• Title/Summary/Keyword: Alkaline water electrolysis

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Evaluating the Durability of Concrete Combined with Ground Granulated Blast Furnace Slag using Electrolysis Alkaline Aqueous as Mixing Water (전기분해 알칼리수를 배합수로 사용한 고로슬래그 미분말 혼입 콘크리트의 내구성)

  • Jeong, Su-Mi;Kim, Ju-Sung;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.4
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    • pp.349-358
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    • 2023
  • This research aimed to enhance the initial strength of concrete that is mixed with ground granulated blast furnace slag, as well as to fortify its resistance to carbonation and chloride ion permeation. To achieve this, alkaline aqueous, produced through the electrolysis of potassium carbonate, was employed as the mixing water in the preparation of concrete. To substantiate the increment in initial strength, compressive strength measurements of the concrete were executed. Additionally, an accelerated carbonation test and a chloride ion permeation resistance test were undertaken. The results confirmed that the initial strength of the concrete, which utilized electrolysis alkaline aqueous as mixing water, exhibited an improvement in comparison to concrete mixed with conventional water. It was also verified that both carbonation resistance and chloride ion permeation resistance showed enhancements.

Transition-metal oxalate-based electrodes for alkaline water electrolysis : a review (전이금속 옥살산염 기반 알칼라인 수전해 전극 응용기술 동향)

  • Ha, Jaeyun;Kim, Yong-Tae;Choi, Jinsub
    • Journal of the Korean institute of surface engineering
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    • v.55 no.2
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    • pp.38-50
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    • 2022
  • As a low-cost and high-efficiency electrocatalysts with high performance and stability become a key challenge in the development of the practical use of water electrolysis, there is an intense interest in transition-metal oxalate-based materials. Transition-metal oxalate-based catalysts with excellent electrochemical performances have been widely applied in water electrolysis due to its low-cost and ease of synthesis. This review provides a useful summary on the development of transition-metal oxalate as potential catalysts for water electrolysis with a focus on the structural and compositional alteration, role of oxalate anion, and enhanced electrochemical performances.

Research on Safety Measures for Design and Operation of Alkaline Water Electrolysis Facility (알칼라인 수전해 설비 설계 및 운영의 안전대책 연구)

  • Hyeon-Ki Kim;Doo-Hyoun Seo;Kwang-Won Rhie;Tae-Hun Kim;Seong-Chul Hong
    • Journal of the Korean Institute of Gas
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    • v.28 no.2
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    • pp.17-23
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    • 2024
  • As interest in sustainable and eco-friendly energy increases due to various problems in the carbon economy, a hydrogen economy that utilizes hydrogen as a main energy source is emerging. Among the methods of producing hydrogen, the water electrolysis method based on renewable energy produces environmentally friendly green hydrogen because it produces hydrogen from water. The water electrolysis facility currently under development produces hydrogen by receiving electricity directly from renewable energy and uses KOH(potassium hydroxide) as an electrolyte. In this study, HAZOP(Hazard and Operability Study), a qualitative risk assessment, was conducted on alkaline water electrolysis facilities to find problems and risk factors in the design and operation of water electrolysis facilities. Risks related to oxygen and KOH, an electrolyte, were identified as major risks, and it is believed that the safety of facilities and workers can be secured based on emergency action plans and safe operation procedures.

Highly Active Electrocatalyst based on Ultra-low Loading of Ruthenium Supported on Titanium Carbide for Alkaline Hydrogen Evolution Reaction

  • Junghwan, Kim;Sang-Mun, Jung;Kyu-Su, Kim;Sang-Hoon, You;Byung-Jo, Lee;Yong-Tae, Kim
    • Journal of Electrochemical Science and Technology
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    • v.13 no.4
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    • pp.417-423
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    • 2022
  • With the emerging importance of catalysts for water electrolysis, developing efficient and inexpensive electrocatalysts for water electrolysis plays a vital role in renewable hydrogen energy technology. In this study, a 1nm thickness of TiC-supported Ru catalyst for hydrogen evolution reaction (HER) has been successfully fabricated using an electron (E)-beam evaporator and thermal decomposition of gaseous CH4 in a furnace. The prepared Ru/TiC catalyst exhibited an outstanding performance for alkaline hydrogen evolution reaction with an overpotential of 55 mV at 10 mA cm-2. Furthermore, we demonstrated that the outstanding HER performance of Ru/TiC was attributed to the high surface area of the support and the metal-support interaction.

