• Journal of Environmental Health Sciences
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• v.27 no.1
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• pp.93-99
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• 2001

This study aims at finding out pertinent reaction conditions for treating high concentration ammonia contained in N-chemical factory wastewater with decompressed ammonia stripping method that was designed. And it also tries to investigate adsorption capability of removed ammonia to soil. The results from experiments are as follows ; 1. The removal rate of N $H_3$-N of synthetic wastewater was under 85% at pH 10 with decompressed ammonia stripping method. The reaction time in pressure 360 mmHg at pH 11 and 12 was shorter than in 460 mmHg, and the removal rate of N $H_3$-N with decompressed ammonia stripping method at 9$0^{\circ}C$ was 11~15% higher than air stripping 2. The optimum conditions for decompressed ammonia stripping with synthetic sample were shown as pH 12, temperature 9$0^{\circ}C$, internal reaction pressure 460 mmHg and reaction time 50 minutes. These conditions were applied to treat the wastewater containing organic-N 290.5mg/$\ell$, N $H_3$-N 168.9mg/$\ell$, N $O_2$-N 23.2mg/$\ell$, N $O_3$-N 252.4mg/$\ell$, T-N 735mg/$\ell$. Organic-N turned out to be removed 60%, the removal rate of N $H_3$-N IS 94%, T-N is 50%. But N $O_2$-N and N $O_3$-N were increased with 7.8% and 14.9% respectively. 3. The CO $D_{Sr}$ removal rate in decompressed ammonia stripping reaction was 42% and S $O_4$$^{2-}$ was removed 8.2%. It was turned out caused with higher pH and thermolysis. 4. In soil adsorption of ammonia desorbed from the decompressed stripping process of wastewater, the recovery rate was 76% in wet soil.

• Resources Recycling
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• v.12 no.3
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• pp.31-37
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• 2003

A study on the characteristics of ammonia desorption from aqueous solutions has been performed by air stripping as the first stage of ammonia recycling for the preparation of ammonium sulfate from it. For air stripping experiments, a stripping column made with acrylic tube of 40 mm diameter was employed and compressed air was injected into solutions through air sparger equipped at the bottom of stripping column. As a result of experiments, the stripping efficiency was increased with the aqueous pH and it was found that the appropriate pH for air stripping of ammonia was between pH 10 and 12. As far as the effect of air flow rate on ammonia stripping was concerned, ammonia stripping was not proportional to the air flow rate although it was affected by the air flow rate to some extent. Moreover, when more than 20 cm of water height was maintained, total ammonia desorbed from solution was not varied with the water height. Stripping temperature was also found to play an important role in ammonia desorption and about 90fo of initial ammonia was desorbed in 14 hours at pH 12.8 and at $60^{\circ}C$ Finally, it was believed that stripping temperature as well as the aqueous pH was one of the most important factors in air stripping of ammonia.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.4
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• pp.503-510
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• 2011

Ammonia in water which is toxic to human, its concentration is regulated below 0.5 mg/L in drinking water. Current study aimed to develop appropriate models for ammonia stripping using hollow fiber membrane contactor. Two different models were developed during the study. Model 1 was assumed only free ammonia ($NH_3$) transfer in stripping process, whereas the Model 2 was assumed with total ammonia ($NH_3+{NH_4}^+$) transfer. Ammonium chloride ($NH_4CI$), sodium hydroxide(NaOH) were used to make ammonia solution, which was concentration of 25 mg as N/L at a pH of 10.5. The experimental conditions were such that, the liquid flow was in tube-side in upward direction and t he gas flow was on shell-side in downward direction a t room temperature. The experimental and modeling results showed that marginal difference were observed at low gas flux. However the difference between the both models and experimental value were increased when the gas flux was increased. The study concludes that the Model 1 with free ammonia is more appropriate when both models were compared and useful in ammonia stripping process at low gas flux.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.2
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• pp.73-79
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• 2006

