• Title/Summary/Keyword: Al concentration

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Fabrication and Characterization of High Purity Al2O3 by Decomposition of Selicite (세리사이드 분해에 의한 고순도 Al2O3의 제조 및 특성에 관한 연구)

  • 이경희;박한수;송명신
    • Journal of the Korean Ceramic Society
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    • v.24 no.5
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    • pp.431-436
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    • 1987
  • High purity Al2O3 has been extracted from serlcite of clayminerals, selicite was treated by H2SO4(2N∼18N) solution, NH4OH treatment(PH8.5∼10.0) and metallic impurities such as Fe were removed by NaOH treatment. The tendency of extraction yield of ${\alpha}$-Al2O3 have been investigated by relating reaction time, acid concentration. Reaction products were analyzed by DT-TGA, chemical analysis and X-ray diffractometer. Prepared ${\alpha}$-Al2O3 power is fired in air at 1400$^{\circ}C$, 1600$^{\circ}C$ 2hr. The results are as follows; 1. The most suitable extracting conditions of ${\alpha}$-Al2O3 from Selicite were N-H2SO4, 120 min acidtreating time. 2. The optimum pH condition was 9.0. 3. Physical properties of sintered Al2O3 bodies were as follows. Relative density is 99%. Water absorption is 0.26%. Rock well hardness is 89.

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Investigation of the Annealing Time Effects on the Properties of Sputtered ZnO:Al Thin Films

  • Kim, Deok Kyu;Kim, Hong Bae
    • Applied Science and Convergence Technology
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    • v.23 no.6
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    • pp.366-370
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    • 2014
  • ZnO:Al transparent conductive films were deposited on glass substrates by RF magnetron sputtering technique and annealed by rapid thermal annealing system. The influence of annealing time on the structural, electrical, and optical properties of ZnO:Al thin films was investigated by atomic force microscopy, X-ray diffraction, Hall method and optical transmission spectroscopy. As the annealing time increases from 0 to 5 min, the crystallinity is improved, the root main square surface roughness is decreased and the sheet resistance is decreased. The lowest sheet resistance of ZnO:Al thin film is 90 ohm/sq. The reduction of sheet resistance is caused by increasing carrier concentration due to substituent Al ion. All films are transparent up to 80% in the visible wavelength range and the adsorption edge is a blue-shift due to Burstein-Moss effect with increasing annealing time.

Lifetime Evaluation of AI-Fe Coating in Wet-seal Environment of MCFC

  • Jun, JaeHo;Jun, JoongHwan;Kim, KyooYoung
    • Corrosion Science and Technology
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    • v.3 no.4
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    • pp.161-165
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    • 2004
  • Aluminum source in an Al-Fe coating reacts with molten carbonate and develops a protective $LiAlO_2$ layer on the coating surface during operation of molten carbonate fuel cells (MCFC). However, if aluminum content in an Al-Fe coating decreases to a critical level for some reasons during MCFC operation, a stable and continuous $LiAlO_2$ protective layer can no longer be maintained. The aluminum content in an Al-Fe coating can be depleted by two different processes; one is by corrosion reaction at the surface between the aluminum source in the coating and molten carbonate, and the other is inward-diffusion of aluminum atoms within the coating into a substrate. In these two respects, therefore, the decreasing rate of aluminum concentration in an Al-Fe coating was measured, and then the influences of these two aspects on the lifetime of Al-Fe coating were investigated, respectively.

