모재와 섬유의 분리에 의해서 야기되는 성형 품의 불균질성을 나타내는 균질도와 섬유의 배향을 표시하는 배향함수와의 상관관계에 대한 실험결과를 보고한다.

FCC 다결정재의 집합조직 발전에 따른 이방성의 변화 (Anisotropy due to Texture Development in FCC Polycrystals)

  • 김응주;이용신
    • 대한기계학회논문집A
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    • 제20권5호
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    • pp.1516-1523
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    • 1996
  • The present study is concerned with the development of anisotropy and deformation texture in polycrystals. The individual grain in an aggregate is assumed to experience the viscoplastic dedformation with crystallographic slip that unsure uniquenessof the active slip systems and shearing rate onthese systems. Two different methods for updating the grain orientation are examined. Texture development for some deformation modes such as plane strain compression, uniaxial tension and simple shear are found. Changes in anisotropic flow potential due to texture development during large deformation are also given. Anisotropic behavior of polycrystals with defferent textures are examined.

섬유강화 복합재료 사출성형품의 섬유배향상태 (Fiber Orientation distribution of Injection Molded Product on the Fiber-Reinforced Polymeric Composites)

  • 이정주;김진우;김혁;한길영;심재기;이동기
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2004년도 춘계학술대회 논문집
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    • pp.76-81
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    • 2004
  • Injection molding is the most widely used process fir the industrial forming of plastic articles. During an injection molding process of composites, the fiber-matrix separation and fiber orientation are caused by the flow of molten polymer/fiber mixture. As a result. the product tends to be nonhomogeneous and anisotropic. Hence, it is very important to clarify the relations between separation orientation and injection molding conditions. So far, there is no research on the measurement of fiber orientation using image processing. In this study, the effects of fiber content ratio and molding condition on the fiber orientation-angle distributions are studied experientially. Using the image processing method, the fiber orientation distribution of welding pars in injection-molded products is assessed. And the effects of fiber content and injection mold shapes on the fiber orientation in case of fiber reinforced polymeric composites are studied experimentally.

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단섬유강화 고분자 복합재료에서 사출성형 형상금형 형상변화에 따른 섬유배향상태 (Fiber Orientation of Short Fiber Reinforced Polymeric Composites Depending on Injection Mold Shape Variations)

  • 김혁;한길영;이동기
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집A
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    • pp.778-784
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    • 2001
  • Injection molding is a very important industrial process for the manufacturing of plastics objects. During an injection molding process of composites, the fiber-matrix separation and fiber orientation are caused by the flow of molten polymer/fiber mixture. As a result, the product tends to be nonhomogeneous and anisotropic. Hence, it is very important to clarify the relations between separation orientation and injection molding conditions. So far, there is no research on the measurement of fiber orientation using image processing. In this study, the effects of fiber content ratio and molding condition on the fiber orientation-angle distributions are studied experimentally. Using the image processing method, the fiber orientation distribution of weld-line parts in injection-molded products is assessed. And the effects of fiber content and injection molding conditions on the fiber orientation functions are also discussed.

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섬유강화 고분자 복합재료 사출성형품의 섬유배향상태 (Fiber Orientation Distribution of Injection Molded Product on the Fiber-Reinforced Polymeric Composites)

  • 이동기;심재기;김진우
    • 한국공작기계학회논문집
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    • 제14권1호
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    • pp.73-80
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    • 2005
  • Injection molding is the most widely used process for the industrial forming of plastic articles. During an injection molding process of composites, the fiber-matrix separation and fiber orientation are caused by the flow of molten polymer/fiber mixture. As a result, the product tends to be nonhomogeneous and anisotropic. Hence, it is very important to clarify the relations between separation orientation and injection molding conditions. So far, there is no research on the measurement of fiber orientation using image processing. In this study, the effects of fiber content ratio and molding condition on the fiber orientation-angle distributions are studied experimentally. Using the image processing method, the fiber orientation distribution of welding parts in injection-molded products is assessed. And the effects of fiber content and injection mold shapes on the fiber orientation in case of fiber reinforced polymeric composites are studied experimentally.

