• 한국초지조사료학회지
• /
• 제37권1호
• /
• pp.56-60
• /
• 2017

Mineralization is an important biological process for conversion of organic nitrogen (N) to inorganic N which can be used by plants directly. To investigate the effect of different manures on soil mineralization, the soil amended with cattle (CtM), goat (GM), chicken manure (ChM) and pig slurry (PS) were incubated under in vitro condition and ammonium N ($NH_4{^+}-N$), ammonification rate and ammonia emission were determined for eighty-four days. $NH_4{^+}-N$ was the highest in PS-amended soil for the whole experimental period. $NH_4{^+}-N$ in PS-amended soil was gradually decreased until day 84, whereas it was rapidly decreased for the first 14 days and then slightly increased until 84 days in ChM-, CtM- and GM-amended soil. The ammonification rate showed negative value for the first 14 days in all treatments. From day 14, ammonification rate started to increase in CtM- and ChM-amended soil, whereas it was maintained in GM- and PS-amended soil until day 84. The daily ammonia emission was the highest in PS-amended soil ($41mg\;kg^{-1}d^{-1}$), followed by CtM-, ChM-, and GM-amended soil at day 1. It was gradually decreased until day 84 in all treatments. The total $NH_3$ emission was the highest in PS-amended soil with $0.6mg\;kg^{-1}$ for 84 days, while less than $0.1mg\;kg^{-1}$ in three other plots. These results indicate that different manures showed different soil ammonification rate and $NH_3$ emission.

• 한국초지조사료학회지
• /
• 제42권1호
• /
• pp.47-53
• /
• 2022

The objective of this study was to verify the effect of pig slurry application with acidification and biochar on feed value, nitrogen use efficiency (NUE) of maize forage, and ammonia (NH₃) emission. The four treatments were applied: 1) non-pig slurry (only water as a control, C), 2) only pig slurry application (P), 3) acidified pig slurry application (AP), 4) acidified pig slurry application with biochar (APB). The pig slurry and biochar were applied at a rate of 150 kg N ha^-1 and 300 kg ha^-1, respectively. The AP and APB treatments enhanced all feed values compared to C and P treatments. The NUE for plant N was significantly increased 92.1% by AP and APB treatment, respectively, compared to the P treatment. On the other hand, feed values were not significantly different between AP and APB treatments. The acidification treatment with/without biochar significantly mitigated NH₃ emission compared to the P treatment. The cumulative NH₃ emission throughout the period of measurement decreased by 71.4% and 74.8% in the AP and APB treatments. Also, APB treatment reduced ammonia emission by 11.9% compared to AP treatment. The present study clearly showed that acidification and biochar can reduce ammonia emission from pig slurry application, and pig slurry application with acidification and biochar exhibited potential effects in feed value, NUE, and reducing N losses from pig slurry application through reduction of NH₃ emission.

• 한국환경농학회:학술대회논문집
• /
• 한국환경농학회 2009년도 정기총회 및 국제심포지엄
• /
• pp.329-338
• /
• 2009

대기 중으로 휘산 되는 대부분의 암모니아는 농경지에 시용하는 가축분뇨, 퇴비 및 질소비료에서 유래하며, 휘산된 암모니아는 강하 (Deposition)를 통해서 자연생태계의 산성화를 초래하고 수계의 부영양화를 유발하는 원인물질로 작용한다. 본 연구에서는 돈분뇨 및 퇴비 시용방법에 따른 암모니아 휘산량을 정량적으로 평가하였다. 돈분퇴비 표층살포 (SA), 표층살포 후 즉시 경운(IRA), 표층살포 3일후 경운 (RA-3d) 처리구의 13일동안 암모니아 휘산량은 각각, 28.7, 8.7, 24.3 kg N/ha 로 IRA 처리구는 SA 처리구에 비해 약 70% 저감효과를 가져왔다. 돈분 액비 표층 살포 후 즉시 경운은 무경에 비해 봄과 가을 각각 26, 50% 의 암모니아 휘산량 저감 효과가 있었다. 그리고 수분 함량에 따른 암모니아 휘산량은 수분 함량이 높을수록 건조 토양에 비해 증가 하였다. 돈분 액비 시용 전후 담수 조건에 따른 암모니아 휘산량은 담수 상태에서 액비를 시용하는 것이 건토에 액비 살포 1일 후 담수 보다 약 4.7배의 암모니아 휘산량 증가가 있었다.

