• 제목/요약/키워드: Al-anode

검색결과 219건 처리시간 0.029초

저순도 Al지금을 사용한 Al-Zn-In-Mg계 Al합금 유전양극의 특성에 관한 연구 (A study of galvanic characteristics of aluminium alloy anode in the Al-Zn-In-Mg system made of the low purity aluminium ingot)

  • 김원녕;김기준;김영대
    • Journal of Advanced Marine Engineering and Technology
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    • 제9권3호
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    • pp.240-249
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    • 1985
  • This paper presents the results of the galvanic anode's characteristicsin the Al-Zn-In-Mg and Al-Zn-In-Mg system anodes used aluminium ingot of low purity, 99.5% grade. The results of thses performance tests are as follows: 1) Zn, In and Mg are an available elements to improve the performance of Aluminium alloy anodes. 2) When the range of zinc content in the Al-Zn-In-Mg system anode is 2-5% the more zinc content, the more improve the anode performance. 3) Al-Zn-In-Mg system anode requires a long term over 50 days for the performance test. 4) The composition of Al-Zn-In-Mg system anode which shows the most excellent performance is Al-(2-3%) Zn-(0.02%) In-(1.0%) Mg. 5) When the Al-Zn-In-Mg system anode is annealed for an hour in 500 to 550 .deg. C, the anode performance is improved. 6) The lower average potential and the better corrosion pattern in the Al-Zn-Mg, Al-Zn-In and Al-Zn-In-Mg system anodes, the more current efficiency is improved.

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해양환경 변화가 알루미늄합금 희생양극의 효율에 미치는 영향에 관한 연구 (A Study on the Influence of Al Alloy Sacrificial Anode Efficiency due to Marine Environmental Variation)

  • 김도형
    • 한국해양공학회지
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    • 제14권2호
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    • pp.106-111
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    • 2000
  • Recently it was reported that the life of Al Sacrifical anode is being used in port piers has been significantly shortened compared with the original design life (e.g. average life shortened from 20 years to 13-15 year) Those factors involving these problems mentioned above were seemed to be a quality of anode material and diverse environmental factors such as pH flow rate temperature Dissolved oxygen Chemical oxygen demand and resistivity etcm In this study flow rate and contamination degree(pH) of sea water affecting to sacrificial anode life hve been investigated in terms of electrochemical characteristics of Al alloy sacrificial anode It was known that the lifetime of Al alloy anode was shortened not only by increasing of self-corrosion quantity by varying flow rate of sea water but also by increasing corrosion current density due to the potential difference increment between Al anode and steel structure cathode by varying contamination degree of sea water. Especially when anode current density is from 1mA/cm2 to 3mA/cm2 and flow rate of sea water is under 2m/s anode current efficiency is 90% above However flow rate is over 2m/s anode current efficiency fell down sharply due to erosion corrosion as well as galvanic corrosion.

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해양환경중에서 A1-합금희생양극에 의한 음극방식특성 (A Study on the Characteristics of Cathodic Protection by Al-Alloy Sacrificial Anode in Marine Environment)

  • 이연호
    • 수산해양기술연구
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    • 제28권1호
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    • pp.53-60
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    • 1992
  • In this study, cathodic protection experiment was carried out by Al-alloy sacrificial anode in marine environments which have specific resistance($\rho$) if 25~7000$\Omega$.cm and investigated protection potential, current density and loss rate of Al-alloy sacrificial anode. The main results resistance($\rho$) of 400$\Omega$.cm, the cathodic protection potential appears high about-720 mV(SCE). But below specific resistance($\rho$) of 300$\Omega$.cm, the cathodic protection potential appears low about-770 mV(SCE) and simultaneously, cathode is protected sufficiently. 2) The loss rate of Al-Alloy sacrificial anode became large with decreasing specific resistance and increasing the ratio(A sub(c)/A sub(a) of bared surface area of anode and cathode. 3) The loss rate of Al-alloy sacrificial anode(w) to the mean current density of anode(i) is as follows. w=ai+b (a, b : experimental constants)

