• Title/Summary/Keyword: Aluminum combustion

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The spectroscopic study of chemical reaction of laser-ablated aluminum-oxygen by high power laser (분광분석을 활용한 고에너지 레이저 환경에서의 알루미늄-산소 화학반응 연구)

  • Kim, Chang-hwan
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.9
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    • pp.789-795
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    • 2016
  • Laser-induced combustions and explosions generated by high laser irradiances were explored by Laser-Induced Breakdown Spectroscopy (LIBS). The laser used for target ablation is a Q-switched Nd:YAG laser with 7 ns pulse duration at wavelength of 1064 nm laser energies from 40 mJ to 2500 mJ ($6.88{\times}10^{10}-6.53{\times}10^{11}W/cm^2$). The plasma light source from aluminum detected by the echelle grating spectrometer and coupled to the gated ICCD(a resolution (${\lambda}/{\Delta}{\lambda}$) of 5000). This spectroscopic study has been investigated for obtaining both the atomic/molecular signals of aluminum-oxygen and the calculated ambient condition such as plasma temperature and electron density. The essence of the paper is observing specific electron density ratio which can support the processes of chemical reaction and combustion between ablated aluminum plume and oxygen from air by inducing high laser energy.

Computer Simulation and Verification of Adiabatic Temperature and Apparent Activity Energy of the NiO/Al Aluminothermic System

  • Song, Yuepeng;Zhu, Yanmin;Gao, Dongsheng;Guo, Jing;Kim, Hyoung Seop
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.332-337
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    • 2013
  • Recently, self-propagating high-temperature synthesis (SHS), related to metallic and ceramic powder interactions, has attracted huge interest from more and more researchers, because it can provide an attractive, energy-efficient approach to the synthesis of simple and complex materials. The adiabatic temperature $T_{ad}$ and apparent activation energy analysis of different thermit systems plays an important role in thermodynamic studies on combustion synthesis. After establishing and verifying a mathematic calculation program for predicting adiabatic temperatures, based on the thermodynamic theory of combustion synthesis systems, the adiabatic temperatures of the NiO/Al aluminothermic system during self-propagating high-temperature synthesis were investigated. The effect of a diluting agent additive fraction on combustion velocity was studied. According to the simulation and experimental results, the apparent activation energy was estimated using the Arrhenius diagram of $ln(v/T_{ad}){\sim}/T_{ad}$ based on the combustion equation given by Merzhanov et al. When the temperature exceeds the boiling point of aluminum (2,790 K), the apparent activation energy of the NiO/Al aluminothermic system is $64{\pm}14$ kJ/mol. In contrast, below 2,790 K, the apparent activation energy is $189{\pm}15$ kJ/mol. The process of combustion contributed to the mass-transference of aluminum reactant of the burning compacts. The reliability of the simulation results was experimentally verified.

Development of High Performance Intelligent Oxy-fuel Combustion Reheating Furnace (고성능 순산소 연소시스템의 가열특성에 대한 연구)

  • Lee, Sang-Jun;Noh, Dong-Soon;Kim, Hyouck-Ju;Lee, Eun-Kyung;Choi, Kyu-Sung;Ko, Chang-Buk;Lee, Sung-Soo
    • 한국연소학회:학술대회논문집
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    • 2004.11a
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    • pp.175-180
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    • 2004
  • Improving furnace efficiency is a high priority need for aluminum, glass, steel and other metal casting industries. Oxy-fuel combustion is considered to be one of the most effective method to improve thermal efficiency and reduce $NO_x$, SOx and $CO_2$ emissions for high temperature furnaces. The characteristics of an oxy-fuel flame, in particular its shape, radiation profile and exhaust gas composition are considerably different to those of an air-fuel burner. For this reason, a new approach is needed regarding factors such as burner design, power input levels, number and positioning strategies of burners and also control philosophies. In this paper will discuss the latest developments of high performance oxy-fuel combustion reheating furnace system. This high performance oxy-fuel combustion system will be shown to be technologically superior to other types of combustion systems in the areas of fuel efficiency, emissions and productivity.