High Temperature Oxidation of Ti-6Al-4V, Ti-4Fe, Ti-(1,2)Si Alloys (Ti-6Al-4V, Ti-4Fe, Ti-(1,2)Si합금의 고온산화)

  • 박기범;이동복
    • Journal of the Korean institute of surface engineering
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    • v.34 no.2
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    • pp.135-141
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    • 2001
  • Arc-melted Ti-6Al-4V, Ti-4Fe and Ti-(1,2) Si alloys were oxidized at 700, 800, 900 and $1000^{\circ}C$ in air. The oxidation resistance of Ti-4Fe was comparable to that of Ti-6Al-4V, while the oxidation resistance of Ti-(1,2) Si was superior to that of Ti-6Al-4V. Ti-2Si displayed the best oxidation resistance among the four alloys, but failed after oxidation at $1000^{\circ}C$ for 17h. The oxide scale formed on Ti-6Al-4V, Ti-4Fe and Ti-(1,2)Si consisted of ($TiO_2$ and a small amount of $Al_2$$O_3$), ($TiO_2$ and a small amount of dissolved iron), and ($TiO_2$ plus a small concentration of amorphous $SiO_2$), respectively. The oxide grains of the surface scale of the four alloys were generally fine and round.

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A Study on the Chemical characteristics of Anion Components and Metallic Elements of PM10 in Miryang and Changwon (밀양·창원지역의 PM10 중 음이온 성분 및 금속성분의 화학적 특성에 관한 연구)

  • Suh Jeong-Min;Jeon Bo-Kyung;Choi Kum-Chan
    • Journal of Environmental Science International
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    • v.13 no.12
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    • pp.1049-1058
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    • 2004
  • PM10 concentration of total 48 samples collected from 4 sites (the root of Miryang University, Sangnam township Office in Miryang. the root of Changwon elementary school, and Junam reservoir in Changwon) turned out to range from 42.29 to 69.49{\mu}g/m^{3}$, and the average concentration was the root of Changwon elementary school $(69.49{\mu}g/m^{3})$>the root of Miryang university $(58.59{\mu}g/m^{3})$>Junam reservoir $(43.56{\mu}g/m^{3})$>Sangnam township Office $(42.29{\mu}g/m^{3}).> In particular, Junam reservoir, the Clean Area, had a slightly higher value than Sangnam township Office. It was thought although the site was plane and windy without pollutants around. it had a higher concentration value influenced by external factors including bigger population and a northeasterly wind due to a newly-established industrial complex nearby. As for water-soluble ions among PM10 particle collected in Miryang and Changwon area, SO42- accounted for $50{/%}$ and NO3-, was $35{\%}$, and the concentration order was S042->N03->Cl->F-. As for the average concentration of metallic components among PM10 particle collected in Miryang and Changwon area. the root of Changwon elementary school had the AI concentration, Fe concentration and Zn concentration 4 times, 3 times and 1.5 times that of Junam reservoir, respectively. The root of Miryang University had the AI concentration 2 times that of Sangnam township Office, and had Fe concentration and Zn concentration $1.2\~1.5$ times those of Sangnam township Office. When it comes to the relation between metallic elements and meteorological factors in Changwon area, the highest coefficient of correlation was between temperature and humidity with 0.92, and temperature and wind speed turned out in the reverse correlation. The coefficient of correlation between Al and Cr was as high as 0.78. Among metallic elements, the coefficient of correlation between Cu and Pb, Cd, Al were 0.84, 0.85, 0.79, respectively. It is thought that the high coefficient of correlation between Cu and Pb is ascribed to busy traffic and wind in the urban areas, Sammun-dong and Gagok-dong in Miryang. Meanwhile, the coefficients of correlation between Fe and Cu, Al, Zn, Cd, Pb were in the reverse correlation. These coefficients of correlation are attributed to the difference in pollutant sources, rather than difference in pollutant and non-pollutant.

