• 제목/요약/키워드: Al dross

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A Study on the Recovery of Aluminum from Aluminum dross (알루미늄 드로스로부터 알루미늄의 회수에 관한 연구)

  • 김홍진;김용현;이병우;이광학
    • Resources Recycling
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    • v.6 no.1
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    • pp.5-10
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    • 1997
  • The aluminum was recovered from the middle size (Q1.0-12.0 mm) aluminum drosses using NaCl and KC1 mixuture as a basic salt flux. The maximum aluminum recovery was about 76.9% when 40% basic salt flux was added to aluminum dross at 850$^{\circ}$C for two hours. Also, aluminum remvery increased with increasing fluoride (1%-5%) addition to basic salt flux. But, there was no considerable effect due ta the increasing of viscosity when the fluorides were added over 5%, respectively. E s p d y , the most aluminum recovery was about 83.5% when 5% cryolite was added to 40% basic salt flux.

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Formation Behavior of Intermetallic Dross Particles in Hot Dip Galvanizing Bath (용융아연 도금욕 내 드로스 생성에 관한 실험적 고찰)

  • Park, Ju-Hyeon;Baek, Du-Jin;Lee, Seok-Gyu
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.216-216
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    • 2015
  • 용융아연 도금 공정에서 강판이 도금욕에 침적되는 동안 강판으로부터 용출되는 Fe는 도금욕 내 Al, Zn와 반응하여 다양한 형태의 드로스를 형성시키는 원인이 된다. 이들 드로스는 강판 표면에 다양한 형태의 결함을 야기하므로, 실제 도금 공정에서 도금욕 내 발생하는 드로스의 생성거동에 관한 이해는 필수적이다. 따라서 본 연구에서는 도금욕 내 $Fe_xAl_yZn_z$계 드로스 생성에 미치는 도금욕 내 Al 및 Fe 함량의 영향에 대해 고찰하였으며, in-situ sampling 기법 및 finger rotating method를 이용하였다.

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A Study of the Metal Recovery from the Aluminium Scrap (Al 스크랩으로부터 금속회수에 관한 연구)

  • 김준수;임병모;윤의박
    • Resources Recycling
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    • v.4 no.1
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    • pp.25-30
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    • 1995
  • In the preparatIon of reclaimed aluminium lllgot from alumimum scrap, the aluminium recovery was studied a as a function of the preliminary treatment of samples, addition of flux and melting atmosphere. AI dross is produced by an oxidation reaction at the surface of liquid metal. The recovery of AI metal increases u up to maximum 95% by adding salt up to 7%, The recovery of AI metal in the compacted chip bale without oil removal mcrease about 14% compared io non-compacted chip. In the case of the AI seed melting process, the recovery of Al metal of the crushed and compacted chip hale is 97%, In meltmg of alumimum scrap under the atmosphere of carbon and nitrogen gas, the recovery of AI metal increase, but it is decreased when the mixture of salt and carbon powder is added excessively.

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An Analysis of Simulation Model for Smelting Reduction Process of Waste Containing Iron Oxide (함철 폐기물의 용융환원 공정에 관한 분석연구)

  • Dong-Joon Min
    • Resources Recycling
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    • v.5 no.4
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    • pp.17-24
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    • 1996
  • The computer simulation model was established to verify the applicability of smelting reduction concept to treatment of industrial wastes which becomes issue on the enviromental and recycling view point. Computer simulation model provides as following results. The increase of post combustion ratio(PCR) and heat transfer efficiency of PC energy(HTE) is effective ways to save energy. But, in order to increase PCR, recovery efficiency of post combustion energy(HTE) have to be higher than 85% HTE considering refractory life and saving energy together. Coke is most useful fuel source because it shows lowest dependence of PCR and low hydrogen content. The quality of hot metal of current process would be expected to the similar level with that of blast furnace. The utilization of scrap and Al dross can be also possible to maximize the advantages of current process which is high temperature and chemical dilution with hot metal and slag. In case of scrap, energy consumption was slightly increases because of heating up energy of scrap. Consquently, current process concept provides the possibility of intergrating recycles of industrial wastes materials such as EAF slag, coke oven dust, life terminated acidic refractory, aluminium dross and scrap by smelting reduction process.

