• Title/Summary/Keyword: Alloy addition

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Effects of Niobium Addition on the Corrosion Behavior of Ti Alloys in NaCl Solution (NaCl 용액에서 Nb 첨가가 Ti 합금의 부식 거동에 미치는 영향)

  • Kim, E.S.;Kim, W.G.;Choe, H.C.
    • Corrosion Science and Technology
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    • v.12 no.1
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    • pp.34-39
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    • 2013
  • In this study, the effect of niobium addition on the passivation behavior of Ti alloys in NaCl solution was investigated using various electrochemical methods. An ${\alpha}$-phase in Ti alloy was transformed into a ${\beta}$-phase and martensite structure decreased as Nb content increased. The corrosion and passivation current density($+300mV_{SCE}$) decreased as Nb content increased, and thereby a stable passive film was formed on the Ti alloy. Potential of Ti-xNb alloy in the passive region increased, whereas, current density decreased with time from results of potentiostatic and galvanostatic tests. Also, the corrosion morphology showed the smaller pits as Nb content increased. Consequently, Ti alloy contained high Nb content showed a good resistance to pitting corrosion in 0.9% NaCl solution.

Effects of Mn, Cr, and Sr Additions on the Microstructure and Tensile Properties of Al-7Si-0.4Mg-1Fe Casting Alloy (Al-7Si-0.4Mg-1Fe 주조합금의 미세조직과 인장성질에 미치는 Mn, Cr 및 Sr 첨가의 영향)

  • Kim, Jeong-Min;Park, Joon-Sik;Kim, Ha-Young;Cho, Jae-Ik;Jung, Chang-Yeol
    • Journal of Korea Foundry Society
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    • v.29 no.1
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    • pp.27-32
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    • 2009
  • The microstructure of Al-7Si-0.4Mg-1Fe alloy mainly consists of aluminum dendrites, Al-Si eutectics, and $Al_5FeSi$ needles. When Mn was added to the alloy, the substantial amount of $Al_5FeSi$ phase was changed into Al(Mn,Fe)Si, however the needle-like morphology was almost unchanged. Combined additions of Cr or Sr with Mn to the base alloy resulted in rod-like Al(Mn, Fe,Si)Si phase. The tensile properties of as-cast alloys were enhanced by the Mn addition, especially when it was added with Sr. The tensile properties after T6 heat treatment was a little improved with 0.7%Mn addition, but Cr or Sr additions with Mn didn't show any positive effect on the properties of heat-treated alloys.

The Study on Fabrication and Sound Absorption Properties of Al-Zn-Mg-Cu Alloy Foams (Al-Zn-Mg-Cu 발포합금 제조 및 흡음특성에 관한 연구)

  • Jeong, Seung-Reung;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.31 no.3
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    • pp.145-151
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    • 2011
  • Metallic foam has been known as a functional material which can be used for absorption properties of energy and sound. The unique characteristics of Al foam of mechanical, acoustic, thermal properties depend on density, cell size distribution and cell size, and these characteristics expected to apply industry field. Al-Zn-Mg-Cu alloy foams was fabricated by following process; firstly melting the Al alloy, thickening process of addition of Ca granule to increased of viscosity, foaming process of addition of titanium hydride powder to make the pores, holding in the furnace to form of cooling down to the room temperature. Metal foams with various porosity level were manufactured by change the foaming temperature. Compressive strength of the Al alloy foams was 2 times higher at 88% porosity and 1.2 times higher at 92% porosity than pure Al foams. It's sound and vibration absorption coefficient were higher than pure Al foams and with increasing porosity.

