• Title/Summary/Keyword: Al-AlN system

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Direct printing of organic single crystal nanowire arrays by using Liquid-bridge-mediated nanotransfer molding

  • Oh, Hyun-S.;Baek, Jang-Mi;Sung, Myung-M.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.473-473
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    • 2011
  • In recent years, organic thin film transistors OTFTs based on conductive-conjugated molecules have received significant attention. We report a fabrication of organic single crystal nanowires that made on Si substrates by liquid bridge-mediated nanotransfer molding (LB-nTM) with polyurethane acrylate (PUA) mold. LB-nTM is based on the direct transfer of various materials from a stamp to a substrate via a liquid bridge between them. In liquid bridge-transfer process, the liquid layer serves as an adhesion layer to provide good conformal contact and form covalent bonding between the organic single crystal nanowire and the Si substrate. Pentacene is the most promising organic semiconductors. However pentacene has insolubility in organic solvents so pentacene OTFTs can be achieved with vacuum evaporation system. However 6, 13-bis (triisopropylsilylethynyl) (TIPS) pentacene has high solubility in organic solvent that reported by Anthony et al. Furthermore, the substituted rings in TIPS-pentacene interrupt the herringbone packing, which leads to cofacial ${\pi}-{\pi}$ stacking. The patterned TIPS-Pentacene single crystal nanowires have been investigated by Atomic force microscopy (AFM), Transmission Electron Microscopy (TEM), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and electrical properties.

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The Reaction Probability and the Reaction Cross-section of N + O2→ NO + O Reaction Computed by the 6th-order Explicit Symplectic Algorithm

  • He, Jianfeng;Li, Jing
    • Bulletin of the Korean Chemical Society
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    • v.27 no.12
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    • pp.1976-1980
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    • 2006
  • We have calculated the reaction probability and the reaction cross-section of the $N(^4S)+O_2(X^3\sum_{g}^{-})\;\rightarrow\;NO(X^2\Pi)+O(^3P)$ reaction by the quasiclassical trajectory method with the 6th-order explicit symplectic algorithm, based on a new ground potential energy surface. The advantage of the 6th-order explicit symplectic algorithm, conserving both the total energy and the total angular momentum of the reaction system during the numerical integration of canonical equations, has firstly analyzed in this work, which make the calculation of the reaction probability more reliable. The variation of the reaction probability with the impact parameter and the influence of the relative translational energy on the reaction cross-section of the reaction have been discussed in detail. And the fact is found by the comparison that the reaction probability and the reaction cross-section of the reaction estimated in this work are more reasonable than the theoretical ones determined by Gilibert et al.

Lattice-based Threshold Ring Signature with Message Block Sharing

  • CHEN, Jiangshan;HU, Yupu;GAO, Wen;Liang, Hongmei
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.13 no.2
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    • pp.1003-1019
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    • 2019
  • Threshold ring signature scheme enables any t entities from N ring members to spontaneously generate a publicly verifiable t-out-of-N signature anonymously. The verifier is convinced that the signature is indeed generated by at least t users from the claimed group, but he cannot tell them apart. Threshold ring signatures are significant for ad-hoc groups such as mobile ad-hoc networks. Based on the lattice-based ring signature proposed by Melchor et al. at AFRICRYPT'13, this work presents a lattice-based threshold ring signature scheme, employing the technique of message block sharing proposed by Choi and Kim. Besides, in order to avoid the system parameter setup problems, we proposed a message processing technique called "pad-then-permute", to pre-process the message before blocking the message, thus making the threshold ring signature scheme more flexible. Our threshold ring signature scheme has several advantages: inherits the quantum immunity from the lattice structure; has considerably short signature and almost no signature size increase with the threshold value; provable to be correct, efficient, indistinguishable source hiding, and unforgeable.

Cutting Conditions of Carbide Insert Drill (초경 인서트 드릴의 절삭 조건에 관한 연구)

  • Choi, Sung-Yun;Hwang, Chul-Woong;Lee, Sang-Tae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.6
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    • pp.10-16
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    • 2021
  • Drilling is a crucial process that takes up a significant amount of weight during machining operations. In addition, drill tip-type tools and related operations have been developed for manufacturing industries to achieve economic efficiency. In this study, SM45C carbon steel, widely used for machine structures, was utilized as the working material after quenching and tempering. Insert-tip types of carbide tools, such as TiN and TiAlN, were used as tool materials. Drilling conditions such as the spindle revolution, feed rate, step of cut, and tool diameter were used to measure roughness, roundness, and straightness using the orthogonal array table statistical method. The surface roughness, roundness, and straightness characteristics based on the conditions were analyzed using ANOVA. The results showed that the spindle speed and feed rate were the main factors influencing carbide insert-tip drilling under the same conditions as the experimental conditions.

