• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1687-1691
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• 2014

This study reports on the synthesis of carbon nanofibers via chemical vapor deposition using Co and Cu as catalysts. In order to investigate the suitability of their catalytic activity for the growth of nanofibers, we prepared catalysts for the synthesis of carbon nanofibers with Cobalt nitrate and Copper nitrate, and found the optimum concentration of each respective catalyst. Then we made them react with Aluminum nitrate and Ammonium Molybdate to form precipitates. The precipitates were dried at a temperature of $110^{\circ}C$ in order to be prepared into catalyst powder. The catalyst was sparsely and thinly spread on a quartz tube boat to grow carbon nanofibers via thermal chemical vapor deposition. The characteristics of the synthesized carbon nanofibers were analyzed through SEM, EDS, XRD, Raman, XPS, and TG/DTA, and the specific surface area was measured via BET. Consequently, the characteristics of the synthesized carbon nanofibers were greatly influenced by the concentration ratio of metal catalysts. In particular, uniform carbon nanofibers of 27 nm in diameter grew when the concentration ratio of Co and Cu was 6:4 at $700^{\circ}C$ of calcination temperature; carbon nanofibers synthesized under such conditions showed the best crystallizability, compared to carbon nanofibers synthesized with metal catalysts under different concentration ratios, and revealed 1.26 high amorphicity as well as $292m^2g^{-1}$ high specific surface area.

• Bulletin of the Korean Chemical Society
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• 제31권8호
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• pp.2304-2308
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• 2010

A $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCAO/C) active material composite cathode was coated with carbon. The conductive carbon coating was obtained by addition of surfactant during synthesis. The addition of surfactant led to the formation of an amorphous carbon coating layer on the pristine LNCAO surface. The layer of carbon coating was clearly detected by FE-TEM analysis. In electrochemical performance, although the LNCAO/C showed similar capacity at low C-rate conditions, the rate capability was improved by the form of the carbon coating at high current discharge state. After 40 cycles of charge-discharge processes, the capacity retention of LNCAO/C was better than that of LNCAO. The carbon coating is effectively protected the surface structure of the pristine LNCAO during Li insertion-extraction.

• 한국기계가공학회지
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• 제2권3호
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• pp.26-33
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• 2003

The term 'High Speed Machining' has been used for many years to describe end milling with small diameter tools at high rotational speeds, typically 10,000-100,000rpm. The process was applied in the aerospace industry for the machining of light alloys, notably aluminum. In recent year, however, the mold and die industry has begun to use the technology for the production of components, including those manufactured from hardened tool steels. With increasing cutting speed used in modern machining operation, the thermal aspects of cutting become more and mole Important. It not only directly influences in rate of tool weal, but also affects machining precision recognized as thermal expansion and the roughness of the surface finish. Hence, one needs to accurately evaluate the rate of cutting heat generation and temperature distributions on the machining surface. To overcome the heat generation, we used to cutting fluid. Cutting fluid plays a roles in metal cutting process. Mechanically coupled effectiveness of cutting fluids affect to friction coefficient at tool-workpiece interface and cutting temperature and chip control, surface finish, tool wear and form accuracy. Through this study, we examined the behavior of heat generation in high-speed machining and the cooling performance of various cooling methods.

• 한국주조공학회지
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• 제31권6호
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• pp.354-361
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• 2011

The liquid metal shearing device was constructed and assembled with a commercial high-pressure die-caster in order to induce intensive turbulent shearing force on molten aluminum alloys. The effect of the liquid metal shearing on the microstructure and tensile properties of A356 alloys was investigated with the variation of iron content. The experimental results show that dendritic primary ${\alpha}$-Al phase was effectively modified into a equiaxed form by the liquid metal shearing. It was also found that the needle-like ${\beta}$-AlFeSi phase in a Fe containing A356 alloy was changed into a blocky shape resulting in the improved mechanical properties. Based on the mechanical properties, it was suggested that the iron content in A356 alloy could be more widely tolerated by utilizing the liquid metal shearing HPDC process.