Influence of Sr and TiB on the Microstructure and Eutectic Temperature of Al-12Si Die-Cast Alloys (Sr과 TiB 첨가에 따른 다이캐스팅용 Al-Si 합금의 미세조직과 공정온도의 변화)

  • Choi, Yong-Lak;Kim, Seon-Hwa;Kim, Dong-Hyun;Yoon, Sang-Il;Kim, Ki-Sun
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.544-551
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    • 2017
  • In order to develop a new commercial Al-12%Si casting alloy with improved physical properties, we investigated the effect of adding Sr and TiB to the alloy. Al-12%Si alloys were prepared by die casting at $660^{\circ}C$. The eutectic temperature of the Sr-modified Al-12%Si alloy decreased to $9^{\circ}C$ and the mushy zone region increased. The shape of the Si phase changed from coarse acicula to fine fiber with the addition of Sr. The addition of TiB in the Al-12%Si alloy reduced the size of the primary ${\alpha}$-Al and eutectic Si phases. When Sr and TiB were added together, it worked more effectively in refinement and modification. The density of twins in the Si phase-doped Sr increased and the width of the twins was refined to 5 nm. These results are related to the impurity induced twinning(IIT) growth.

Effect of Cd addition on the Fatigue Properties of Al-Cu-Mn cast alloy (Al-Cu-Mn 주조합금의 피로성질에 미치는 Cd 첨가의 영향)

  • Kim, Gyeong-Hyeon;Lee, Byeong-Hun;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.11 no.4
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    • pp.300-304
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    • 2001
  • Effect of Cd addition on the fatigue properties of Al-Cu-Mn cast alloy was investigated by low and high cycle fatigue tests. With increasing Cd content, fatigue life and tensile strength were increased. It was found that the fatigue strength was 115MPa and the fatigue ratio was 0.31. Metallographic observation revealed that the fatigue crack initiated at the surface and propagated along the grain boundary. This propagation path was attributed to the presence of PFZ along the grain boundary. The tensile strength increased from 330MPa in the Cd-free Al-Cu- Mn cast alloy to 401MPa in the 0.15%Cd-containing alloy.

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A study on the factors affecting Cu(Mg) alloy resistivity (Cu(Mg) alloy의 비저항에 영향을 미치는 인자에 대한 연구)

  • 조흥렬;조범석;이재갑;박원욱;이은구
    • Journal of the Korean institute of surface engineering
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    • v.32 no.6
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    • pp.695-702
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    • 1999
  • We have explored the factors affecting the resistivity of Cu (Mg) alloy, which was prepared by sputtering. The results show that the resistivity is a function of Mg content, annealing temperature, annealing time, and Cu-alloy thickness. Addition of Mg to copper increases the resistivity through solute scattering. In addition, increasing Mg content promotes the interfacial reaction between Mg and SiO$_2$ to produce the free silicon and the generated free silicon dissolves into copper, resulting in a significant increase of resistivity. Furthermore, increasing oxidation temperature rapidly decreases the resistivity at the initial stage of oxidation and then continues to increase the resistivity to the saturation value with increasing oxidation time. The saturation value depends on the residual Mg content and the thickness of the alloy. TEM and AES analyses reveal that dense, uniform MgO grows to the limiting thickness of about $150\AA$. However, interfacial MgO does not show the limiting thickness, instead continues to grow until Mg is completely exhausted. From these facts, we proposed the maximum available Mg content needed to from the dense MgO on the surface and suppress the excessive interfacial reaction.

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Effect of Sb on the Creep Behavior of AZ31 Alloy (AZ31합금의 크립특성에 미치는 Sb의 영향)

  • Son, Geun-Yong;TiAn, Su-Gui;Kim, Gyeong-Hyeon
    • 연구논문집
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    • s.33
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    • pp.137-145
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    • 2003
  • The effects of antimony addition on the microstructures and creep behavior of AZ31 magnesium alloy have been investigated. Constant load creep tests were carried out at temperatures ranging from $150^{\circ}C$ to $200^{\circ}C$, and an initial stress of 50MPa for AZ31 alloys containing antimony up to 0.84% by weight. Results show that small additions of antimony to AZ31 effectively decreased the creep extension and steady state creep rates. The steady state creep rate of AZ31 was reduced 2.5 times by the addition of 0.84% of antimony. The steady state creep rate of AZ31-0.84Sb alloy was controlled by dislocation climb in which the activation energy for creep was 128 kJ/mole. The microstructure of as-cast AZ31-0.84%Sb alloy showed the presence of $Mg_3Sb_2$ precipitates dispersed throughout the matrix. The main reason for the higher creep resistance in AZ31-Sb alloys is due to the presence $Mg_3Sb_2$, which effectively hindered the movement of dislocations during the elevated temperature creep.