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Optical Diagnostic Study for Flame Characteristic Analysis in Aluminum Dust Clouds (알루미늄 군입자 화염특성 분석을 위한 광학기법 연구)

  • Lee, Sanghyup;Ko, Taeho;Lim, Jihwan;Lee, Dohyung;Yoon, Woongsup
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.5
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    • pp.47-53
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    • 2013
  • In this study, In order to develop the measurement method of high energy density metal aluminum dust cloud combustion, flame temperature and emission spectrum was measured using spectrometer. Because of the ultra high ${\mu}m$-sized aluminum flame temperature more than 2400 K, it was measured by non-contact optical technique which is the modified two wavelength pyrometry with 520, 640 nm and spectrum comparison method. These methods were applied to experiment after accurate verification. As a result, we could identify that flame temperature is more than 2400 K in bottom of combustor in both methods. And on the emission spectrum analysis, we could measure AlO radical which is occurred dominantly in aluminum combustion.

The Study of Heat Resistant Aluminum Alloy with CrW Homogeneous Solid Solution (CrW 전율고용체 첨가 내열 알루미늄 합금에 관한 연구)

  • Kim, Jin-Pyeong;Sung, Si-Young;Han, Beom-Suck;Kim, Sang-Ho
    • Journal of Korea Foundry Society
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    • v.33 no.3
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    • pp.122-126
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    • 2013
  • Recently, heat-resistant aluminum alloy has been re-focused as a downsizing materials for the internal combustion engines. Heat-resistant Al alloy development and many researches are still ongoing for the purpose of improving thermal stability, high-temperature mechanical strength and fatigue properties. The conventional principle of heat-resistant Al alloy is the precipitation of intermetallic compounds by adding a variety of elements is generally used to improve the mechanical properties of Al alloys. Heat resistant aluminum alloys have been produced by CrW homogeneous solid solution to overcome the limit of conventional heat resistant aluminum alloy. From EPMA, it is found that CrW homogeneous soild solution phases with the size of $50-100{\mu}m$ have been dispersed uniformly, and there is no reaction between aluminum and CrW alloy. In addition, after maintaining at high temperature of 573 K, there is no growth of hardening phase, nor desolved, but CrW still exists as a homogeneous solid solution.

Anti-Icing Characteristics of Aluminum 6061 Alloys According to Surface Nanostructure (알루미늄 6061 합금의 표면 나노 구조물 변화에 따른 방빙 특성 연구)

  • Rian, Kim;Chanyoung, Jeong
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.476-486
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    • 2022
  • Recently, aluminum 6061 instead of copper alloy is used for cooling heat exchangers used in the internal combustion of engines due to its economic feasibility, lightweight, and excellent thermal conductivity. In this study, aluminum 6061 alloy was anodized with oxalic acid, phosphoric acid, or chromic acid as an anodizing electrolyte at the same concentration of 0.3 M. After the third anodization, FDTS, a material with low surface energy, was coated to compare hydrophobic properties and anti-icing characteristics. Aluminum was converted into an anodization film after anodization on the surface, which was confirmed through Energy Dispersive X-ray Spectroscopy (EDS). Pore distance, interpore distance, anodization film thickness, and solid fraction were measured with a Field Emission Scanning Electron Microscope (FESEM). For anti-icing, hydrophobic surfaces were anodized with oxalic acid, phosphoric acid, or chromic acid solution. The sample anodized in oxalic acid had the lowest solid fraction. It had the highest contact angle for water droplets and the lowest contact hysteresis angle. The anti-icing contact angle showed a tendency to decrease for specimens in all solutions.

Numerical Study of Regular Start and Unstart Process of Superdetonative Speed Ram Accelerator (초폭굉속도 램 가속기의 정상발진 및 불발과정의 수치적 연구)

  • Moon, G.W.;Jeung, I.S.;Choi, J.Y.
    • Journal of the Korean Society of Combustion
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    • v.5 no.1
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    • pp.31-41
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    • 2000
  • A numerical study was conducted to investigate the combustion phenomena of regular start and unstart processes based on ISL#s RAMAC 30 experiments with different diluent amounts in a ram accelerator. The initial projectile launching speed was 1800m/s which corresponded to the superdetonative speed of the stoichiometric $H_2/O_2$ mixture diluted with $5CO_2\;or\;4CO_2$. In this study, it was found that neither shock nor viscous heating was sufficient to ignite the mixture at a low speed of 1800m/s, as was found in the experiments using a steel-covered projectile. However, we could succeed in igniting the mixtures by imposing a minimal amount of additional heat to the combustor section and simulate the regular start and unstart processes found in the experiments with an aluminum-covered projectile. The numerical results matched almost exactly to the experimental results. As a result, it was found that the regular start and unstart processes depended on the strength of gas mixture, development of shock-induced combustion wave stabilized by the first separation bubble, and its size and location.

