• Title/Summary/Keyword: Aluminum anodizing

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Surface Treatment Effect on Electrochemical characteristics of Al Alloy for ship

  • Lee, Seung-Jun;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.149-149
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    • 2017
  • Aluminum alloys have poor corrosion resistance compared to the pure aluminum due to the additive elements. Thus, anodizing technology artificially generating thick oxide films are widely applied nowadays in order to improve corrosion resistance. Anodizing is one of the surface modification techniques, which is commercially applicable to a large surface at a low price. However, most studies up to now have focused on its commercialization with hardly any research on the assessment and improvement of the physical characteristics of the anodized films. Therefore, this study aims to select the optimum temperature of sulfuric electrolyte to perform excellent corrosion resistance in the harsh marine environment through electrochemical experiment in the seawater upon generating porous films by variating the temperatures of sulfuric electrolyte. To fabricate uniform porous film of 5083 aluminum alloy, we conducted electro-polishing under the 25 V at $5^{\circ}C$ condition for three minutes using mixed solution of ethanol (95 %) and perchloric (70 %) acid with volume ratio of 4:1. Afterward, the first step surface modification was performed using sulfuric acid as an electrolyte where the electrolyte concentration was maintained at 10 vol.% by using a jacketed beaker. For anode, 5083 aluminum alloy with thickness of 5 mm and size of $2cm{\times}2cm$ was used, while platinum electrode was used for cathode. The distance between the two was maintained at 3 cm. Anodic polarization test was performed at scan rate of 2 mV/s up to +3.0 V vs open circuit potential in natural seawater. Surface morphology was compared using 3D analysis microscope to observe the damage behavior. As a result, the case of surface modification showed a significantly lower corrosion current density than that without modification, indicating excellent corrosion resistance.

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Evaluation of Mechanical Tearing based Cell Disruption Capability to Shape Nanostructures formed on Nanoporous Alumina Filter (다공성 알루미나 필터 표면에 형성된 나노구조물의 형상에 따른 찢어짐에 의한 세포파쇄 특성 평가)

  • Lee, Yong-Hun;Han, Eui-Don;Kim, Byeong-Hee;Seo, Young-Ho
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.26 no.1
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    • pp.1-5
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    • 2017
  • This study investigated the mechanical tearing of a cell membrane using a nanostructured alumina filter for easy and quick mechanical cell disruption. Nanostructured alumina filters were prepared by a multi-step aluminum anodizing process and nanopore etching process. Six different types of nanostructures were formed on the surface of the nanoporous alumina filters to compare the mechanical cell disruption characteristics according to the shape of the nanostructure. The prepared alumina filter was assembled in a commercial filter holder, and then, NIH3T3 fibroblast cells in a buffer solution were passed through the nanostructured alumina filter at a constant pressure. By measuring the concentration of proteins and DNA, the characteristics of mechanical cell disruption of the nanostructured alumina filter were investigated.

Heat dissipation of Al2O3 Insulation layer Prepared by Anodizing Process for Metal PCB (Metal PCB에 있어서 양극산화법으로 제작한 Al2O3절연막의 방열특성)

  • Jo, Jae-Seung;Kim, Jeong-Ho;Ko, Sang-Won;Lim, Sil-Mook
    • Journal of the Korean institute of surface engineering
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    • v.48 no.2
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    • pp.33-37
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    • 2015
  • High efficiency LED device is being concerned due to its high heat loss, and such heat loss will cause a shorter lifespan and lower efficiency. Since there is a demand for the materials that can release heat quickly into the external air, the organic insulating layer was required to be replaced with high thermal conductive materials such as metal or ceramics. Through anodizing the upper layer of Al, the Breakdown Voltage of 3kV was obtained by using an uniform thickness of $60{\mu}M$ aluminum oxide($Al_2O_3$) and was carried out to determine the optimum process conditions when thermal cracking does not occur. Two Ni layers were formed above the layer of $Al_2O_3$ by sputtering deposition and electroplating process, and saccharin was added for the purpose of minimizing the remain stress in electroplating process. The results presented that the 3-layer film including the Ni layer has an adhesive force of 10N and the thermal conductivity for heat dissipation is achieved by 150W/mK level, and leads to improvement about 7 times or above in thermal conductivity, as opposed to the organic insulation layer.

Study on Fabrication of Highly Ordered Nano Patterned Master by Using Anodic Aluminum Oxidation (AAO를 이용한 나노 패턴 마스터 제작에 관한 연구)

  • Shin, H.G.;Kwon, J.T.;Seo, Y.H.;Kim, B.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.05a
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    • pp.368-370
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    • 2007
  • AAO(Anodic Aluminum Oxidation) method has been known that it is practically useful for the fabrication of nano-structures and makes it possible to fabricate the highly ordered nano masters on large surface and even on the 2.5 or 3D surface at low cost comparing to the expensive e-beam lithography or the conventional silicon processing. In this study, by using the multi-step anodizing and etching processes, highly ordered nano patterned master with concave shapes was fabricated. By varying the processing parameters, such as initial matter and chemical conditions; electrical and thermal conditions; time scheduling; and so on, the size and the pitch of the nano pattern can be controlled. Consequently, various alumina/aluminum nano structures can be easily available in any size and shape by optimized anodic oxidation in various aqueous acids. The resulting good filled uniform nano molded structure through hot embossing molding process shows the validity of the fabricated nano pattern masters.