Aeration is the most important and indispensable operation unit for the treatment of swine manure using aerobic liquid-composting process. The composting of swine manure depends on biological treatment process, but the highly concentrated ammonia nitrogen is required a pretreatment to expect the appropriate efficiency of the biological treatment process. In this study, pilot experiments have been carried out to estimate of the fit condition about ammonia stripping process as a pretreatment to aerobic liquid- composting. pH adjustment with $Ca(OH)_2$ was economically superior to use of NaOH and optimum pH of ammonia stripping was 12.3, ammonia nitorgen was rapidly removed as pH were increased at $$35^{\circ}C$$. When air stripping is performed before aerobic liquid-stripping, a high initial pH is required for complete ammonia removal and is additional effects such as organic substances, phosphorus, turbidity, and color removal. Stripping process was very efficient in the pretreatment of highly concentrated ammonia nitrogen for composting of swine manure. Emission rate of gaseous ammonia was $0.5355mole\;s^{-1}$ at initial time and $0.0253mole\;s^{-1}$ at finitial time. The fit condition of ammonia stripping in this study were at the temperature of $$35^{\circ}C$$, and the pH of 12.3 during 48 hours.

• Journal of Korean Society on Water Environment
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• v.20 no.1
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• pp.86-92
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• 2004

Lab-scale experiments have been carried out to investigate ammonia stripping with a modified spray tower for removing ammonia nitrogen from swine wastewater. The operating conditions such as initial pH, temperature, air flow, hole size of distributor determining the diameter of water drops, and influent solids concentration were closely examined focusing on removal efficiency of ammonia. As a result of the experiment, in order to achieve high rate of ammonia removal by the air stripping system, the air flow rate must be supplied at high rate with sufficiently high initial pH, temperature. The optimum operating condition to meet the residual ammonia concentration of 300 mg/L was the initial pH of 11.0 at $35^{\circ}C$ with the air flow rate of 20 L/min. It also showed that the smaller hole size is, the higher removal rate of ammonia is expected. However, when used a small sized distributor (2 mm), the flooding problem at the upper column occurred due to clogging of the hole. With regard to the influent solids concentration, it was showed that the lower concentration of solids, the higher removal rate of ammonia. The removal of particulate materials in influent led to improve the removal efficiency of ammonia, rather than to control the operating condition including initial pH, temperature, and air flow. The empirical correlation between KLa and operating parameters would be driven as, $K_{La}=(0.0003T-0.0047){\cdot}G^{0.3926}{\cdot}L^{-0.5169}{\cdot}C^{-0. 1849}$. The calculated $K_{La}$ from proposed formula can be used effectively to estimate the optimum reaction time and to calculate the volume of modified spray tower system.

• Journal of Korean Society on Water Environment
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• v.22 no.5
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• pp.846-850
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• 2006

The biological nutrient removal from domestic wastewater with low C/N ratio is difficult. Therefore, this study was performed to increase influent C/N ratio by ammonia stripping without required carbon source and for improving treatment efficiencies of sewerage by the combination process of ammonia stripping and BNR (StripBNR). The results of this study were summarized as follows. BOD removal efficiencies of BNR and StripBNR were 95.3% and 93.2%, respectively. T-N and T-P removal efficiencies of BNR were 53.3% and 40.8%, respectively. T-N and T-P removal efficiencies of StripBNR were 72.8% and 62.9%, respectively. Concentrations of $NH_3-N$, $NO_2-N$ and $NO_3-N$ at BNR effluent were 0.03 mg/L, 0.08 mg/L and 9.12 mg/L, respectively. On the other hands, concentrations of $NH_3-N$, $NO_2-N$ and $NO_3-N$ at StripBNR effluent were 5.79 mg/L, 0.01 mg/L and 0.14 mg/L, respectively. Consequently, influent C/N ratio of BNR process was increased by ammonia stripping. Removal efficiency of T-N and T-P was improved about 20% by the process of StripBNR.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.9
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• pp.935-939
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• 2006

The biological nutrient removal from domestic wastewater with low C/N ratio is difficult. Therefore, this study was performed to examine effect of operational parameters such as air supply, hydraulic retention time, pH on the nitrogen removal by ammonia stripping and to increase influent C/N ratio without required carbon source. The ammonia stripping system used for the bench-scale experiment in laboratory had a dimension of 15 cm diameter and 150 cm height. The ammonia stripping reactors were classified into two types, type AS I and type AS II, according to there using or not media. Results of the research showed that the T-N removal efficiency of AS I using plastic media is slightly higher than AS II without media. In experimental condition of air supply 30 L/min and pH 12.5, T-N removal efficiencies increased as HRT of ammonia stripping reactor became longer from 8 hr to 36 hr. In experimental condition of HRT 36 hr, it was also found that the T-N removal efficiencies improved through increase of air supply. On the other hand, C/N ratio of wastewater was increased from average 3.9 to 5.4 by ammonia stripping.

