• Title/Summary/Keyword: Ammonium hydroxide

Search Result 168, Processing Time 0.027 seconds

Preparation of Ultra Fine Alumina Powder Via Ammonium Aluminium Carbonate Hydroxide (AACH 를 이용한 고순도 알루미나 분말 제조)

  • Tun, Zhu;Shin, Kun-Chul
    • Journal of Industrial Technology
    • /
    • v.24 no.B
    • /
    • pp.65-71
    • /
    • 2004
  • The ultra fine gamma-alumina powder was prepared via ammonium aluminium carbonate hydroxide (AACH). The XRD, SEM, BET, thermal analysis were used to characterize the samples. The effects of various reaction parameters as concentration, of solution, anion on specific area, PH, aging time and thermal decomposition condition on the produced AACH and alumina were discussed.

  • PDF

Mixed Micellar Properties Dodecyldimethyl(3-sulfopropyl)ammonium Hydroxide with Other Surfactants (Dodecyldimethyl(3-sulfopropyl)ammonium Hydroxide와 다른 계면활성제와의 혼합미셀화에 관한 연구)

  • Lee, Nam-Min;Lee, Byung-Hwan
    • Journal of the Korean Applied Science and Technology
    • /
    • v.31 no.4
    • /
    • pp.602-611
    • /
    • 2014
  • The critical micelle concentration (CMC) of the zwitterionic surfactant of dodecyldimethyl(3-sulfopropyl)ammonium hydroxide(LSB, $CH_3(CH_2)_{11}N^+(CH_3)_2(CH_2)_3SO{_3}^-$) and LSB/Tween-20, LSB/Tween-40, LSB/Tween-80 and LSB/DTAB, LSB/TTAB, LSB/CTAB mixed surfactant systems were determined by using the UV/Vis absorbance method from 284 K to 312 K. And the effects of temperature on the micellization have been measured for the thermodynamic study. The results show that the measured values of gibbs free energy are all negative in the whole measured. The values of enthalpy are positive Tween-20, And negative other surfactants. but the values of entropy are positive in the whole measured temperature region. The results show that all of the thermodynamic parameters are dependent on temperature and alkyl-group's length.

Synthesis of N-doped Titania using Ammonium Hydroxide and Photocatalytic Degradation of Humic Acid (암모니아수를 이용한 N-doped TiO2 제조 및 부식산의 광촉매 분해)

  • Cho, A-Young;Nam, Yun-Seon;Rhee, Dong-Seok
    • Journal of Industrial Technology
    • /
    • v.32 no.A
    • /
    • pp.95-102
    • /
    • 2012
  • To advance luminance efficiency of Titania at visible range, N-doped $TiO_2$ was prepared by using ammonium hydroxide as a source of nitrogen. The photoactivities of the synthesized $TiO_2$ were evaluated on the basis of degradation of humic acid in aqueous solutions with different light sources, UV-C, UV-A and fluorescent lamp. As a result, at UV-C is high efficiency $UV_{254}$ decrease and TOC removal. In this study, the best synthetic conditions of N-doped $TiO_2$ were 5.0 M of ammonium hydroxide concentration and calcination temperature of $550^{\circ}C$. The degradation rate of humic acid as an evaluation of photoactivities of the catalysts were conducted with pH variation, decrease rate of molecular absorption, removal rate of total organic carbon and fluorescece evolution for humic acid solution. XRD and SEM were applied for analysis of surface analysis of the catalysts.

  • PDF

A study on the Synthesis of Nickel Hydroxide by Ammonium Sulfate from Waste Nickel-Cadmium Batteries (폐니켈-카드뮴 전지로부터 황산암모늄을 이용한 수산화니켈 제조 방안 연구)

  • Kim, Min-Jun;Park, Il-Jeong;Kim, Dae-Weon;Jeong, Hang-Chul
    • Resources Recycling
    • /
    • v.28 no.5
    • /
    • pp.51-59
    • /
    • 2019
  • This study focused on the synthesis of the nickel hydroxide using ammonium sulfate in leaching solution from waste nickel-cadmium batteries. The effect of pH, temperature and the input amount of ammonium sulfate in leaching solution was investigated. The ammonium nickel sulfate with high purity was obtained in acidic leaching solution and the solution temperature of $60^{\circ}C$. The suitable molar ratio of the input amount of ammonium sulfate to nickel in solution is 2:1. The impurity about 1.4 at.% of Cd was included in the nickel hydroxide precipitates when ammonium nickel sulfate was used. At the process using sodium sulfide which precipitates the cadmium in solution, nickel and iron compounds were precipitated together.

Optimization on the fabrication process of Si pressure sensors utilizing piezoresistive effect (압저항 효과를 이용한 실리콘 압력센서 제작공정의 최적화)

  • Yun Eui-Jung;Kim Jwayeon;Lee Seok-Tae
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • v.42 no.1
    • /
    • pp.19-24
    • /
    • 2005
  • In this paper, the fabrication process of Si pressure sensors utilizing piezoresistive effect was optimized. The efficiency(yield) of the fabrication process for Si piezoresistive pressure sensors was improved by conducting Si anisotrophic etching process after processes of piezoresistors and AI circuit patterns. The position and process parameters for piezoresistors were determined by ANSYS and SUPREM simulators, respectively. The measured thickness of p-type Si piezoresistors from the boron depth-profile measurement was in good agreement with the simulated one from SUPREM simulation. The Si anisotrohic etching process for diaphragm was optimized by adding ammonium persulfate(AP) to tetramethyl ammonium hydroxide (TMAH) solution.

