• Title/Summary/Keyword: Alum

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Removal of Dissolved Organic Nitrogen from Surface Water and Reclaimed Water by Coagulation (지표수 및 재이용수내 용존 유기질소의 응집처리)

  • Lee, Wontae;Choi, June-Seok;Oh, Hyun Je
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.11
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    • pp.729-734
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    • 2012
  • During chlorination processes dissolved organic nitrogen (DON) can form toxic nitrogenous disinfection byproducts and organic chloramines which have little or no bactericidal activity. DON needs to be removed before chlorination processes to reduce the formation of those products. This study investigated the removal of DON from surface water and reclaimed water by coagulation with aluminum sulfate (alum) and a cationic polymer (polyDADMAC). Removal characteristics of dissolved organic carbon (DOC) and ultraviolet absorbance at 254 nm ($UVA_{254}$) were compared with that of DON. Coagulation with alum removed DON, DOC, and $UVA_{254}$ with similar trends, but the removal of $UVA_{254}$ was highest. A dual coagulation strategy of alum and cationic polymer improved the removal of DON. Coagulation with cationic polymer alone was not effective due to its narrow range of charge neutralization. DON in reclaimed water was easier to remove than that in surface water, and higher molecular weight fraction (>10,000 Da) of DON was preferentially removed.

Effects of Applyng Two Different Chemical Additives to the Litter on Broiler Performance and the Carbon Dioxide Gas Production in Poultry Houses (깔짚에 두 가지의 다른 화학제제를 첨가하였을 때 육계의 생산성과 계사내의 이산화탄소 가스 발생에 미치는 영향)

  • Choi I. H.;Nahm K. H.
    • Korean Journal of Poultry Science
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    • v.31 no.3
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    • pp.171-176
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    • 2004
  • The objectives of this study were to determine the effect of applying two different additives to the litter on broiler performance and the carbon dioxide gas production in poultry cages. In two different experiments, the carbon dioxide gas production in poultry litter used for 42 days was measured. The chemical additives were applied to the litter at a rate of 200 g aluminum chloride(A1Cl$_3$ㆍ6$H_2O$) or 200 g aluminum sulfate [Al$_2$(SO$_4$)$_3$ㆍ14$H_2O$, Alum] + 50 g carbon carbonate per kg litter. There was no effect on broiler performance by the litter additives, but the values of carbon dioxide gas produced from broiler litters which were treated with chemical additives were significantly lower(P < 0.05 and 0.01) than that of the control. This study showed that carbon dioxide gas production can be reduced by chemically treating the litter with A1Cl$_3$ or Alum + CaCO$_3$.

Precipitation-Filtering Method for Reuse of Uranium Electrokinetic Leachate (우라늄 오염 동전기 침출액의 재이용을 위한 침전-여과 방법)

  • Kim, Gye-Nam;Shon, Dong-Bin;Park, Hye-Min;Kim, Ki-Hong;Lee, Ki-Won;Moon, Jeik-kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.2
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    • pp.63-71
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    • 2011
  • A large volume of uranium electrokinetic leachate has been generated during the electrokinetic decontamination to remove uranium from contaminated soil. The treatment technology for the reuse of the uranium leachate was developed. The concentration of uranium in the generated uranium leachate was 180 ppm and concentrations of Mg(II), K(I), Fe(II), and Al(III) ions ranged from 20 ppm to 1,210 ppm. The treatment process for uranium leachate consisted mainly of mixing and cohesion, precipitation, concentration, and filtration. In order to obtain the pH=11 of a precipitate solution, the calcium hydroxide needs to be 3.0g/100ml and the sodium hydroxide needed to be 2.7g/100ml. The results of several precipitation experiments showed that a mixture of NaOH+0.2g alum+0.15g magnetite was an optimal precipitant for filtration. The average particle size of precipitate with NaOH+alum+0.15g magnetite was $600\;{\mu}m$. Because the total value of metal concentrations in supernatant at pH=9 was the smallest, sodium hydroxide should be added with 0.2g alum and 0.15g magnetite for pH=9 of leachate.