Removal of Cobalt Ion by adsorbing Colloidal Flotation (흡착 교질 포말부선법에 의한 Cobalt Ion의 제거)

  • 정인하;이정원
    • Resources Recycling
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    • v.7 no.3
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    • pp.3-10
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    • 1998
  • Simulated waste liquid containing 50 ppm cobalt ion was treated by adsorbing colloidal flotation using Fe(III) or Al(IlI) as flocclant and a sodium lamyl sulfate as a collector. Parameters such as pH, surfactant concentration, Fe(III) or Al(III) concentration, gas flow rate, etc., W앙e considered. The flotation with Fe(III) showed 99.8% removal efficiency of cohalt on the conditions of initial cobalt ion concentration 50 ppm, pH 9.5, gas flow rate 70 ml/min, and flotation time 30 min. When the waste solution, was treated with 35% $H_2O_2$ prior to adsorbing colloidal flotation, the optimal pH for removing cobalt shifted m to weak alkaline range and flotation could be applied in wider range of pH as compared to non-use of $H_2O_2$. Additional use of 20 ppm Al(III) after precipitation of 50 ppm Co(II) with 50 ppm Fe(III) made the optimal pH range for preferable flotation w wider. Foreign ions such as, $NO_3^-$, $SO_4^{2-}$, $Na^+$, $Ca^{2+}$ were adopted and their effects were observed. Of which sulfate ion was f found to be detrimental to removal of cob퍼t ion by flotation. Coprecipitation of Co ion with Fe(III) and Al(III) resulted in b better removal efficiency of cobalt IOn 피 the presence of sulfate ion.

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Synthesis and photoluminescence characteristics of SrAl2O4:Mn4+ phosphor for LED applications (LED용 SrAl2O4:Mn4+ 형광체 합성 및 발광특성 연구)

  • Byoung Su Choi;Jun Ho Lee;Sungu Hwang;Jin Kon Kim;Byeong Woo Lee;Hyun Cho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.1
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    • pp.1-16
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    • 2023
  • A non-rare earth-based strontium-aluminate red light emitting phosphor was synthesized by a solid-state reaction method and the effect of synthesis temperature and Mn4+ activator concentration on the photoluminescence characteristics of the phosphor was studied. The synthesized SrAl2O4:Mn4+ phosphor showed broad band absorption characteristics in the near-ultraviolet and blue regions with peaks at wavelengths of near 330 and 460 nm, and a triple band deep red emission consisted of three peaks at near 644, 658, and 673 nm. The SrAl2O4:Mn4+ phosphor synthesized at a temperature 1600℃ and a Mn4+ activator concentration of 0.5 mol% showed the strongest PL emission intensity, and concentration quenching was observed at concentrations higher than 0.7 mol%. FE-SEM and DLS particle size distribution analysis showed that the synthesized SrAl2O4:Mn4+ phosphor had a particle size distribution of 2~6.4 ㎛ and an irregular spherical shape with an average particle size of ~4 ㎛.

A study of aluminum toarance of wheats (밀의 Aluminum 耐性에 관한 硏究)

  • Chung, Hee-Joo;Lee, In-Sook
    • The Korean Journal of Ecology
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    • v.15 no.2
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    • pp.157-172
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    • 1992
  • Studies were conducted to evaluate the differential al tolerance of suwon 205 and olmil wheats grown is nutrient solution and determine the impact of NH4+-N or Ca2+ nutrition of the response of the two wheat vareties to al. In various concentrations of al, olmil induced lower ph levels than suwon 205 in nutrient solutions and the reduction of root length and dry weight was greater in olmil than in suwon 205. The uptake of al was greater in root than in shoot of the two wheat varieties, but more increased in root of olimil. also the uptake of ca, mg, k and p was inhibited by al especialy decrease of ca and p uptake in roots of olmil was more pronounced than in those of suwon 205. In nutrient solutions that contained NH4+-N plus 9ppm al, the ability of both varienties to raise the ph was reduced as the level of NH4+-N in nutrient solutions was increased, and al-sensitive olimil induced lower ph than did al-tolerant suwon 205. al toxicity was intensified by increasing the concentration of NH4+-N in nurient and toxic effect was greater in olmil. al toxicity in the two wheat varieties was steadily increased as the ca level of nutrient solution was reduced, sepecialy this effect was stronger in al-sensitive olmil than in al-tolerant suwon 205.

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