Thermal-flow Analysis of the Cooling System in the Medicated Water Electrolysis Apparatus (냉이온수기 냉각시스템에 관한 열유동 해석)

  • Jeon, Seong-Oh;Lee, Sang-Jun;Lee, Jong-Chul;Kim, Youn-Jea
    • The KSFM Journal of Fluid Machinery
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    • v.14 no.3
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    • pp.33-38
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    • 2011
  • Medicated water electrolysis apparatus, which electrolyzes water into acidic water and alkaline water, was in the spotlight as becoming known the effect of alkaline water. It is known as good for health as removing active oxygen in the human's body and promoting digestion. But, the customers could not get that desired water temperature because these apparatuses are directly connected with a water pipe. So, the cooling system was developed for controlling the temperature of the alkaline water. One of the typical way is to store water in water tank and control the temperature. But, in this way, storing water can be polluted impurities coming from outside. For protecting this pollution, the cooling system based on indirect heat exchange method through phase change between water and ice was developed. In this study, we have calculated efficiency of the cooling system with phase change by experiment and commercial CFD(Computational Fluid Dynamics) code, ANSYS CFX. To consider the effect of latent heat that is generated by melting ice, we have simulated two phase numerical analyses used enthalpy method and found the temperature, velocity, and ice mass distribution for calculating the efficiency of cooling. From the results of numerical analysis, we have obtained the relationship between the cooling efficiency and each design factor.

Study on the Preparation of Polyvinyl Chloride Anion Exchange Membrane as a Separator in the Alkaline Water Electrolysis (알칼리 수전해용 격막으로서 폴리염화비닐(polyvinyl chloride) 음이온교환막의 제조에 관한 연구)

  • Park, Jong-Ho;Bong, Soo-Yeon;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.23 no.6
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    • pp.469-474
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    • 2013
  • An anion exchange membrane was prepared for a separator in the alkaline water electrolysis. An anion exchange membrane was prepared by the chloromethylation and amination of polyvinyl chloride (PVC) used as a base polymer. The membrane properties of the prepared anion exchange membrane such as the membrane resistance and ion exchange capacity were measured. The minimum membrane resistance of the prepared anion exchange membrane was $2.9{\Omega}{\cdot}cm^2$ in 1M NaOH aq. solution. This membrane had 2.17 meq./g-dry-membrane and 43.4% for the ion exchange capacity and water content, respectively. The membrane properties of the prepared anion exchange membrane was compared with that of the commercial anion exchange membrane. The membrane resistance decreased in the order; AHT>IOMAC> Homemade membrane> AHA>APS=AFN. The ion exchange capacity decreased in the order; Homemade membrane>AFN>APS>AHT>AHA>IOMAC.

Evaluation of Commercial Anion Exchange Membrane for the application to Water Electrolysis (수전해 시스템에 적용하기 위한 상용 음이온교환막의 특성평가)

  • Jun Ho, Park;Kwang Seop, Im;Sang Yong, Nam
    • Membrane Journal
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    • v.32 no.6
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    • pp.496-513
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    • 2022
  • In this study, we sought to verify the applicability of anion exchange membrane water electrolysis system using FAA-3-50, Neosepta-ASE, Sustainion grade T, and Fujifilm type 10, which are commercial anion exchange membranes. The morphology of the commercial membranes and the elements on the surface were analyzed using SEM/EDX to confirm the distribution of functional groups included in the commercial membranes. In addition, mechanical strength and decomposition temperature were measured using UTM and TGA to check whether the driving conditions of the water electrolyte were satisfied. The ion exchange capacity and ion conductivity were measured to understand the performance of anion exchange membranes, and the alkaline resistance of each commercial membrane was checked and durability test was performed because they were driven in an alkaline environment. Finally, a membrane-electrode assembly was manufactured and a water electrolysis single cell test was performed to confirm cell performance at 60℃, 70℃, and 80℃. The long-term cell test was measured 20 cycles at other temperatures to compare water electrolysis performance.