• 대한기계학회논문집
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• 제12권4호
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• pp.781-789
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• 1988

본 연구에서는 용접성이 좋고 강도도 적당하며 부식에 대한 저항성이 좋아 해 양구조물 및 용접구조용재로서 널리 사용되고 있는 5083-H113 Al 합금을 준비하고 이 재료의 균열형태에 따른 피로균열진전거동을 밝히기 위하여 관통균열과 포면균열의 진 전거동에 미치는 응력비의 영향을 균열닫힘과 함께 검토하였다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 추계학술대회 논문집
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• pp.907-910
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• 1997

With increasing the needs for micro and precision parts, micro machining technology has been studied to fabricate a small part with high density such as electronics, optics, communications, and medicine industry more than before. But there are many problems to be solved requiring a high-level technology. So this research presents the new method to fabricate a small part through applying chemical mechanical micro machining (C3M) for the Al wafer. Al(thickness I ,u m) was sputtered on the Si substrate. Al is widely used as a lightweight material. However form defect such as burr has a bad effect on products. To improve machinability of ductile material, oxide layer was formed on the surface of AI wafcr before grooving by chemical reaction with HN03(10wt%). And then workpieces were machined to compare conventional micro-machining process with newly suggested method at different machining condition such as load and feed rate. To evaluate whether or not the machinability was improved by the effect of chemical condition, such as the size, the width of grooves 'and burr generation were measured. Finally, it is confirmed that C3M is one of the feasible tools for micro machining with the aid of effect of the chemical reaction.

• 한국생산제조학회지
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• 제20권5호
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• pp.541-546
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• 2011

This study was numerically investigated on thermal deformation of AC4C and AC7A aluminum alloy casting material for manufacturing the automobile tire mold. The metal casting device was used in order to manufacture the mold product of automobile tire at the actual industrial field. The temperature distribution and the cooling time of these materials were numerically calculated by finite element analysis. Thermal deformation with stress distribution was also calculated form the temperature distribution results. The thermal deformation was closely related to the temperature difference between the surface and inside of the casting. As shown by numerical analysis result, the thermal deformation of AC7A casting material became higher than AC4C casting material. In addition, the results of displacement and stress distributions appeared to be larger at the center parts of casting than on its sides because of the shrinkage caused by the cooling speed difference.

• Interaction and multiscale mechanics
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• 제2권4호
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• pp.375-396
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• 2009

In the present work, the elasto-viscoplastic behavior, interactions between grains, and the texture evolution in polycrystalline materials subjected to finite deformations are modeled using a multiscale analysis procedure within a finite element framework. Computational homogenization is used to relate the grain (meso) scale to the macroscale. Specifically, a polycrystal is modeled by a material representative volume element (RVE) consisting of an aggregate of grains, and a periodic distribution of such unit cells is considered to describe material behavior locally on the macroscale. The elastic behavior is defined by a hyperelastic potential, and the viscoplastic response is modeled by a simple power law complemented by a work hardening equation. The finite element framework is based on a Lagrangian formulation, where a kinematic split of the deformation gradient into volume preserving and volumetric parts together with a three-field form of the Hu-Washizu variational principle is adopted to create a stable finite element method. Examples involving simple deformations of an aluminum alloy are modeled to predict inhomogeneous fields on the grain scale, and the macroscopic effective stress-strain curve and texture evolution are compared to those obtained using both upper and lower bound models.

• 대한화학회지
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• 제45권2호
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• pp.156-161
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• 2001

여러 가지 산화상태의 폴리아닐린을 화학적으로 합성하여 FT-IR, UV-Vis, GPC, TG-DTA로 측성 분석하였다. ITO 기관위에 다양한 산화상태의 LEB-PAN/NMP 용액으로 스핀코팅하고, AI 전극을 진공증착하여 단일층 발광다이오드를 제작하고 I-V 특성과 EL 스팩트럼에서 완전환원형인 LEB 함량이 증가할수록 ${\pi}$-${\pi}$* 전이의 장파장이동과 분자 엑시톤 전이 세기가 감소하고 PL과 EL 세기가 증가하는 것을 확인하였다. ITO/LEB/AI 구조의 LED에서 작동 전압은 5V 이었다. 백색광은 단지 폴리아닐린의 환원형 구조에서만 발광하는 것을 확인하였다.

• 한국정밀공학회지
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• 제13권11호
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• pp.38-45
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• 1996

In recent years, ultrasonic has been widely applied in measurement and industrial fields and its application range has been expanded as a result of continuous research and development. Wire Bonding Machine, an instrument fabricating semi-conductor, makes use of ultrasonic bonding method. Specially, the method utilizes the longitudinal vibration of ultrasonic transducer composed of piezoelectric vibrator and horn. This work investigates the design conditions affecting the dynamic characteristics through the theretical and experimental analysis. It conducts separately the system identification of piezoelectric vibrator in time domain and the modal analysis of horn in frequency domain. The integrated modeling is conducted via a combbination of dynamic identification of piezoelectric vibrator and theroretical analysis of horn. Then comparison is made for theroretical and experimental results of the dynamic characteristics of the ultrasonic transducer comprised of piezoelectric vibrator and horn. Form the results of the comparison we develop the design technique of ultrasonic transducer using dynamic characteristics analysis and propose the possibility of ultrasonic bonding considering the optimal conditions for the longitudinal vibration of ultrasonic transducer and other conditions.