• Title/Summary/Keyword: Aluminum Oxide

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Degassing of Aluminum and Aluminum Alloy Powders as Studied by Gas Chromatography

  • Watanabe, Ryuzo;Choi, Duk-Sun;Kawasaki, Akira
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.716-717
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    • 2006
  • Gas release behavior from aluminum and Al 7075 alloy powders during heating in argon was investigated by in-situ gas chromatography. Water vapor, hydrogen, carbon mono-oxide were detected as individual evolution spectra against heating temperature and time. The mechanisms of water and hydrogen evolutions were studied in detail for the determination of effective degassing condition. Magnesium in the alloy powder was found to lower the hydrogen evolution temperature to enhance overall hydrogen release.

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Ignition Characteristics of Aluminum Metal Powder Fuel with Thermal Plasma (플라즈마를 이용한 분말형 금속 연료 알루미늄의 점화 특성)

  • Lee, Sang-Hyup;Lim, Ji-Hwan;Yoon, Woong-Sup
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.737-744
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    • 2011
  • The success of continuous aluminum powder combustion with steam plasma is different from hydrocarbon ignition source. Ignition characteristics of aluminum powder with high temperature thermal plasma is studied with oxidizer-free environment. Experiment with argon plasma has same temperature conditions at 4500 K and particle feeding condition for previous combustion test with steam plasma and swirl combustor. The temperature of the plasma was measured using Optical Emission Spectroscopy method. Ignition characteristics were analyzed by SEM image and EDS. Aluminum powder with plasma has rapid evaporation mechanism contrast to hydrocarbon ignition source. It enhances to aluminum powder effective ignition characteristics.

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Interaction of oxygen with the ordered Ni3Al(111) alloy surface: adsorption and oxide islands formation at 800 K and 1000 K (Ordered Ni3Al(111) 합금표면과 산소와의 상호작용 : 800 K와 1000 K에서의 흡착과 oxide islands 형성연구)

  • Kang, B.C.;Boo, J.H.
    • Journal of the Korean Vacuum Society
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    • v.16 no.5
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    • pp.322-329
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    • 2007
  • The interaction of oxygen with the ordered $Ni_3Al(111)$ alloy surface at 800 K and 1000 K has been investigated using LEED, STM, HREELS, UPS, and PAX. The clean $Ni_3Al(111)$ surface exhibits a "$2{\times}2$" LEED pattern corresponding to the ordered bulk-like terminated surface structure. For an adsorption of oxygen at 800 K, LEED shows an unrelated oxygen induced superstructure with a lattice spacing of $2.93\;{\AA}$ in addition to the ($1{\times}1$) substrate spots. The combined HREELS and the UPS data point to an oxygen chemisorption on threefold aluminum sites while PAX confirms an islands growth of the overlayer. Since such sites are not available on the $Ni_3Al(111)$ surface, we conclude the buildup of an oxygen covered aluminum overlayer. During oxygen exposure at 1000 K, however, we observe the growth of ${\gamma}'-Al_2O_3$ structure on the reordered $Ni_3Al(111)$ substrate surface. This structure has been identified by means of HREELS and STM. The HREELS data will show that at 800 K the oxidation shows a very characteristic behavior that cannot be described by the formation of an $Al_2O_3$ overlayer. Moreover, the STM image shows a "Strawberry" structure due to the oxide islands formation at 1000 K. Conclusively, from the oxygen interaction with $Ni_3Al(111)$ alloy surface at 800 K and 1000 K an islands growth of the aluminum oxide overlayer has been found.

A Miniaturized 2.5 GHz 8 W GaN HEMT Power Amplifier Module Using Selectively Anodized Aluminum Oxide Substrate (선택적 산화 알루미늄 기판을 이용한 소형 2.5 GHz 8 W GaN HEMT 전력 증폭기 모듈)

  • Jeong, Hae-Chang;Oh, Hyun-Seok;Yeom, Kyung-Whan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.12
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    • pp.1069-1077
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    • 2011
  • In this paper, a design and fabrication of a miniaturized 2.5 GHz 8 W power amplifier using selectively anodized aluminum oxide(SAAO) substrate are presented. The process of SAAO substrate is recently proposed and patented by Wavenics Inc. which uses aluminum as wafer. The selected active device is a commercially available GaN HEMT chip of TriQuint company, which is recently released. The optimum impedances for power amplifier design were extracted using the custom tuning jig composed of tunable passive components. The class-F power amplifier are designed based on EM co-simulation of impedance matching circuit. The matching circuit is realized in SAAO substrate. For integration and matching in the small package module, spiral inductors and single layer capacitors are used. The fabricated power amplifier with $4.4{\times}4.4\;mm^2$ shows the efficiency above 40 % and harmonic suppression above 30 dBc for the second(2nd) and the third(3rd) harmonic at the output power of 8 W.