Study about a density (ph) change of an alkaline ion by PWM voltage control necessary for a living body (PWM 전압제어로 생체에 필요한 알칼리 이온수의 농도(ph)변화에 관한 연구)

  • 권윤중;이성창
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.41 no.6
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    • pp.37-42
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    • 2004
  • It is necessary for what just keep a living body balance be devoted to it being varied with acidity serious trouble, and constitution of a study person about the density (ph) change that an alkaline ion necessary for a living body is numerical to supply a human body with number alkali by PWM voltage control. Works in the water which included the calcium (Ca), kalium (K), magnesium (Mg), natrium (Na) back who is helpful for a human body, and there is Alkaline. It is done this alkaline electrolysis to ask in order to create a number, and minerals are gathered through isolated layer (isolated special layer) to a - electrode direction, and is created. of course, prominent derelicts gather, and the acidity capital is happened, and -ion of a chlorine (Cl), phosphorus(P), sulfur (S) back is usable unfavorably in water of different use to a + electrode direction. Microprocessor was used with a - pole and a + pole with a PWM(pulse width modulation) voltage in this electrolysis process, and four kinds of PWM voltages were implemented, and a voltage every ph density change tried to be considered. It is expected by getting exactly if number alkaline ion of ph density value necessary is done with setting value if PWM control is used thus.

A Study on Performance Characteristic and Safety of Alkaline Water Electrolysis System (알카라인 수전해 시스템 성능 특성 및 안전에 관한 연구)

  • PARK, SOON-AE;LEE, EUN-KYUNG;LEE, JUNG-WOON;LEE, SEUNG-KUK;MOON, JONG-SAM;KIM, TAE-WAN;CHEON, YOUNG-KI
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.6
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    • pp.601-609
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    • 2017
  • Hydrogen is a clean, endlessly produced energy and it is easy to store and transfer. So, hydrogen is regarded as next generation energy. Among various ways for hydrogen production, the way to produce hydrogen by water electrolysis can effectively respond to fossil fuel's depletion or climate change. As interest in hydrogen has increased, related research has been actively conducted in many countries. In this study, we analyzed the performance characteristics and safety of water electrolysis system. In this study, we analyzed the performance characteristics and safety of water electrolysis system. The items for safety performance evaluation of the water electrolysis system were derived through analysis of international regulations, codes, and standards on hydrogen. Also, a prototype of the overall safety performance evaluation station was designed and developed. The demonstration test was performed with a prototype $10Nm^3/h$ class water electrolysis system that operated stably under various pressure conditions while measuring the stack and system efficiency. At 0.7MPa, the efficiency of the alkaline water electrolysis stack and the system that used in this study was 76.3% and 49.8% respectively. Through the GC analysis in produced $H_2$, the $N_2$ (5,157ppm) and $O_2$ (1,646 ppm) among Ar, $O_2$, $N_2$, CO and $CO_2$ confirmed as main impurities. It can be possible that the result of this study can apply to establish the safety standards for the hydrogen production system by water electrolysis.

Evaluation of the Stability of Oxidation-Reduced Potential (ORP) Using the Filter of the Alkaline Water (알칼리 환원수 필터의 산화환원전위 안정화 평가)

  • Nam, Sangyep;Kwon, Yunjung
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.8
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    • pp.129-135
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    • 2016
  • This study is about ionic water generator filter Recently, a lot of people feel deep interest in health and drinking water. Evaluation of the stability of oxidation-reduced potential (ORP) using the filter of the alkaline water. This study utilizes the three filter of activated carbon, UF, carbon block in alkaline reduced water equipment. Passing the water to the filter is evaluated that the OPR values are stability in accordance with the change of the volume in the bucket. Alkaline reduced water equipment is a system that has the function of making the water reduction. This system is the values of the human body beneficial minerals and ORP are made in the functional water has a very low value than general water. Which has passed through the filter the water in the water negative ions and positive ions through the electrolytic. After electrolysis, the cathode side by water, including $Ca^+$, $K^+$, $Mg^+$, $Na^+$ water gets Alkaline Reduced Water containing the minerals beneficial to the human body. A positive electrode side is made of the organic materials that have an anion such as chlorine (Cl), phosphorus (P), sulfur(S). This experiment uses the Alkaline Reduced Water to adjust the magnitude of the voltage of the electrolysis in the Alkaline Reduced Water. That is 1st step(pH8) 2nd step (pH8.5) 3th step (pH9), 4th step (pH9.5) in the Alkaline Reduced Water and -1st step (pH6.0), -2nd step (pH5.0) used as the acidic oxidation water. When the water passes through the three filter in this system was evaluated whether the ORP values are changed and stabilized. When about 100 liters of water passing through the filter was confirmed that the ORP values are stability and evaluation.