The Effects of Gardenia jasminoides J.Ellis on Allergic Inflammation in RBL-2H3 Mast Cells and OVA/alum-sensitized Mice (쥐 비만세포 (RBL-2H3)와 OVA/alum 감작 마우스에서 치자 추출물의 알레르기 염증 억제 효과)

  • Kim, Kyeong Ri;Lee, Jin Hwa;Kim, Eun Jin;Kim, Yun Hee
    • The Journal of Pediatrics of Korean Medicine
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    • v.32 no.4
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    • pp.71-86
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    • 2018
  • Objectives The purpose of this study is to investigate the effects of Gardenia jasminoides for. grandiflora extracts' (GAJ) anti-inflammatory effect on RBL-2H3 mast cells and OVA/alum-sensitized mice. Methods In this study, IL-4 and IL-13 production was measured via ELISA analysis, and mRNA expressions of GM-CSF, IL-4, IL-5, $TNF-{\alpha}$, IL-6 were analyzed by real-time PCR. In addition, MAPKs and $NF-{\kappa}B$ p65 transcription factors were examined using western blotting, and ELISA was used to understand IgE, IL-4, and IL-13 production in ovalbumin-allergic mice in in vitro study. Results As a result of this study, 1. GAJ were observed to suppress the mRNA expression of GM-CSF, IL-4, IL-13, IL-5, $TNF-{\alpha}$, IL-6 in comparison to PMA 50 ng/ml, ionomycin $0.5{\mu}M$ (PI) control group. 2. GAJ also inhibited the IL-4, IL-13 production in comparison to PI control group. 3. Western blot analysis showed decrease on the expression of mast-cell-specific transcription factors, including MAKPs (ERK, JNK, p38) and $NF-{\kappa}B$ p65. 4. Orally-administered GAJ group in OVA/alum induced Balb/c mice showed decreased level of OVA-specific IgE in the serum. This group also has shown decreased the level of IL-4, IL-13 in the splenocyte culture supernatant. Conclusions Obtained results suggest that GAJ may regulate the allergic inflammation by transcription factors MAKPs (ERK, JNK, p38) and $NF-{\kappa}B$ p65 causing inhibition of Th2 cytokines in mast cells and OVA/alum-sensitized mice.

The Discoloration Characteristics of Orpiment used as Traditional Yellow Mineral Pigments in Painting Cultural Properties (채색문화재에 적용된 전통 황색 광물안료 석황의 채색 특성)

  • Jin Young Do
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.1
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    • pp.1-17
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    • 2023
  • On painting cultural properties to which Orpiment, a traditional yellow mineral pigment, is applied, the color's degeneration is frequently observed. To identify the cause of the degeneration, this study takes a look into orpiment and the various pigments that are mixed into it (Lead White, Lead Red, and Cinnabar) in powder and painting state. The pigment was mixed with Argyo glue and then applied to korean traditional paper and silk. Considering the possibility that alum causes the discoloration, it was applied to the specimen. With a UV tester, the powders and the painted specimens were subjected to a light resistance test in three phases (96 hour). Color changes were measured with a colorimeter and minerals, chemical composition and structural changes were analysed by XRD, SEM/EDS and Raman spectrometers. While the color change of pure Orpiment powder according to the light resistance test was small, the colored specimen became darker. The color change was large in the Orpiment colored on the silk and in the alum-treated specimen. In Orpiment powder was produced white arsenolite as altered orpiment after UV test. In the mixed powder of Orpiment and Lead White were detected only the constituent minerals of Orpiment and Lead White, and no altered substances were produced. Whereas after the UV test, orpiment and arsenolite, which were altered substances of orpiment, and the constituent minerals of Lead White were detected. In the case of mixing the two pigments in the powder state, darkening did not occur even by the UV test. However, the specimens colored with the mixed powder were darkened by the UV test. The color change of Orpiment was different depending on the mixed pigment and base material. The color change was greater in the case of alum treatment than in the case without alum treatment, and it was found that alum also had an influence on the color change of Orpiment.

Suppressive Effect of CheongGiGeoYangTang on Allergic Inflammation of RBL-2H3 Mast Cells and OVA/alum-sensitized Mice (청기거양탕(淸肌祛痒湯)의 RBL-2H3 비만세포와 OVA/alum 감작 생쥐의 알레르기 염증 반응 억제 효과)

  • Lee, Hye-Lim;Han, Jae-Kyung;Kim, Yun-Hee
    • The Journal of Pediatrics of Korean Medicine
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    • v.26 no.1
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    • pp.1-15
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    • 2012
  • $CheongGiGeoYangTang$ has been used for anti-allergenic purpose. However there was no experimental study about its effect. Therefore, this study was designed to investigate the anti-allergenic effect of $CheongGiGeoYangTang$. Methods Modifiability of RBL-2H3 mast cells' IL-4, IL-13 was analyzed by qRT-PCR and ELISA. Also, the suppressive effect of GATA-1, GATA-2, NF-AT1, NF-AT2, AP-1 and NF-${\kappa}B$ p65 transcription factors was observed by western blotting. OVA-specific IgE, IL-4 and IL-13 production in ovalbumin allergy model was examined as well. Results It was showed that the RBL-2H3 mast cells treated with $CheongGiGeoYangTang$ extract(CGGYT) was significantly suppressed mRNA expression, production of IL-4 and IL-13, and prominently inhibited the expression of transcription factors including GATA-1, GATA-2, NFAT-1, NFAT-2, c-Fos and NF-${\kappa}B$ p65 but not c-Jun. The administration of CGGYT was suppressed the amount of OVA-specific IgE, IL-4 and IL-13 in OVA/alum-sensitized mice. Conclusions We considered CGGYT would regulate the allergic inflammation as inhibition of IL-4 and IL-13 production in activated mast cells and Th2 cells.