Camelina oil transesterification using mixed catalyst of tetra methyl amonium hydroxide and potassium hydroxide on the tubular reactor

  • Hyun, Young-Jin
    • Journal of the Korean Applied Science and Technology
    • /
    • v.28 no.2
    • /
    • pp.178-184
    • /
    • 2011
  • The analysis of reaction kinetics provided that the reaction order was the $1^{st}$ of triglyceride and the rate constant was 0.067 $min^{-1}$. The transesterification of camelina oil using 0.6 wt% mixed catalyst which consists of 40 v/v% of potassium hydroxide (1 wt%) and 60 v/v% of tetra methyl ammonium hydroxide (0.8 wt%), was carried out at $65^{\circ}C$ on the tubular reactor packed with static mixer. The conversion was shown to be 95.5% at the 6:1 molar ratio of methanol to oil, flow rate of feed of 3.0 mL/min and 24 of element of static mixer. The volume of washing water emitted by 0.6 wt% mixed catalyst was the half of the volume emitted by 1 wt% potassium hydroxide.

Nonlinear Regression Analysis of Acid-Base Titration System (산-염기 적정 시스템의 비선형 회귀분석에 관한 고찰)

  • Park, Chung-Oh;Hong, Jae-Jin
    • Korean Journal of Clinical Laboratory Science
    • /
    • v.40 no.1
    • /
    • pp.18-25
    • /
    • 2008
  • In classical titrimetric analyses, the major concern is the concentration of titrant, usually the aqueous solution of hydrochloric acid or sodium hydroxide, that could be changed as time goes by and it is accompanied with the inaccuracy of the resulting data. And the statistical approach, the nonlinear regression analysis, which is a well-known statistical method, was introduced to determine the accurate concentration of the titrant and the exact value of parameters, $K_a$, r, $C_a$, $C_b$, for 0.01 M aqueous solutions of analytes, sodium pyruvate, sodium acetate, sodium bicarbonate, ammonium hydroxide, ammonium chloride and acetic acid at $25^{\circ}C$. We used Gauss-Newton method for the linearlization of the nonlinear titration system and the two-parameter fitting showed appreciable convergent data for the parameters of the analytes set with the various range of $K_a$ value.

  • PDF

The Saw Damage Etching Characteristics of Silicon Wafer for Solar Cell with Alkaline Solutions (염기용액을 이용한 태양전지용 실리콘 기판의 절삭손상층 식각 특성)

  • Kwon, Soon-Woo;Yi, Jong-Heop;Yoon, Se-Wang;Kim, Dong-Hwan
    • New & Renewable Energy
    • /
    • v.5 no.1
    • /
    • pp.26-31
    • /
    • 2009
  • The surface etching characteristics of single crystalline silicon wafer were investigated using potassium hydroxide (KOH) and tetramethylammonium hydroxide (TMAH). The saw damage layer was removed after 10min by KOH 45wt% solution at $80^{\circ}C$. The wafer etched at high temperature ($90^{\circ}C$) and in low concentration (4wt%) of TMAH solution showed an increased etch rate of silicon wafer and wavy patterns on the surface. Especially, pyramidal textures were formed in 4wt% TMAH solution without alcohol additives.

  • PDF

Transfer of RNA from Methylmercury-agarose Gel to Nitrocellulose Membrane (메칠머큐리젤에 분리된 리보핵산의 니트로셀루로스막으로 이동)

  • 안정선
    • Journal of Plant Biology
    • /
    • v.30 no.2
    • /
    • pp.109-116
    • /
    • 1987
  • Effects of staining, buffer washing and denaturing agents on the transferrability of RNA fractionated on a methylmercury hydroxide-agarose gel to a nitrocellulose membrane were studied. Ethidium bromide staining and ammonium acetate buffer washing inhibited RNA transfer, while 3% HCHO and 0.5 M NaOH treatments stimulated transfer which was negated in the ammonium acetate buffer. Accordingly, maintenance of primary structure of RNA was proved to be essential for transferring RNA from the methylmercury hydroxideagarose gel to the nitrocellulose membrane.

  • PDF

Effect of Ultrasonic Wave on the Nickel-Zine Alloy Deposition whit the Variation of Ammonium Chloride Concertration (Ni-Zn 함금도금에서 염화암몬 농도에 따른 초음파의 영향)

  • 양학희;고광진;김재원
    • Journal of the Korean institute of surface engineering
    • /
    • v.21 no.4
    • /
    • pp.168-175
    • /
    • 1988
  • The nickel0zinc allot depositions have been studjen in ammonium chloridw added chloride baths to fine out the effects of ultrasonic irradiation for the electrodeposition processes. The compositions of deposited alloys, the current efficiencies, corrosion resistance and brightness in various conditions of electrodeposition were investigated, in the range of ultrasonic irradiation of 50,500 and 1,000kc/s respectively. The results obtained are as follows; 1. the ratio of nikel to zinc in the deposit increased according 시 the ammonium chloride concentration in irradiated baths. 2. The current efficiencies became also higer in the irradiated bath. 3. Ammonium ions in solution seem to retard formation of zinc hydroxide. 4. The corrsion resistance and brightness of the deposits are dependent upon nickel content of deposits which ranges 10-18%(wt)nickel in the irradiated baths and 11-15%(wt)in ninirradisted baths. 5. The corrosion resistance and brightnes of the deposited are appreciably better in the irradiated baths than in non-irradiated bath with the mole ratio of 3.4(NH+4/Ni+++Zn++).

  • PDF