• Title/Summary/Keyword: Ambient gas

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Process Control of Titanium Silicide Formation Using RTP (RTP를 사용한 타이타늄 실리사이드 형성의 공정 조절)

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    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.15 no.5
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    • pp.399-405
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    • 1990
  • Rapid Thermal Process(RTP) has been used to precisely control and study the reaction rate for the formation of refractory titanuium silicide. Samples were prepared by sputtering deposition layer of titanium on n-type, poly-deposit silicon wafers. The process were then sujected to a matrix of rapid time-temperature profile under nitrgen, argon gas ambient to precisely control the silicide formation. Reacted films were analyzed by the sheet resistance measursrement, SEM, ASR and X-ray diffraction. Results were shown that the resistivity of the silicide films are below 20u-cm and the thickness of silicide films are about two times than that of as-deposited titanium films. Silicidation ambient was likely to happen at the same tamperature-time condition for argon and nitrogen gas.

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Concentrations of $C_2$~$C_9$ Volatile Organic Compounds in Ambient Air in Seoul (서울 대기 중에서 $C_2$~$C_9$ 휘발성 유기화합물의 농도)

  • Na, Gwang-Sam;Kim, Yong-Pyo;Kim, Yeong-Seong
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.2
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    • pp.95-106
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    • 1998
  • Volatile organic compounds (VOCs) from Ca to C9 were investigated with nine ambient air samples collected in April 26, August 17, 1996 and January 23, 1997 in a Seoul site. On each sampling day, three 2-hr integrated canister samples were collected in early morning, early afternoon and late afternoon, respectively to study temporal . variation of VOCs. Most of VOC species showed diurnal variation with higher concentrations in the early morning and lower concentrations in the afternoon. The concentrations of light alkanes were high, probably due to the emission from liquefied petroleum gas (LPG) and evaporation of gasoline. Especially, the concentration of propane was the highest in the morning samples. The concentrations of propane, ethylene, acetylene, and toluene were prominent in their hydrocarbon groups, respectively. These components were the main source of car exhaust, gasoline evaporization, LPG, or solvent usage.

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On-line GC Analysis of Odorous VOC and S Gas Pollutant Levels in Ambient Air of a Residential Area at Ansan City, Korea (안산시 주거지역을 중심으로 한 환경대기 중 휘발성 유기화합물과 황계열 성분의 온라인 연속측정 연구)

  • Kim K.-H;Ju DW;Choi YJ;Hong YJ;Sa JH;Park JH;Jeon EC;Choi CR;Koo YS
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.1
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    • pp.107-118
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    • 2005
  • In this study, the concentrations of major odorous compounds including reduced sulfur compounds (OMS, CS$_2$, and DMDS) and aromatic VOC (benzene, toluene, xylene, etc.) were measured continuously using an on-line GC analytical system. Our measurements were made from a residential area of Ansan sity during about two week period of October, 2004. The highest mean concentrations of Sand VOC were found as 56.9 pbb of DMS and 21.7 ppb of toluene, respectively. The results of this study generally show that the pollution levels for both types of chemicals are significant relative to previous measurement results reported from comparable sites, if the results are compared simply in terms of the magnitude of the measured concentration data. Moreover, when the relative importance of different compounds is compared in terms of the odor strength, it indicated that the contribution of reduced S compounds may be much more important than that of VOC in the study area.

Thermal Stability of the Interface between TaN Deposited by MOCVD and Electroless-plated Cu Film (MOCVD 방법으로 증착된 TaN와 무전해도금된 Cu박막 계면의 열적 안정성 연구)

  • 이은주;황응림;오재응;김정식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.12
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    • pp.1091-1098
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    • 1998
  • Thermal stability of the electroless deposited Cu thin film was investigated. Cu/TaN/Si multilayer was fabricated by electroless-depositing Cu thin layer on TaN diffusion barrier layer which was deposited by MOCVD on the Si substrate, and was annealed in $H_2$ ambient to investigate the microstructure of Cu film with a post heat-treatment. Cu thin film with good adhesion was successfully deposited on the surface of the TaN film by electroless deposition with a proper activation treatment and solution control. Microstructural property of the electroless-deposited Cu layer was improved by a post-annealing in the reduced atmosphere of $H_2$ gas up to $600^{\circ}C$. Thermal stability of Cu/TaN/Si system was maintained up to $600^{\circ}C$ annealing temperature, but the intermediate compounds of Cu-Si were formed above $650^{\circ}C$ because Cu element passed through the TaN layer. On the other hand, thermal stability of the Cu/TaN/Si system in Ar ambient was maintained below $550^{\circ}C$ annealing temperature due to the minimal impurity of $O_2$ in Ar gas.

