• Title/Summary/Keyword: Alloy formation

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Characteristics of Butt Welded AZ31 Magnesium Alloy with Laser Welding Conditions (레이저 용접조건에 따른 AZ31 마그네슘합금 맞대기 용접부의 특성)

  • Kim, Jong-Do;Lee, Jung-Han;Kim, Jang-Soo
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.4
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    • pp.517-523
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    • 2009
  • Magnesium alloys have many advantages such as a low density, high strength/weight ratio and well recycle. And joining process is absolutely necessary to expand the field of application of magnesium alloy. The main problems of conventional process such as arc welding for magnesium alloy are the inflammability, a tendency toward crack formation and the appearance of porosity during solidification. Laser welding technology is a promising means for overcoming these difficulties. This study is related to the laser weldability of AZ31 magnesium alloy, an all-purpose wrought alloy with good strength and ductility. The effect of welding conditions on the weldability of butt joints was examined. Also, the mechanical properties of butt welded joints were investigated by tensile test and hardness test.

Effects of Aluminium Alloy on the Oxidative Stability of Frying Oil

  • Jong-Youn Son;Soo
    • The Korean Journal of Food And Nutrition
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    • v.7 no.4
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    • pp.318-322
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    • 1994
  • Aluminium alloy, comprising water, silicone manganese and porous aluminium carrier added into soybean oil in order to investigated its effect on polar lipid content, polymer content, conjugated dienoic acid and free fatty acid value during deep-fat frying at 185$^{\circ}C$. Increase rates of polar lipid and polymer content of the frying ell were reduced about one thirds of the oil without aluminium alloy during deep-fat frying. The aluminium alloy, however, have no significantly effect to inhibit the increase of conjugated dienoic acid and free fatty acid value. Treatment of the frying oil with aluminium alloy was found to be able to inhibit polymer and polar lipid formation.

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INVESTIGATION OF "STEPPED" DISCHARGE CURVES IN SINTERED TYPE NICKEL-CADMIUM CELL

  • SASAKI, Y.;YAMASHITA, T.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.360-362
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    • 1999
  • Formation of the nickel-cadmium alloy in the negative electrode of nickel-cadmium cell subjected to continuous charging at elevated temperatures ($40~45^{\circ}C$) is shown to be one of the causes of the 'stepped' discharge curves. The alloy has been characterized by electrode potential measurement and X-ray diffraction method. The potential lowering during discharge is related to discharge of the alloy. X -ray diffraction suggests that the nickel-cadmium alloy can be formed during charge in negative electrode by interaction of the two metals. Addition of Ni $(OH)_2$ into $Cd{\;}(OH)_2$ active material is found to form the alloy more readily than sintered negative electrode alone.ode alone.

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A Study on the Burr Formation in Shearing with Al Alloy (Al합금의 전단시 버어에 관한 연구)

  • 고대림;전치용;김진무;안흥천
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.1440-1443
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    • 2004
  • Shearing including punching, blanking, trimming, slitting, etc is one of the most frequently used processes in sheet metal manufacturing. It has been widely used for manufacturing autobody, electronic components, aircraftbody, etc. In this paper, it has been researched by the experiment to examine the effect of burr height corresponding to die clearance, cutting angle, tool sharpness, etc. This paper presents the experimental results with using Al alloy sheet.

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Fragmentation of Particles in Hydriding and Dehydriding (Hydriding과 Dehydriding에서 입자 미세화)

  • Nam, In-Tak
    • Journal of Industrial Technology
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    • v.3
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    • pp.47-51
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    • 1983
  • The fragmentation of Mg and Mg-25(w/o) Al alloy particles in hydriding-dehydriding was studied. The formation of hydride was made in autoclave, and formed hydrides were $MgH_2$ in both pure Mg and Mg-25(w/o) Al alloy particles. Pure Mg was more fractured than Mg-25(w/o) Al alloy in hydriding. The addition of Al exhibited fragmentation in hydriding, but displayed the same fragmentation as Mg in dehydriding.

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Outer Diameter Stress Corrosion Cracking Susceptibility of Steam Generator Tubing Materials (증기발생기 전열관 재료의 2차측 응력부식균열 민감성)

  • Kim, Dong-Jin;Kim, Hyun Wook;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • v.10 no.4
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    • pp.118-124
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    • 2011
  • Alloy 600 (Ni 75 wt%, Cr 15 wt%, Fe 10 wt%) as a heat exchanger tube of the steam generator (SG) in nuclear power plants (NPP) has been degraded by various corrosion mechanism during the long-term operation. Especially lead (Pb) is known to be one of the most deleterious species in the secondary system causing outer diameter stress corrosion cracking (ODSCC). Oxide formation and breakdown is requisite for SCC initiation and propagation. Therefore it is expected that a property change of the oxide formed on SG tubing materials by lead addition into a solution is closely related to PbSCC. In the present work, the SCC susceptibility was assessed by using a slow strain rate test (SSRT) in caustic solutions with and without lead for Alloy 600 and Alloy 690 (Ni 60 wt%, Cr 30 wt%, Fe 10 wt%) used as an alternative of Alloy 600 because of outstanding superiority to SCC. The results were discussed in view of the oxide property formed on Alloy 600 and Alloy 690. The oxides formed on Alloy 600 and Alloy 690 in aqueous solutions with and without lead were examined by using a transmission electron microscopy (TEM), equipped with an energy dispersive x-ray spectroscopy (EDXS).

