• Title/Summary/Keyword: Aldehyde compound

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Seasonal Analysis of Odorous Compounds Emitted From the Chemical Plant (계절별 악취물질의 배출량 분석 및 평가에 관한 연구)

  • Cho, Jae-Sung;Kim, Jae-Woo
    • Journal of Environmental Science International
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    • v.16 no.1
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    • pp.27-32
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    • 2007
  • In this study, the concentrations of offensive odorous compounds seasonally emitted from the chemical plant at Chongju industrial complex in Korea were determined by the analytical methods of gas chromatography, high performance liquid chromatography and uv/vis spectroscopy. The kinds of offensive odorous compounds examined are formaldehyde, acetaldehyde, butyl aldehyde, propion aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide, dimethyl disulfide, trimethyl amine and ammonia. The seasonally emission levels of all odorous compounds except dimethyl sulfide at 13 sampling points of plant were lower than those of the regulation standard levels of the industrial complex in Korea. The levels were the highest in June, and lowest in December. The propion aldehyde and iso-valeric aldehyde in June and December, butyl aldehyde in December, and n-valeric aldehyde were not detected in all the three seasons at any sampling points of the plant examined. But in June, dimethyl sulfide was emitted up to 16 times than that of the regulation level.

Analysis of Offensive Odorous Compounds Emitted From the Chemical Plants (화학공장에서 배출되는 악취규제물질의 분석 및 평가)

  • Choi, Jae-Sung;Kim, Jae-Woo
    • Journal of Environmental Science International
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    • v.16 no.1
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    • pp.33-38
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    • 2007
  • The concentrations of offensive odorous compounds emitted from the two chemical plants in Chongju and Yeosu industrial complex in Korea were determined by uv/vis spectroscopy, gas chromatography, and high performance liquid chromatography. The odorous compounds examined in this study are ammonia, trimethyl amine, formaldehyde, acetaldehyde, propion aldehyde, butyl aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide and dimethyl disulfide. The concentrations of those were determined from the 10 sampling points of the two plants, respectively. The emission concentrations of all odorous com-pounds examined in the two plants were lower than those of the regulation standard levels of industrial complex in Korea, respectively. The propion aldehyde, n-valeric aldehyde, methyl mercaptan and dimethyl disulfide in Chongju and Yeosu plants, and butyl aldehyde and iso-valeric aldehyde in Yeosu plant were not detected at any sampling points examined.

Anti-Alcohol and Anti-Aldehyde Hangover Effect of Aldehyde Dehydrogenase Related Compounds in Rat (랫드에서 Aldehyde Dehydrogenase Related Compounds의 알콜 및 알데히드 분해 효능평가)

  • Hye-Jeong Sin;Se-Young Choung;Sora Kang;Hung-Taeck Kwon;Bae-Hwan Kim
    • Journal of Environmental Health Sciences
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    • v.49 no.2
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    • pp.99-107
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    • 2023
  • Background: Excessive alcohol consumption is at the root of serious social problems such as hangovers, liver dysfunction, and alcoholism. Objectives: This study was carried out to determine the hangover ameliorating effect of fermented rice extract and a combination of yeast-fermented powder and lysate containing aldehyde dehydrogenase (ALDH) (improved new ingredients) in an ethanol-induced rat study. Methods: The concentrations of alcohol, acetaldehyde, and malondialdehye in serum were evaluated to assess the anti-alcohol and anti-aldehyde hangover effect in two experiments, one with fermented rice extract) and a second with yeast-fermented powder and lysate, using animal studies. Results: Experiment 2 with yeast-fermented powder and lysate containing ALDH showed similar and higher activity, respectively, in reducing ethanol and acetaldehyde concentration compared with Experiment 1 with fermented rice extract. Experiment 2 also significantly reduced malondialdehyde, a type of lipid peroxide. The ALDH-related compound (ARC) lysate showed better hangover relief effect than ARC powder. Conclusions: These results indicate that ALDH-related compounds exhibit a hangover relief effect, and fermented lysate is considered to be a better candidate for hangover relief.

Performance Improvement of Nonformaldehyde Wrinkle Resistant Finished Cotton Fabrics Treated with Dialdehydes

  • Park, Hyung-Min;Kim, Yong-Min
    • Fibers and Polymers
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    • v.2 no.4
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    • pp.190-195
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    • 2001
  • Additives, such as sodium perborate and borax, were examined in dialdehyde wrinkle resistant finishing of cotton. Results indicated that the whiteness index(WI) of cotton treated with dialdehyde and additive showed about 90% of WI of the untreated cotton but with decrease in wrinkle recovery angle (WRA) due to inhibition effect of these additives. Effect of additive on the WRA reduction was more prominent with glutaraldehyde than with glyoxal. Reduction in WRA of cotton treated with both dialdehydes and boron compound was minimized by simultaneous addition of formic acid in the bath. Addition of formic acid was also generally beneficial in maintaining WI retentions after 8 months storage. Furthermore, boron compounds were also effective in improving retentions of mechanical properties. By FTIR analysis the residual aldehyde group was detected on the dialdehyde-finished cotton, whereas no peak was shown by addition of boron compounds. This suggested that the residual aldehyde group was a main cause of fabric yellowing on the dialdehyde-finished cotton. Dialhehyde with boron compound, therefore, can be used to replace a conventional formaldehyde-containing wrinkle resistant finishing of cotton.

