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A Study on Performance Characteristic and Safety of Alkaline Water Electrolysis System

알카라인 수전해 시스템 성능 특성 및 안전에 관한 연구

  • 박순애 (한국가스안전공사 가스안전연구원) ;
  • 이은경 (한국가스안전공사 가스안전연구원) ;
  • 이정운 (한국가스안전공사 가스안전연구원) ;
  • 이승국 (한국가스안전공사 가스안전연구원) ;
  • 문종삼 (한국가스안전공사 가스안전연구원) ;
  • 김태완 ((주)주진테크) ;
  • 천영기 ((주)주진테크)
  • Received : 2017.11.22
  • Accepted : 2017.12.29
  • Published : 2017.12.31

Abstract

Hydrogen is a clean, endlessly produced energy and it is easy to store and transfer. So, hydrogen is regarded as next generation energy. Among various ways for hydrogen production, the way to produce hydrogen by water electrolysis can effectively respond to fossil fuel's depletion or climate change. As interest in hydrogen has increased, related research has been actively conducted in many countries. In this study, we analyzed the performance characteristics and safety of water electrolysis system. In this study, we analyzed the performance characteristics and safety of water electrolysis system. The items for safety performance evaluation of the water electrolysis system were derived through analysis of international regulations, codes, and standards on hydrogen. Also, a prototype of the overall safety performance evaluation station was designed and developed. The demonstration test was performed with a prototype $10Nm^3/h$ class water electrolysis system that operated stably under various pressure conditions while measuring the stack and system efficiency. At 0.7MPa, the efficiency of the alkaline water electrolysis stack and the system that used in this study was 76.3% and 49.8% respectively. Through the GC analysis in produced $H_2$, the $N_2$ (5,157ppm) and $O_2$ (1,646 ppm) among Ar, $O_2$, $N_2$, CO and $CO_2$ confirmed as main impurities. It can be possible that the result of this study can apply to establish the safety standards for the hydrogen production system by water electrolysis.

