• Title/Summary/Keyword: Alkali Activation

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Changes in Polysaccharides Content and Cell Morphology of Fomitopsis pinicola Mycelium during Submerged Culture (소나무잔나비버섯(Fomitopsis pinicola) 균사체 배양에 따른 함량 및 세포의 형태학적 변화)

  • Jung Yoo-Kyung;Shin Kyung-Ok;Park Hong-Duok;Kim Soon-Dong
    • Food Science and Preservation
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    • v.13 no.3
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    • pp.397-403
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    • 2006
  • This experiment was conducted to examine the changes in polysaccharide concentration and morphological variation of Fomitopsis pinicola mycelium during submerged-culture in the citrus peel medium (CP). On the 12 days culture, the yields of mycelium and alcohol insoluble substance were 40.21%(w/v) and 6.94%(w/w), respectively, which were much higher than 11.29%(w/v, wet basis) and 3.17%(w/w, wet basis) obtained from YM medium. A large amount of acid soluble polysaccharides was derived from YM medium while a larger amount of alkali soluble polysaccharide was produced from CP medium. Yields of the mycelium were higher when cultured in CP medium However, there was no significant difference in formation of membranous vesicle between mycelia cultured in CP medium and YM medium. It was also observed that the formation of vacuole was closely related to the activation of the multivescular body known as cytolysome. As a result activation of mycelium and cell wall biosynthesis were more accelerated in CP medium.

Adsorptive Removal of TBM and THT Using Ion-exchanged NaY Zeolites (이온교환된 NaY 제올라이트를 이용한 TBM와 THT의 흡착제거)

  • Jung, Gap-Soon;Lee, Seok-Hee;Cheon, Jae-Kee;Choe, Jae-Wook;Woo, Hee-Chul
    • Clean Technology
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    • v.15 no.1
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    • pp.60-66
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    • 2009
  • Adsorptive removal of tetrahydrothiophene (THT) and tert-butylmercaptan (TBM) that were widely used sulfur odorants in pipeline natural gas was studied using various ion-exchanged NaY zeolites at ambient temperature and atmospheric pressure. In order to improve the adsorption ability, ion exchange was performed on NaY zeolites with alkali metal cations of $Li^+,\;Na^+,\;K^+$ and transition metal cations of $Cu^{2+},\;Ni^{2+},\;Co^{2+},\;Ag^+$. Among the adsorbents tested, Cu-NaY and Ag-NaY showed good adsorption capacities for THT and TBM. These good behaviors of removal of sulfur compound for Cu-NaY and Ag-NaY zeolites probably was influenced by their acidity. The adsorption capacity for THT and TBM on the best adsorbent Cu-NaY-0.5, which was ion exchanged with 0.5 M copper nitrate solution, was 1.85 and 0.78 mmol-S/g at breakthrough, respectively. It was the best sulfur capacity so far in removing organic sulfur compounds from fuel gas by adsorption on zeolites. While the desorption activation energy of TBM on the Cu-NaY-0.5 was higher than NaY zeolite, the difference of THT desorption activation energy between two zeolites was comparatively small.

Study on Characteristics of Antibody from Milk Immunized with Some Helicobacter pylori Antigen (Helicobacter pylori 항원을 이용한 면역우유의 항체특성에 관한 연구)

  • Park, Chang-Ho;Ye, Eun-Ju;Kim, Soo-Jung;Bae, Man-Jong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.5
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    • pp.619-625
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    • 2005
  • This study has been carried out to examine the characteristics of anti-H. pylori antibodies of milk produced from cows immunized with antigen of Helicobacter pylori such as peculiarity of antigen antibody, agglutination of H. pylori strain, stability of antibody against acid, alkali and heat treatments. The molecular weight of anti-H. pylori antibody measured by SDS-PAGE were turned out as about 50 kDa in the heavy chain and about 24 kDa in the light chain. Twenty protein bands were visualized in H. pylori interacting with anti-H. pylori antibody which was made in dairy cow by immunization with H. pylori. The western blotting was peformed in order to examine the antigen peculiarity of anti-H. pylori, The results were all 7 antigen substances including serum, furified serum, whey and furified whey could be confirmed and the major antigen substances were 97, 66,34 kDa of molecular weight. As a result of agglutination response anti-H. pylori antibody in whey showed 1/10 agglutination value against H. pylori. In stability test about acid and alkali of antibody, there was $100\%$ activated at the range of $pH5\~pH10$. In stability test about heat, the antibody showed stable condition at $60^{\circ}C$ for 60 minutes and comparatively stable condition at $70^{\circ}C$, but reduced activation to $40\%$ after 60 minutes. It maintained $77\%$ activation at $80^{\circ}C$ for 4 minutes and comparatively stable at $100^{\circ}C$ for 1 minute.

