• Title/Summary/Keyword: Aluminum Combustion

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Effect of Diluent Size on Aluminum Nitride Prepared by Using Self-Propagating High-Temperature Synthesis Process (희석제 입도가 고온자전연소법에 의한 질화알루미늄 합성에 미치는 영향)

  • Lee, Jae-Ryeong;Lee, Ik-Kyu;Shin, Hee-Young;Chung, Hun-Saeng
    • Journal of the Korean Ceramic Society
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    • v.42 no.1
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    • pp.69-75
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    • 2005
  • To investigate the morphological effect on synthesis of aluminum nitride by SHS Process, two type of Al Powder (granular and flacky shape) with the mean size of 34 $\mu$m and the diluent AIN powders of four different mean sizes.0.12, 9.7, 39.3, 50.5 $\mu$m, were used to prepare green compact. The packing density was fixed to $35 TD\%. The initial pressure of $N_{2}$ and diluent fraction was varied in the range of $1\~10 MPa,\;0.4\~0.7$, respectively. AlN with high purity of $98\% or over and large particle size of about several tens fm can be synthesized by SHS reaction as a consequence of adjusting particle size of AlN dilutent similarly to that of Al reactant. This may be caused by improvement of $N_{2}$ gas permeation to compact after passing the propagation wave. In the case of flaky-shape aluminum used as reactant, instead of granular Al-powder, unstable combustion would be occurred. As the result, irregular propagation of combustion wave and falling-off of maximum temperature would be observed during the reaction.

Fundamental Study for Reformation of Safety Standard about Portable Butane Gas Range (이동식 부탄 연소기의 안전기준 개정을 위한 기초 연구)

  • Kim, Sooik;Keum, Kuk Bin;Yu, Byeonghun;Lee, Chang-Eon;Kim, Young-Gu
    • Journal of the Korean Society of Combustion
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    • v.19 no.4
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    • pp.35-41
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    • 2014
  • The experiment was conducted to measure temperature and pressure around operating portable butane gas ranges with oversized cookwares. In this experiment, portable butane gas range with different safety equipment and two kinds of oversized cookware, each of which is made of aluminum alloy and rock, was used. As a result, temperature of the bottom of the butane and the pressure of butane barrel tend to aligned with each other. Through this result, it is reasonable that a safety criteria can be decided based on the temperature of the bottom of butane. Especially, portable butane gas ranges are safely conducted under the condition of the temperature is under 50 degree and pressure is under 500 kPa, respectively, at the bottom of the butane barrel.

Conceptual Design of the Slag Removal Method in the Metal Powder Combustor and Condition Tests for the Water Film Formation (금속분말 연소기의 slag 제거기법 개념 설계 및 Water Film 형성 조건 기초실험)

  • Kim, Kwang-Yeon;Shmelev, V.;Ko, Hyun;Lee, Sung-Woong;Cho, Yong-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.554-557
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    • 2011
  • One of the issues that occurs in development of a combustor using Metal Powder as a fuel is an alumina slag processing. A water film formed inside the combustor is expected to be able to solve this issue. The experiments about the formation of a water film were carried out as a preliminary study. As the tangential velocity of water jet is increasing, the angle derivation from horizontal is decreasing for the test model. Results of the experiments showed that the thin water film on the inner surface appeared at the velocity of 10~15 m/s.

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Photoluminescence Characteristics of $Y_3Al_5O_{12}$:$Tb^{3+}$ nano-Phosphors by various reagents (반응제에 따른 $Y_3Al_5O_{12}$ : $Tb^{3+}$ 나노형광체의 발광 특성)

  • Kwak, Hyun-Ho;Kim, Se-Jun;Cha, Jae-Hyeok;Choi, Hyun-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.440-441
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    • 2007
  • For this study, terbium-doped yttrium aluminum garnet (YAG:Tb) phosphor powders were prepared via the combustion process using the varous reagents. The characteristics of the synthesized nano powder were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscope(SEM), and photoluminescence (PL). Single-phase cubic YAG:Tb crystalline powder was obtained at $1000^{\circ}C$ by directly crystallizing it from amorphous materials, as determined by XRD techniques. The SEM image showed that the resulting YAG:Tb powders had uniform sizes and good homogeneity. The photoluminescence spectra of the YAG:Tb nanoparticles were investigated to determinethe energy level of electron transition related to luminescence processes. There were three peaks in the excited spectrum, and the major one was a broad band of around 274 nm. Also, the YAG:Tb nanoparticles showed two emission peaks in the range of 450~500 nm and 525~560 nm, respectively, and had maximum intensity at 545 nm.

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Preparation of Hydrazinium 5-aminotetrazolate(HAT) with High Nitrogen Content and Energetic Material (고질소 에너지 물질 Hydrazinium 5-aminotetrazolate (HAT)의 제조)

  • Lee, Woonghee;Kim, Seung Hee
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.5
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    • pp.53-59
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    • 2019
  • Solid fuel reacts with an oxidizer during combustion of a propellant to increase performance. Representative solid fuels are aluminum, cyclotrimethylenetrinitramine (RDX) and octahydro-1, 3,5,7-tetra nitro-1,3,5,7-tetrazocin (HMX). During combustion, these compounds generate white smoke by reacting with moisture and produce materials that are harmful to the environment, such as carbon monoxide, carbon dioxide, and methane gas. This study prepared a high-nitrogen-containing energetic material, hydrazinium 5-aminotetrazolate (HAT), which could be applied as a solid fuel. The compound was characterized by nuclear magnetic resonance (NMR) spectroscopy, and a thermal analysis was measured by differential scanning calorimetry (DSC). Also, the specific impulses and volumes of detonation gases were calculated using the EXPLO5 program.