• 플랜트 저널
• /
• 제18권3호
• /
• pp.52-61
• /
• 2022

본 연구는 실제 운영중인 영동에코발전본부 1호기 125 MW 우드펠릿 발전소를 대상으로 탈질설비 운전조건이 NOx 발생량에 미치는 영향을 시험하였다. SNCR 요소 유량 증가에 따라 NOx 농도는 점차 감소하였으나 SCR 후단 암모니아 슬립은 상승하였다. 시험대상 보일러는 고온의 내부온도로 인해 SNCR 운영에 불리한 구조이며 노즐의 최적위치 검토가 필요할 것이다. SCR 희석공기 온도변화는 NOx 발생량에 영향을 미치지 않았다. SCR 암모니아 유량 증가는 SCR 후단 NOx 농도를 감소시켰고 NOx 제거효율도 증가시켰다. 다만 암모니아 슬립 자체 기준치를 초과하지 않는 암모니아 유량 111 kg/h가 최대 운전기준으로 추정된다. SCR 믹서 압력 상승은 NOx 농도를 감소시키고 제거효율도 최대로 측정되어 NOx 생성을 가장 효과적으로 억제하는 변수로 파악되었다.

• Environmental Engineering Research
• /
• 제20권4호
• /
• pp.397-402
• /
• 2015

SCR has been popularly approved as one of the most effective means for NOx emission control in heavy-duty and medium-duty vehicles currently. However, high urea dosing would lead to ammonia slip. And $NH_3$ sensor for vehicle emission applications has not been popularly used in real applications. This paper presents experimental studies on the diesel engine urea-SCR system by using a double NOx sensor system that is arranged in the downstream of the SCR catalyst based on ammonia cross-sensitivity. It was shown that the NOx conversion efficiency rised as $NH_3/NOx$ increases and the ammonia slip started from the $NH_3/NOx$ equal to 1.4. The increase of temperature caused high improvement of the SCR reaction rate while the space velocity had no obvious change. The ammonia slip was in advance as catalyst temperature or space velocity increase and the ammonia storage reduced as catalyst temperature or space velocity increase. The NOx real-time conversion efficiency rised as the ammonia accumulative storage increase and reached the maximum value gradually.

• 한국유기농업학회지
• /
• 제13권2호
• /
• pp.185-195
• /
• 2005

Two hundred [(Duroc${\times}$Yorkshire)${\times}$Landrace] pigs were used in a 117-d growth assay (including four growth stages) to determine the effects of dietary supplementation of Lactobacillus reuteri on performance of swine, fecal and rectumal microflora and carcass grade. Pig diet was divided tow types, commercial diet (Control group) and supplemention of 0.1% Lactobacillus reuteri (Treatmental group). There was tend to increased in average daily gain (ADG) and feed efficiency (Feed/gain) in treatmental group than control group during the whole experimental period. The number of Lactobacilius spp. into rectum and feaces and carcass rate tended to increase in treatmental group than control group. Ammonia emission from excreta were decrease by supplemention of 0.1% Lactobacillus reuteri in feed (P<0.05). These results indicated that the dietary Lactobacillus reuteri were effective in performance, increasing of Lactobacilius spp. into rectum and feaces, decreasing ammonia emission from excreta, and it had also effective the carcass rate in swine.

