• Analytical Science and Technology
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• v.28 no.3
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• pp.160-167
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• 2015

This study aims to develop a new analytical method to detect zinc pyrithione, the ingredient of cosmetics appointed as restricted ingredients and used as preservatives.. The analytical method was based on data gathered from the relevant literature. Information about the amounts of these ingredients was researched in order to select the base-matrix materials used to validate the analytical method. After selecting and preparing the base-matrix materials, the analytical method was validated by method validation procedures. The analytical method was verified first by inter-laboratory validation and then through analyzing the cosmetics sold in the market. Based on the results of this study, guidelines are proposed for the analysis of restricted ingredients in cosmetics, which will provide a method to test the cosmetics circulating in the Korean market. The use of the proposed guidelines will increase the quality of the cosmetics as well as the safety of human health, which will enhance the competitiveness of the Korean cosmetics industry and lead to an increase in the exportation of cosmetics.

• Economic and Environmental Geology
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• v.53 no.1
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• pp.11-21
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• 2020

One-dimensional analytical solutions were used for forward and back diffusion of trichloroethylene (TCE) and tetrachloroethylene (PCE) in a single system with high- and low-permeability layers. Concentration profiles in a low-permeability layer, diffusive fluxes at the interface between the high- and low-permeability layers, and contaminant persistence in the high-permeability layer due to back diffusion were simulated with a comparison of semi-infinite and finite analytical solutions. In order to validate the analytical solutions used in this study, the results of one-dimensional analytical solutions developed by Yang et al. (2015) were compared with Nash-Sutcliffe model efficiency coefficient (NSE). When compared with Yang et al. (2015), the analytical solutions used in this study showed good agreements (NSE = 0.99). When compared with semi-infinite analytical solutions, TCE and PCE concentration profiles in the low-permeability layer, the diffusive fluxes, and the contaminant tailings of the high-permeability layer were underestimated. In order to determine the appropriate analytical solutions based on the effective diffusion coefficient, the thickness of the low-permeability layer, and the diffusion time in the TCE and PCE contaminated site, a term of dimensionless diffusion length (Z_d) was used. If the Z_d is less than 0.7, the semi-infinite solutions can be used to simulate accurate concentration profiles in low-permeability layers. If the Z_d is greater than 0.7, the reliability of simulations may be improved by using the finite solutions.

• Structural Engineering and Mechanics
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• v.48 no.6
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• pp.809-822
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• 2013

Base isolation is widely used in seismic resisting buildings due to its low construction cost, high reliability, mature theory and convenient usage. However, it is difficult to design the isolation layer in high-rise buildings using the available bearings because high-rise buildings are characterized with long period, low horizontal stiffness, and complex re-distribution of the internal forces under earthquake loads etc. In this paper, a simple and innovative isolation bearing, named Teflon-based lead rubber isolation bearing, is developed to address the mentioned problems. The Teflon-based lead rubber isolation bearing consists of friction material and lead rubber isolation bearing. Hence, it integrates advantages of friction bearings and lead rubber isolation bearings so that improves the stability of base isolation system. An experimental study was conducted to validate the effectiveness of this new bearing. The effects of vertical loading, displacement amplitude and loading frequency on the force-displacement relationship and energy dissipation capacity of the Teflon-based lead rubber isolation bearing were studied. An analytical model was also proposed to predict the force-displacement relationship of the new bearing. Comparison of analytical and experimental results showed that the analytical model can accurately predict the force-displacement relationship and elastic shear deflection of the Teflon-based lead rubber isolation bearings.

• Computational Structural Engineering
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• v.5 no.4
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• pp.133-142
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• 1992

An analytical model was developed for predicting the pullout behavior of straight beam longitudinal bars anchored at exterior beam-column connections. The model incorporates a local bond constitutive simulation capable of considering the effects of anchored bar diameter, yield strength and the spacing, concrete compressive strength, and column pressure on the bond characteristics of deformed bars in confined conditions of exterior joints. The analytical techniques adopted in this study were shown to satisfactorily predict the results of pullout tests on straight bars embedded in confined concrete specimens. An evaluation of the ACI-ASCE Committee 352 development length requirements in exterior joint conditions was made using the developed analytical approach. The results of this analytical evaluation are indicative of the conservatism of the current development length requirements in the confined conditions of exterior joints.

