• Title/Summary/Keyword: Analytical technique

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Surface-enhanced Raman scattering (SERS) spectroscopy: a versatile spectroscopic and analytical technique used in nanoscience and nanotechnology

  • Sur, Ujjal Kumar
    • Advances in nano research
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    • v.1 no.2
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    • pp.111-124
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    • 2013
  • Surface-enhanced Raman scattering (SERS) effect deals with the enhancement of the Raman scattering intensity by molecules in the presence of a nanostructured metallic surface. The first observation of surface-enhanced Raman spectra was in 1974, when Fleischmann and his group at the University of Southampton, reported the first high-quality Raman spectra of monolayer-adsorbed pyridine on an electrochemically roughened Ag electrode surface. Over the last thirty years, it has developed into a versatile spectroscopic and analytical technique due to the rapid and explosive progress of nanoscience and nanotechnology. This review article describes the recent development in field of surface-enhanced Raman scattering research, especially fabrication of various SERS active substrates, mechanism of SERS effect and its various applications in both surface sciences and analytical sciences.

Magneto-thermo-elastic response of exponentially graded piezoelectric hollow spheres

  • Allam, M.N.M.;Tantawy, R.;Zenkour, A.M.
    • Advances in Computational Design
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    • v.3 no.3
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    • pp.303-318
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    • 2018
  • This article presents a semi-analytical solution for an exponentially graded piezoelectric hollow sphere. The sphere interacts with electric displacement, elastic deformations, electric potentials, magneto-thermo-elasticity, and hygrothermal influences. The hollow sphere may be standing under both mechanical and electric potentials. Electro-magneto-elastic behavior of magnetic field vector can be described in the hollow sphere. All material, thermal and magnetic properties of hollow sphere are supposed to be graded in radial direction. A semi-analytical technique is improved to deduce all fields in which different boundary conditions for radial stress and electric potential are presented. Numerical examples for radial displacement, radial and hoop stresses, and electric potential are investigated. The influence of many parameters is studied. It is seen that the gradation of all material, thermal and magnetic properties has particular effectiveness in many applications of modern technology.

Selecting optimized mix proportion of bagasse ash blended high performance concrete using analytical hierarchy process (AHP)

  • Praveenkumar, S.;Sankarasubramanian, G.;Sindhu, S.
    • Computers and Concrete
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    • v.23 no.6
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    • pp.459-470
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    • 2019
  • Apart from strength properties, durability, toughness and workability are also important criteria in defining the performance of a concrete structure. Hence "High Performance Concrete (HPC)" is introduced. It is different from high strength concrete and can have various applications. In this paper, the properties (Mechanical and Durability) of High Performance Concrete blended with bagasse ash at 5%, 10%, 15% and 20% are studied. However, it is difficult to analyze the performance based on different properties obtained from different experiments. Hence it is necessary to combine all the criteria/properties into a single value to obtain a result by a technique called Analytical Hierarchy Process (AHP).It is an effective tool for dealing with complex decision making, and may aid the decision maker to set priorities and make the best decision. In addition, the AHP incorporates a useful technique for checking the consistency of the decision maker?s evaluations, thus reducing the bias in the decision making process.

Analytical Technique and Load Transfer Features on Pile Using Finite Difference Method (유한차분법을 이용한 말뚝의 하중전이특성 및 해석기법)

  • Han, Jung-Geun;Lee, Jae-Ho
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.9 no.5
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    • pp.10-21
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    • 2006
  • For analyze of the bearing capacity, skin friction and settlements of pile on axial compressive loading, both Load transfer tests of pile and pile loading test in field have application to commonly before pile installing. A bearing capacity of pile was affected by the characteristics of surrounding ground of pile. Especially, that is very different because of evaluation of settlement due to each soil conditions of ground depths. The ground characteristics using evaluation of bearing capacity of pile through load transfer analysis depends on N values of SPT, and then a bearing capacity of pile installed soft ground and refilled area may be difficult to rational evaluation. An evaluation of bearing capacity on pile applied axial compressive loading was effected by strength of ground installed pile, unconfined compressive strength at pile tip, pile diameter, rough of excavated surface, confining pressure and deformation modules of rock etc and these are commonly including the unreliability due to slime occurred excavation works. Load transfer characteristics considered ground conditions take charge of load transfer of large diameter pile was investigated through case study applied load transfer tests. To these, matrix analytical technique of load transfer using finite differential equation developed and compared with the results of pile load test.

Mechanism Analysis of Thermal Overload Relay (열동형 과부하 계전기의 메커니즘 해석)

  • Lee, Kyung-Ku
    • Proceedings of the KIEE Conference
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    • 1999.07a
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    • pp.287-289
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    • 1999
  • This paper proposes mechanism analysis in thermal overload relay. Overload protection performance is closely connected with mechanism of thermal overload relay. In shortage of analytical technique, we have experienced many difficulties in development of thermal overload relay. We applied analytical results to develop optimum thermal overload relay.