Investigation of Transparent Conductive Oxide Films Deposited by Co-sputtering of ITO and AZO (ITO와 AZO 동시 증착법으로 제조된 투명전도막의 특성 연구)

  • Kim, Dong-Ho;Kim, Hye-Ri;Lee, Sung-Hun;Byon, Eung-Sun;Lee, Gun-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.42 no.3
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    • pp.128-132
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    • 2009
  • Transparent conducting thin films of indium tin oxide(ITO) co-sputtered with aluminum-doped zinc oxide(AZO) were deposited on glass substrate by dual magnetron sputtering. It was found that the electrical properties and structural characteristics of the films are significantly changed according to the sputtering power of the AZO target. The IAZTO film prepared with D.C power of ITO at 100 W and R.F power of AZO at 50 W shows an electrical resistivity of $4.6{\times}10^{-4}{\Omega}{\cdot}cm$ and a sheet resistance of $30{\Omega}/{\square}$ (for 150 nm thick). Besides of the improvement of the electrical properties, compared to the ITO films deposited at the same process conditions, the IAZTO films have very smooth surface, which is due to the amorphous nature of the films. However, the electrical conductivity of the IAZTO films was found to be deteriorated along with the crystallization in case of the high temperature deposition (above $310^{\circ}C$). In this work, high quality amorphous transparent conductive oxide layers could be obtained by mixing AZO with ITO, indicating possible use of IAZTO films as the transparent electrodes in OLED and flexible display devices.

Aluminum Based Oxide/Metal/Oxide Structures for the Application in Transparent Electrodes (알루미늄 기반 Oxide/Metal/Oxide 구조의 투명전극 적용성 기초 연구)

  • Kim, Daekyun;Choi, Dooho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.7
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    • pp.481-485
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    • 2018
  • In this study, oxide/metal/oxide-type transparent electrodes based on Al and ZnO were investigated. Thin films of these materials were sputter-deposited at room temperature. To evaluate the thickness dependence of the oxide layers, the top and bottom ZnO layers were varied in the range of 5~80 nm and 2.5~20 nm, respectively. When the thicknesses of the top and bottom ZnO layers were fixed at 30 nm and 2.5 nm, a maximum transmitance of 66% and sheet resistance of $16.5{\Omega}/{\square}$ were achieved, which is significantly improved compared with the Al layer without top and bottom ZnO layers showing a maximum transmitance of 44.3% and sheet resistance of $44{\Omega}/{\square}$.

Comparison Study on Burning and Ignition Characteristics for Single Aluminum and Magnesium Particles (EDB에 의해 부양된 알루미늄과 마그네슘 단일 입자의 점화 및 연소 특성 비교 연구)

  • Lim, Ji-Hwan;Yoon, Woong-Sup
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.311-316
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    • 2010
  • The ignition and the burning characteristics of aluminum and magnesium particles ($30-110{\mu}m$ in diameter) isolated due to electrodynamic levitation were experimentally investigated. The burning time, the ignition delay time, the flame temperature, and the flame diameter were measured. The thermal radiation intensity was measured using the photomultiplier tube and the combustion history was monitored by high-speed cinematography. Two-wavelength pyrometry measured the temperature of the burning particles. The burning times of aluminum particles were measured approximately 5 to 8 times longer than those of magnesium particles. Exponents of $D^n$-law, for the burning rate of magnesium and aluminum particles of diameters less than $110{\mu}m$, are found to be 0.6 and 1.5, respectively. The instant of aluminum ignition is clearly distinguished with the ignition delay time little less than 10 ms, however the burning history of magnesium particle exhibits no distinct instant of the ignition. The ignition delay time of magnesium particle (less than $110{\mu}m$) were approximately shown in the range from 50 to 200 ns. The flame temperatures of single metal particles are lower than the boiling point of the oxide. The nondimensional flame diameters for magnesium are decreased with increasing of the diameter. The nondimensional flame diameters for aluminum are not changed significantly.

