• Title/Summary/Keyword: Aluminum phosphate

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TEMPERATURE CHANGES IN THE PULP ACCORDING TO VAR10US RESTORATIVE MATERIALS AND BASES DURING POLISHING PROCEDURE (연마시 여러 가지 수복재와 이장재의 사용에 따른 치수내 온도변화)

  • Baik, Byeong-Ju;Lee, Doo-Cheol;Kim, Mi-Ra;Kim, Jae-Gon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.27 no.3
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    • pp.410-418
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    • 2000
  • An in vitro study was performed to evaluate the effect of four variables on the temperature rise produced by polishing of restorations. The four variables were : restorative material, base, thickness of remaining dentin, continuous polishing or intermittent polishing. Class V cavities were cut on extracted molar and restored with composite resin, resin-modified glass ionomer cement, compomer, amalgam on the various bases (glass ionomer cement, zinc oxide eugenol cement, zinc phosphate cement) Dentin thickness under the restoration was 0.5mm, 1.5mm. Polishing was done with an aluminum oxide-coated disc. Polishing time was continuous or intermittent for up to 1 minute. Intra-pulpal temperature increased almost linearly in all cases. Amalgam produced highest temperature rises at the pulp, while the composite resin, resin-modified glass ionomer cement and compomer were not different for each other. The rate and extent of temperature rising of amalgam restoration was reduced by presence of a cement base. Zinc oxide eugenol cement bases showed the highest temperature rise, while glass ionomer cement, zinc phosphate cement were not different to the untreated tooth Thickness of remaining dentin was only significant for the amalgam restoration. Continuous polishing produced higher temperature rise than intermittent polishing.

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Selective Laser Sintering of Alumina Using an Inorganic Binder Monoclinic $HBO_2$ and Post-Processing

  • 이인섭
    • Journal of Powder Materials
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    • v.5 no.3
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    • pp.199-209
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    • 1998
  • A new low melting inorganic binder, monoclinic $HBO_2$, has been developed for Selective Laser Sintering (SLS) of alumina powder by dehydration process of boron oxide powder in a vacuum oven at $120^{\circ}C$. It led to better green SLS parts and higher bend strength far green and fired parts compared to other inorganic binders such as aluminum and ammmonium phosphate. This appeared to be due to its low viscosity and better wettability of the alumina particle surface. A low density single phase ceramic, aluminum borate ($Al_{18}B_4O_{33}$), and multiphase ceramic composites, $A_{12}O_3-A_{14}B_2O_9$, were successfully developed by laser processing of alumina-monoclinic $HBO_2$ powder blends followed by post-thermal processing; both $Al_{18}B_4O_{33}$ and $A_{14}B_2O_9$ have whisker-like grains. The physical and mechanical properties of these SLS-processed ceramic parts were correlated to the materials and processing parameters. Further densification of the $A_{12}O_3-A_{14}B_2O_9$ ceramic composites was carried out by infiltration of colloidal silica, and chromic acid into these porous SLS parts followed by heat-treatment at high temperature ($1600^{\circ}C$). The densities obtained after infiltration and subsequent firing were between 75 and 80% of the theoretical densities. The bend strengths are between 15 and 33 MPa.

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Field Experiment on Iron and Aluminum Removal from Acid Mine Drainage Using an Apatite Drain System (인회석 배수시스템을 이용한 산성수의 철 및 알루미늄 제거에 대한 현장경험)

  • Choi, Jung-Chan;West, Terry R.
    • Economic and Environmental Geology
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    • v.29 no.3
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    • pp.315-323
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    • 1996
  • An apatite drain was constructed on September 30, 1994 at the Green Valley Abandoned Coal Mine site near Terre Haute in west central Indiana. The primary objective of this experiment is to evaluate the long-term ability of the apatite drain to mitigate acid mine drainage (AMD) under field conditions. The drain 9 m long, 3.3 m wide, and 0.75 m deep, contain 95 rum to No. 30 mesh-size apatite ore (francolite) and receive AMD seepage from reclaimed gob piles, and designed according to the laboratory testing. The apatite drain was covered with limestone riprap and filter fabric to protect the drainage system from stormwater and siltation. The drain consists of about 50 metric tons of apatite ore obtained from a phosphate mine in Florida. A gabion structure was constructed downstream of the apatite drain to create a settling pond to collect precipitates. Apatite effectively removed iron up to 4,200 mg/l, aluminum up to 830 mg/l and sulfate up to 13,430 mg/l. The pH was nearly constant for the influent and effluent, ranging between 3.1 and 4.3. Flow rate measured at the gabion structure ranged from 3 to 4.5 l/m. Precipitates of iron and aluminum phosphate (yellow and white suspendid solids) continued to accumulate in the settling pond.