Characteristics of Flue Gas Using Direct Combustion of VOC and Ammonia (휘발성 유기 화합물 및 암모니아 직접 연소를 통한 배기가스 특성)

  • Kim, JongSu;Choi, SeukCheun;Jeong, SooHwa;Mock, ChinSung;Kim, DooBoem
    • Clean Technology
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    • v.28 no.2
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    • pp.131-137
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    • 2022
  • The semiconductor process currently emits various by-products and unused gases. Emissions containing pollutants are generally classified into categories such as organic, acid, alkali, thermal, and cabinet exhaust. They are discharged after treatment in an atmospheric prevention facility suitable for each exhaust type. The main components of organic exhaust are volatile organic compounds (VOC), which is a generic term for oxygen-containing hydrocarbons, sulfur-containing hydrocarbons, and volatile hydrocarbons, while the main components of alkali exhaust include ammonia and tetramethylammonium hydroxide. The purpose of this study was to determine the combustion characteristics and analyze the NOX reduction rate by maintaining a direct combustion and temperature to process organic and alkaline exhaust gases simultaneously. Acetone, isopropyl alcohol (IPA), and propylene glycol methyl ether acetate (PGMEA) were used as VOCs and ammonia was used as an alkali exhaust material. Independent and VOC-ammonia mixture combustion tests were conducted for each material. The combustion tests for the VOCs confirmed that complete combustion occurred at an equivalence ratio of 1.4. In the ammonia combustion test, the NOX concentration decreased at a lower equivalence ratio. In the co-combustion of VOC and ammonia, NO was dominant in the NOX emission while NO2 was detected at approximately 10 ppm. Overall, the concentration of nitrogen oxide decreased due to the activation of the oxidation reaction as the reaction temperature increased. On the other hand, the concentration of carbon dioxide increased. Flameless combustion with an electric heat source achieved successful combustion of VOC and ammonia. This technology is expected to have advantages in cost and compactness compared to existing organic and alkaline treatment systems applied separately.

Development of Light-weight Fire Protection Materials Using Fly Ash and Light-weight Aggregate (플라이애시 및 경량골재를 활용한 경량 내화성 마감재료 개발)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu;Lee, Sea-Hyun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.95-102
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    • 2012
  • The serious issue of tall building is to ensure the fire resistance of high strength concrete. Therefore, Solving methods are required to control the explosive spalling. The fire resistant finishing method is installed by applying a fire resistant material as a light-weight material to structural steel and concrete surface. This method can reduce the temperature increase of the reinforcement embedded in structural steel and concrete at high temperature due to the installation thickness control. This study is interested in identifying the effectiveness of light-weight fire protection material compounds including the inorganic admixture such as fly ash, meta-kaolin and light-weight aggregate as the fire resistant finishing materials through the analysis of fire resistance and components properties at high temperature. Also, this paper is concerned with change in microstructure and dehydration of the light-weight fire protection materials at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of SEM and XRD. The study results show that the light-weight fire resistant finishing material composed of fly ash, meta-kaolin and light-weight aggregate has the thermal stability of the slight decrease of compressive strength at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate. Developed light-weight fire protection materials showed good stability in high Temperatures. Thus, the results indicate that it is possible to fireproof panels, fire protection of materials.

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Additivity Factors Analysis of Compositions in Li2O-TeO2-ZnO Glass System Determined from Mixture Design (혼합물설계법에 의한 Li2O-TeO2-ZnO 유리의 물성에 대한 조성의 가성성인자 분석)

  • Jung, Young-Joon;Lee, Kyu-Ho;Kim, Tae-Ho;Kim, Young-Seok;Na, Young-Hoon;Ryu, Bong-Ki
    • Korean Journal of Materials Research
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    • v.18 no.11
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    • pp.617-622
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    • 2008
  • In this study, the additivity factors of compositions to density and glass transition point ($T_g$) in a $xLi_2O-(1-x)[(1-y)TeO_2-yZnO]$ (0$T_g$ was discussed. As a method for predicting the relation between glass structure and ionic conductivity, density was measured by the Archimedes method. The glass transition point was analyzed to predict the relation between ionic conductivity and the bonding energy between alkali ions and non-bridge oxygen (NBO). The relation equations showing the additivity factor of each composition to the two properties are as follows: Density(g/$cm^3$) = $2.441x_1\;+\;5.559x_2\;+\;4.863x_3\;T_g(^{\circ}C)$ = $319x_1\;+\;247x_2\;+\;609x_3\;-\;1950x_1x_3$ ($x_1$ : fraction of $Li_2O$, $x_2$ : fraction of $TeO_2$, $x_3$ : fraction of ZnO) The density decreased as $Li_2O$ content increased. This was attributed to change of the $TeO_2$ structure. From this structural result, the electric conductivity of the glass samples was predicted following the ionic conduction mechanism. Finally, it is expected that electric conductivity will increase as the activation energy for ion movement decreases.

