• Title/Summary/Keyword: Al concentration

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Abnormal Behavior of MOCVD Grown $Al_xIn_{1-x}N$ Observed by Various Material Characterizations

  • Chung, Roy Byung-Kyu;DenBaars, Steven P.;Speck, James S.;Nakamura, Shuji
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.14-14
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    • 2011
  • AlInN has been studied extensively over the past few years due to its interesting material properties that are not present in other ternary nitrides. However, basic material study of AlInN has not been reported as much compared to device applications due to the difficulty in the growth. We have performed the material studies from various aspects. A secondary ion mass spectrometry (SIMS) has shown high oxygen content above $1{\times}10^{18}\;cm^{-3}$ with its insensitivity to the growth conditions. While the free carrier concentration observed by the capacitance-voltage (C-V) measurements was about $3{\times}10^{17}\;cm^{-3}$, the activation energy measured by temperature dependent C-V was only about 4 meV. Si doped AlInN (Si level ${\sim}2{\times}10^{18}\;cm^{-3}$) showed almost no carrier freeze-out at carrier density of $1{\times}10^{18}\;cm^{-3}$. More studies were carried out with a transmission electron microscopy, time-resolved photoluminescence and other analytical techniques to understand the results from SIMS and C-V studies. In this report, we will discuss the possible correlations between the abnormal characteristics in AlInN.

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Tensile Properties and Thermal Conductivities of Mg-Al alloy with As-Cast and Discontinuous Precipitates Microstructures (주조 및 불연속 석출물 미세조직을 가지는 Mg-Al 합금의 인장 특성 및 열전도도)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.33 no.5
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    • pp.219-225
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    • 2020
  • The objective of this study was to investigate the tensile properties and thermal conductivities of Mg9.3%Al alloy in as-cast state and heat-treated state consisting of fully discontinuous precipitates (DPs), respectively. The fully DPs microstructure was obtained by solution treatment at 405℃ for 24 h, followed by furnace cooling to RT. The as-cast alloy showed a partially divorced eutectic β(Mg17Al12) phase particles formed along the α-(Mg) cell boundaries. The DPs had various apparent (α+β) interlamellar spacings, which is related to different transformation temperatures during the furnace cooling. The DPs microstructure exhibited better tensile strength than the as-cast one, resulting from the higher value of elongation in response to its more homogeneous microstructure. It is noticeable that the DPs microstructure had 12.4% higher thermal conductivity in average than the as-cast one between RT and 200℃. The XRD analyses revealed that the lower Al concentration in the α-(Mg) matrix may well be responsible for the better thermal conductivity of the DPs microstructure.

Effects of Ni Addition on the Precipitate Formation and Interfacial Reaction in Hot Dipped Galvanizing Bath (Ni 첨가된 용융아연 도금욕의 석출물과 계면반응)

  • Lee, K. K.;Choi, J.;Cho, K. Z.;Lee, D. J.
    • Journal of the Korean institute of surface engineering
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    • v.34 no.3
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    • pp.206-214
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    • 2001
  • The purpose of this study is to determine the effects of Ni on precipitate formation in a Ni added galvanizing bath, which has various Ni content from 0.03wt.% to 0.5wt.%. The addition of hi in the Ni containing galvanizing bath resulted in the formation of Al-Ni intermetallic compounds such as $Al_3$$Ni_2$ and $Al_2$Ni, which make up most of the top precipitates. At 0.07wt.%Ni, Al-Ni intermetallic compound formed sensitively with small amount of Al addition. By analysing the reaction thickness of galvanized steel, it was found that Ni addition in a Zn-0.18w1.%Al bath tended to suppress the formation of Fe-Zn intermetallic compounds but the formation of these compounds increased with increasing Ni concentration above 0.1wt.%.

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Optimization of the Gate Field-Plate Structure for Improving Breakdown Voltage Characteristics. (AlGaN/GaN HEMT의 항복전압특성 향상을 위한 게이트 필드플레이트 구조 최적화)