• 한국초지조사료학회지
• /
• 제38권3호
• /
• pp.145-149
• /
• 2018

The objective of this study was to determine the effect of injection application of pig slurry on ammonia ($NH_3$) and nitrous oxide ($N_2O$) emission from timothy (Phleum pretense L.) sward. The three treatments were applied: 1) only water as a control, 2) pig slurry application by broadcasting, 3) pig slurry application by injection. The pig slurry was applied at a rate of $200kg\;N\;ha^{-1}$. Total $NH_3$ and $N_2O$ emission, expressed as a cumulative amount throughout the measurement time (40 days), was $2.68kg\;NH_3-N\;ha^{-1}$ and $6.58g\;N_2O-N\;ha^{-1}$, respectively, in the control. The injection application of pig slurry decreased total $NH_3$ and $N_2O$ emission by 39.8% and 33.3%, respectively, compared to broadcasting application of pig slurry. The present study clearly showed that injection application exhibited positive roles in reducing N losses through $NH_3$ and $N_2O$ emission.

• 한국농공학회논문집
• /
• 제63권1호
• /
• pp.75-87
• /
• 2021

Air quality related to particulate matters and ammonia is being come to the fore as the national concern in Korea. CAPSS (Clean Air Policy Support System) provides emission coefficients of these kinds of particulate and gaseous matters in the fields of livestock; however reliability issues are consistently mentioned. Evaluation of emission rates of PM2.5 and NH3 of the country is very important, but only few studies are available as the background related to observation of the concentration of the particulate matter and ammonia, especially within livestock house in Korea. In this paper, long-term measurement of PM10, PM2.5, and ammonia within the mechanically ventilated broiler house were carried out to introduce backgrounds of generation and emission of the particulate matters and ammonia. Measurement results were analyzed according to seasonal changes, age of broilers(weeks) and measurement locations. Concentration of inhalable and respirable dust were also evaluated in terms of occupational respiratory health according to increase in broiler's activity. From the results of this study, identification of the generation mechanisms of the particulate and gaseous matters, and evaluation of the emission rate of these in the broiler house will be carried out.

• 플랜트 저널
• /
• 제15권3호
• /
• pp.23-28
• /
• 2019

본 연구에서는 580 MW급 세종복합발전소의 선택적 촉매환원방식 탈질설비 1호기를 대상으로 강화된 대기환경보전법 및 환경평가협의 질소산화물 허용배출기준을 준수하는 암모니아 소모량을 찾고자 가스터빈 출력별 암모니아 투입량을 조절하며 측정하였다. 측정을 위해 가스터빈 출력은 50, 99, 149 그리고 198 MW로 변동시키고 각 출력단계별 연소가스 및 암모니아 공급조건을 고정한 상태에서 탈질설비 내 암모니아 소모량을 조절하였다. 질소산화물 배출기준을 10 ppm에서 8 ppm으로 변경하였을 때 출력대별 암모니아 소모량은 각각 78, 93, 105 그리고 133 kg/h에서 89, 113, 132 그리고 176 kg/h로 증가 되었다. 암모니아 소모량 증가율은 질소산화물 배출기준 10 ppm 대비 출력대 별 각각 14, 22, 26 그리고 32%로 출력이 증가할 수 록 증가율도 늘어남을 알 수 있었다.

• 한국토양비료학회지
• /
• 제50권1호
• /
• pp.49-55
• /
• 2017

Chinese cabbage cultivation and ammonia volatilization experiments were done to evaluate the efficiency of Agrotain coated urea (GSP 80% + Agro; GSP 100% + Agro) against conventional urea (GSP 80%; GSP 100%). Fresh weight of Chinese cabbage were 17.2% and 7.3% higher in the treatments that received GSP 80% + Agro and GSP 100% + Agro, respectively, of those from the treatments that received urea alone. Likewise, the nitrogen use efficiency of Chinese cabbage in the treatments that received Agrotain coated urea were significantly higher at the rate of 3.5% (GSP 80% + Agro) and 1.9% (GSP 100% + Agro) compared to urea alone treatments. Ammonia emission was substantially higher at the rate of $107.6N\;mg\;chamber^{-1}$ with the application of only GSP 100%. However, nearly 28.3% of ammonia emission was considerably reduced with the use of Agrotain coated urea. Hence, we recommend the use of Agrotain coated urea in conventional farming for increased crop yield as well as simultaneous reduction of nitrogenous fertilizer use.