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Regeneration of nitrate and phosphate from toilet wastewater using waste alumina adsorbent for cultivation of Spirulina platensis

  • Lee, Sang-Jun;Park, Seonghwan;Noh, Won;Yeom, Dong-Hyuk;Kim, Sooyeon;Kim, Dae-wook;Kim, Jungmin
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.393-399
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    • 2020
  • The use of different types of wastewater (WW) for the cultivation of microalgae and cyanobacteria during recent decades has provided important economic and environmental benefits. However, direct use of WW can lead to growth inhibition and biomass contamination. In the present study, we separated the key WW nutrients, namely nitrate and phosphate, by adsorption and regeneration and used the resulting regenerated water to cultivate the cyanobacterium Spirulina platensis. The adsorbent was granular γ-alumina derived from waste aluminum cans. This procedure recovered 19.9% of nitrate and 23.7% of phosphate from WW. The cyanobacterial cultures efficiently assimilated the nutrients from the medium prepared using regenerated WW, and the growth and nutrient uptake were similar to those in a synthetic medium. In addition, imposing nutrient limitations to increase carbohydrate productivity was easily achieved using regenerated wastewater nutrients, without requiring additional dilution or complex processing. In acute toxicity tests, the harvested biomass in a regenerated medium had similar toxicity levels compared to the biomass obtained from a synthetic medium. The proposed method of using regenerated WW to produce contamination-free biomass has broad potential applications.

Cervical Esophageal Hemangioma Combined with Thyroid Cancer

  • Lee, Jong-Cheol;Kim, Jeong-Won;Lee, Yong-Jik;Lee, Seong-Rok;Park, Chang-Ryul;Jung, Jong-Pil
    • Journal of Chest Surgery
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    • v.44 no.4
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    • pp.311-313
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    • 2011
  • Hemangiomas that arise in cervical esophagus are extremely rare, representing 3.3% of all benign esophageal tumors. Although endoscopic mucosal resection (EMR) and potassium titanyl phosphate/yttrium aluminum garnet (KTP/YAG) laser therapy have been used with success for small tumors, the safety and efficacy in the case of large tumors remains uncertain. We report the successful resection of cervical esophageal hemangioma through a cervical esophagotomy in a patient with thyroid cancer who needed a cervical collar incision.

Aluminium-Pilland Bentonites with Amphoteric Surfactant as a Novel Organoclay for Phosphate Removal (양쪽성 계면 활성제로 치환된 알루미늄 층간가교 유기 벤토나이트를 이용한 수중 인산염 제거)

  • Kim, Soo-Hong;Kim, Ja-Keun;Park, Jae-Woo
    • Journal of Korean Society on Water Environment
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    • v.23 no.6
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    • pp.966-972
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    • 2007
  • A novel organoclay has been developed with aluminium-pillared clay modified with an amphoteric surfactant, N-Dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate (DDAPS). This novel organoclay is expected to have phosphorus removal capacity as well as organic and inorganic contaminant removal capacity, due to aluminum inside the clay structure. It also exhibited less surfactant desorption than conventional cation surfactant-based organoclays. Phosphorus in water can be decreased from 0.2 mg/L to 0.0012 mg/L in 27 hours with this organoclay. Also, cadmium could removed from water using this proposed organo-clay. Experiments were performed under various pHs and amphoteric surfactants sorption capability was the highest at pH 5 when more of the amphoteric surfactant head group took on positive charges.

Analysis for forging of trochoidal gears (트로코이드 기어의 단조 해석)

  • Cho, Hae Yong;Min, Gyu Sik;Choi, Jongung
    • Journal of the Korean Society for Precision Engineering
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    • v.13 no.9
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    • pp.77-83
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    • 1996
  • This paper describes forging of trochoidal gears, which are being widely used in timing belt pulley, pump pulley etc., as a series of development of the simulator for non-axisymmetric elements. Kinematically admissible velocity fields for forging of trochoidal gear were proposed and the loads were calculated by numerical method. When the simulation was carried out, half pith of gear was divided into 6 deformation regions which have different velicity fields by assumptions and boundary conditions. The neutral surface was introduced into forging of trochoidal gears with flat punch and, for each step, it is assumed as a circle with its radius r$_{n}$. The experimental set-up was installed in 200 ton hydraulic press for forging. The billets, of A1 2218 aluminum alloy, were slightly phosphate-coated. It was shown that thd theoretical solutions, as upper bound, are useful to predict the forging load for forging of trochoidal gears, because thdt give estimates that are substantially higher than experimental loads.s.

