• Title/Summary/Keyword: Alkali agent

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Immobilization Characteristics of Hexavalent Chromium Contaminated Soils Treated with Phosphate and Chromium Reducing Agent (크롬환원제와 인산염으로 처리된 6가 크롬 오염토양의 고정화)

  • Lee, Eui-Sang
    • Journal of Environmental Impact Assessment
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    • v.16 no.1
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    • pp.27-33
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    • 2007
  • Hexavalent chromium-contaminated soils are encounted at many unregulated discharge and improper handling of wastes from electroplating, leather tanning, steelmaking, corrosion control, and wood preservation industries. Contamination of hexavalent chromium in the soil is a major concern because of its toxicity and threat to human life and environment. Current technologies for hexavalent chromium-contaminated soil remediation are usually costly and/or cannot permanently prohibit the toxic element from entering into the biosphere. Thus, as an alternative technique, immobilization is seen as a cost-effective and promising remediation technology that may reduce the leachable potential of hexavalent chromium. The purpose of this paper is to develope an immobilization technique for the formation of the geochemically stabilized hexavalent chromium-contaminated soil from the reactions of labile soil hexavalent chromium forms with the added soluble phosphate and chromium reducing agent. From the liquid phase experiment, reaction order of chromium reducing agent, soluble phosphate, alkali solution shows the best removal efficiency of 95%. In addition, actual soil phase experiment demonstrates up to 97.9% removal efficiency with 1:1 molar ratio of chromium reducing agent and soluble phosphate. These results provide evidence for the potential use of soluble phosphate and chromium reducing agent for the hexavalent chromium-contaminated soil remediation.

Utilization of Pine Bark (Part 7) -Applicability of Spent Liquor Obtained from Alkaline Sulfite-Anthraquinone (AS-AQ) Cooking of Pine Bark as a Deinking Agent- (소나무 수피의 총합적 이용(제7보) -소나무 수피 AS-AQ 증해폐액의 탈묵제로서의 적용 가능성-)

  • 문성필;박성천
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.4
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    • pp.42-48
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    • 2001
  • The spent liquor (BSL) obtained from alkaline sulfite-anthraquinone (AS-AQ) cooking of pine bark was applied as a deinking agent. In the ONP deinking system, although BSL removed the small size of ink particles (${\geq}$$12.5{\mu}m$), it did not improve the brightness of pulp. The brightness of pulp slightly improved when treated with BSL at 150~$180^{\circ}C$. However, the brightness of the pulp was lower than that of a commercial deinking agent (oleic acid). It seems that BSL treated with a high temperature still had a high dispersing ability on the ink particles. Intensive oxidations were introduced, and remarkable deinking effects were observed at 13kgf/$cm^2$ oxygen pressure, $160^{\circ}C$ and 2h. When BSL treated at 13kgf/$cm^2$ oxygen pressure, $170^{\circ}C$ and a time period of 30~90 min is added to the pulp, at 0.1% or lower, the deinking effect became higher than that of oleic acid. On the other hand, additional alkali treatments during the oxidation possibility as a deinking agent when oxidized. However, since the oxidized BSL still has a high dispersing ability and lower molecular weight, several modifications need to be done in the near future in order to be applied as a high quality deinking agent.

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Design for Wastewater Neutralization Network in Yeosu Petrochemical Complex by Multi-Criteria Decision Making Strategy (다중척도 의사결정 전략을 이용한 여수 석유화학단지의 폐수 중화망 설계)

  • Lee, Tai-Yong
    • Clean Technology
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    • v.17 no.2
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    • pp.175-180
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    • 2011
  • A novel multi-criteria decision making strategy is developed for the construction of industrial symbiosis network in eco-industrial park and the strategy is applied to the construction of acid/alkali wastewater neutralization network in Yeosu industrial complex. Acid (or alkali) wastewater is commonly generated in chemical industries, and it can be used as neutralizing agent for alkali (or acid) wastewater generated from another source. As a consequence, a large-scale industrial symbiosis network for wastewater neutralization can be constructed in petrochemical complexes where a large amount of acid/alkali wastewater is generated. In this study, substance flow model is constructed which describes the wastewater neutralization network and multi-criteria decision making strategy is applied to find a few candidate for industrial symbiosis network.