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Influence of Gadolinium Addition on Mechanical and Corrosion Properties of 2205 Duplex Stainless Steel (가돌리늄 첨가에 따른 2205 듀플렉스 스테인레스 강의 기계적 및 부식 특성 변화)

  • Lim, Jae-han;Ahn, Ji-Ho;Moon, Byung-Moon;Kim, Young-Jig
    • Journal of Korea Foundry Society
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    • v.35 no.6
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    • pp.163-169
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    • 2015
  • This study reports the influence of gadolinium (Gd) addition on mechanical and corrosion properties of 2205 duplex stainless steel. In all alloys produced, regardless of the initial Gd content, Gd-based inclusions were well distributed in the duplex stainless steel matrix. As the Gd content increased from 0 wt% to 0.19 wt%, the ultimate tensile strength and hardness of the alloy increased from 630 MPa to 977 MPa and from 57 to 61, respectively, while elastic modulus, tensile elongation and impact energy of the alloy decreased. The critical crevice temperatures of Alloy1, Alloy2 and Alloy3 were $20^{\circ}C$, $20^{\circ}C$ and $15^{\circ}C$, respectively.

The Effect of Misch Metal Addition on the Microstructure and Mechanical Property of Rapidly Solidified AZ91 Alloy (급속응고한 AZ91 합금의 미세조직 및 기계적 특성에 미치는 Misch metal 첨가의 영향)

  • Eum, Seung-Yeul;Park, Hoon-Mo;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.20 no.1
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    • pp.29-37
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    • 2000
  • The purpose of this study is to investigate the effect of misch metal addition on the microstructure and mechanical property of rapidly solidified AZ91 alloy by melt spinning process. As the contents of misch metal(rare earth element:Ce,La, Nd, Pr)was increased, the microstructure of RS ribbons and extrudates became finer than those of AZ91, and RE related phases($Al_{11}RE_3$, $Al_2RE$) were formed. At room temperature, the rapidly solidified AZ91+1 wt%Mm alloy showed the highest tensile strength, 430 MPa due to precipitation strengthening of${\beta}(Mg_{17}Al_{12})$ phase and Al11RE3 phase. At the elevated temperature, the mechanical property of AZ01+3 wt%Mm alloy was higher than those of other Mg alloys. The reasons were that $Al_{11}La_3$ phase was thermally stable and suppressed the grain growth. In contrast with $Al_{11}La_3$ phase, ${\beta}$ phase was thermally unstable and could not suppress the grain growth at the elevated temperature. Therefore, Al11RE3 phase contributed to improve the thermal stability of RS AZ91 Alloy.

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The Effects of TiC Content on Microstructure of Modified A6013-3wt.%Si Alloy Powder Compact (TiC 첨가량에 따른 개량된 A6013-3wt.%Si 합금 분말성형체의 미세조직 변화)

  • Yoo, Hyo-Sang;Kim, Yong-Ho;Son, Hyeon-Taek
    • Journal of Powder Materials
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    • v.29 no.1
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    • pp.28-33
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    • 2022
  • Aluminum-based powders have attracted attention as key materials for 3D printing owing to their low density, high specific strength, high corrosion resistance, and formability. This study describes the effects of TiC addition on the microstructure of the A6013 alloy. The alloy powder was successfully prepared by gas atomization and further densified using an extrusion process. We have carried out energy dispersive X-ray spectrometry (EDS) and electron backscatter diffraction (EBSD) using scanning electron microscopy (SEM) in order to investigate the effect of TiC addition on the microstructure and texture evolution of the A6013 alloy. The atomized A6013-xTiC alloy powder is fine and spherical, with an initial powder size distribution of approximately 73 ㎛ which decreases to 12.5, 13.9, 10.8, and 10.0 ㎛ with increments in the amount of TiC.