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The Evaluation of Tensile-shear Strength on the Al-Alloy Single-lap Adhesive Joints (AI합금 단순겹치기 접착이음의 인장-전단강도 평가)

  • Oh, S. K.;Yu, Y. C.;Jeong, E. S.;Yi, W.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.04a
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    • pp.567-571
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    • 1997
  • Recently, automobile industry has led to increasing use of aluminum alloy for weight reduction. Automobile made of aluminum alloy can be given lighter, stronger and a harder surface by anodizing than one made of steel-alloy. In this paper, we investigate the influence of lap length, adherend thickness and adhesive thickness on adhesive strength of single-lap adhesive joints by conducting tensile-shear tests. Single-lap adhesive joints of aluminum was calculated using joint factor by using adhesive length, adherend thickness of specimen.

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Enhanced Properties of Aluminum Oxide Layers with Post Heat Treatment (후열처리에 의한 알루미늄 산화층의 특성 향상)

  • Jeon, Yoonnam;Kim, Sangjun;Park, Jihyun;Jeong, Nagyeom
    • Journal of the Korean institute of surface engineering
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    • v.52 no.5
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    • pp.275-281
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    • 2019
  • Anodization is widely used to enhance the properties of aluminum, such as hardness, electric resistance, abrasion resistance, corrosion resistance etc. But these properties can be enhanced with additional process. According to the partial crystallization of oxide layer with post heat treatment, enhanced hardness can be expected with partial crystallization. In this study, post heat treatments were applied to the anodized aluminum alloys of Al6061 to achieve the partial crystallization, and crystallizations were evaluated with the reduced breakdown voltages. Interestingly, remarkable enhanced hardness (21~29%), abrasion resistance (26~62%), and reduced breakdown voltage (24~44%) were observed for the sulfuric acid anodized samples when we annealed the anodized samples with 1hour post heat treatment at $360^{\circ}C$. For the Al5052 alloys, a lot of cracks were observed when we applied the post heat treatment.

Sliding Wear Properties of Ni-Al based Intermetallics Layer coated on Aluminum through Reaction Synthesis Process (알루미늄 기판 위 반응합성 Coating 된 Ni-Al계 금속간화합물의 미끄럼마모 특성 해석)

  • Lee, Han-Young
    • Tribology and Lubricants
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    • v.34 no.2
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    • pp.67-73
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    • 2018
  • Ni-Al intermetallic coating technology is an available method for the strengthening of aluminum substrate. In this study, Ni-Al intermetallics were coated on an aluminum substrate through a reaction synthesis process at a temperature lower than melting point of aluminum. And the sliding wear properties of the coatings have been investigated to verify their usability and compared the wear properties with those of a cast Al-12.5%Si alloy and an anodizing layer on aluminum. Results show that the wear rate of the coating layer greatly increased at 1 m/s and 1.5 m/s when compared with that of the cast Al-12.5%Si alloy. Much pitting damages were observed on the worn surfaces at these sliding speeds, unlike at other sliding speeds. The wear of the intermetallic coating layer at these sliding speeds seems to be increased by pitting as a consequence of adhesion. In contrast, wear of the coating layer at other speeds hardly occurs, regardless of wear periods. Nevertheless, the wear properties of the intermetallic coating layer on the aluminum substrate through the reaction synthesis process are more stable than those of anodized aluminum and are superior to those of the cast Al-12.5%Si alloy in a steady-state wear period.

Development of the Limit Switch Box for a Ship and Its Performance Evaluation against Salt Water

  • Lee, Seung-Heui;Go, Seok-Jo;Lee, Min-Cheol;Kim, Chang-Dong
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.1334-1338
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    • 2005
  • A limit switch box is used for an indicator of a valve actuator. This device indicates an opening and closing of a valve or a throttle in the valve actuator. In a ship, equipments require safety and robustness because of a rough environment and a specific condition during a voyage. However, the limit switch box has been used in an indoor environment generally. This study developed a new limit switch box which can be used at an outdoor environment. This study designed the new limit switch box. The housing of the limit switch box was made by an aluminum die cast method with surface painting after anodizing or chromate coating. In order to evaluate the endurance of the housing, the endurance tests against salt water have been conducted. Experiment results showed that the proposed device provides a reliable performance against salt water.

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Effects of Sealing Solution for Anodized Mg-Al Alloys and Its Corrosion Resistance Property (양극산화한 Mg-Al합금에 대한 봉공처리액 조성의 효과와 그 내식성)

  • 장석기;김정일;김성종
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.5
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    • pp.782-792
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    • 2004
  • The effects of sealing solution for anodized Mg-Al alloys and their corrosion resistance property were investigated. focusing on the effects of anodizing potentials aluminum contents and sealing solutions. All of the anodized specimens showed better corrosion resistance than that of non-anodized specimens, regardless of applied potentials. It was found that the anodic film formed at 4 V had the best corrosion resistance. The sealing effects were improved by increasing the temperature of distilled water. the pH of solution and the relative intensity ratio of $Mg(OH)_2$.