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Effect of the Injection Parameters on Diesel Spray Characteristics

  • Song Kyu Keun;Sim Sang Cherl;Jung Byong Koog;Kim Hyung Gon;Kim Jang Heon
    • Journal of Mechanical Science and Technology
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    • v.19 no.6
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    • pp.1321-1328
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    • 2005
  • The characteristics of the diesel spray have affected certain aspects of engine performance, such as the power, fuel consumption, and emissions. Therefore, this study was performed to investigate the effects of various injection parameters. In order to obtain the effect of injection parameters on diesel spray characteristics, the experiment is performed by using a high temperature and pressure chamber. The behaviors of the spray are visualized by using a high speed video camera, spray angle, penetration, and various other things. The results of the experiment are summarized as follows. (1) The correlation of the spray penetration can be expressed as follows. $$0< t $$t_{b} (2) The correlation of the spray angle can be expressed as follows $$T_a=293K\;tan({\theta}/2)=0.59({\rho}a/{\rho}f)^{0.437}$$ $$T_a=473K\;tan({\theta}/2)=0.588({\rho}a/{\rho}f)^{0.404}$$ (3) The measured macro characteristics that include the spray tip penetration and spray angle corresponded with the established correlations.

Performance Test of a Small Simulated High-Altitude Test Facility for a Gas-turbine Combustor (가스터빈 저온/저압 점화장치 구성 및 운영조건 확인 시험)

  • Kim, Tae-Woan;Lee, Yang-Suk;Ko, Young-Sung;Lim, Byeung-Jun;Kim, Hyeong-Mo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.153-156
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    • 2008
  • Ignition and combustion performance of a gas-turbine engine were changed by various high-altitude condition. A goal of this study is to make the small test facility to simulate high-altitude condition. To perform the low pressure condition, a diffuser was used in various diffuser front of primary nozzle pressure. To perform the low temperature, heat exchanger was used in various mixture ratio of cryogenic air and ambient temperature air. The experimental result shows that high-altitude conditions can be controled by diffuser front of primary nozzle pressure and mixture ratio of cryogenic air and ambient temperature air.

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A Study on Evaporative Characteristics of Multi-component Mixed Fuels Using Mie Scattered Light and Shadowgraph Images (Mie 산란광법 및 Shadowgraph법을 이용한 다성분 혼합연료의 증발특성연구)

  • Yoon, Jun-Kyu;Myong, Kwang-Jae;Jiro Senda;Fujimoto Hajime;Cha, Kyung-Ok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.7 s.250
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    • pp.682-691
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    • 2006
  • This study was conducted to assess the effect of mixed fuel composition and mass fraction on spray inner structure in evaporating transient spray under the various ambient conditions. Spray structure and spatial distribution of liquid phase concentration are investigated using a thin laser sheet illumination technique on the multi-component mixed fuels. A pulsed Ar+ laser was used as a light source. The experiments were conducted in a constant volume vessel with optical access. Fuel was injected into the vessel with electronically controlled common rail injector. Used fuel contain $i-octane(C_8H_{18}),\;n-dodecane(C_{12}H_{26})$ and $n-hexadecane(C_{16}H_{34})$ that are selected as low-, middle- and high-boiling point fuel, respectively. Experimental conditions are 25Mpa, 42MPa, 72MPa and 112MPa in injection pressure, $5kg/m^3,\;15kg/m^3\;and\;20kg/m^3$ in ambient gas density, 400K, 500K, 600K and 700K in ambient gas temperature, 300K and 368K in fuel temperature, and different fuel mass fraction. Experimental results indicate that the more high-boiling point component, the longer the liquid phase it were closely related to fuel physical properties, but injection pressure had no effect on. And there was a high correlation between the liquid phase length and boiling temperature at 75% distillation point.