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Characterization of Fluorocarbon Thin Films by Contact Angle Measurements (접촉각 측정을 통한 불화 유기박막의 특성 평가)

  • 박진구;차남구;신형재;박장호
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.1
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    • pp.39-49
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    • 1999
  • Monolayer thick fluorocarbon films were characterized by the contact angle measurements. The contact angles of three different liquids, water, formamide and diiodomethane were measured on spun coated, vapor phased deposited films and Teflon surface. The highest contact angle over $130^{\circ}$was observed on fluorocarbon films deposited on Al substrates while the lowest angles below $70^{\circ}$deposited on oxide. The surface energies were calculated based on Lewis acid /base theory. The surface energies of Teflon and spin coated FC films were calculated to have 18 and 8.4 dynes /cm, respectively. Higher energies of 31 to .35 dynes /cm were calculated on vapor phase deposited films on silicon and oxide. However vapor phase deposited films on aluminum only showed a large Lewis base energy term. It might be explained by the surface roughness and heterogeneity as observed by dynamic contact angles and AFM measurements.

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Phosphate Removal from Aqueous Solution by Aluminum (Hydr)oxide-coated Sand

  • Han, Yong-Un;Park, Seong-Jik;Park, Jeong-Ann;Choi, Nag-Choul;Kim, Song-Bae
    • Environmental Engineering Research
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    • v.14 no.3
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    • pp.164-169
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    • 2009
  • A powder form of aluminum (hydr)oxides is not suitable in wastewater treatment/filtration systems because of low hydraulic conductivity and large sludge production. In this study, aluminum (hydr)oxide-coated sand (AOCS) was used to remove phosphate from aqueous solution. The properties of AOCS were analyzed using a scanning electron microscopy (SEM) combined with an energy dispersive X-ray spectrometer (EDS) and an X-ray diffractometer (XRD). Kinetic batch, equilibrium batch, and closed-loop column experiments were performed to examine the adsorption of phosphate to AOCS. The XRD pattern indicated that the powder form of aluminum (hydr)oxides coated on AOCS was similar to a low crystalline boehmite. Kinetic batch experiments demonstrated that P adsorption to AOCS reached equilibrium after 24 h of reaction time. The kinetic sorption data were described well by the pseudo second-order kinetic sorption model, which determined the amount of P adsorbed at equilibrium ($q_e$ = 0.118 mg/g) and the pseudo second-order velocity constant (k = 0.0036 g/mg/h) at initial P concentration of 25 mg/L. The equilibrium batch data were fitted well to the Freundlich isotherm model, which quantified the distribution coefficient ($K_F$ = 0.083 L/g), and the Freundlich constant (1/n = 0.339). The closed-loop column experiments showed that the phosphate removal percent decreased from 89.1 to 41.9% with increasing initial pH from 4.82 to 9.53. The adsorption capacity determined from the closed-loop experiment was 0.239 mg/g at initial pH 7.0, which is about two times greater than that ($q_e$ = 0.118 mg/g) from the kinetic batch experiment at the same condition.

Fabrication of Hexagonally Assembled Gold Nonodots Based on Anodization of Aluminum (알루미늄 양극산화를 이용한 육각구조로 규칙적으로 배열된 금 나노구조 제조)

  • Lee, Joon Ho;Lee, Han Sub;Choi, Jinsub
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.191-194
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    • 2009
  • Porous alumina prepared by anodization has been widely studied since it shows very regular nanostructures at inexpensive prices. In this article, porous alumina is obtained by anodization of aluminum in the oxalic acid. After the first formed oxide is selectively removed from the aluminum substrate, the hexagonal nanostructures on the fresh aluminum are converted to nanodots by the second anodization in boric acid. Nanodots are arrayed in the convex of the hexagonal nanostructures. The optimization condition for the fabrication of nanodots with a height of 20 nm is investigated in detail. Subsequently, a gold film is deposited on the nanodots, resulting in the formation of gold nanodots arrays which are probably interesting substrate for biosensor applications.