Modeling and Application of Chlorine Bulk Decay in Drinking Water Distribution System (배급수계통에서 잔류염소 감소 특성 및 적용연구)

  • Ahn, Jae-Chan;Park, Chang-Min;Koo, Ja-Yong
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.4
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    • pp.487-496
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    • 2005
  • Chlorine bulk decay tests were carried out by bottle test under controlled conditions in a laboratory. Experiments were performed at different temperatures: $5^{\circ}C$, $15^{\circ}C$, $25^{\circ}C$, and the water temperatures when samples were taken from the effluent just before entering to its distribution system. 38 bulk tests were performed for water of Al (water treatment plant), 4 bulk tests for A2 (large service reservoir), and A3(pumping station). Residual chlorine concentrations in the amber bottles were measured over time till about 100 hours and bulk decay coefficients were evaluated by assuming first-order, parallel first-order, second-order. and $n^{th}-order$ reaction. The $n^{th}-order$ coefficients were obtained using Fourth-order Runge-Kutta Method. A good-fit by the average coefficient of determination ($R^2$) was first-order ($R^2=0.90$) < parallel first-order ($R^2{_{fast}}=0.92$, $R^2{_{slow}}=0.95$) < second-order ($R^2=0.95$) < $n^{th}-order$ ($R^2=0.99$). But if fast reaction of parallel first-order bulk decay were applied to the effluent of large service reservoir with ca. 20 hours of travel time and slow reaction in the water distribution system following the first 20 hours, parallel first-order bulk decay would be best and easy for application of water quality modeling technique.

A Method for Direct Application of Human Plasmin on a Dithiothreitol-containing Agarose Stacking Gel System

  • Choi, Nack-Shick;Chung, Dong-Min;Yoon, Kab-Seog;Maeng, Pil-Jae;Kim, Seung-Ho
    • BMB Reports
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    • v.38 no.6
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    • pp.763-765
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    • 2005
  • A new simplified procedure for identifying human plasmin was developed using a DTT copolymerized agarose stacking gel (ASG) system. Agarose (1%) was used for the stacking gel because DTT inhibits the polymerization of acrylamide. Human plasmin showed the lowest activity at pH 9.0. There was a similar catalytically active pattern observed under acidic conditions (pH 3.0) to that observed under alkaline conditions (pH 10.0 or 11.0). Using the ASG system, the primary structure of the heavy chain could be established at pH 3.0. This protein was found to consist of three fragments, 45 kDa, 23 kDa, and 13 kDa. These results showed that the heavy chain has a similar structure to the autolysed plasmin (Wu et al., 1987b) but there is a different start amino acid sequence of the N-termini.

A Study on the Semiconductor Wastewater Treatment and Recycling by VSEP system (진동막분리장치에 의한 반도체폐수처리와 재이용에 관한 연구)

  • Kang Gyung-Hwan
    • Journal of Environmental Science International
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    • v.14 no.3
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    • pp.335-343
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    • 2005
  • The objective of this research is to evaluate a feasibility of wastewater reuse by membrane treatment with vibrating membrane separation equipment. Molecular weight of compounds in wastewater, permeability of membrane and retentate characterization after membrane filtration were investigated in order to determine appropriate membrane pore size and materials for wastewater treatment. Selected membrane was evaluated with vibration membrane separation equipment to optimize operating conditions. The following conclusion are drawn. 1. We got as following test results after the distribution of particles in the semiconductor wastewater, are made up of $1\~20{\mu}m$. Si, gold and Al in turn are contained in semiconductor wastewater. 2. Recovery rate is changeless under increasing recovery rate in operation. Though a value can be if pressure can be changed, the highest value of permeate rate is presented in 150 psi. 3. The AS-100(polysulpone) was selected as the most appropriate membranes for the treatment of semi-conductor wastewater to VSEP system. The fouling almost did not occur during this experiments. The analyses of treated water with VSEP system showed conductivity: 0.059,us/cm, TDS: 40mg/l, COD: 20mg/l, SS : 5mg/l, n-Hexane: 8.3mg/l. Comparing previous systems, operating expenses is decreased by more $50\%$.