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Impact response analysis of delaminated composite laminates using analytical solution (이론 해를 이용한 층간 분리된 적층판의 충격거동 해석)

  • Kim, Sung-Joon;Shin, Jeong-Woo;Chae, Dong-Chul
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.315-320
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    • 2007
  • An analytical solution has been developed for the impact response of delaminated composite plates. The analysis is based on an expansion of loads, displacements, and rotations in a Fourier series which satisfies the end boundary conditions of simply-supported. The analytical formulation adopts the Laplace transformation technique, requiring a linearization of contact deformation. In this paper, the nonlinear contact stiffness is replaced by a linearized stiffness, to provide an estimate of the additional compliance due to contact area deformation effects. It has been shown that defects such as delaminations may be modeled as spring stiffness. The change in the impact characteristics as this spring stiffness has been investigated theoretically. Predicted impact responses using analytical solution are compared with the numerical ones from the 3-D non-linear finite element model. From the results, it is shown that analytical solution was found to be reliable for predicting the impact response.

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Dynamic Nonlinear Analysis Model for Reinforced Concrete Elements considering Strain Rate Effects under Repeated Loads (변형율속도를 고려한 반복하중을 받는 철근콘크리트 부재의 동적 비선형 해석모델)

  • 심종성;문일환
    • Proceedings of the Korea Concrete Institute Conference
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    • 1990.04a
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    • pp.78-83
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    • 1990
  • The current analytical techniques for R/C elements under severe dynamic repeated loads, like earthquake or impact, has two major problems; one is that the effects of strain rate are not considered and the other one is the current model was developed based on flexural behavior only. Thus, this study develops a computer software that can idealize the flexural and shear behavior of R/C elements using several parameters and also can consider the effects of strain rate. The analytical results using the developed analytical technique were compared with several experimental results and were generally satisfied.

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A GN-based modified model for size-dependent coupled thermoelasticity analysis in nano scale, considering nonlocality in heat conduction and elasticity: An analytical solution for a nano beam with energy dissipation

  • Hosseini, Seyed Mahmoud
    • Structural Engineering and Mechanics
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    • v.73 no.3
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    • pp.287-302
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    • 2020
  • This investigation deals with a size-dependent coupled thermoelasticity analysis based on Green-Naghdi (GN) theory in nano scale using a new modified nonlocal model of heat conduction, which is based on the GN theory and nonlocal Eringen theory of elasticity. In the analysis based on the proposed model, the nonlocality is taken into account in both heat conduction and elasticity. The governing equations including the equations of motion and the energy balance equation are derived using the proposed model in a nano beam resonator. An analytical solution is proposed for the problem using the Laplace transform technique and Talbot technique for inversion to time domain. It is assumed that the nano beam is subjected to sinusoidal thermal shock loading, which is applied on the one of beam ends. The transient behaviors of fields' quantities such as lateral deflection and temperature are studied in detail. Also, the effects of small scale parameter on the dynamic behaviors of lateral deflection and temperature are obtained and assessed for the problem. The proposed GN-based model, analytical solution and data are verified and also compared with reported data obtained from GN coupled thermoelasticity analysis without considering the nonlocality in heat conduction in a nano beam.

Calibration Methods for the Gas Chromatographic Analysis of ppt-level Hydrogen Sulfide (H2) in Air (환경 대기 중 ppt 수준의 황화수소 분석을 위한 GC 방식의 검량 기법에 대한 연구)

  • 김기현;오상인;최여진;최규훈;주도원
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.679-687
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    • 2003
  • In this study, we investigated the analytical techniques to quantify the ambient concentration of hydrogen sulfide (H$_2$S) in air at ppt concentration level. For this purpose, an on-line GC analytical system equipped with both pulsed-flame photometric detector (PFPD) and thermal desorption unit (TDU) was investigated by collecting ambient air samples. The results of our study generally indicated that calibration conditions of GC system is highly sensitive to affect the accuracy of the analytical technique. Most importantly. we found that the use of different matrices in the the preparation stage of working standards was sensitive to control the overall performance of this technique. The calibration of our analytical system was tested by the two types of working standard (prepared by mixing either with high purity $N_2$ or with the ambient air). According to this test, the latter represented more efficiently the detecting conditions of actual air samples. The peak occurrence patterns of both air samples and standards (prepared by mixing with ambient air) were altered in a similar manner as the function of the loaded volume; however, it was not the case for the $N_2$-mixed standards. Results of our study suggest that detection of H$_2$S is highly different from other sulfides and that its quantification requires minimiaing interfering effects of non -pure substance (like water vapor) and (either sorptive or destructive) loss effects.

A Study on the Research of Analytical Method for 1,4-Dioxane in Water (1,4-Dioxane의 분석방법 연구)

  • Park, Sun-Ku;Kim, Tae-Ho;Rim, Yeon-taek;Myung, Nho-Il
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.549-563
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    • 2005
  • The study was carried out to develop and standardize the analytical method of 1,4-dioxane in water. The National Institute of Environmental Research in Korea has monitored for 1,4-dioxane in water since 1998 and it has been detected in environmental water occasionally. But the environmental pollution and analytical method in water is not well known over the world. The trace analytical method at low-${\mu}/L$ level is prerequisite in order to evaluate the residue of 1,4-dioxane in water. Evaluation of the method was demonstrated by comparing and analyzing with liquid-liquid extraction, solid-phase extraction and purge & trap technique. As a result of experiment by standard solutions and raw samples, the precision and accuracy for three methods were obtained within error rate of about 10%. Therefore, three methods were standardized as official monitoring method in Korea. Also, a convenient and simple liquid-liquid extraction method for the analysis of 1,4-dioxane in water was developed by combined with gas chromatography/mass spectrometry and applied to the water samples in Korea