Keywords

References

  1. R. W. Fri and M. L. Savitz, "Rethinking energy innovation and social science", Energy Research & Social Science, Vol. 1, 2014, pp. 183-187. https://doi.org/10.1016/j.erss.2014.03.010
  2. A. Alaswad , A. Baroutaji, H. Achour, J. Carton, A. I. Makky, and A. G. Olabi, "Developments in fuel cell technologies in the transport sector", International Journal of Hydrogen Energy, Vol. 41, No. 37, 2016, pp. 16499-16508. https://doi.org/10.1016/j.ijhydene.2016.03.164
  3. K. L. Kovacs, G. Maroti, and G. Rakhely, "A novel approach for biohydrogen production", International Journal of Hydrogen Energy, Vol. 31, No. 11, 2006, pp. 1460-1468. https://doi.org/10.1016/j.ijhydene.2006.06.011
  4. K. Zeng and D. Zhang, "Recent progress in alkaline water electrolysis for hydrogen production and applications", Progress in Energy and Combustion Sciencem, Vol. 36, No. 3, 2010, pp. 307-326. https://doi.org/10.1016/j.pecs.2009.11.002
  5. I. Dincer, "Green methods for hydrogen production", International Journal of Hydrogen Energy, Vol. 37, No. 2, 2012, pp. 1954-1971. https://doi.org/10.1016/j.ijhydene.2011.03.173
  6. K. Mazloomi and C. Gomes, "Hydrogen as an energy carrier: Prospects and challenges", Renewable and Sustainable Energy Reviews, Vol. 16, No. 5, 2012, pp. 3024-3033. https://doi.org/10.1016/j.rser.2012.02.028
  7. M. Wang, Z. Wang, X. Gong, and Z. Guo, "The intensification technologies to water electrolysis for hydrogen production-A review", Renewable and Sustainable Energy Reviews, Vol. 29, 2014, pp. 573-588. https://doi.org/10.1016/j.rser.2013.08.090
  8. R. Fernandez-Saavedra, M. B. Gomez-Mancebo, C. Caravaca, M. Sanchez, A. J. Quejido, and A. Vidal, "Hydrogen production by two-step thermochemical cycles based on commercial nickel ferrite: Kinetic and structural study", International Journal of Hydrogen Energy, Vol. 39, No. 13, 2014, pp. 6819-6826. https://doi.org/10.1016/j.ijhydene.2014.02.076
  9. A. A. Ismail and D. W. Bahnemann, "Photochemical splitting of water for hydrogen production by photocatalysis: A review", Solar Energy Materials and Solar Cells, Vol. 128, 2014, pp. 85-101. https://doi.org/10.1016/j.solmat.2014.04.037
  10. J. Pacheco, G. Soria, M. Pacheco, R. Valdivia, F. Ramos, H. Frias, M. Duran, and M. Hidalgo, "Greenhouse gas treatment and H2 production, by warm plasma reforming", International Journal of Hydrogen Energy, Vol. 40, No. 48, 2015, pp. 17165-17171. https://doi.org/10.1016/j.ijhydene.2015.08.062
  11. Y. Wang, S. Wang, G. Zhao, Y. Guo, and Y. Guo, "Hydrogen production by partial oxidation gasification of a phenol, naphthalene, and acetic acid mixture in supercritical water", International Journal of Hydrogen Energy, Vol. 41, No. 4, 2016, pp. 2238-2246. https://doi.org/10.1016/j.ijhydene.2015.12.115
  12. B. G. Kim, G. S. Shin, K. S. Chio, and H. M. Kim, "A Theoretical Study on Proton Exchange Membrane Electrolyzer", Journal of Automotive Engineering, 2011, pp. 38-42.
  13. M. H. Seo, H. S. Hong, K. H. Kang, J. M. Kim, S. K. Lee, and Y. S. Yun, "Development of preparation technology of materials for high temperature electrolysis", Journal of Korea New & Renewable Energy, 2007, pp. 61-64.
  14. K. Moon and D. Pak, "The Characteristics of Hydrogen Production According to Electrode Materials in Alkaline Water Electrolysis", Journal of Energy Engineering, Vol. 24, No. 2, 2015, pp. 33-39. https://doi.org/10.5855/ENERGY.2015.24.4.033
  15. F. ezzahra Chakik, M. Kaddami, and M. Mikou, "Effect of operating parameters on hydrogen production by electrolysis of water", International Journal of Hydrogen Energy, Vol. 42, No. 40, 2017, pp. 25550-25557. https://doi.org/10.1016/j.ijhydene.2017.07.015
  16. S. M. M. Ehteshami, S. Vignesh, R. K. A. Rasheed, and S. H. Chan, "Numerical investigations on ethanol electrolysis for production of pure hydrogen from renewable sources", Applied Energy, Vol. 170, 2016, pp. 388-393. https://doi.org/10.1016/j.apenergy.2016.03.001
  17. T. H. Lee, "Overview and prospect of the water electrolytic device technology", Journal of the Electric World, 2015, pp. 14-17.
  18. M. H. Sellami and K. Loudiyi, "Electrolytes behavior during hydrogen production by solar energy", Renewable and Sustainable Energy Reviews, Vol. 70, 2017, pp. 1331-1335. https://doi.org/10.1016/j.rser.2016.12.034
  19. S. K. Mazloomi and Nasri Sulaiman, "Influencing factors of water electrolysis electrical efficiency", Renewable and Sustainable Energy Reviews, Vol. 16, No. 16, 2012, pp. 4257-4263. https://doi.org/10.1016/j.rser.2012.03.052
  20. Z. Dobo, and A. B. Palotas, "Impact of the voltage fluctuation of the power supply on the efficiency of alkaline water electrolysis", International journal of Hydrogen Energy, Vol. 41, No. 28, 2016, pp. 11849-11856. https://doi.org/10.1016/j.ijhydene.2016.05.141