Journal of Korean Society on Water Environment (한국물환경학회지)

Korean Society on Water Environment (한국물환경학회)
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A Study on the Research of Analytical Method for 1,4-Dioxane in Water

1,4-Dioxane의 분석방법 연구

  • Park, Sun-Ku (Water Quality Research Department, National Institute of Environmental Research) ;
  • Kim, Tae-Ho (Water Quality Research Department, National Institute of Environmental Research) ;
  • Rim, Yeon-taek (Water Quality Research Department, National Institute of Environmental Research) ;
  • Myung, Nho-Il (Water Quality Research Department, National Institute of Environmental Research)
  • 박선구 (국립환경과학원 환경측정기준부 유기물질분석연구과) ;
  • 김태호 (국립환경과학원 환경측정기준부 유기물질분석연구과) ;
  • 임연택 (국립환경과학원 환경측정기준부 유기물질분석연구과) ;
  • 명노일 (국립환경과학원 환경측정기준부 유기물질분석연구과)
  • Received : 2005.06.03
  • Accepted : 2005.08.03
  • Published : 2005.11.30
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Abstract

The study was carried out to develop and standardize the analytical method of 1,4-dioxane in water. The National Institute of Environmental Research in Korea has monitored for 1,4-dioxane in water since 1998 and it has been detected in environmental water occasionally. But the environmental pollution and analytical method in water is not well known over the world. The trace analytical method at low-${\mu}/L$ level is prerequisite in order to evaluate the residue of 1,4-dioxane in water. Evaluation of the method was demonstrated by comparing and analyzing with liquid-liquid extraction, solid-phase extraction and purge & trap technique. As a result of experiment by standard solutions and raw samples, the precision and accuracy for three methods were obtained within error rate of about 10%. Therefore, three methods were standardized as official monitoring method in Korea. Also, a convenient and simple liquid-liquid extraction method for the analysis of 1,4-dioxane in water was developed by combined with gas chromatography/mass spectrometry and applied to the water samples in Korea

Keywords

References

  1. 국립환경연구원, 수돗물에서의 미량유해물질 분석방법연구 및 함유실태 조사 (2003)
  2. 박선구, 수돗물에서 미량유해물질 관리방안, 워터저널, pp. 71-84 (2005a)
  3. 박선구, 임연택, 1, 4-다이옥산 분석방법의 과학적 표준화 체계 구축, 수질측정 첨단 기술 동향과 정도향상 전략 (2005년 세계 물의 날 기념 국제 세미나), 국립환경연구원, pp. 75-98 (2005b)
  4. 환경부, 먹는 물 수질감시 항목 운영지침 및 시험방법 (2004)
  5. 日木, 新しい水質基準の制度の制定 . 改正, 固相抽出-ガスク ロマトブラフ-質量分析法 ここて對象とする項目は, 1,4-ヅオキサン である (2004)
  6. Akemi ABE, Determination Method for 1,4-Dioxane in Water Samples by Solid Phase Extraction - GC/MS, Journal of Environmental Chemistry, 7(1), pp, 95-100 (1997)
  7. Canada Centre for Inland Waters, Manual of Analytical Methods, Major ions and Nutrients, Ontario, Canada, 1, p. 1 (1994)
  8. Harris, L. E., Budde, W. L. and Eichelberger, J. W., DirectAnalysis of Water Samples for Organic Pollutants with Gas Chromatography-Mass Spectrometry, Analytical Chemistry, 46(13), pp. 1912-1917 (1974) https://doi.org/10.1021/ac60349a001
  9. Storer R. A. and Cornillot, J. L., Annual Book of ASTM Standards, water(1), Fazio, C. f, Elizabeth, L. G., Sharon, L. K., Joanne, G. K., Christine, M. L., Vernice, A. M. and Partricia, A. M., Ed., American Society for Testing and Materials, Philadelphia, PA U.S.A., 11(01), p, 14 (1993a)
  10. Storer, R. A. and Cornillot, J, L., Annual Book of ASTM Standards, water(I), Fazio, C. f., Elizabeth, L. G., Sharon, L. K., Joanne, G. K., Christine, M. L,, Vernice, A. M. and Partricia, A. M., Ed., American Society for Testing and Materials, Philadelphia, PA U.S.A., 11(01), p, 21 (1993b)
  11. Tayler, J. K., Quality Assurance of Chemical Measurements, Lewis Publishers, Inc., U.S.A., p. 1 (1987a)
  12. Tayler, J. K., Quality Assurance of Chemical Measurements, Lewis Publishers, Inc., U.S.A., p, 15 (1987b)
  13. US EPA Method 1624, Volatile Organic Compounds by Isotope Dilution GC/MS (1991)
  14. US EPA Method 8240A, Volatile Organics by Gas Chromatography/ Mass Spectrometry (GC/MS) (1992)
  15. US EPA Method 8260B, Volatile Organics by Gas Chromatography/ Mass Spectrometry (GC/MS) (1996a)
  16. US EPA Method 8270C, Semivolatile Organic Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) (1996b)
  17. US EPA Method 5030C, Purge-and-Trap for Aqueous Samples (2003)
  18. WCAS(West Coast Analytical Service) Lab., 1,4-Dioxane by GC/MS, http://www.cas.com/tech/DIOXANE.Htm (accessed July, 2004)