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Preparation of Inorganic Coagulants Using Red Mud (적니를 이용한 무기응집제의 제조연구)

  • Kim, Jung-Sik;Lee, Jae-Rok;Han, Sang-Won;Hwang, In-Gook;Bae, Jae-Heum
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.2085-2095
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    • 2000
  • Red mud is generated as a by-product during the production of aluminum hydroxide from bauxite ore. In this study inorganic coagulants were prepared by leaching aluminum and iron from red mud with acids under various operating conditions. The optimum leaching efficiency of Al and Fe was obtained by contacting red mud with acids of 5M $H_2SO_4$ and 9M HCI with the ratio of 1/10(g/mL) at $85^{\circ}C$ and $25^{\circ}C$, respectively. In addition. the removal experiments of heavy metal ions($Pb^{2+}$, $Cd^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $Cr^{3+}$), turbidity and phosphate phosphorus($PO_4{^{3-}}-P$) in aqueous solutions were also studied in various experimental conditions. As a result, the developed coagulants are found to show a good removal performance of heavy metal ions. turbidity and phosphate phosphorus in aqueous solutions.

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A Study on the Preparation of Halogen Free M-P Flame Retardant and Its Application to Composite Material (비할로겐 M-P 난연제 제조 및 복합재료 응용 연구)

  • Lee, Soon-Hong
    • Journal of the Korean Society of Safety
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    • v.24 no.6
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    • pp.63-71
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    • 2009
  • In order to improve flame retardancy, the halogen free organic melamine phosphate(M-P) flame retardant was synthesized from melamine and phosphoric acid by the reaction of precipitation. The ignition test was carried out preparing hybrid flame retardant compound($H_bFRC$) consisting of organic M-P and inorganic Mg$(OH)_2$ as a flame retardant in the polyolefin resins. The flame retardancy and mechanical properties of flame retardant aluminum composite panel($H_bFRC$-ACP) were performed to investigate the possibility of the composite material, which was contained M-P, as a inner core for $H_bFRC$-ACP. For this study, the results of ignition test indicate that a char formation and drip suppressing effect, and combustion time reduced as the content of M-P increased. The limited oxygen index(LOI) values were measured 17.4vol% and 31.5vol% for LDPE only and $H_bFRC$-3(M-P content: 15wt%), respectively. And it was verified that the $H_bFRC$-3 was needed more oxygen quantity with the increase of M-P content when it combustion. Also, the results from thermogravimetric analysis were observed endothermic peak at $350^{\circ}C$ and $550^{\circ}C$, it was confirmed predominant thermal stability though the wide temperature range by the mixture of M-P and Mg$(OH)_2$. The LDPE-ACP (using only LDPE as a inner core), $35.13kW/m^2$ of heat release rate(HRR) and 13.43MJ/m2 of total heat release(THR) were measured while the $H_bFRC$-ACP, $10.44kW/m^2$ of HRR and 1.84MJ/m2 of THR were measured by results of cone calorimeter test. In case of $H_bFRC$-ACP, the average gas emission amount of CO and $CO_2$ could be decreased down to 25% and 20%, respectively, in comparison with LDPE-ACP. The mechanical properties such as tensile strength, bending strength and adhesion strength of $H_bFRC$-ACP were revealed slightly high values $54N/mm^2$, $152N/mm^2$ and 120N/25mm, respectively, compared with LDPE-ACP. It was confirmed that flame retardancy was improved with the synergy effect because of char formation by M-P and hydrolysis by Mg$(OH)_2$. The result of this study suggest that $H_bFRC$ can be applied for an adequate halogen free flame retardant composite material as a inner core for ACP.

Properties of Glass Melting Using Recycled Refused Coal Ore (선탄 경석 재활용 원료를 이용한 유리 용융 특성)

  • Lee, Ji-Sun;Kim, Sun-Woog;Ra, Yong-Ho;Lee, Youngjin;Lim, Tae-Young;Hwang, Jonghee;Jeon, Dae-Woo;Kim, Jin-Ho
    • Korean Journal of Materials Research
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    • v.29 no.11
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    • pp.727-733
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    • 2019
  • In this study, the glass melting properties are evaluated to examine the possibility of using refused coal ore as replacement for ceramic materials. To fabricate the glass, refused coal ore with calcium carbonate and sodium carbonate in it (which are added as supplementary materials) is put into an alumina crucible, melted at $1,200{\sim}1,500^{\circ}C$ for 1 hr, and then annealed at $600^{\circ}C$ for 2 hrs. We fabricate a black colored glass. The properties of the glass are measured by XRD (X-ray diffractometry) and TG-DTA (thermogravimetry-differential thermal analysis). Glass samples manufactured at more than $1,300^{\circ}C$ with more than 60 % of refused coal ore are found by XRD to be non-crystalline in nature. In the case of the glass sample with 40 % of refused coal ore, from the sample melted at $1,200^{\circ}C$, a sodium aluminum phosphate peak, a disodium calcium silicate peak, and an unknown peak are observed. On the other hand, in the sample melted at $1,300^{\circ}C$, only the sodium aluminum phosphate peak and unknown peak are observed. And, peak changes that affect crystallization of the glass according to melting temperature are found. Therefore, it is concluded that glass with refused coal ore has good melting conditions at more than $1,200^{\circ}C$ and so can be applied to the construction field for materials such as glass tile, foamed glass panels, etc.