  • Son, Sung-Hun;Jung, Kang-Min;Kim, Su-Jin;Kim, Tae-Geun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.337-337
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    • 2010
  • 갈륨-질화물 (GaN) 기반의 고 전자 이동도 트랜지스터 (High Electron Mobility Transistor, HEMT)는 GaN의 큰 밴드갭 (3.4~6.2 eV), 높은 항복전계 (Ec~3 MV/cm) 및 높은 전자 포화 속도 (saturation velocity $-107\;cm{\cdot}s-1$) 특성과 AlGaN/GaN 등과 같은 이종접합구조(Heterostructure )로부터 발생하는 높은 면밀도(Sheet Concentration)를 갖는 이차원 전자가스(Two-Dimensional Electron Gas, 2DEG) 채널로 인해 차세대 고출력/고전압 소자로서 각광받고 있다. 하지만 드레인 쪽의 게이트 에지부분에 집중되는 전계로 인한 애벌린치 할복현상(Breakdown)이 발생하는 문제점이 있다. 따라서 AlGaN/GaN HEMT의 항복전압 향상을 위한 방법으로 필드플레이트(Field-Plate) 구조가 많이 사용되고 있다. 본 논문에서는 2D 시뮬레이션을 통한 AlGaN/GaN HEMT의 필드플레이트 구조 최적화를 수행하였다. 이를 위해 ATLASTM 전산모사 프로그램을 이용하여 필드플레이트 길이, 절연체 증류 및 두께에 따른 전류 전압 특성 및 전계 분산효과에 대한 전산모사를 수행하여 그 결과를 비교, 분석 하였다, 이를 바탕으로 기존의 구조에 비해 약 300%이상 향상된 항복전압을 갖는 AlGaN/GaN HEMT의 최적화된 필드 플레이트 구조를 제안하였다.

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Fabrication of α-Alumina Nanopowders by Thermal Decomposition of Ammonium Aluminum Carbonate Hydroxide (AACH) (암모늄 알루미늄 탄산염(hhCH)의 열분해에 의한 α-알루미나 나노분말 제조)

  • O, Yong-Taeg;Shin, Dong-Chan;Kim, Sang-Woo
    • Journal of the Korean Ceramic Society
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    • v.43 no.4 s.287
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    • pp.242-246
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    • 2006
  • [ ${\alpha}-Al_2O_3$ ] nanopowders were fabricated by the thermal decomposition and synthetic of Ammonium Aluminum Carbonate Hydroxide (AACH). Crystallite size of 5 to 8 nm were fabricated when reaction temperature of AACH was low, $8^{\circ}C$, and the highest $[NH_4{^+}][AlO(OH)_n{(SO_4){^-}}_{3-n/2}][HCO_3]$ ionic concentration to pH of the Ammonium Hydrogen Carbonate (AHC) aqueous solution was 10. The phase transformation fem $NH_4Al(SO_4)_2$, rhombohedral $(Al_2(SO_4)_3)$, amorphous-, ${\theta}-,\;{\alpha}-Al_2O_3$ was examined at each temperature according to the AACH. A Time-Temperature-Transformation (TTT) diagram for thermal decomposition in air was determined. Homogeneous, spherical nanopowders with a particle size of 70 nm were obtained by firing the 5 to 8 m crystallites, which had been synthesized from AACH at pH 10 and $8^{\circ}C,\;at\;1150^{\circ}C$ for 3 h in air.

Hydrothermally synthesized Al-doped BiVO4 as a potential antibacterial agent against methicillin-resistant Staphylococcus aureus

  • Vicas, Charles Sundar;Keerthiraj, Namratha;Byrappa, Nayan;Byrappa, Kullaiah
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.566-571
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    • 2019
  • One-pot hydrothermal route was adopted to synthesize Al:BiVO4, at 4 h and 8 h reaction durations, by adding 1% aluminiumoxide powder (w/v) to the precursors. The products were investigated using several characterization techniques that conform a significant morphological change and a decrease in bandgap energy of the materials upon Al modification of scheelite monoclinic bismuth vanadate matrix at both hydrothermal durations. Antibacterial experiments were performed against methicillin-resistant Staphylococcus aureus in visible light condition to harness the photoxidation property of Al-doped BiVO4 and compare to that of unaltered BiVO4. Minimum inhibitory concentration of the synthesized materials was identified. The results indicate that Al-doping on BiVO4 has a significant effect on its photocatalytic antibacterial performance. Al:BiVO4 synthesized at 8 h hydrothermal treatment parades excellent sunlight-driven photocatalysis compared to the one synthesized at 4 h.