FRP의 사출성형에 있어서 섬유배향상태와 섬유함유율분포에 관한 연구 (Study on the Fiber Orientation and Fiber Content Ratio Distribution during the Injection Molding for FRP)

  • 이동기;심재기;김진우
    • 한국공작기계학회논문집
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    • 제15권4호
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    • pp.1-7
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    • 2006
  • Injection molding is a very important industrial process for the manufacturing of plastics objects. During an injection molding process of composites, the fiber-matrix separation and fiber orientation are caused by the flow of molten polymer/fiber mixture. As a result, the product tends to be nonhomogeneous and anisotropic. Hence, it is very important to clarify the relations between separation orientation and injection molding conditions. So far, there is no research on the measurement of fiber orientation using image processing. In this study, the effects of fiber content ratio and molding condition on the fiber orientation-angle distributions are studied experimentally. Using the image processing method, the fiber orientation distribution of weld-line in injection-molded products is assessed. And the effects of fiber content and injection mold-gate conditions on the fiber orientation are also discussed.

섬유강화 고분자 복합재의 사출성형에 있어서 웰드라인부의 섬유배향측정 (Measurement of the Fiber Orientation on Weld-Line Parts for Injection Molding of Fiber Reinforced Polymeric Composites)

  • 김혁;강명구;최유성;이동기;한길영;김이곤
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2000년도 추계학술발표대회 논문집
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    • pp.265-270
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    • 2000
  • Injection molding is a very important industrial process for the manufacturing of plastics objects. During an injection molding process of composites, the fiber-matrix separation and fiber orientation are caused by the flow of molten polymer/fiber mixture. As a result, the product tends to be nonhomogeneous and anisotropic. Hence, it is very important to clarify the relations between separation· orientation and injection molding conditions. So far, there is no research on the measurement of fiber orientation using image processing. In this study, the effects of fiber content ratio and molding condition on the fiber orientation-angle distributions are studied experimentally. Using the image processing method, the fiber orientation distribution of weld-line parts in injection-molded products is assessed. And the effects of fiber content and injection molding conditions on the fiber orientation functions are also discussed

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단섬유강화 플라스틱 복합재료 구조해석 기법연구 (A study on structure analysis system for short fiber reinforced plastics)

  • 윤지용;김상우;박봉현;이성훈;권태헌;김기태
    • Composites Research
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    • 제24권4호
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    • pp.41-47
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    • 2011
  • 본 연구는 사출 성형 공정을 통하여 제작되는 단섬유강화 플라스틱 복합재료의 구조해석 기법에 관한 내용으로 소재의 이방성 기계물성을 예측하고 이를 구조해석에 적용하도록 하였다. 사출 성형 공정을 통하여 제작되는 단섬유강화 플라스틱 복합재료의 구조해석에 있어서 기존의 경우는 일반적으로 소재의 기계적 물성을 균질 등방성 탄성 모델로 이용하여 왔으나, 실제 부품 파손 모드와 크게 상이한 경우가 많다. 이러한 점을 극복하고자 사출 성형 g,름 해석, 일방향성 복합재료의 Halpin-Tsai 식과 배향 평균 모델을 도입하여 단섬유강화 플라스틱 복합재료의 섬유배향 효과가 고려되도록 새로운 구조해석 시스템을 개발하였다. 해석의 정확도는 시편시험 결과와의 비교를 통하여 검증하였으며, 섬유 배향 및 웰드라인 영향 및 섬유 함량에 따른 변화가 해석에 장 반영됨을 확인하였다. 또한 자동차 부품에 개발된 해석 시스템을 적용하여 균질 등방 모델과 달리 부품의 위치별로 다른 기계적 성능이 반영되고, 사출 게이트 위치에 따라 유리섬유 배향이 변화하여 부품의 성능이 달라짐을 확인하였다.

CIP 부피비에 따른 이방성 MRE의 전단계수 변화율 (The Variation Rate of Shear Modulus for Anisotropic Magneto-rheological Elastomer due to Volume Fraction of CIP)

  • 정운창;윤지현;양인형;이유엽;오재응
    • 한국소음진동공학회논문집
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    • 제21권12호
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    • pp.1132-1137
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    • 2011
  • MRE(magneto-rheological elastomers) is a material which shows reversible and various modulus in magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb vibration of broader frequency range. These characteristic phenomena result from the orientation of magnetic particles named carbonyl iron powder(CIP) in rubber matrix. In this paper, simulation on variation rate of shear modulus for anisotropic MRE due to volume fraction of CIP and an effective permeability model was applied to predict the field-induced shear modulus of MREs. Also, the variation rate of shear modulus for anisotropic MRE was derived using magneto-mechanical theory. Based on Maxwell-Garnett mixing rule, the increment of shear modulus was calculated to evaluate the shear modulus of MREs with column structure of CIP due to induced current. The simulation results on variation rate of shear modulus can be applied to the variable mechanical system of MRE such as tunable vibration absorber, stiffness variable bush and mount.