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알루미늄 실리콘 나노분말을 이용한 리튬이온전지 음극재료에 관한 연구 (The Research on Aluminum and Silcon Nanoparticles as Anode Materials for Lithium Ion Batteries)

  • 김형조;;김형진;박원조
    • 동력기계공학회지
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    • 제17권1호
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    • pp.110-115
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    • 2013
  • The electrochemical performance and microstructure of Al-Si, Al-Si/C was investigated as anode for lithium ion battery. The Al-Si nano composite with 5 : 1 at% ratio was prepared by arc-discharge nano powder process. However, some of problem is occurred, when Al nano composite was synthesized by this manufacturing. The oxidation film is generated around Al-Si particles for passivating processing in the manufacture. The oxidation film interrupts electrical chemistry reaction during lithium ion insertion/extraction for charge and discharge. Because of the existence the oxidation film, Al-Si first cycle capacity is very lower than other examples. Therefore, carbon synthsized by glucose ($C_6H_{12}O_6$) was conducted to remove the oxidation film covered on the composite. The results showed that the first discharge cycle capacity of Al-Si/C is improved to 113mAh/g comparing with Al-Si (18.6mAh/g). Furthermore, XRD data and TEM images indicate that $Al_4C_3$ crystalline exist in Al-Si/C composite. In addition the Si-Al anode material, in which silicon is more contained was tested by same method as above, it was investigated to check the anode capacity and morphology properties in accordance with changing content of silicon, Si-Al anode has much higher initial discharge capacity(about 500mAh/g) than anode materials based on Aluminum as well as the morphology properties is also very different with the anode based Aluminum.

전계방출광원용 고효율 에노드 형광막 특성 연구(I) - 금속막 (Study on the High Efficiency of Anode Phosphor Electrode for Filed Emission Lamp (I) Metal Layer)

  • 이선희;김광복;김용원;유용찬
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2007년도 춘계학술대회 논문집
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    • pp.7-10
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    • 2007
  • The electron charging and degradation of anode phosphor layers are showed major problems in high electric field with anode electrode of field emission devices. An Al metal layer on the phosphor layer may get rid of these problems. This Al metal layer are formed with the roughness of phosphor surface layer without interlayer and cannot be given rise to enhance the luminance efficiency. In order to enhance the brightness, an anode layer need to be flated between phosphor layer and Al metal layer in anode electrode. After optimizing the anode phosphor layer, an anode layer with Al metal and inter layer increased the brightness and luminescence efficiency 1.5 times more than only phosphor layer in anode.

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High reflective anode for top emission OLED

  • Pang, Hee-Suk;Han, Chang-Wook;Kim, Ki-Yong;Chung, In-Jae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.820-823
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    • 2004
  • We present high reflective anode for top emission OLED. Anode consists of two layers, which are increasing the ability of hole injection and the reflectivity of emitted light. Thin Cr is deposited on AlNd that has a high thermal resistance and reflectivity. The current-voltage characteristics of Cr(30${{\AA}}$)/AlNd(1000${{\AA}}$) anode are poor but these of Cr(50${{\AA}}$)/AlNd(1000${{\AA}}$) anode are superior to these of Cr(30${{\AA}}$)/AlNd(1000${{\AA}}$) and the work function of cr(50${{\AA}}$)/AlNd(1000${{\AA}}$) is higher that of Cr(30${{\AA}}$)/AlNd(1000${{\AA}}$).

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전기방식시 적용되는 희생양극의 성능개발에 대한 연구 (A Study on the Sacrificial Anode for Imparting High Capabilities to Cathodic Protection)

  • 김성종
    • 수산해양기술연구
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    • 제34권1호
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    • pp.37-42
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    • 1998
  • Al alloy anode is mostly used for protecting marine structures such as pier steel piles and ship's body. Recently it has been reported that the life of Al alloy anode has been shortened significantly than the original design life. It is suggested that the suspected reasons for this problem mentioned above seems to be the improper protection design of alloy of anode on sea water regardless of environmental facotrs such as flow rate, temperature, contamination degree etc. However there is few paper about to the sea water contamination degree affecting to the life of Al alloy anode. In this study, the property of Al alloy anode was investigated as a parameter of sea water contamination degree such as variation of pH 2, 4, 6, 8, 10 and each sea port's contaminated waters.