A Study on the Isomerization Reactions of Tricyclopentadiene Derivatives Using Aluminum Chloride(AlCl3) Catalyst(I) (알루미늄클로라이드 촉매를 이용한 Tricyclopentadiene 유도체의 이성화 반응 연구(I))

  • Jo, Hyun-Hye;Kwon, Tae-Soo;Park, Chang-Sun;Han, Jeong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.2
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    • pp.17-24
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    • 2012
  • Tetrahydrotricyclopentadiene(below THTCPD) isomer is a good candidate materials for the high performance liquid fuel component because of its high density and heat of combustion value. The object of this study was to find out the proper reaction condition to improve the fluidity of THTCPD which is solid state at room temperature. Therefore, we have carried out isomerization reactions using aluminum chloride in the varying reaction condition such as reaction temperature and solvents. The results showed that when using aluminum chloride catalyst, THTCPD isomerization reaction was more active in the polar halogenated reaction media such as dichloromethane(methylene chloride: MC), 1,2-dichloroethane(ethylene chloride: EC) and chloroform than in non-polar hydrocarbon media such as n-Hexnae and toluene and was effected by reaction temperature variation.

Effects of Solid Propellant Cases on the Thermal Response of Nozzle Liner (노즐 내열재 열반응에 미치는 고체 추진제 연소가스의 영향)

  • Hwang, Ki-Young;Yim, Yoo-Jin;Ham, Hee-Cheol;Kang, Yoon-Goo;Bae, Joo-Chan
    • Journal of the Korean Society of Propulsion Engineers
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    • v.11 no.2
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    • pp.26-36
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    • 2007
  • The thermal response characteristics of nozzle liner for a solid rocket motor applying highly aluminized PCP or HTPB propellant with slotted tube grain have been investigated. The SEM photographs of aluminum oxide particles taken from nozzle liner show that the PCP propellant with the finer and less contents of oxidizer can offer greater possibility for increasing aluminum agglomeration than the HTPB propellant. The PCP propellant shows locally greater mechanical erosion at 4 circumferential areas of the nozzle entrance in line with grain slot due to the impingement of large particles, but the HTPB propellant shows greater thermochemical ablation at the nozzle blast tube, the throat insert and the exit cone because of relatively much more mole fraction of $H_2O\;and\;CO_2$ in combustion gases.

A Study on the isomerization reactions of Tricyclopentadiene Derivatives using aluminum chloride($AlCl_3$) catalyst(I) (알루미늄클로라이드 촉매를 이용한 Tricyclopentadiene 유도체의 이성화 반응 연구(I))

  • Joo, Hyun-Hye;Joo, Hyeong-Uk;Park, Chang-Sun;Han, Jeong-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.800-803
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    • 2010
  • Tetrahydrotricyclopentadiene(below THTCPD) isomer is a good candidate for the high performance liquid fuel component because of high density and heat of combustion value. But it has bad fluidity. The object of this study was to find out the optimal reaction condition to improve the fluidity of THTCPD because initial reactant is solid state, So we have carried out isomerization reactions using aluminum chloride catalyst under varying the reaction condition such as reaction temperature and reaction solvents. The results showed that when using aluminum chloride catalyst, isomerization reaction was more active in dichloromethane(methylene chloride: MC), 1,2-dichloroethane(ethylene chloride: EC) and chloroform than n-hexnae and toluene and was effected by reaction temperature.

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A Numerical Study on the Structural Stability Optimization of the Core Components of a 17cc Automotive Compressor (17cc급 자동차용 압축기 핵심부품의 구조 안정성에 관한 수치적 연구)

  • Yang, Yong-Kun;Wu, Yu-Ting;Qin, Zhen;Lyu, Sung-Ki
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.5
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    • pp.69-75
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    • 2021
  • Fuel economy has always been a major issue for the automotive industry due to environmental concerns. In particular, it is known that only 5-20% of the energy generated in a car that mainly uses an internal combustion engine is converted to increase fuel efficiency, many methods have been proposed. Among these methods, weight reduction is most commonly used because it is the simplest and cheapest. Weight is always the main reason for energy consumption, therefore, reducing weight is the best way to increase fuel efficiency while simultaneously saving on material costs. To reduce the weight of a compressor, material substitution is used. However, aluminum (a lighter metal substitute) is more fragile than steel, therefore, structural stability must be verified through testing. In this paper, we performed a 3D analysis to investigate whether aluminum can be used without compromising structural stability. Our investigation included static analysis and thermal analysis. As a result, we found that an aluminum swash plate can be safely applied on a shaft instead of steel; it reduces weight while maintaining stability that is equal to or better than steel.

Energy Storage Characteristics in Fixed Beds;Part 1. Charging Mode

  • Hassanein, Soubhi A.;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.158-164
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    • 2004
  • In the present work, the numerical model was refined to predict the thermal analysis of energy storage in a fixed beds during charging mode. The governing energy equations of both fluid and the solid particles along with their initial and boundary conditions are derived using a two-phase, one dimensional model. The refined model is carried out by taking into account change of (air density , air specific heat) with air temperature and also by taking into considerations heat losses from bed to surrounding. Finite difference method was used to obtain solution of two governing energy equations of both fluid and solid particles through a computer program especially constructed for this purpose. The temperature field for the air and the solid are obtained, also energy stored inside the bed is computed. A comparison between refined model and non refined model is done. Finally using refined model the effect of bed material (Glass, Fine clay ,and aluminum ), and air flow rate per unit area Ga (0.3, 0.4, and 0.5 kg/$m^2$-s) on energy storage characteristics was studied.

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