A Fundamental Study on the Effect of Anti-Freezing Agent of Concrete (콘크리트용 내한제의 효과에 관한 기초적 연구)

  • 윤기원;조병영;한천구;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.04a
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    • pp.163-168
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    • 1994
  • If the concrete is exposed below freezing point of the outer temperature before hardened, the quality of the concrete will be lowered after hardened. Anti-freezing agent which doesn't corrode the steel bar and doesn't generate the alkali-aggregate reaction by noncholride recently developed in Japan and Northern Europe. But the effects of these agents are rarely known. Therefore, this study is desigend for analyzing the freezing properties at the condition of solution of solution and cement paste. And this study aims to present the reference data for practical use of the concrete works using anti-freezing agent.

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Remediation of Oil Contaminated Soils by Rice Straw Ash (Rice Straw Ash를 이용한 유류오염토양 정화)

  • 정경원;장성호
    • Journal of Environmental Science International
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    • v.12 no.7
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    • pp.783-789
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    • 2003
  • This study was conducted to reuse the rice straw ash as washing agent for oil contaminated soils. The results are summarized as follows. The physical characteristics of rice straw before and after burning were as follows ; In case of burning rice straw 1g, the rice straw ash was generated 0.14g and pH was changed neutrality into alkali(pH 10.9) and specific surface area was increased to five times and particle distribution was corresponded to fine silt.(under 0.05mm) The physical characteristics of rice straw ash were Carbon 10.9%, Hydrogen 1.5%, Oxygen 23.4%, Nitrogen 5.2%, Sulfate 1.2% and chemical characteristics were Si 189.2ppm, Ca 10.2ppm, Mg 4.7ppm. Oil cleanup ratio by pH variation were about 40∼50% of initial concentration of oil by pH 10∼11. As the result of cleanup comparative experiment, the rice straw ash was about 20∼30%, the tritonX-100 about 40∼50% of washing efficiency, and then in the future it will be possibility of substitute washing agent.

Drying shrinkage and Pore Structure of Blast Furnace Slag Concrete Mixed Alkaline Stimulation (알칼리 자극제 혼입 고로슬래그 콘크리트의 건조수축과 공극구조)

  • Park, Ji-Woong;Lee, Gun-Cheol;Gao, Shan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.32-33
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    • 2016
  • This purpose of this study is to find the properties of pore structure and length change of blast furnace slag cement added alkali powder stimulant on shrinkage reducing agent presence. In length change, the specimen added alkaline stimulant was smaller than normal blast furnace slag concrete. And the specimen added shrinkage reduction agent was confirmed to show smaller rate of length change than the length. In MIP analysis of 1day-age, 0.1㎛ subsequent pore amount of the specimen added alkaline stimulant was significantly smaller value the normal blast furnace slag concrete specimen.

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Studies on the Stabilities of Insectcides Combined with some Stabilizers (살충제제(殺蟲製劑)의 안정성(安定性)에 관(關)한 연구(硏究))

  • Woo, Chong-Hak;Kim, Jae-Wan
    • Journal of Pharmaceutical Investigation
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    • v.1 no.1
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    • pp.101-108
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    • 1971
  • The stability and toxicity test for p.p'-DDT, DDVP and dipterex that put to used sample in this study effects is follows A. about p.p'-DDT (1) In elevating the stability of p.p'-DDT, best stabilizing solvent was benzene. (2) The stability-agent has no difficulty as long as it not contain metal ion for instance $Z_n^{2+}$,$C_r^{3+}$,$Al^{3+}$,and $Fe^{2+or3+}$ but in case of contain $F_e^{3+}$, the combination of salicylaminoguanidine is best effective. (3) Using this product for water-suspension, We must use span 40 for stability agent and adding it at the same time. (4) We must use container which does not week alkali and metal ion but it is to preserved in tight light-resistant container. (5) The stopper of container is adapted with above-mentioned condition of container, but it is better not to use metal material. (6) This product needs opening ventilation more than 30 minutes after diffusion or spray and in the room we remove cause of remained poison by cleaning the bottom. B. about DDVP and Dipterex (1) Benzene or toluene in best solvent to preserve stability of DDVP and Dipterex. (2) Span 40 is superior for stability agent of this product and second is span 80. (3) The pH of solution is very stable in pH 5-6 and comparative stable in alkali more than p,p'-DDT. (4) Container is to preserved in tight, lightresistant container and especially be careful of outflow and inflow of water. (5) Because this product is centeral stimulant poison, we must pay attention to prevent cause of contact diadermic toxicity after use.