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은의 표면 부식 및 변색을 방지하기 위해 설치된 Al 희생양극의 전기화학적 특성에 미치는 황산 농도의 영향 (Effect of concentration of H2SO4 on electrochemical properties of equipped Al sacrificial anode to prevent the corrosion and discolor of silver surface)

  • 신병현;정원섭
    • 한국표면공학회지
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    • 제54권1호
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    • pp.12-17
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    • 2021
  • Among the various precious metals, silver is used in various fields because of its low price than other precious metals. However, the surface of silver remains after rain in the atmosphere containing sulfur ions and chlorine ions, causing silver corrosion and discoloration. Existing documents have developed a anode to prevent corrosion but that are concentrated on secondary batteries. This study tried to prevent corrosion and discoloration of silver by using an Al sacrificial anode. Sulfuric acid decreased the potential of silver and increased the current density at active polarization and OCP. The amount of corrosion of silver with the Al sacrificial anode was reduced from 0.5 % to 6.5%. When silver is used for decoration outside, corrosion and discoloration of silver can be suppressed by installing an Al anode.

용융탄산염 연료전지의 양극 대체재료의 개발에 관한 연구 (A Study on the Development of Anode Material for Molten Carbonate Fuel Cell)

  • 황응림;김선지;강성군
    • 에너지공학
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    • 제2권3호
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    • pp.293-299
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    • 1993
  • 용융탄산염연료전지(MCFC)용 다공성 Ni 양극에 3~10 wt% Al를 첨가하여 tape casting 법으로 제조된 Ni-Al 양극의 전기화학적성능 및 구조적안정성이 조사되었다. 본 연구에서 제조된 양극의 전기화학적 성능이 $650^{\circ}C$, MCFC 양극분위기(80% H$_2$+20% $CO_2$)를 모사한 half-cell 에서 양분극 특성으로 평가되었는데, 전류밀도 150 ㎃/$\textrm{cm}^2$ 에서의 분극전압은 약 100 ㎷로 실용전지의 양극으로서 가능성을 보였다. Ni-Al 양극의 소결과 creep에 대한 저항성은 Ni 양극에 비해 증가되었는데, 이는 Ni 입자 표면에 형성된 $Al_2$O$_3$의 영향으로 판단되었다.

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용융탄산염 연료전지용 $Ni-5wt.\%Al$ Anode의 creep 특성에 관한 연구 (A study on creep behaviors of $Ni-5wt.\%Al$ Anode for MCFC)

  • 김규범;문영준;임희천;이덕열
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 2001년도 연료전지심포지움 2001논문집
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    • pp.231-236
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    • 2001
  • 용융탄산염 연료전지용 anode의 creep 현상을 개선하기 위해 $Ni-5wt.\%Al$ green sheet를 사용하여 다양한 소결조건을 적용, $Al_2O_3$를 형성시킨 전극을 제조하고 그 $Al_2O_3$의 형태에 따른 creep 특성에 대해 연구하였다. 소결은 각각 환원분위기, 완전산화-환원분위기, 부분 산화-환원분위기의 서로 다른 분위기에서 진행하였는데, 부분산화-환원분위기로 소결한 경우 Ni-Al 고용체 네트워크를 깨드리지 않고 $A1_2O_3$를 미세한 입자형태로 분산시킬 수 있었다. 그리고, 상기의 방법으로 제조된 anode를 $650^{\circ}C$에서 100psi로 가압하면서 creep test를 실시한 결과 약 $2.3\%$의 변형율을 나타내었다.

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