• Wind and Structures
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• v.25 no.5
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• pp.459-474
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• 2017

In this study an analytical expression is derived for the natural frequency of the wind turbine towers supported on flexible foundation. The derivation is based on a Euler-Bernoulli beam model where the foundation is represented by a stiffness matrix. Previously the natural frequency of such a model is obtained from numerical or empirical method. The new expression is based on pure physical parameters and thus can be used for a quick assessment of the natural frequencies of both the real turbines and the small-scale models. Furthermore, a relationship between the diagonal and non-diagonal element in the stiffness matrix is introduced, so that the foundation stiffness can be obtained from either the p-y analysis or the loading test. The results of the proposed expression are compared with the measured frequencies of six real or model turbines reported in the literature. The comparison shows that the proposed analytical expression predicts the natural frequency with reasonable accuracy. For two of the model turbines, some errors were observed which might be attributed to the difference between the dynamic and static modulus of saturated soils. The proposed analytical solution is quite simple to use, and it is shown to be more reasonable than the analytical and the empirical formulas available in the literature.

• Structural Engineering and Mechanics
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• v.60 no.3
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• pp.529-545
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• 2016

In this article, the generalized coupled non-Fickian diffusion-thermoelasticity analysis is carried out using an analytical method. The transient behaviors of field variables, including mass concentration, temperature and displacement are studied in a strip, which is subjected to shock loading. The governing equations are derived using generalized coupled non-Fickian diffusion-thermoelasticity theory, which is based on Lord-Shulman theory of coupled thermoelasticity. The governing equations are transferred to the frequency domain using Laplace transform technique and then the field variables are obtained in analytical forms using the presented method. The field variables are eventually determined in time domain by employing the Talbot technique. The dynamic behaviors of mass concentration, temperature and displacement are studied in details. It is concluded that the presented analytical method has a high capability for simulating the wave propagation with finite speed in mass concentration field as well as for tracking thermoelastic waves. Furthermore, the obtained results are more realistic than that of others.

• Steel and Composite Structures
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• v.21 no.5
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• pp.963-980
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• 2016

The jib system with middle strut is widely used to achieve the large arm length in the large scale tower crane and the deployability in the mobile construction crane. In this paper, an analytical solution for the out-of-plane buckling of the jib system with middle strut is proposed. To obtain the analytical expression of the buckling characteristic equation, the method of differential equation was adopted by establishing the bending and torsional differential equation of the jib system under the instability critical state. Compared with the numerical solutions of the finite element software ANSYS, the analytical results in this work agree well with them. Therefore, the correctness of the results in this work can be confirmed. Then the influences of the lateral stiffness of the cable fixed joint, the dip angle of the strut, the inertia moment of the strut, and the horizontal position of the cable fixed joint on the out-of-plane buckling behavior of the jib system were investigated.

• Mass Spectrometry Letters
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• v.7 no.2
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• pp.31-40
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• 2016

The analysis of nuclear materials and environmental samples is an important issue in nuclear safeguards and nuclear forensics. An analysis technique for safeguard samples has been developed for the detection of undeclared nuclear activities and verification of declared nuclear activities, while nuclear forensics has been developed to trace the origins and intended use of illicitly trafficked nuclear or radioactive materials. In these two analytical techniques, mass spectrometry has played an important role in determining the isotope ratio of various nuclides, contents of trace elements, and production dates. These two techniques typically use similar analytical instruments, but the analytical procedure and the interpretation of analytical results differ depending on the analytical purpose. The isotopic ratio of the samples is considered the most important result in an environmental sample analysis, while age dating and impurity analysis may also be important for nuclear forensics. In this review, important aspects of these techniques are compared and the role of mass spectrometry, along with recent progress in related technologies, are discussed.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.E1
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• pp.29-33
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• 2004

In environmental studies, decisions are often made on the analytical data indicating certain contaminants as being 'detected' or 'non-detectible.' Since detection limits are analytical method specific, one has to first review the concepts and definitions associated with analytical method systems and specifications. In this study, the experimental analytical values for a series of low level standards (for an ionic species) were used as an example to estimate two different method detection limits (MDL). The scores of EPA's MDL and Pallesen's MDL determined by real analytical scores are 0.0575 and 0.0561 mg/L, respectively for our nitrate data. These scores determined by two different MDL models are roughly similar, while there are apparent differences between two methods with respect to statistical and systematical procedure. However, determination of MDL for one's laboratory provides some practical applications which helps to assure one's regulating authorities that one's measured scores are accurate.

• Geotechnical Engineering
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• v.13 no.3
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• pp.53-62
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• 1997

Analytical studies were conducted to develop the Spectral-Analysis-of-Surface-Waves (SASW) method for underwater use. For the precise estimation of the in-situ soil stiffness profile from SASW measurements, it is essential to determine economical and reasonable theoretical dispersion curves reflecting various experimental conditions. In this paper, therefore, analytical methods are mainly discussed, which were developed to determine theoretical dispersion curves of surface waves propagated along the soil-water interface. Application of the analytical methods is then illustrated by an example involving estimation of a stiffness profile through a forward modeling process of SASW measurements. Applicabilities of the SASW method as well as the developed analytical methods are evaluated, respectively, from the example.