Characteristics of Catalytic Combustible Gas Sensor Based on Planar Technology (평탄형 접촉 연소식 가스 센서의 특성)

  • Kim, Yeong-Bok;Noh, Hyo-Sub;Park, Jin-Seong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.9
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    • pp.812-817
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    • 2008
  • A catalytic combustible sensor for LPG/LNG detection was fabricated on $Al_2O_3$ substrate using planar technology. The catalysts of Pd and Pt were added to ${\alpha}$- and ${\gamma}-Al_2O_3$ powders. The mixture of Pt, Pd and $Al_2O_3$ were homogenized by using a three roll mixer. TCR characteristics of Pt heater were optimized with the heat treatment temperature. Sensing properties were investigated as a function of the microstructure of $Al_2O_3$, the gas concentration and the variation of input voltage. ${\alpha}-Al_2O_3$ sintered at 500 $^{\circ}C$ is more suitable as LPG/LNG sensor due to good grain shape and size distribution of about 300 nm than that of ${\gamma}-Al_2O_3$ which is in irregular shape and with a particle size of 5-30 ${\mu}m$. The sensor has shown maximum output voltage of 14 mV for 1000 ppm $C_4H_{10}$ and 3.8 mV for 1000 ppm $CH_4$ at 5.0 V input voltage.

Properties of Natural Dyeing of Bast Fiber(Part 3) Combination dyeing of gallnut-sappan wood and gardenia (인피섬유의 천연염색 및 염색성(제 3보) - 오배자, 소목, 치자의 복합염)

  • Park, Myung-Ox;Yoon, Seung-Lak
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.1
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    • pp.1-10
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    • 2011
  • To investigate the combination dyeing properties of natural dyes, the combination dyeing using gallnut,-Al, Cu, Fe-sappan wood, and gallnut-Al, Cu, Fe-gardenia was performed on bast fiber of mulberry, cotton, silk, and their K/S values, colors, and sunlight fastness were measured. The gallnut-Al, Cu, Fe-gardenia dyeing showed the highest K/S values when the dyeing concentration of gallnut is 3%. It tended to show the higher K/S values than gallnut-Al, Cu, Fe-sappan wood. The silk showed the highest values of in K/S, and then followed by cotton, and bast fiber of mulberry. The mordants developed different colors on the bast fiber and the cotton treated with gallnut-Al, Cu, Fe-sappan wood. However, the silk showed a series of YR, showing no effect of the mordants on the development of color. The combination dyeing of gallnut-Al, Cu, Fe-gardenia showed a series of Y. The results showed that sappan wood could develop various colors but gardenia could develop a series of Y. No distinct improvement on sunlight fastness of the combination dyeing was observed.

Evaluation on Design Factors of Electrolytic Flotation Reactor by Measuring Polarization Curve (분극곡선 측정을 통한 전해부상조의 설계인자 평가)

  • Lim, Bong-Su;Jin, Jing-Zhu;Choi, Chan-Soo
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.244-250
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    • 2007
  • This study was carried out to obtain the optimum design factors for an eletrolytric flotation reactor. When the effluent of the leachate treatment facility was treated under the condition of 10 volts, 30 minutes, at the Al-Al electrode system; COD removal efficiency was 45%, and total phosphorus removal efficiency was 98%. The high removal efficiency was caused by the fact that phosphate was removed by leaching $Al^{3+}$ from two electrodes. The leachate containing high ammonium nitrogen concentration was treated by a batch test under the condition of 60 minutes reaction time and added chloride ion; ammonium nitrogen removal efficiency was 89%. This high efficiency was affected by added chloride ion to wastewater. To find the optimum current density and voltage of the leachate containing chloride ion (ratio of $Cl^-/NH_4-N$ is 11) a electrochemical polarization curve was used. These values were found to be $4.5mA/cm^2$ and about 2.1 V, respectively. When C-Al electrode system was used at a batch test, the total nitrogen removal efficiency was increased by 1.8 to 3.3 times, compared to Al-Al electrode system due to high $Cl_2$ gas production.

Damping Capacities of Mg-Al alloy with As-Cast and Discontinuous Precipitates Microstructures (주조 및 불연속 석출물 미세조직을 가지는 Mg-Al 합금의 진동감쇠능)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.5
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    • pp.218-225
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    • 2021
  • In this study, damping capacities were comparatively investigated for Mg-9%Al alloy with as-cast (AC) and fully discontinuous precipitates (DPs) microstructures, respectively. The DPs microstructure was obtained by solution treatment at 678 K for 24 h, followed by furnace cooling to RT. The AC microstructure was typically characterized by partially divorced eutectic β(Mg17Al12) phase particles distributed along the α-(Mg) matrix cell boundaries. The DPs microstructure showed lamellar morphology consisting of α and β thin layers with various interlamellar spacings. The DPs microstructure had better damping capacity than the AC microstructure in the strain-amplitude independent region, while in the strain-amplitude dependent region, the damping behavior was reversed. In view of the microstructural features of AC and DPs, the lower concentration of Al in the α-(Mg) phase for the DPs microstructure and the lower β phase number density for the AC microstructure would be responsible for the higher damping capacities in the strain-amplitude independent and strain-amplitude dependent regions, respectively.