Cutting Characteristics of Micro grooving by Cutting Environments in High Speed Machining using Ball End Mill (미세홈 고속가공시 절삭유제 공급방식에 따른 가공성 평가)

  • 배정철;정연행;강명창;이득우;김정석
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.172-175
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    • 2002
  • High speed machining is one of the most effective technologies to improve productivity. It can give great advantage for manufacture of die and Moulds. However, when machining of micro groove in high speed machining a severely thermal damage was generated on workpiece and cutting tool. Generally, the cutting fluid is used to improve penetration. lubrication. and cooling effect. In order to rise the performance of lubrication. it contains extreme pressure agents (Cl, S, P). But the environment of work room go bad by those additive. Therefore, the compressed chilly air with oil mist system was developed to replace the conventional cutting fluid system. This paper carried out the tests to evaluate the machinability by the cutting environment in high speed micro groove machining of NAK80 (HrC40). Compressed chilly air with oil mist was ejected on the contact area between cutting edge and workpiece. The effect of this developed compressed chilly air with oil mist system was evaluated in terms of tool life. The results showed that the tool lift of carbide tool coated TiAlN with compressed chilly air mist cooling was much longer than that of the dry and flood coolant when cutting the material.

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A new merging-zone flow injection system for the quantification of ferrous and ferric ions in aqueous solution and sludge of wastewater

  • Farhood, Ahmed Saleh;Taha, Dakhil Nassir
    • Analytical Science and Technology
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    • v.35 no.5
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    • pp.218-227
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    • 2022
  • A simple and fast throughput flow injection (FI) system with a merging-zone technique was designed to determine ferrous and ferric in an aqueous solution. The method is based on the direct reaction of ferrous with a Bathophenanthroline reagent (Bphen) in acidic media. The forming red complex absorbs light at 533 nm. All conditions of the flow injection system were investigated. The analytical curve of ferrous was linear in the range of 0.07 to 4 mg/L with an r2 value of 0.9968. The detection and quantification limits were 0.02 and 0.04 mg/L, respectively. The molar absorptivity and Sandell's sensitivity were 4.0577 × 106 L/mol cm and 25 × 10-5 ㎍/cm2, respectively. The homemade valve was low-cost with high repeatability (n = 7) at an RSD of 1.26 % and zero dead volume. The values of the dispersion coefficient were 2.318, 2.022, and 1.636 for the concentrations of 0.2, 1, and 3 mg/L, respectively. The analysis throughput of the designed flow injection unit was 57 sample per hour.

Etch characteristics of TiN thin film adding $Cl_2$ in $BCl_3$/Ar Plasma ($BCl_3$/Ar 플라즈마에서 $Cl_2$ 첨가에 따른 TiN 박막의 식각 특성)

  • Um, Doo-Seung;Kang, Chan-Min;Yang, Xue;Kim, Dong-Pyo;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.168-168
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    • 2008
  • Dimension of a transistor has rapidly shrunk to increase the speed of device and to reduce the power consumption. However, it is accompanied with several problems like direct tunneling through the gate dioxide layer and low conductivity characteristic of poly-Si gate in nano-region. To cover these faults, study of new materials is urgently needed. Recently, high dielectric materials like $Al_2O_3$, $ZrO_2$, and $HfO_2$ are being studied for equivalent oxide thickness (EOT). However, poly-Si gate is not compatible with high-k materials for gate-insulator. Poly Si gate with high-k material has some problems such as gate depletion and dopant penetration problems. Therefore, new gate structure or materials that are compatible with high-k materials are also needed. TiN for metal/high-k gate stack is conductive enough to allow a good electrical connection and compatible with high-k materials. According to this trend, the study on dry etching of TiN for metal/high-k gate stack is needed. In this study, the investigations of the TiN etching characteristics were carried out using the inductively coupled $BCl_3$-based plasma system and adding $Cl_2$ gas. Dry etching of the TiN was studied by varying the etching parameters including $BCl_3$/Ar gas mixing ratio, RF power, DC-bias voltage to substrate, and $Cl_2$ gas addition. The plasmas were characterized by optical emission spectroscopy analysis. Scanning electron microscopy was used to investigate the etching profile.

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