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Characterization analysis of SCR catalyst contained recycling Aluminium dross (재활용 된 알루미나를 포함한 SCR 탈질 촉매의 특성 분석)

  • Bae, Min-A;Kim, Hong-Dae;Kim, Kwang-Ho;Lee, Man-Sig
    • Proceedings of the KAIS Fall Conference
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    • 2011.12b
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    • pp.496-498
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    • 2011
  • 본 논문에서는 알루미늄 드로스를 재활용하여 생성 된 수산화알루미늄을 이용하여 질소산화물 제거 SCR 촉매를 제조하였다. 현재 상용중인 촉매와 화학적 특성과 질소산화물 제거 효율을 비교하기 위해 동일 타입의 하니컴 형태의 $V_2O_5-WO_3-TiO_2-Al_2O_3$ SCR 촉매를 제조하였으며, XRF와 BET를 사용하여 화학적 특성을 평가 비교하였다. 또한 MR(Micro Reactor)을 이용하여 $350^{\circ}C$$450^{\circ}C$에서 질소산화물 제거 평가를 실시하였으며, 평가 결과 80~90%의 제거 효율을 확인하였다.

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Effect of Bismuth Addition on the Zinc Consumption in Hot-Dip Galvanizing (용융아연도금에서 비스머스 첨가에 의한 아연 수율향상에 관한 연구)

  • Kim, S.K.;Yoo, J.S.
    • Journal of the Korean institute of surface engineering
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    • v.36 no.1
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    • pp.42-47
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    • 2003
  • Hot-dip galvanizing process is used widely in industry to achieve corrosion resistant coatings. Poor drainage during this process often leads to problems such as icicle formation and bridging In this work, mild steel specimens were hot-dip galvanized. Influence of the addition of bismuth, aluminum and both (bismuth and aluminum) to the zinc bath on the zinc drainage were determined. Bismuth additions improved the drainage significantly. Zinc bath containing 0.1 wt.% Bi and 0.025∼0.05 wt.% Al showed uniformity of coatings. Industrial trials with this bath composition showed reduction in zinc consumption, reduction of ash and dross, and good luster of workpiece.

Synthesis of Na-A type Zeolite From Melting Slag (소각재 용융슬래그를 이용한 제올라이트 Na-A의 합성)

  • Jang Young-Nam;Chae Soo-Chuu;Bae In-Kook;Ryou Kyung-Won
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.1
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    • pp.11-17
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    • 2005
  • Na-A zeolite were synthesized from melting slag of the incinerated ash by the alkaline activation processes. The experiments were performed in stainless steel vessels, with continuous stirring during the reaction periods. The silica-rich solution, a starting material, which was the waste of crystal growth factory, contains 5.7 wt% SiO₂ and 3.2 wt% Na₂O. And NaAlO₂ was made by the reaction of aluminium dross and NaOH solution and its molar ratios were Na₂O/Al₂O₃= 1.2 and H₂O/Na₂O=9. During the residence time of 7∼8 h at 80℃, the mixing of the silica-rich solution, NaAlO₂ and melting slag yields the production of homogeneous Na-A zeolite. The optimal reactant composition in molar ratio of Na₂O:Al₂O₃:SiO₂ was 1.3∼l.4 : 0.8∼0.9 : 2 and mixing ratio of solution and slag was 1/7∼10 (g/cc). Synthesized Na-A zeolite has cubic form uniformly and its size ranges about 1 ㎛. Ca/sup 2+/ ion exchange capacity of the Na-A was about 180∼210 meq/100g, corresponding approximately 80% to the commercial detergent builder.