• Journal of the Korean Chemical Society
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• v.42 no.1
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• pp.78-83
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• 1998

It's necessary to develope a facile methodology forming ${\alpha}$-altropyranosidic linkage, for the synthesis of trisaccharide repeating unit of O-antigenic part of Campylobacter jejuni gram negative bacteria. In this paper, the effective synthesis of disaccharides containing ${\alpha}$-altropyranosidic linkage by 1,2-trans glycosidation of allal derivatives was discussed. 4, 6-O-Benzylidene-3-O-(t-butyldimethylsilyl)-D-allal was treated with DMDO (3,3-dimethy ldioxirane) to yield 1,2-anhydro-4, 6-O-benzylidene-3-O-(t-butyldimethylsilyl)-${\beta}$-D-altropyranose. The reaction of 1,2-anhydro-4, 6-O-benzylidene-3-O-(t-butyldimethylsilyl)-${\beta}$-D-altropyranose with allyl alcohol gave allyl 4, 6-O-benzylidene-3-(t-butyldimethylsilyl)-${\alpha}$-D-altropyranoside quantitatively, and reactions with glucals were also successful to prepare ${\alpha}$-altropyranosodic disaccharides. It is convinced that 1,2-trans glycosidation of allal derivatives should be an attractive choice for preparing oligosaccharides containing ${\alpha}$-altropyranosidic linkages.

• Bulletin of the Korean Chemical Society
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• v.26 no.7
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• pp.1104-1106
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• 2005

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.250-250
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• 2017

글로벌 위성 기반의 강수량 관측에 대한 역사는 1979년에 Arkin의 의해 제안된 IR방법에 의해 위성으로부터 강우자료를 유도하는 개념이 도입된 이후 1987년 해양에서의 비교적 정확한 강수량 추정이 가능한 다중 채널의 마이크로파(MW) 복사계를 이용한 방법으로 위성강수 추정에 대한 연구가 활발히 진행되었다. 이후 두 IR과 MW를 혼합한 방법에서, 또다시 1997년 TRMM위성의 PR(Precpipitation Radar)의 레이더를 이용하는 방법, 그리고 2014년 GPM 핵심 위성(GPM Core Observatory)에 탑재된 Dual PR에 의한 방법으로 위성강수의 정확도를 매우 높여가고 있다. 본 연구는 KOICA 사업으로 진행중인 모로코 세부강 유역 홍수방지 마스터플랜 사업에서 모로코 세부강 유역의 2010년 홍수사상에 대한 위성강우 및 지상계측 일일자료를 이용하여 홍수유출량을 추정하는 것으로 목적으로 하고 있다. 모로코 세부강(Oued Sebou) 유역은 모로코의 서북부에 위치하며 유역면적은 한강유역과 유사한 $38,380km^2$이고 하천연장은 450km로 모로코 국토면적의 약 7% 정도를 차지하며 모로코 농업생산의 중심지역이고 유역의 기후 및 기상 특성은 겨울철 온난다습하고 여름에 고온 건조한 지중해성 기후를 나타내며, 연강수량은 400mm이상으로 보고하고 있다(이산 등, 2015). 유역내 49개 관측소의 일일 강우량 자료를 분석한 결과 2000년부터 2010년까지의 유역 산술평균 강수량은 607.1mm/yr로 분석되었고, 2010년 가장 많은 강수를 기록한 지역은 Jbel oudka로 1874.1mm/yr였고, 가장 적은 강수량을 기록한 지역은 Allal Al Fassi - Barrage로 289.9mm/yr로 나타났다. 2010년 홍수가 발생한 시기인 2009년 12월 19일부터 2010년 1월 18일까지의 1시간 간격의 위성강우자료와 1일 관측 지상계측자료를 합성하여 위성보정강우량을 추정하였다. 보정 방법은 순위상관방법을 적용하였다. 사용한 모형은 일본 ICHARM에서 개발한 IFAS와 한국건설기술연구원의 MapWindow 기반 GRM 모형(mwGRM)을 이용하였다. 모형의 적용 결과 세부강 유역 본류의 첨두유출량은 $6,010m^3/s$(mwGRM)과 $5,878m^3/s$(IFAS)로 분석되었다. 향후 위성강우 및 지상계측 강우의 시계열적 정확도와 총강우량 등의 정확도 평가를 수행할 계획이다.

• Journal of Plant Biotechnology
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• v.48 no.4
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• pp.246-254
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• 2021

Environmental stresses are estimated to have reduced global crop yields of wheat by 5.5%. However, traditional approaches for the transfer of resistance to these stresses in wheat plants have yielded limited results. In this regard, genetic transformation has undoubtedly opened up new avenues to overcome crop losses due to various abiotic stresses. Particle bombardment has been successfully employed for obtaining transgenic wheat. However, most of these procedures employ immature embryos, which are not available throughout the year. Therefore, the present investigation utilized mature seeds as the starting material and used the calli raised from three Moroccan durum wheat varieties as the target tissue for genetic transformation by the biolistic approach. The pANIC-5E plasmid containing the SINA gene for drought and salinity tolerance was used for genetic transformation. To enhance the regeneration capacity and transformation efficiency of the tested genotypes, the study compared the effect of copper supplementation in the induction medium (up to 5 μM) with the standard MS medium. The results show that the genotypes displayed different sensitivities to CuSO₄, indicating that the transformation efficiency was highly genotype-dependent. The integration of transgenes in the T₀ transformants was demonstrated by polymerase chain reaction (PCR) analysis of the obtained resistant plantlets with primers specific to the SINA gene. Among the three genotypes studied, 'Isly' showed the highest efficiency of 9.75%, followed by 'Amria' with 1.25% and 'Chaoui' with 1%.

• Journal of Electrochemical Science and Technology
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• v.13 no.2
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• pp.237-253
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• 2022

The methyl 2-(1,3-dithietan -2- ylidene)-3-oxobutanoate (MDYO) and 2-(1,3-dithietan-2-ylidene) cyclohexane -1,3-dione (DYCD) were synthesized and tested at various concentrations as corrosion inhibitors for 316L stainless steel in 1 M HCl using weight loss, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), surface analysis techniques (SEM / EDX and Raman spectroscopy) and Functional Density Theory (DFT) was also used to calculate quantum parameters. The obtained results indicated that the inhibition efficiency of MDYO and DYCD increases with their concentration, and the highest value of corrosion inhibition efficiency was determined in the range of concentrations investigated (0.01 × 10^-3 - 10^-3 M). Polarization curves (Tafel extrapolation) showed that both compounds act as mixed-type inhibitors in 1M HCl solutions. Electrochemical impedance spectra (Nyquist plots) are characterized by a capacitive loop observed at high frequencies, and another small inductive loop near low frequencies. The thermodynamic data of adsorption of the two compounds on the stainless steel surface and the activation energies were determined and then discussed. Analysis of experimental results shows that MDYO and DYCD inhibitors adsorb to the metal surface according to the Langmuir model and the mechanism of adsorption of both inhibitors involves physisorption. SEM-EDX results confirm the existence of an inhibitor protective film on the stainless steel surface. The results derived from theoretical calculations supported the experimental observation.