Combustion characteristics of two imported Indonesia coals as a pulverized fuel of thermal power plants (인도네시아산 발전용 수입 석탄 2종의 연소특성 비교 평가)

  • Lee, Hyun-Dong;Kim, Jae-Kwan
    • Journal of Energy Engineering
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    • v.19 no.2
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    • pp.136-142
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    • 2010
  • Combustion reactivity and thermal behavior of two imported coals used as a pulverized fuel of commercially thermal power plant were investigated by thermogravimetric analysis (TGA) and large scale test furnace of 200 kg/hr. TGA results showed that combustion efficiency of high moisture coal has lower than reference coal due to the slow combustion completion rate although it has the low ignition temperature, and activation energies of high moisture coal with 79 kJ/mol for overall combustion was higher than reference coal of 53 kJ/mol. Test furnace results ascertained that flame of black band of high moisture coal during the combustion in boiler broke out compared to reference coal and then it becomes to unburned carbon due to the less reactivity and combustion rate. But, Blending combustion of high moisture coal with design coal of high sulfur are available because sulfur content of high moisture coal was too low to generate the low SOx content in flue gas from boiler during the combustion. The ash analysis results show that it was not expected to be associated with slagging and fouling in pulverized coal fired systems due to the low alkali metal content of $Na_2O$ and $K_2O$ compared to bituminous coal.

A Fundamental Study on Nano-cement by Chemical Synthesis (화학적 방법에 의한 나노시멘트 개발에 관한 기초 연구)

  • Jo, Byung-Wan;Kang, Seok-Won;Yoon, Kwang-Won;Choi, Ji-Sun
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.713-718
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    • 2009
  • Advanced industries-IT, BT, NT and ET are rapidly developing in 21 century. And the cement industry is becoming the principal factor in air pollution because of the creation of $CO_2$ during manufacturing. Also, the cement industry will be faced with a crisis due to the exhaustion of natural resources. In this study, nano cement by Bottom-up method of a chemical synthesis was developed. The generation of $CO_2$ during the plasticization process of cement manufacturing was avoided. The purpose was to produce building materials that have both high strength and durability as the high value-added growth engine industry of the 21 century. The nano cement was developed using hydrothermal synthesis. This is a method of mixing after ripening, by manufacturing the high density gel and low gel, which does not require special test equipment or pressure conditions to produce. Particle size, SEM, EDX, and porosity tests were conducted. This study investigated the compressive strength of concrete with various compositions. Specimens were tested for compressive strength at 3, 7, 14 and 28 days. The medium-sized (50% by weight) cement particles created by chemical synthesis were less than 168 nm. The compressive strength of the mortar prepared using this cement was 53.9 MPa. But it was judged that succeeding study will be necessary for development of nano building materials with high ability and economical analysis.

Thermal property of geopolymer on fly ash-blast furnace slag system with the addition of alumina aggregate (알루미나 골재 첨가에 따른 플라이애쉬-고로슬래그계 지오폴리머의 열적특성)

  • Kim, Jin-Ho;Nam, In-Tak;Park, Hyun;Kim, Kyung-Nam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.1
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    • pp.47-56
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    • 2017
  • In this study, the higher temperature thermal property of the fly ash-blast furnace slag system Geopolymer including alumina aggregate was investigated whether that Geopolymer will be or not useful as thermal-resistant construction materials. Under every mixing conditions, the crack on the surface of hardened body was not observed up to $800^{\circ}C$ and it corresponded with fact that level of changes was not significant before and after heating process. Residual compressive strength is most high when mixing Blast-Furnace Slag ratio is 60 wt% until temperature reaches $800^{\circ}C$. The major hydrates of hardened body of Geopolymer; amorphous halo pattern between $20{\sim}35^{\circ}$ (2theta) and mullite ($3Al_2O_3{\cdot}2SiO_2$) and quartz ($SiO_2$) was found during the experiment. Amorphous halo pattern was a aluminosilicate gel generated by geopolymeric polycondensation and it was found that the halo pattern of aluminosilicate gel was preserved up to $800^{\circ}C$. The patterns of aluminosilicate gel disappeared from $1,000^{\circ}C$ and crystal phases like gehlenite, calcium silicate, calcium aluminum oxide, microcline was observed with the increase of exposure temperature.

A Study on the Field Application of Ground Stabilizer using Circulating Resource for Improvement of Soft Ground in Saemangeum Area (새만금 지역의 연약지반 개량을 위한 순환자원 활용 지반안정재의 현장적용에 관한 연구)

  • Seo, Se-Gwan;Kim, You-Seong;Cho, Dae-sung
    • Journal of the Korean Geosynthetics Society
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    • v.19 no.1
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    • pp.103-110
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    • 2020
  • The DMM (Deep mixing method) is a construction method in which an improved pile is installed in the soft ground by excavation ground using an auger and then mixing ground stabilizer with soil. Improved pile installed in the soft ground by the DMM may have different compressive strength depending on the properties and characteristics of the soil. In the previous study, laboratory tests were performed on the ground stabilizer for the DMM developed by using the ash of the circulating fluidized bed boiler as a stimulator for alkali activation of the blast furnace slag. And the test results were analyzed to derive the correlation between the unit weight of binder (γB) and the uniaxial compressive strength (qu). In this study, comparative reviews were conducted on the correlations derived from the same laboratory tests on soil material collected from the Saemangeum area and the stability of the site was evaluated by analyzing the test results performed at the site. As a result, the clay collected from the Saemangeum area satisfies the correlation between the unit weight of binder (γB) and the uniaxial compressive strength (qu) derived from the previous study. And the result of the test at the field showed a higher uniaxial compressive strength than the standard strength at the field, indicating excellent stability.