The Study of the Sn-In Ratio on the Oxidation Reaction of Rapidly Solidified Ag-Sn-In Alloys (급속응고한 Ag-Sn-In 합금의 산화반응에 미치는 Sn-In 첨가량 비율에 관한 연구)

  • Chang, Dae-Jung;Kwon, Gi-Bong;Cho, Dae-Hyoung;Kim, Jung-Su;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.27 no.2
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    • pp.72-76
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    • 2007
  • Contact materials are widely used as electrical parts. Ag-Cd alloy has a good wear resistance and stable contact resistance. But the Cd exists as coarse oxide in alloy so it have an effect on mechanical properties badly. Moreover, the Cd is an injury material to environment. Nowadays, the use of Cd is strictly restricted. Because of these disadvantage, Ag-Sn-In alloy has been developed. In Ag-Sn-In alloy, the Sn : In ratio affects the internal oxidation properties, such as the formation of the oxide layer on the surface. In this work, we changed and optimized the Sn : In ratio variety for good internal oxidation properties. We have shown that a internal oxidation process did not fully completed when the Sn : In ratio is over 4 : 1 because of the Sn oxide layer at surface. The increase of In decelerates the formation of Sn oxide layer.

Cyclic Oxidation Behavior of Fe-Cr-Al Joint Brazed with Nickel-Base Filler Metal (Ni계 합금으로 브레이징된 Fe-Cr-Al 합금 접합부의 주기산화거동)

  • Mun, Byeong-Gi;Choe, Cheol-Jin;Park, Won-Uk
    • 연구논문집
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    • s.29
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    • pp.141-149
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    • 1999
  • Brazing of Fe-Cr-Al alloy was carried out at $1200^{\circ}C$ in vacuum furnace using nickel-based filler metals : BNi-5 powder(Ni-Cr-Si-Fe base alloy} and MBF-50 foil (Ni-Cr-Si-B). The effect of boron content on the stability of oxide scale on the brazed joint was investigated by means of cyclic oxidation test performed at $1050^{\circ}C$ and $1200^{\circ}C$. Apparently, the joints brazed with MBF-50 containing boron showed relatively stable oxidation rates compared to boron-free BNi-5 at both temperatures. However, it was considered that the slower weight loss of MBF-50 brazed specimen wasn’t resulted from the low oxidation rate but from the spallation of oxide layer. The oxide layer consisted of thick spinel oxide on the surface and $Al_2 O_3$ internal oxide layer along the interface between mother alloy and braze, the mother alloy was also eroded seriously by the formation of spinel oxides such as $FeCr_2 O_4$ and $NiCr_2 O_4$ on the surface, likely to be induced by the change of oxide forming mechanism due to diffusion of boron from the braze. On the contrary, the joint brazed with BNi-5 showed the good oxidation resistance during the cyclic oxidation test. It seems that the oxidation can be retarded by the formation of stable $Al_2 O_3$ layer at the surface.

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Formation of Thicker Hard Alloy Layer on Surface of Aluminum Alloy by PTA Overlaying with Metal Powder (알루미늄 합금의 표면경화)

  • Lee, Young-Ho
    • Proceedings of the KWS Conference
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    • 1996.10a
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    • pp.3-15
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    • 1996
  • The formation of a thicker hard alloyed layer have been investigated on the surface of aluminum cast alloy (AC2B) by PTA overlaying process with Cr, Cu and Ni motel powders under the condition of overlaying current 125-200A. overlaying speed 150 mm/min and different powder feeding rate 5-20 g/min. In addition the characteristics of hardening and wear resistance of alloyed layer here been examined in relation to the microstructure of alloyed layer. Main results obtained were summarized as follows: 1) There was an optimum overlaying condition to get a good alloyed layer with smooth surface. This good layer became easy to be formed as increasing overlaying current and decreasing powder feeding rate under a constant overlaying speed. 2) Cu powder was the most superior one in metal powders used due to a wide optimum overlaying condition range, uniform hardness distribution of Hv250-350, good oar resistance and freedom from cracking in alloyed layer with fine hyper-eutectic structure. 3) On the contrary, irregular hardness distribution was usually obtained in Cr ar Ni alloyed layers of which hardness was increased as Cr or Ni contents and reached to maximum hardness of about Hv400-850 at about 60wt%cr or 40wt%Ni in alloyed layer. 4) Cracking occurred in Cr or Ni alloyed layers with higher hardness than Hv250-300 at mere than 20-25wt% of Cr or Ni contents in alloyed layer. Porosity was observed in all alloyed layers but decreased by usage of spherical powder with smooth surface.

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Effects of Alloying Elements on the Corrosion Layer Formation of Pb-Grid/Active Materials Interface (Pb 기판/활물질 계면의 부식층형성에 미치는 합금원소영향)

  • Oh, Se-Woong;Choe, Han-Cheol
    • Journal of the Korean institute of surface engineering
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    • v.40 no.5
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    • pp.225-233
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    • 2007
  • Effects of alloying elements on the corrosion layer formation of Pb-grid/active materials interface has been researched for improvement of corrosion resistance of Pb-Ca alloy. For this research, various amounts of alloying elements such as Sn, Ag and Ba were added to the Pb-Ca alloys and investigated their corrosion behaviors. Batteries fabricated by using these alloys as cathode grids were subjected to life cycle test. Overcharge life cycle test was carried out at $75^{\circ}C$, 4.5 A, for 110 hrs. with KS standard (KSC 8504). And then, after keeping the battery with open circuit state for 48 hr, discharge was carried out at 300A for 30 sec. Corrosion morphology and interface between Pb-grid and active materials were investigated by using ICP, SEM, WDX, and LPM. Corrosion layer of Pb-Ca alloy got thicken with increasing Ca content. For Pb-Ca-Sn alloy, thickness of corrosion layer decreased as Sn and Ag content increased gradually. In case of Pb-Ca-Sn-Ba alloy, thickness of corrosion layer decreased up to 0.02 wt% Ba addition, whereas, it was not changed in case of above 0.02 wt% Ba addition.