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Synthesis of Anisyltitanium Compounds and their Reactivity (O-Anisyltitanium 화합물의 합성 및 반응성)

  • Koo, Bon-Joon;Kyung, Suk-Hun
    • Applied Biological Chemistry
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    • v.37 no.3
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    • pp.216-220
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    • 1994
  • Organoanisyltitanium compounds which have chlorine or isopropoxy group as ligand were synthesized and purely isolated. These new compounds were proved to be stable at $0^{\circ}C$ under argon atmosphere for some weeks. They react readily at low temperature with carbonyl compound, especially aldehyde and ketone, to coresponding alcohols. In competition reaction of aldehyde/ketone pair these organotitanium species showed complete aldehyde selectivity.

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Hepatoprotective Effect of Extracts and Phenolic Compound from Marine Algae in Bromobenzene-treated Rats (해조류 추출물과 페놀성화합물의 in vitro 및 in vivo 간보호활성)

  • Choi, Jae-Sue;Song, Sang-Ho;Choi, Myeong-Rak;Kim, Kwang-Young;Choi, Jong-Won;Park, Jong-Cheol
    • Korean Journal of Pharmacognosy
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    • v.28 no.4
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    • pp.239-246
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    • 1997
  • The methanol extracts of some marine algae were tested for investigating the effects on the formation of lipid peroxide and the activities of free radical generating enzyme in vitro in bromobenzene-treated rat. The extracts of Enteromorpha compressa, Capsosiphon fulvescens, Gelidium amansii, Hizikia fusiformis, Sargassum siliquastrum and Sargassum thunbergii which decreased the formation of lipid peroxide, inhibited the activity of xanthine and aldehyde oxidases by adding of each extracts. Phloroglucinol isolated from Ecklonia stolonifera reduced bromobenzene-induced hepatic lipid peroxidation. This compound administered daily over one week before intoxication with bromobenzene did not affect the activities of aminopyrine N-demethylase, aniline hydroxylase and glu tathione S-transferase. Epoxide hydrolase activity was decreased by bromobenzene, which was restored by pretreatment of phloroglucinol, The results suggest that the bromobenzene-induced hepatic lipid peroxidation by phloroglucinol is reduced by enhancing the activity of epoxide hydrolase.

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A New HPLC-analytical Method for Total Sphingosine Contents as an Indirect Index for the Ganglioside Contents of Deer Antlers

  • Choi, Hye-Ok;Kim, Jeung-Won;Jo, Sung-Jun;Kim, Jung-Hwan;Han, Byung-Hoon
    • Natural Product Sciences
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    • v.17 no.4
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    • pp.315-320
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    • 2011
  • Routinely applicable HPLC assay procedures for the ganglioside content in various deer antler preparations were established through the creation of a UV-absorbing chromophoric substance - trans-${\alpha},{\beta}$-unsaturated-hexadecene-aldehyde - from the sphingosine moiety in ganglioside molecules by two step chemical reactions. In order to guarantee the assay's accuracy and sensitivity, the HPLC-assay procedure adopted internal reference procedures by mixing cis-${\alpha},{\beta}$-unsaturated-hexadecene aldehyde[V] or cis-3-heptadecene- 1,2-diol[IV] to assay samples. The internal reference compound [IV] or [V] was synthesized in our laboratory starting from mannitol-diacetonide through three or four step organic reactions. This new HPLC-assay procedure was successfully applied to deer antler extracts with good dose-dependent calibration curves at the picomole level of gangliosides.

Structure-Activity Relationships of Gagaminine and Its Derivatives on the Inhibition of Hepatic Aldehyde Oxidase Activity and Lipid Peroxidation

  • Lee, Dong-Ung;Shin, Uk-Seob;Huh, Keun
    • Archives of Pharmacal Research
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    • v.21 no.3
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    • pp.273-277
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    • 1998
  • In order to determine the structure-activity relationships for antioxidative effects of gagaminine, a steroidal alkaloid isolated from the roots of Cynanchum wilfordi (Asclepiadaceae), two derivatives identified as sarcostin and penupogenin were prepared from gagaminine by hydrolysis and reduction. These compounds were evaluated for the inhibitory effects on the aidehyde oxidase activity and on lipid perbxidation in vitro. Furthermore, their effects were compared with those of gagaminine and the related compounds, cinnamic acid and nicotinic acid. The results of this study prove that the cinnamoyl group in the structure of gagaminine is critical in inhibition of the aldehyde oxidase activity while the nicotinoyl group may be necessary for anti-lipid peroxidation of the compound.

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