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An Experimental Study on Combustion Characteristics of Aluminum Composite Panels for Flame Retardant and General Materials (난연소재와 일반소재 알루미늄복합패널의 연소특성 비교에 관한 실험적 연구)

  • Min, Se-Hong;Yun, Jung-Eun;Kim, Mi-Suk
    • Fire Science and Engineering
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    • v.26 no.2
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    • pp.105-111
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    • 2012
  • In this research, aluminum composite panels of the general materials and fire retardant materials as building claddings make researches about fire performance comparison analysis. Test methods of the small and medium cone calorimeter experiments and SBI (Single Burning Item) experiments was applied to the determination. As a result, in the experiments peak heat release rate cone calorimeter the general aluminum composite panel $1,293kW/m^2$ ($75kW/m^2$), flame-retardant aluminum composite panel $70kW/m^2$ ($75kW/m^2$) was measured. In the SBI experiments fire growth rate the general fire aluminum composite panel is approximately 743 W/s and the flame-retardant aluminum composite panel is approximately 97 W/s of the value were measured. Thus, a standards enactment are urgently required in this case it is used as building claddings of the aluminum composite panel by fire risk assessment.

Design of a Microthruster using Laser-Sustained Solid Propellant Combustion

  • Kakami, Akira;Masaki, Shinichiro;Horisawa, Hideyuki;Tachibana, Takeshi
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.605-610
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    • 2004
  • Solid propellants allow thrusters to be light-weight, com-pact and robust because they require neither tank nor valve, Moreover, the solid propellant will not leak, spill or slosh. Consequently, the solid propellant thruster is one of the potential candidates for the microthruster. On the other hand, the control of the solid propellant combustion is difficult, since the conventional solid propellant continues to bum until all the stored propellant is consumed. Although particular devices like thrust reverser were designed to control the combustion, these devices were rarely used in the practical rocket motors. These devices rise thruster weight as well as complicate the thruster operation. In this study, a solid propellant microthruster using laser sustained combustion was designed in order to develop a high-efficiency microthruster overcoming the previously-mentioned difficulty. This designed thruster has semiconductor lasers and non-self-combustible solid propellants in addition to the conventional solid propellant thruster. In this designed thruster, the semiconductor laser controls the combustion of the non-self-combustible solid propellant. In order to demonstrate that the solid propellant combustion is controllable with laser, some non-self-combustible solid propellants were irradiated with the laser at a back-pressure of about 1㎪. A 40-W class Neodymium Yttrium Aluminum Garnet (ND:YAG) laser was used as a tentative alternate to the semiconductor laser. This experiment has shown that the solid propellant combustion was controllable with 10- W class laser irradiation.

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A Study on the Fire Characteristics of Aluminum Composite Panel by Large Scale Calorimeter (라지스케일 칼로리미터에 의한 알루미늄 복합패널 외장재의 연소특성에 관한 연구)

  • Yun, Jung-Eun;Min, Se-Hong;Kim, Mi-Suck;Choi, Sung-Bok
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.89-96
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    • 2010
  • In this research, exterior material combustion experiment was really tested to evaluate fire risks of aluminium complex panel which is used a lot for building exterior material. As a result, We saw fast fire spreading of aluminium complex panel. The reason is polyethylene in aluminum complex panel combust spreading fast fire flame vertically. In this test, the highest heat release rate of aluminum complex panel was 1,144 kW and surface temperature which is measured by thermocouple went up to more than $903.3^{\circ}C$, that temperature is quite a higher than $660^{\circ}C$ which is aluminum melting temperature. So, fire of aluminum complex panel can be evaluated to give us severe damage both by fast fire spreading vertically and by fire spreading through openings internally. These results from real experiment will be able to use to predict fire spreading of aluminum complex panel by comparing to modeling materialization of aluminum complex panel in the future.