An Experimental Analysis on the Spray Structure of Multi-component Fuels Using Magnification Photograph and Mie Scattering Images (확대촬영법 및 Mie 산란광법을 이용한 다성분연료의 분무구조에 관한 실험적 해명)

  • Myong, Kwang-Jae;Yoon, Jun-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.5
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    • pp.707-716
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    • 2008
  • The objective of this study was to analyze the effect of mixed fuel composition and mass fraction on spray inner structure in evaporating transient spray under the variant ambient conditions. Spray structure and spatial distribution of liquid phase concentration were investigated using a thin laser sheet illumination technique on the three component mixed fuels. A pulsed Nd:YAG laser was used as a light source. The experiments were conducted in a constant volume vessel with optical access. Fuel was injected into the vessel with electronically controlled common rail injector. Used fuel contains i-octane($C_8H_{18}$), n-dodecane($C_{12}H_{26}$) and n-hexadecane($C_{16}H_{34}$) that were selected as low-, middle- and high-boiling point fuel, respectively. Experimental conditions are 42 MPa, 72 MPa and 112 MPa in injection pressure, $5\;kg/m^3$, $15kg/m^3$ and $30kg/m^3$ in ambient gas density, 300 K, 500 K, 600 K and 700 K in ambient gas temperature, 300 K and 368 K in fuel temperature and different fuel mass fraction. Experimental results indicated that the multi-component fuels made two phase region mixed vapor and liquid so that it would are helpful to improve combustion, for the fuels of high boiling point component could accelerate evaporation very much according as low boiling point fuel was added to high boiling point fuel.

Measurement of Atmospheric Dry Deposition and Size Distribution of Particulate PCBs in 1999 at Seoul

  • Park, Seong-Suk;Shin, Hye-Joung;Yi, Seung-Muk;Kim, Yong-Pyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.E1
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    • pp.35-43
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    • 2006
  • Ambient particle size distributions of PCBs and their dry deposition fluxes were measured at a site in Seoul to quantify dry deposition fluxes of PCBs and size characteristics of PCBs in the air, and to estimate ambient concentrations of gaseous PCBs and dry deposition fluxes. The dry deposition plate was used to measure dry deposition fluxes of particulate mass and PCBs and a cascade impactor and rotary impactor were used to measure ambient particle size distributions for small ($D_p<9{\mu}m$) and large ($D_p>9{\mu}m$) particles, respectively. Six sample sets were collected from April to July 1999. The fluxes of particulate total PCBs (the sum of 43 congeners) ranged from 160 to $607ng\;m^{-2}day^{-1}$. The size distribution of total PCBs was bimodal with two peaks in small particle size ($D_p{\sim}0.6\;and\;6{\mu}m$, respectively) and, thus, mass concentration being dominant in small particles. The mean particulate PCBs concentration was $6.9{\mu}g$ PCBs/g. The concentrations of PCB homologues in the gas phase were estimated based on the particle/gas partition coefficient ($K_p$) with the measured values of particulate PCBs in this study and they were comparable to those observed in other previous studies. Dry deposition fluxes were estimated by calculating dry deposition velocities.

Modeling the Influence of Gas Pressure on Droplet Impact Using a Coupled Gas/liquid Boundary Element Method

  • Park, Hong-Bok;Yoon, Sam S.;Jepsen Richard A.;Heister Stephen D.
    • Journal of ILASS-Korea
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    • v.11 no.2
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    • pp.89-97
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    • 2006
  • An inviscid axisymmetric model capable of predicting droplet bouncing and the detailed pre-impact motion, influenced by the ambient pressure, has been developed using boundary element method (BEM). Because most droplet impact simulations of previous studies assumed that a droplet was already in contact with the impacting substrate at the simulation start, the previous simulations could not accurately describe the effect of the gas compressed between a failing droplet and the impacting substrate. To properly account for the surrounding gas effect, an effect is made to release a droplet from a certain height. High gas pressures are computationally observed in the region between the droplet and the impact surface at instances just prior to impact. The current simulation shows that the droplet retains its spherical shape when the surface tension energy is dominant over the dissipative energy. When increasing the Weber number, the droplet surface structure is highly deformed due to the appearance of the capillary waves and, consequently, a pyramidal surface structure is formed; this phenomenon was verified with our experiment. Parametric studies using our model include the pre-impact behavior which varies as a function of the Weber number and the surrounding gas pressure.

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