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Hitological Changes on the Wound Healing Process of Alkali Burned Mouse Cornea (알칼리 화상을 입은 마우스 각막에서 상처 치유과정 중 관찰된 조직학적 변화)

  • Lee, Ji-Young;Lee, Koon-Ja
    • Journal of Korean Ophthalmic Optics Society
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    • v.13 no.4
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    • pp.161-169
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    • 2008
  • Purpose: To better understand the corneal regeneration after alkali burn regarding the initial clinical progression and the therapy, we investigated the changes of the multi factors following chemical injury in cornea. Methods: This study was performed to observation on the healing process of alkali burned cornea in aspect of immunohistochemistry by immunofluorescence or H-E staining and TUNEL assay. Results: The results showed that although a healing process occurred after alkali burn, apoptosis of epithelial, stromal and endothelial cells in the cornea was continuously observed. Neovascularization and expression of ${\alpha}$-smooth muscle actin (${\alpha}$-SMA) from limbus and from injured cornea, respectively, were observed after 3 days of alkali burn. Formation of collagen III in corneal stroma and increased expression of chondroitin sulfate are coincident with expression of ${\alpha}$-SMA and transforming growth factor-${\beta}$ (TGF-${\beta}$). Conclusions: These data suggest that medical treatment within 3 days of alkali burn will be effective to inhibit neovascularization and formation of collagen III and chondroitin sulfate. This study extends our immumohistochemical understanding of healing process in alkali burned cornea, and the results get in this study will be cornerstones in the development of therapeutic agent for accelerating renewal of chemical damaged cornea.

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Modification of Tencel Fabric Treated with Chitosan( II ) - Change of Dyeing Properties - (키토산처리에 의한 텐셀 직물의 개질기능화(II) - 염색성의 변화 -)

  • 육은영;배현숙
    • Textile Coloration and Finishing
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    • v.14 no.3
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    • pp.1-10
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    • 2002
  • Tencel fabric cationized with chitosan can be effectively dyed with anionic dyes. To investigate the change of dyeing properties of cationized Tencel fabric, some experiments were performed under the several dyeing conditions with acid and reactive dyes. Whiteness index decreased with the increment of crosslinking agent concentration. The cationized Tencel fabric was dyed well by anionic dye such as acid dye, the dyeability of reactive dye was improved by addition of a little salt without alkali. The dye fixation on the cationized Tencel fabric was increased with chitosan concentration without electrolyte and alkali. The dyeability of Tencel treated with chitosan was better than controlled Tencel, especially under the acidic conditions. According to the number and the types of functional group of reactive dyes, dye affinity of the modified Tencel fabric varied and wash fastness of acid dye was better than reactive dye.

The Effect of Temperature, Cooling and Surface Tension on the Fining in Alkali-Alkaline Earth-Silica Glassmelts Containing ZnO

  • Kim, Ki-Dong
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.176-182
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    • 1998
  • The effects of temperature, cooling surface tension on the fining were studied in alkali-alkaline earth-silica TV screen glassmelts containing ZnO. Sodium antimonate $(Na_2OSb_2O_5)$ was used as a fining agent. Viscosity and surface tension of the melts were determined. On the basis of these properties, fining tests for several batches were performed by "MF" (Melting and Fining) and "PMF" (Profiled melting and Fining) methods. The results of these tests showed an opposite behavior each other with increase in ZnO content. This hehavior has been discussed in terms of two fining processes-growth of bubbles and shrinkage of seeds. shrinkage of seeds.

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