• Korean Membrane Journal
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• v.7 no.1
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• pp.28-33
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• 2005

The feasibility of producing sulfuric acid and ammonia water from ammonium sulfate was investigated by an integrated process including ammonia stripping (AS) and electrodialysis with bipolar membrane (EDBM). It was suggested that the production of sulfuric acid using ammonia stripping-electrodialysis with bipolar membrane (ASEDBM) was effective in obtaining high concentration of sulfuric acid compared with EDBM alone. AS was carried out over pH 11 and within the range of temperatures, $20^{\circ}C{\~}60^{\circ}C$. Sodium sulfate obtained using AS was used as the feed solution of EDBM. The recovery of ammonia increased from $40\%$ to $80\%$ at $60^{\circ}C$ due to the increased mobility of ammonium ion. A pilot-scale EDBM system, which is composed of two compartments and 10 cell pairs with an effective membrane area of $200 cm^2$ per cell, was used for the recovery of sulfuric acid. The performance was examined in the range of 0.1 M${\~}$1.0 M concentration of concentrate compartment and of $25 mA/cm^2{\~}62.5 mA/cm^2$ of current density. The maximum current efficiency of $64.9\%$ was obtained at 0.1 M sulfuric acid because the diffusion rate at the anion exchange membrane decreased as the sulfuric acid of the concentrate compartment decreased. It was possible to obtain the 2.5 M of sulfuric acid in the $62.5 mA/cm^2$ with a power consumption of 13.0 kWh/ton, while the concentration of sulfuric acid was proportional to the current density below the limiting current density (LCD). Thus, the integrating process of AS-EDBM enables to recover sulfuric acid from the wastewaters containing ammonium sulfate.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.10
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• pp.1893-1904
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• 2000

Nitrogen compounds are one of the major pollutants which cause eutrophication problems of the river or lake and red tides problems of the ocean. Currently available technologies for the removal of nitrogen compounds are mostly biological treatment. However, biological treatment is only effective for the wastewater which contains low concentration of nitrogen compounds. Leachate from solid waste landfill or industrial wastewater which contains high concentration of nitrogen can not be effectively treated by most of the currently available biological treatment technologies. With this connection. the objective of this study is to examine the applicability of ammonia stripping technology for the removal of high concentration of ammonia nitrogen compounds of the leachate from solid waste landfill. It can be concluded that ammonia stripping technology which was placed before the biological treatment process was very effective for the removal of high concentration of ammonium compounds. The chemical cost for the ammonia stripping was 16 percent higher than MLE process, so other methods like sludge recycling are needed for the reduction of operation cost. Further details are discussed in this paper.

• Clean Technology
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• v.29 no.4
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• pp.297-304
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• 2023

The rapid advancement of the high-tech electronics industry has led to a significant increase in high-concentration ammonia wastewater. Various methods have been attempted to reliably treat wastewater containing high concentrations of ammonia, but no successful technology has yet been developed and applied. In this study, the removal efficiency and characteristics of ammonia nitrogen was evaluated according to changes in temperature, air loading rate, and liquid loading rate using a closed circulation countercurrent packed tower type demonstration facility for wastewater containing high concentrations of ammonia generated in the high-tech electronics industry. The temperature was varied while maintaining operating conditions of a wastewater flowrate of 20.8 m³ h^-1 and an air flow rate of 18,000 Nm³ h^-1. The results showed that at temperatures of 45,50,55, and 60℃, the removal efficiencies of ammonia nitrogen (NH₃-N) were 87.5%, 93.4%, 96.8%, and 98.7%, respectively. It was observed that temperature had the most significant impact on the removal efficiency of NH₃-N under these conditions. As the air loading rate increases, the removal rate also increases, but the increase in removal efficiency is not significant because droplets from the absorption tower flow into the stripping tower. Even if the liquid loading rate was changed by ±30%, the removal rate did not change significantly. This does not mean that the removal rate was unaffected, but was believed to be due to the relatively high air load rate. Through demonstration research, it was confirmed that ammonia stripping is a reliable technology that can stably treat high-concentration ammonia wastewater generated in the high-tech electronics industry.