Pollutant Removal and Characteristic of Floc by Alum Coagulation (응집 현상에 따른 오염물질 제거 및 입자 형태 특성: Alum을 사용한 경우)

  • Moon, Byung-Hyun;Kim, Seung-Hyun;Lee, Hyang-In
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.7
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    • pp.1263-1271
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    • 2000
  • This study investigated the floc structure and removal of turbidity and organic matter by alum coagulation. Results of this study indicated that sweep floc and charge neutralization area were shifted to more acidic region than that in the Amirtharajah's diagram. This was caused by organic matter present in the raw water. Removal regions of turbidity and organic matter were generally overlapped. However, organic matters was removed better at lower pH than turbidity. Floc structure was characterized by measuring fractal dimension and volume diameter using AIA and SALLS. SALLS method was found to be more reliable than AIA method. Floes in sweep floc region had larger size and fractal dimension than flocs in charge neutralization region. As pollutant removal increased, larger fractal dimension and size of floc were measured.

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A Study on Coagulation and MF Membrane Process for the Reuse of Sewage Effluent (하수처리장 방류수의 응집 및 정밀여과 처리공정에 관한 연구)

  • Paik, Ke-Jin
    • Journal of environmental and Sanitary engineering
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    • v.20 no.3 s.57
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    • pp.36-43
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    • 2005
  • Prior to the study of the sewage treatment methods, water quality for Gwangju sewage of fluent was investigated from January to December, 2004 for sewage water reuse. Monthly mean values of BOD, SS, turbidity, total phosphorus and color were 4.1 mg/L, 2.9 mg/L, 0.8 NTU, 1.3 mg/L, and 27 unit, respectively. Jar-test was performed to investigate the removal efficiency of pollutants under the coagulation conditions of fast mixing for 5 min, slow mixing for 15 min and precipitation for 1hr. Here, alum and polyaluminium chloride (PAC) were used as coagulants to reduce color, turbidity, total phosphorus (TP) and total organic carbon (TOC) in sewage effluents. The results showed that PAC gave better efficiency in removing turbidity and dissolved phosphorus than alum. It was also found from the relative molecular weight (RMW) distribution analysis that organic matter over 1,000 Dalton (Da) was easily removed by coagulation and subsequently MF treatment, while it was not effective for less than 500 Da. Based on tis result, Natural organic matter (NOM) with lower molecular weight (< 500 Da) may cause harmful disinfectant by-product (DBP) after chlorine treatment. Thus, activated carbon adsorption seems to be required for the complete removal of DBP in the hybrid system.

Coagulation-membrane separation hybrid treatment of secondary treated effluent for high efficiency phosphorus removal (하수 2차처리 방류수의 총인 고효율 처리를 위한 응집·막분리 혼성처리)

  • Choi, Wookjin;Lee, Byungha;Park, Joonhong;Cha, Hoyoung;Lee, Byungchan;Song, Kyungguen
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.1
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    • pp.47-53
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    • 2018
  • This study investigated phosphorus removal from secondary treated effluent using coagulation-membrane separation hybrid treatment to satisfy strict regulation in wastewater treatment. The membrane separation process was used to remove suspended phosphorus particles after coagulation/settlement. Membrane separation with $0.2{\mu}m$ pore size of micro filtration membrane could reduce phosphorus concentration to 0.02 mg P/L after coagulation with 1 mg Al/L dose of polyaluminum chloride (PACl). Regardless of coagulant, the residual concentration of phosphorus decreased as the dose increased from 1.5 to 3.5 mg Al/L, while the target concentration of 0.05 mg P/L or less was achieved at 2.5 mg Al/L for the aluminum sulfate (Alum) and 3.5 mg Al/L for PACl. Moreover, alum showed better membrane flux as make bigger particles than PACl. Alum showed a 40% of flux decrease at 2.5 mg Al/L dose, while PACl indicated a 50% decrease of membrane flux even with a higher dose of 3.5 mg Al/L. Thus, alum was more effective coagulant than PACl considering phosphorus removal and membrane flux as well as its dose. Consequently, the coagulation-membrane separation hybrid treatment could be mitigate regulation on phosphorus removal as unsettleable phosphorus particles were effectively removed by membrane after coagulation.